Metals Ion In Solution

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Metal Complexes in Aqueous Solutions

Author : Arthur E. Martell
Publisher : Springer Science & Business Media
ISBN 13 : 1489914862
Total Pages : 259 pages
Book Rating : 4.4/5 (899 download)

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Book Synopsis Metal Complexes in Aqueous Solutions by : Arthur E. Martell

Download or read book Metal Complexes in Aqueous Solutions written by Arthur E. Martell and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 259 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stability constants are fundamental to understanding the behavior of metal ions in aqueous solution. Such understanding is important in a wide variety of areas, such as metal ions in biology, biomedical applications, metal ions in the environment, extraction metallurgy, food chemistry, and metal ions in many industrial processes. In spite of this importance, it appears that many inorganic chemists have lost an appreciation for the importance of stability constants, and the thermodynamic aspects of complex formation, with attention focused over the last thirty years on newer areas, such as organometallic chemistry. This book is an attempt to show the richness of chemistry that can be revealed by stability constants, when measured as part of an overall strategy aimed at understanding the complexing properties of a particular ligand or metal ion. Thus, for example, there are numerous crystal structures of the Li+ ion with crown ethers. What do these indicate to us about the chemistry of Li+ with crown ethers? In fact, most of these crystal structures are in a sense misleading, in that the Li+ ion forms no complexes, or at best very weak complexes, with familiar crown ethers such as l2-crown-4, in any known solvent. Thus, without the stability constants, our understanding of the chemistry of a metal ion with any particular ligand must be regarded as incomplete. In this book we attempt to show how stability constants can reveal factors in ligand design which could not readily be deduced from any other physical technique.

Kinetics of Metal Ion Adsorption from Aqueous Solutions

Author : Sotira Yiacoumi
Publisher : Springer Science & Business Media
ISBN 13 : 9780792396000
Total Pages : 256 pages
Book Rating : 4.3/5 (96 download)

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Book Synopsis Kinetics of Metal Ion Adsorption from Aqueous Solutions by : Sotira Yiacoumi

Download or read book Kinetics of Metal Ion Adsorption from Aqueous Solutions written by Sotira Yiacoumi and published by Springer Science & Business Media. This book was released on 1995-06-30 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph is intended to provide a systematic presentation of theories concerning the adsorption of metal ions from aqueous solutions onto surfaces of natural and synthetic substances and to outline methods and procedures to estimate the extent and progress ofadsorption. As heavy metals and the problems associated with their transport and distribution are of serious concern to human health and the environment, the materials presented in this volume have both theoretical and practical significance. In writing this monograph, one ofour goals was to prepare a book useful to environmental workers and practicing engineers. For this reason, our presentation relies heavily on concepts commonly used in the environmental engineering literature. In fact, the volume was prepared for readers with a basic understanding of environmental engineering principles and some knowledge of adsorption processes. No prior familiarity with the ionic solute adsorption at solid-solution interfaces is assumed. Instead, introduction of the necessary background information was included. Generally speaking, metal ion adsorption may be studied in terms of three distinct but interrelated phenomena: surface ionization, complex formation, and the formation and presence of an electrostatic double layer adjacent to adsorbent surfaces. Analyses of these phenomena with various degrees of sophistication are xviii ADSORPTION OF METAL IONS FROM AQUEOUS SOLUTIONS presented, and their various combinations yield different models that describe metal ion adsorption.

Chemistry

Author : Bruce Averill
Publisher :
ISBN 13 : 9780321413703
Total Pages : 1233 pages
Book Rating : 4.4/5 (137 download)

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Book Synopsis Chemistry by : Bruce Averill

Download or read book Chemistry written by Bruce Averill and published by . This book was released on 2007 with total page 1233 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emphasises on contemporary applications and an intuitive problem-solving approach that helps students discover the exciting potential of chemical science. This book incorporates fresh applications from the three major areas of modern research: materials, environmental chemistry, and biological science.

Hydrolysis of Metal Ions

Author : Paul L. Brown
Publisher : John Wiley & Sons
ISBN 13 : 3527656200
Total Pages : 1449 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Hydrolysis of Metal Ions by : Paul L. Brown

Download or read book Hydrolysis of Metal Ions written by Paul L. Brown and published by John Wiley & Sons. This book was released on 2016-02-23 with total page 1449 pages. Available in PDF, EPUB and Kindle. Book excerpt: Endlich ein Fachbuch, das die Theorie, Methoden und die verschiedenen Arten von Metall-Ionen-Komplexen in Wasser (Hydrolyse) umfassend behandelt. Geschrieben wurde dieses Referenzwerk von einem Kernchemiker aus dem Hochschulbereich und einem Geochemiker aus der Industrie. Behandelt werden Kationen- und Anionen-Komplexe sowie die Metall-Ionen-Hydrolyse, zu der zunächst Hintergrundinformationen geliefert werden, bevor eine Beschreibung der Dissoziation von Wasser, aller verschiedenen Hydrolysekomplexe und Verbindungen von Metall und Wasser folgt. Ein Muss für Wissenschaftler im universitären Umfeld und in der Industrie, die sich mit diesem interdisziplinären Thema beschäftigen.

Biological Inorganic Chemistry

Author : Robert R. Crichton
Publisher : Elsevier
ISBN 13 : 0080556221
Total Pages : 383 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Biological Inorganic Chemistry by : Robert R. Crichton

Download or read book Biological Inorganic Chemistry written by Robert R. Crichton and published by Elsevier. This book was released on 2007-12-11 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: The importance of metals in biology, the environment and medicine has become increasingly evident over the last twenty five years. The study of the multiple roles of metal ions in biological systems, the rapidly expanding interface between inorganic chemistry and biology constitutes the subject called Biological Inorganic Chemistry. The present text, written by a biochemist, with a long career experience in the field (particularly iron and copper) presents an introduction to this exciting and dynamic field. The book begins with introductory chapters, which together constitute an overview of the concepts, both chemical and biological, which are required to equip the reader for the detailed analysis which follows. Pathways of metal assimilation, storage and transport, as well as metal homeostasis are dealt with next. Thereafter, individual chapters discuss the roles of sodium and potassium, magnesium, calcium, zinc, iron, copper, nickel and cobalt, manganese, and finally molybdenum, vanadium, tungsten and chromium. The final three chapters provide a tantalising view of the roles of metals in brain function, biomineralization and a brief illustration of their importance in both medicine and the environment.Relaxed and agreeable writing style. The reader will not only fiind the book easy to read, the fascinating anecdotes and footnotes will give him pegs to hang important ideas on.Written by a biochemist. Will enable the reader to more readily grasp the biological and clinical relevance of the subject.Many colour illustrations. Enables easier visualization of molecular mechanismsWritten by a single author. Ensures homgeneity of style and effective cross referencing between chapters

Kinetics of Metal Ion Adsorption from Aqueous Solutions

Author : Sotira Yiacoumi
Publisher : Springer Science & Business Media
ISBN 13 : 1461523192
Total Pages : 239 pages
Book Rating : 4.4/5 (615 download)

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Book Synopsis Kinetics of Metal Ion Adsorption from Aqueous Solutions by : Sotira Yiacoumi

Download or read book Kinetics of Metal Ion Adsorption from Aqueous Solutions written by Sotira Yiacoumi and published by Springer Science & Business Media. This book was released on 2013-11-27 with total page 239 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph is intended to provide a systematic presentation of theories concerning the adsorption of metal ions from aqueous solutions onto surfaces of natural and synthetic substances and to outline methods and procedures to estimate the extent and progress ofadsorption. As heavy metals and the problems associated with their transport and distribution are of serious concern to human health and the environment, the materials presented in this volume have both theoretical and practical significance. In writing this monograph, one ofour goals was to prepare a book useful to environmental workers and practicing engineers. For this reason, our presentation relies heavily on concepts commonly used in the environmental engineering literature. In fact, the volume was prepared for readers with a basic understanding of environmental engineering principles and some knowledge of adsorption processes. No prior familiarity with the ionic solute adsorption at solid-solution interfaces is assumed. Instead, introduction of the necessary background information was included. Generally speaking, metal ion adsorption may be studied in terms of three distinct but interrelated phenomena: surface ionization, complex formation, and the formation and presence of an electrostatic double layer adjacent to adsorbent surfaces. Analyses of these phenomena with various degrees of sophistication are xviii ADSORPTION OF METAL IONS FROM AQUEOUS SOLUTIONS presented, and their various combinations yield different models that describe metal ion adsorption.

A Textbook of Inorganic Chemistry – Volume 1

Author : Mandeep Dalal
Publisher : Dalal Institute
ISBN 13 : 8193872002
Total Pages : 482 pages
Book Rating : 4.1/5 (938 download)

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Book Synopsis A Textbook of Inorganic Chemistry – Volume 1 by : Mandeep Dalal

Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.

Anion Exchange Separations of Metal Ions in Partially Nonaqueous Solutions

Author : Donald J. Pietrzyk
Publisher :
ISBN 13 :
Total Pages : 124 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Anion Exchange Separations of Metal Ions in Partially Nonaqueous Solutions by : Donald J. Pietrzyk

Download or read book Anion Exchange Separations of Metal Ions in Partially Nonaqueous Solutions written by Donald J. Pietrzyk and published by . This book was released on 1960 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Alkali Metals

Author : Kristi Lew
Publisher : The Rosen Publishing Group, Inc
ISBN 13 : 143585330X
Total Pages : 50 pages
Book Rating : 4.4/5 (358 download)

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Book Synopsis The Alkali Metals by : Kristi Lew

Download or read book The Alkali Metals written by Kristi Lew and published by The Rosen Publishing Group, Inc. This book was released on 2009-08-15 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explains the characteristics of alkali metals, where they are found, how they are used by humans, and their relationship to other elements found in the periodic table.

The Elements of Physical Chemistry

Author : Harry Clary Jones
Publisher :
ISBN 13 :
Total Pages : 676 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Elements of Physical Chemistry by : Harry Clary Jones

Download or read book The Elements of Physical Chemistry written by Harry Clary Jones and published by . This book was released on 1907 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Recent Advances in Ionic Liquids

Author : Mohammed Rahman
Publisher : BoD – Books on Demand
ISBN 13 : 1789841178
Total Pages : 194 pages
Book Rating : 4.7/5 (898 download)

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Book Synopsis Recent Advances in Ionic Liquids by : Mohammed Rahman

Download or read book Recent Advances in Ionic Liquids written by Mohammed Rahman and published by BoD – Books on Demand. This book was released on 2018-09-26 with total page 194 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent Advances in Ionic Liquids contains research on the preparation, characterization, and potential applications of stable ionic liquids (ILs). ILs are a class of low- and stable-melting point, ionic compounds that have a variety of properties allowing many of them to be sustainable green solvents. It is promising novel research from top to bottom and has received a lot of interest over the last few decades. It covers the advanced topics of physical, catalytic, chemical, polymeric, and potential applications of ILs. This book features interesting reports on cutting-edge science and technology related to the preparation, characterization, polymerization, and potential applications of ILs. This potentially unique work offers various approaches on the R

Biosorbents for Metal Ions

Author : D A John Wase
Publisher : CRC Press
ISBN 13 : 0203483049
Total Pages : 249 pages
Book Rating : 4.2/5 (34 download)

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Book Synopsis Biosorbents for Metal Ions by : D A John Wase

Download or read book Biosorbents for Metal Ions written by D A John Wase and published by CRC Press. This book was released on 1997-08-05 with total page 249 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metals can be dispersed, both naturally and by man's activities, into any of the Earth's elements - soil, water or air. Biological techniques for removing metal pollutants from soil, air or water are now attracting great interest, both because they are seen as more environmentally friendly than chemical treatments, and because, in some cases at lea

Determination and Use of Stability Constants

Author : Arthur Earl Martell
Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 216 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Determination and Use of Stability Constants by : Arthur Earl Martell

Download or read book Determination and Use of Stability Constants written by Arthur Earl Martell and published by Wiley-VCH. This book was released on 1992 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes potentiometric methods for determining stability constants and explains how these constants can be used to describe metal ion speciation in complex environmental and biological systems. It also provides three original computer programs on a disk for calculating stability constants and for using stability constants to calculate concentrations of molecular species in solution. The author gives examples of calculations for simple metal chelates, for metal complexes of large organic molecules, and for mixtures containing several metal ions and complexing agents in aqueous solution. They also describe common errors in calculating stability constants and how to avoid them. This carefully revised second edition is now even more useful to the reader, and, in particular, to those who make use of the program disk. Each program has been revised to improve speed, control, and error trapping.

Hydrolysis of Metal Ions

Author : Paul L. Brown
Publisher : John Wiley & Sons
ISBN 13 : 3527330100
Total Pages : 954 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Hydrolysis of Metal Ions by : Paul L. Brown

Download or read book Hydrolysis of Metal Ions written by Paul L. Brown and published by John Wiley & Sons. This book was released on 2016-05-31 with total page 954 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the need for a comprehensive treatment that covers the theory, methods and the different types of metal ion complexes with water (hydrolysis), this handbook and ready reference is authored by a nuclear chemist from academia and an industrial geochemist. The book includes both cation and anion complexes, and approaches the topic of metal ion hydrolysis by first covering the background, before proceeding with an overview of the dissociation of water and then all different metal-water hydrolysis complexes and compounds. A must-have for scientists in academia and industry working on this interdisciplinary topic.

Chemistry of Iron

Author : J. Silver
Publisher : Springer Science & Business Media
ISBN 13 : 9401121400
Total Pages : 316 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Chemistry of Iron by : J. Silver

Download or read book Chemistry of Iron written by J. Silver and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is designed to be of use to the reader in two different ways. First, it is intended to provide a general introduction to all aspects of iron chemistry for readers from a variety of different scientific backgrounds. It has been written at a level suitable for use by graduates and advanced undergraduates in chemistry and biochemistry, and graduates in physics, geology, materials science, metallurgy and biology. It is not designed to be a dictionary of iron compounds but rather to provide each user with the necessary tools and background to pursue their ,individual interests in the wide areas that are influenced by the chemistry of iron. To achieve this goal each chapter has been written by a contemporary expert active in the subject so that the reader will benefit from their individual insight. Although it is generally assumed that the reader will have an understanding of bonding theories and general chemistry, the book is well referenced so that any deficiencies in the reader's background can be addressed. The book was also designed as a general reference book for initial pointers into a scientific literature that is growing steadily as the understanding and uses of this astonishingly versatile element continue to develop. To meet this aim the book attempts some coverage of all aspects of the chemistry of iron, not only outlining what understanding has been achieved to date but also identifying targets to be aimed at in the future.

The Canning Trade

Author :
Publisher :
ISBN 13 :
Total Pages : 1890 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis The Canning Trade by :

Download or read book The Canning Trade written by and published by . This book was released on 1927 with total page 1890 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Milestones in Powerful Adsorbents of Heavy-Metal Ions

Author : Xin-Gui Li
Publisher : Cambridge Scholars Publishing
ISBN 13 : 1527529010
Total Pages : 882 pages
Book Rating : 4.5/5 (275 download)

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Book Synopsis Milestones in Powerful Adsorbents of Heavy-Metal Ions by : Xin-Gui Li

Download or read book Milestones in Powerful Adsorbents of Heavy-Metal Ions written by Xin-Gui Li and published by Cambridge Scholars Publishing. This book was released on 2024-04-02 with total page 882 pages. Available in PDF, EPUB and Kindle. Book excerpt: Serious challenges instigated by pollution are driving research seeking feasible strategies for social, economic, and environmental sustainability. The fascinating science of selective adsorbents of heavy- or precious-metal pollutants such as lead, mercury, gold, and silver ions has attracted investigation by many capable materials scientists, chemists, and environmental engineers, resulting in rapidly increasing progress with time. This book reveals theoretical and practical information that will assist in the study, research, and innovations of effective adsorbents towards toxic and noble metal ions. It allows the reader to pursue an answer to this mystery through interdisciplinary scientific knowledge of material design, synthesis, and environmental purification of strong adsorbents, as has never been presented systematically before, demonstrating the nature of the unique molecular and morphological structures of the adsorbent and how to design and optimize molecular and material structures.