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Author : Ian R. Dunkin
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (139 download)
Download or read book Matrix-isolation Techniques written by Ian R. Dunkin and published by . This book was released on 1998 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Stephen Cradock
Publisher : CUP Archive
ISBN 13 : 9780521207591
Total Pages : 160 pages
Book Rating : 4.2/5 (75 download)
Download or read book Matrix Isolation written by Stephen Cradock and published by CUP Archive. This book was released on 1975-10-09 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt: This 1975 book shows how and why matrix isolation developed and describes the necessary apparatus.
Author : M. J. Ricks
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (16 download)
Download or read book Some Spectroscopic Applications of Matrix Isolation Techniques written by M. J. Ricks and published by . This book was released on 1969 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Lester Andrews
Publisher :
ISBN 13 :
Total Pages : 448 pages
Book Rating : 4.3/5 (91 download)
Download or read book Chemistry and Physics of Matrix-isolated Species written by Lester Andrews and published by . This book was released on 1989 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Matrix-isolation spectroscopy, as a technique for studying unstable species, has had tremendous lasting powers. Since 1954, matrix-isolation has been able to assimilate new technology rather than being replaced by it. The matrix-isolation technique for producing and trapping new chemical species has been applied to an ever increasing range of chemical and physical problems since its inception. The last 12 years have seen a substantial number of new developments and applications of the matrix technique. The chapters in this book describe many of the contributions of matrix-isolation spectroscopy to chemistry and physics in the last decade, and as such predict the continued evolution of this technique over the next decade. Experimental techniques are generally closely related to the development of new apparatus, and each chapter has a section describing innovations in instrumentation such as the closed-cycle cryogenic cooler that has revolutionized the technique. In addition, each chapter describes many of the specialized methods used to prepare, trap and study particular new subject species. The volume will be an indispensable reference source for graduate students and other scientists new to this field, as well as chemists and physicists already involved in applied spectroscopy.
Author : A. Barnes
Publisher : Springer Science & Business Media
ISBN 13 : 9400985401
Total Pages : 602 pages
Book Rating : 4.4/5 (9 download)
Download or read book Matrix Isolation Spectroscopy written by A. Barnes and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 602 pages. Available in PDF, EPUB and Kindle. Book excerpt: The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com plexes, and intermolecular forces.
Author : Ian R. Dunkin
Publisher : Oxford University Press on Demand
ISBN 13 : 9780198558637
Total Pages : 242 pages
Book Rating : 4.5/5 (586 download)
Download or read book Matrix-isolation Techniques written by Ian R. Dunkin and published by Oxford University Press on Demand. This book was released on 1998 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt: Matrix isolation is a technique for trapping reactive species at very low temperatures and studying them spectroscopically. This book offers detailed practical advice on how to carry out matrix-isolation experiments, and is a unique introduction to the subject. Chapter 1 introduces a briefhistorical survey of the development of the technique that incorporates a discussion of its strength and limitations. Chapter 2 provides a thorough description of the building of a matrix-isolation laboratory from scratch. All the necessary equipment is described in full and there are diagrammaticexamples throughout. In later chapters, ancillary equipment for generating reactive species, and an informative description of the various methods for forming low-temperature matrices are dealt with. There then follows a chapter on the specialized technique of matrix photochemistry with polarizedlight. The final chapter comprises an extensive collection of classic matrix experiments which have been selected due to their ease of application and which will thus serve as useful exercises for testing new pieces of equipment. This accessible text offers thorough coverage of the topic and willbe invaluable to postgraduate and industrial chemists as an introduction to matrix isolation techniques. Researchers in chemistry and related fields who are considering whether matrix isolation can play a part in their own research will also find this book useful.
Author :
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (141 download)
Download or read book Matrix Isolation written by and published by . This book was released on 1975 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Alexander Gorski
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (84 download)
Download or read book Applications of Polarized Spectroscopy and Matrix Isolation Techniques written by Alexander Gorski and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Leif Fredin
Publisher :
ISBN 13 :
Total Pages : 11 pages
Book Rating : 4.:/5 (186 download)
Download or read book Matrix Isolation Technique as a Tool for Infrared Studies of Weak Charge Transfer Complexes written by Leif Fredin and published by . This book was released on 1974 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Leif Fredin
Publisher :
ISBN 13 :
Total Pages : 11 pages
Book Rating : 4.:/5 (487 download)
Download or read book Matrix isolation technique as a tool for infrared studies of weak charge transfer complex written by Leif Fredin and published by . This book was released on 1974 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : John Dickson Baldeschwieler
Publisher :
ISBN 13 :
Total Pages : 472 pages
Book Rating : 4.:/5 (28 download)
Download or read book The Structures of Unstable Compounds by Matrix Isolation Techniques written by John Dickson Baldeschwieler and published by . This book was released on 1959 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Matrix Isolation Studies with Fourier Transform Ir written by and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The combination of Fourier transform infrared (FT-IR) spectroscopy with the matrix-isolation techniques has advantages compared with the use of more conventional grating spectroscopy. Furthermore, the recent commercial availability of Fourier transform spectrometers has made FT-IR a practical alternative. Some advantages of the FT-IR spectrometer over the grating spectrometer are the result of the computerized data system that is a necessary part of the FT-IR spectrometer; other advantages are a consequence of the difference in optical arrangements and these represent the inherent advantages of the FT-IR method. In most applications with the matrix-isolation technique, the use of FT-IR spectroscopy results in either an improved signal-to-noise ratio or a shorter time for data collection compared with grating infrared spectroscopy. Fourier transform infrared spectroscopy has been used in the laboratory to study several molecular species in low-temperature matrices. Some species have been produced by high-temperature vaporization from Knudsen cells and others by sputtering. By sputtering, Ar and Kr matrices have been prepared which contain U atoms, UO, UO2, UO3, PuO, PuO2, UN, or UN2, depending upon the composition of the gas used to sputter as well as the identity of the metallic cathode. Infrared spectra of matrices containing these compounds are presented and discussed. (JRD).
Author : Shelle J. David
Publisher :
ISBN 13 :
Total Pages : 200 pages
Book Rating : 4.:/5 (12 download)
Download or read book Infrared Matrix Isolation Studies written by Shelle J. David and published by . This book was released on 1984 with total page 200 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Richard L. Redington
Publisher :
ISBN 13 :
Total Pages : 89 pages
Book Rating : 4.:/5 (227 download)
Download or read book Infrared Studies Using the Matrix Isolation Technique written by Richard L. Redington and published by . This book was released on 1969 with total page 89 pages. Available in PDF, EPUB and Kindle. Book excerpt: Briefly summarized are the results of research using matrix isolation techniques to study the infrared spectra of reactive halogen compounds such as SbF5, AsF5, ClF3, BrF3, BrF5, LiF, CH3COOH, and CCl3COOH. The main text of the report consists of four articles with the following titles: Infrared matrix-isolation spectra and the mechanism for F atom exchange in ClF3, BrF3, and SF4; On the calculation of unique force constants (F2O, O3, Cl2O, H2S, H2O, NF3, H2CO); Properties of LiF molecules; and Infrared spectra of matrix isolated acetic acid monomers.
Author : Robert Engel
Publisher :
ISBN 13 :
Total Pages : 76 pages
Book Rating : 4.:/5 (554 download)
Download or read book Studies of VOCI[subscript 2} by Infrared Matrix Isolation Method written by Robert Engel and published by . This book was released on 1964 with total page 76 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Yuet-May Huang
Publisher :
ISBN 13 :
Total Pages : 286 pages
Book Rating : 4.:/5 (29 download)
Download or read book Matrix Isolation: the Trapping of Methane and Water in Carbon Dioxide Matrix written by Yuet-May Huang and published by . This book was released on 1970 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : George C. Pimentel
Publisher :
ISBN 13 :
Total Pages : 6 pages
Book Rating : 4.:/5 (227 download)
Download or read book Preparation of Reactive Molecules Using the Matrix Isolation and Flash Photolysis Techniques written by George C. Pimentel and published by . This book was released on 1973 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: Developments in rapid scan spectroscopy and matrix isolation are briefly reviewed with regard to CH3 and CD3 radicals, and 'lithium bonding'.
