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Liquid Phase Aerobic Oxidation Catalysis
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Book Synopsis Liquid Phase Aerobic Oxidation Catalysis by : Shannon S. Stahl
Download or read book Liquid Phase Aerobic Oxidation Catalysis written by Shannon S. Stahl and published by John Wiley & Sons. This book was released on 2016-10-10 with total page 454 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.
Book Synopsis Liquid Phase Oxidation via Heterogeneous Catalysis by : Mario G. Clerici
Download or read book Liquid Phase Oxidation via Heterogeneous Catalysis written by Mario G. Clerici and published by John Wiley & Sons. This book was released on 2013-04-26 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.
Book Synopsis Liquid Phase Aerobic Oxidation Catalysis by : Shannon S. Stahl
Download or read book Liquid Phase Aerobic Oxidation Catalysis written by Shannon S. Stahl and published by John Wiley & Sons. This book was released on 2016-07-13 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.
Book Synopsis Catalytic Aerobic Oxidations by : Esteban Mejía
Download or read book Catalytic Aerobic Oxidations written by Esteban Mejía and published by Royal Society of Chemistry. This book was released on 2020-07-14 with total page 349 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidation reactions are an important chemical transformation in both academia and industry. Among the major advances in the field has been the development of catalytic processes, which are not only selective and efficient, but also allow the replacement of common stoichiometric oxidants with molecular oxygen, ideally from air at atmospheric pressure. This results in processes with higher atom efficiency, where water is the only side product in line with the principles of green chemistry. Focusing on the use of molecular oxygen as the terminal oxidant, this book covers recent advances in both heterogeneous and homogeneous systems, with and without metals and on the “taming” of the highly reactive oxygen gas by use of micro-flow reactors and membranes. A useful reference for industrial and academic chemists working on oxidation processes, as well as green chemists.
Book Synopsis Transition Metal Catalysis in Aerobic Alcohol Oxidation by : Francesca Cardona
Download or read book Transition Metal Catalysis in Aerobic Alcohol Oxidation written by Francesca Cardona and published by Royal Society of Chemistry. This book was released on 2015 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with the search for environmentally benign procedures for the oxidation of alcohols and gives an overview of their transition-metal-catalyzed aerobic oxidation.
Book Synopsis Green Chemistry and Catalysis by : R. A. Sheldon
Download or read book Green Chemistry and Catalysis written by R. A. Sheldon and published by John Wiley & Sons. This book was released on 2007-06-27 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect: · Numerous catalytic reductions and oxidations methods · Solid-acid and solid-base catalysis · C-C bond formation reactions · Biocatalysis · Asymmetric catalysis · Novel reaction media like e.g. ionic liquids, supercritical CO2 · Renewable raw materials Written by Roger A. Sheldon -- without doubt one of the leaders in the field with much experience in academia and industry -- and his co-workers, the result is a unified whole, an indispensable source for every scientist looking to improve catalytic reactions, whether in the college or company lab.
Book Synopsis Catalyst and Reactor Development for Aerobic Oxidation of Organic Substrates by : Yuliya Preger
Download or read book Catalyst and Reactor Development for Aerobic Oxidation of Organic Substrates written by Yuliya Preger and published by . This book was released on 2018 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Safe and selective aerobic oxidation of organic substrates represents a grand challenge in catalysis. The productive utilization of oxygen is key to many, seemingly disparate, systems, for example, enzymatic catalysis, fine chemical production, and energy generation in fuel cells. This thesis describes new methods for carrying out aerobic oxidation in the latter two applications. Fuel cells are a promising technology for generating electrical energy from the energy in chemical bonds. However, the high loadings of Pt needed to catalyze oxygen reduction at the cathode have hindered broad adoption. To address this, a new fuel cell design was developed wherein oxygen reduction is executed off-electrode in an external reactor with non-Pt catalysts, using quinones as electron-proton transfer mediators. This represents the first instance of organic mediator use outside of low-power, enzymatic fuel cells. The latter part of this thesis details the development of new reactors and catalysts for general aerobic alcohol oxidations. Safe execution of aerobic oxidation in the presence of organic solvents is typically achieved by operating below the limiting oxygen concentration with inert diluents. 'Tube in shell' membrane reactors offer an intriguing alternative, permitting passage of O2 from the gas phase into a liquid-phase reaction through semi-permeable membranes. Use of a membrane reactor with inexpensive PTFE tubing enabled alcohol oxidation at rates an order of magnitude higher than previously reported. Heterogeneous catalysts, particularly noble metals such as Pt and Pd, have been extensively studied for alcohol oxidation. However, these catalysts exhibit low rates and limited substrate scopes due to poisoning by excess oxygen or various heterocycles; thus, various species were explored as catalyst 'promoters.' In the oxidative coupling of alcohols and ammonia to make nitriles, the addition of Bi to a Pt catalyst accelerated the rate of alcohol oxidation and enabled high yields with challenging heterocyclic alcohols. Furthermore, the addition of Bi and Te to a Pd catalyst increased the yield and rate for the oxidative coupling of alcohols with methanol to make methyl esters. Collectively, the above work highlights the opportunities for reaction engineering to enable the safe and selective utilization of oxygen in a range of chemistries.
Book Synopsis Catalytic Oxidation: Principles And Applications - A Course Of The Netherlands Institute For Catalysis Research (Niok) by : R A Sheldon
Download or read book Catalytic Oxidation: Principles And Applications - A Course Of The Netherlands Institute For Catalysis Research (Niok) written by R A Sheldon and published by World Scientific. This book was released on 1995-10-30 with total page 393 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book consists of lectures presented by international authorities in the field, at a course on Oxidation Catalysis organized by the Dutch Research School in Catalysis at Rolduc in June 1994.The material covered spans the whole range of the subject from the fundamental principles of gas and liquid phase oxidations to reactor engineering for industrial processing. The use of catalytic oxidation in both bulk and fine chemicals manufacture and the different types of catalysis — heterogeneous-gas phase, homogeneous-liquid phase and heterogeneous-liquid phase — are discussed. In addition, a few special topics, such as electrocatalytic and high-temperature oxidation are dealt with.The book is intended for graduate students or industrial researchers who wish to acquaint themselves with the underlying principles of catalytic oxidations and the numerous applications of this important technology.
Book Synopsis The Technology of Catalytic Oxidations by : Philippe Arpentinier
Download or read book The Technology of Catalytic Oxidations written by Philippe Arpentinier and published by Editions Technip. This book was released on 2001 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 1 covers the most important technological aspects of the use of molecular oxygen for catalytic oxidation reactions.Volume 2 addresses the safety issues associated with the use of oxygen in catalytic oxidation reactions.Contents Vol. 1: 1. Introduction. 2. Chemical-physical properties of molecular oxygen. 3. Oxygen production technologies. 4. Chemical fundamentals of oxidation reactions. 5. Reactor technologies for multiphase systems. 6. Liquid phase oxidations. 7. Gas phase selective oxidations. 8. Selective oxidation of paraffins. References. Index. Vol. 2: 9. Introduction to safety problems in the chemical industry. 10. Chemical aspects of combustion in the gaseous phase. 11. Homogeneous chemical explosions: autoignition or spontaneous ignition. 12. Deflagration or propagation of flame. 13. Conditions governing flame propagation capability. 14. Detonation in the gaseous phase. 15. Prevention of and protection against explosions. References. Index.
Book Synopsis Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry by : Daniel Duprez
Download or read book Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry written by Daniel Duprez and published by World Scientific. This book was released on 2014-07-24 with total page 1035 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive overview of the most recent developments in both total oxidation and combustion and also in selective oxidation. For each topic, fundamental aspects are paralleled with industrial applications. The book covers oxidation catalysis, one of the major areas of industrial chemistry, outlining recent achievements, current challenges and future opportunities. One distinguishing feature of the book is the selection of arguments which are emblematic of current trends in the chemical industry, such as miniaturization, use of alternative, greener oxidants, and innovative systems for pollutant abatement. Topics outlined are described in terms of both catalyst and reaction chemistry, and also reactor and process technology.
Download or read book Gold Catalysis written by Laura Prati and published by CRC Press. This book was released on 2016-01-05 with total page 521 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the first report on alcohol oxidation in 1998, many studies have highlighted some peculiarity of gold with respect to other metals. Some analogies have been found between gas and liquid phases, but the big challenge to operate in a condensed phase lies in the role of the solvent in tuning the reactant-catalyst contact. Liquid-phase oxidation
Book Synopsis Modern Heterogeneous Oxidation Catalysis by : Noritaka Mizuno
Download or read book Modern Heterogeneous Oxidation Catalysis written by Noritaka Mizuno and published by John Wiley & Sons. This book was released on 2009-11-18 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling a gap in the current literature, this comprehensive reference presents all important catalyst classes, including metal oxides, polyoxometalates, and zeolites. Readers will find here everything they need to know -- from structure design to characterization, and from immobilization to industrial processes. A true must-have for anyone working in this key technology.
Book Synopsis Interfacial Catalysis by : Alexander G. Volkov
Download or read book Interfacial Catalysis written by Alexander G. Volkov and published by CRC Press. This book was released on 2002-12-12 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive volume on interfacial catalysis, this book includes contributions from an international group of specialists in chemistry, environmental science, informatics, physiology, nuclear energy, and physics. The editor has organized the material into the main topics of fundamental characteristics, phase transfer catalysis, reversed micelles, biological aspects, and interfacial photocatalysis. Individual topics include self-organized microheterogeneous structures, nanochemistry, interfacial catalysis in metal complexation, the role of water molecules in ion transfer at the oil/water interface, and ultrathin films in enhanced oil recovery.
Book Synopsis Bifunctional Molecular Catalysis by : Takao Ikariya
Download or read book Bifunctional Molecular Catalysis written by Takao Ikariya and published by Springer. This book was released on 2011-06-24 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: Masakatsu Shibasaki, Motomu Kanai, Shigeki Matsunaga, and Naoya Kumagai: Multimetallic Multifunctional Catalysts for Asymmetric Reactions.- Takao Ikariya: Bifunctional transition metal-based molecular catalysts for asymmetric syntheses.- Chidambaram Gunanathan and David Milstein: Bond Activation by Metal-Ligand Cooperation: Design of ”Green” Catalytic Reactions Based on Aromatization-Dearomatization of Pincer Complexes.- Madeleine C. Warner, Charles P. Casey, and Jan-E. Bäckvall: Shvo’s Catalyst in Hydrogen Transfer Reactions.- Noritaka Mizuno, Keigo Kamata, and Kazuya Yamaguchi: Liquid-Phase Selective Oxidation by Multimetallic Active Sites of Polyoxometalate-Based Molecular Catalysts.- Pingfan Li and Hisashi Yamamoto: Bifunctional Acid Catalysts for Organic Synthesis.- Jun-ichi Ito, Hisao Nishiyama: Bifunctional Phebox Complexes for Asymmetric Catalysis.
Author :Francesc X. Llabrés i Xamena Publisher :Royal Society of Chemistry ISBN 13 :1849735727 Total Pages :446 pages Book Rating :4.8/5 (497 download)
Book Synopsis Metal Organic Frameworks as Heterogeneous Catalysts by : Francesc X. Llabrés i Xamena
Download or read book Metal Organic Frameworks as Heterogeneous Catalysts written by Francesc X. Llabrés i Xamena and published by Royal Society of Chemistry. This book was released on 2013-07-01 with total page 446 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book examines the latest research and discovery in the use of MOFs in catalysis, highlighting the extent to which these materials have been embraced by the community.
Author :Roger A. Sheldon Publisher :World Scientific Publishing Company Incorporated ISBN 13 :9789810221867 Total Pages :381 pages Book Rating :4.2/5 (218 download)
Book Synopsis Catalytic Oxidation by : Roger A. Sheldon
Download or read book Catalytic Oxidation written by Roger A. Sheldon and published by World Scientific Publishing Company Incorporated. This book was released on 1995 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Modern Oxidation Methods by : Jan-Erling Bäckvall
Download or read book Modern Oxidation Methods written by Jan-Erling Bäckvall and published by John Wiley & Sons. This book was released on 2011-08-02 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: While rust is an unwanted oxidation reaction, there are also many other useful oxidation reactions that are extremely important and number among the most commonly used reactions in the chemical industry. This completely revised, updated second edition now includes additional sections on industrial oxidation and biochemical oxidation. Edited by one of the world leaders in the field, high-quality contributions cover every important aspect from classical to green chemistry methods: - Recent Developments in Metal-catalyzed Dihydroxylation of Alkenes - Transition Metal-Catalyzed Epoxidation of Alkenes - Organocatalytic Oxidation. Ketone-Catalyzed Asymmetric Epoxidation of Alkenes and Synthetic Applications - Catalytic Oxidations with Hydrogen Peroxide in Fluorinated Alcohol Solvents - Modern Oxidation of Alcohols using Environmentally Benign Oxidants - Aerobic Oxidations and Related Reactions Catalyzed by N-Hydro xyphthalimide - Ruthenium-Catalyzed Oxidation for Organic Synthesis - Selective Oxidation of Amines and Sulfides - Liquid Phase Oxidation Reactions Catalyzed by Polyoxometalates - Oxidation of Carbonyl Compounds - Manganese-Catalyzed Oxidation with Hydrogen Peroxide - Biooxidation with Cytochrome P450 Monooxygenases By providing an overview of this vast topic, the book represents an unparalleled aid for organic, catalytic and biochemists working in the field.
