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Author : James S. Poole
Publisher :
ISBN 13 :
Total Pages : 530 pages
Book Rating : 4.:/5 (222 download)
Download or read book Kinetic Investigations of Free Radical Addition Reactions written by James S. Poole and published by . This book was released on 1999 with total page 530 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Michael Silaev
Publisher : LAP Lambert Academic Publishing
ISBN 13 : 9783659373565
Total Pages : 60 pages
Book Rating : 4.3/5 (735 download)
Download or read book The Kinetic Investigation of the Free-Radical Addition written by Michael Silaev and published by LAP Lambert Academic Publishing. This book was released on 2013 with total page 60 pages. Available in PDF, EPUB and Kindle. Book excerpt: Five reaction schemes are suggested for the initiated nonbranched-chain addition of free radicals to the multiple bonds of the unsaturated compounds. The proposed schemes include the reaction competing with chain propagation reactions through a reactive free radical. The chain evolution stage in these schemes involves three or four types of free radicals. One of them is relatively low-reactive and inhibits the chain process by shortening of the kinetic chain length. Based on the suggested schemes, nine rate equations (containing one to three parameters to be determined directly) are deduced using quasi-steady-state treatment. These equations provide good fits for the nonmonotonic (peaking) dependences of the formation rates of the molecular products (1:1 adducts) on the concentration of the unsaturated component in binary systems consisting of a saturated component (hydrocarbon, alcohol, etc.) and an unsaturated component (olefin, allyl alcohol, formaldehyde, or dioxygen). The unsaturated compound in these systems is both a reactant and an autoinhibitor generating low-reactive free radicals. The energetics of the key radical-molecule reactions is considered.
Author : E. T. Denisov
Publisher : John Wiley & Sons
ISBN 13 : 0471281832
Total Pages : 903 pages
Book Rating : 4.4/5 (712 download)
Download or read book Handbook of Free Radical Initiators written by E. T. Denisov and published by John Wiley & Sons. This book was released on 2005-01-14 with total page 903 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.
Author : Howard Maskill
Publisher : John Wiley & Sons
ISBN 13 : 0470994169
Total Pages : 392 pages
Book Rating : 4.4/5 (79 download)
Download or read book The Investigation of Organic Reactions and Their Mechanisms written by Howard Maskill and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: A range of alternative mechanisms can usually be postulated for most organic chemical reactions, and identification of the most likely requires detailed investigation. Investigation of Organic Reactions and their Mechanisms will serve as a guide for the trained chemist who needs to characterise an organic chemical reaction and investigate its mechanism, but who is not an expert in physical organic chemistry. Such an investigation will lead to an understanding of which bonds are broken, which are made, and the order in which these processes happen. This information and knowledge of the associated kinetic and thermodynamic parameters are central to the development of safe, efficient, and profitable industrial chemical processes, and to extending the synthetic utility of new chemical reactions in chemical and pharmaceutical manufacturing, and academic environments. Written as a coherent account of the principal methods currently used in mechanistic investigations, at a level accessible to academic researchers and graduate chemists in industry, the book is highly practical in approach. The contributing authors, an international group of expert practitioners of the techniques covered, illustrate their contributions by examples from their own research and from the relevant wider chemical literature. The book covers basic aspects such as product analysis, kinetics, catalysis, and investigation of reactive intermediates. It also includes material on significant recent developments, e.g. computational chemistry, calorimetry, and electrochemistry, in addition to topics of high current industrial relevance, e.g. reactions in multiphase systems, and synthetically useful reactions involving free radicals and catalysis by organometallic compounds.
Author : J. A. Kerr
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (257 download)
Download or read book Final Report on Survey of Kinetic Data on Atomic and Free-radical Addition Reactions written by J. A. Kerr and published by . This book was released on 1972 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Henry Eyring
Publisher : Elsevier
ISBN 13 : 0323142397
Total Pages : 817 pages
Book Rating : 4.3/5 (231 download)
Download or read book Reaction In Condensed Phases written by Henry Eyring and published by Elsevier. This book was released on 2012-12-02 with total page 817 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physical Chemistry: An Advanced Treatise: Reactions in Condensed Phases, Volume VII, deals with reactions in condensed phases. The purpose of this treatise is to present a comprehensive treatment of physical chemistry for advanced students and investigators in a reasonably small number of volumes. An attempt has been made to include all important topics in physical chemistry together with borderline subjects which are of particular interest and importance. The book begins by discussing the basic principles of reaction rates in solution. This is followed by separate chapters on estimating the rate parameters of elementary reactions; the use of correlation diagrams to interpret organic reactions; perturbation of reaction rates by substituents; and inorganic reactions. Subsequent chapters cover the important field of free radicals, including chain reactions and solvent effects; heterogeneous catalysis; various types of surface reactions; surface annealing; electron reactions; nucleation; and radiation chemistry. The book presents a broad picture of current developments in reaction rates in condensed phases in a form accessible to all students of chemical kinetics. This treatment, by experts in widely different areas, will hopefully meet many student needs and provide a useful overview for all.
Author : Rayson L. Huang
Publisher : Hodder Education
ISBN 13 :
Total Pages : 264 pages
Book Rating : 4.:/5 (51 download)
Download or read book The Chemistry of Free Radicals written by Rayson L. Huang and published by Hodder Education. This book was released on 1974 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Milan Lazar
Publisher : CRC Press
ISBN 13 : 9780849353871
Total Pages : 322 pages
Book Rating : 4.3/5 (538 download)
Download or read book Free Radicals in Chemistry and Biology written by Milan Lazar and published by CRC Press. This book was released on 1989-03-31 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elementary radical reactions are described in terms of fundamental knowledge of organic chemistry and chemical physics in this valuable reference text. The complex radical processes of nonchain and chain mechanisms, such as dimerization, alkylation, polymerization, telomerization, halogenation pyrolysis, oxidation and combustion, are complemented by reactions in chemical lasers and in the cosmos, as well as by reactions in biological objects under normal or pathological metabolism. The text also provides the synthesis of facts from various fields of research and involves mechanisms where free radicals appear either as main or side intermediates in one of the several alternatives of the reaction pathway. Highlights include 38 tables and 39 figures.
Author : Hamish Cattanach Low
Publisher :
ISBN 13 :
Total Pages : 354 pages
Book Rating : 4.:/5 (651 download)
Download or read book Kinetic Studies of Free Radical Reactions written by Hamish Cattanach Low and published by . This book was released on 1977 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Le Zeng
Publisher :
ISBN 13 :
Total Pages : 260 pages
Book Rating : 4.:/5 (224 download)
Download or read book Kinetic Studies on Free Radical Reactions Involving Chiral Radicals written by Le Zeng and published by . This book was released on 2005 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher :
ISBN 13 :
Total Pages : 456 pages
Book Rating : 4.3/5 (91 download)
Download or read book Kinetics and Mechanism of Polyreactions: Radical polymerization. Radiation and photo-chemical polymerization. Polymerization in heterogeneous systems written by and published by . This book was released on 1969 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Zeev B. Alfassi
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 392 pages
Book Rating : 4.F/5 ( download)
Download or read book S-Centered Radicals written by Zeev B. Alfassi and published by John Wiley & Sons. This book was released on 1999-03-22 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: S-centered Radicals Edited by Ben Gurion University of the Negev, Israel Sulfur containing radicals, formed from sulfur emissions from natural sources (e.g. volcanoes), power plants and from car exhausts, play an important role in our atmosphere. In the living cell, sulfur constitutes an essential part of the defence against oxidative damage and in the course of this mechanism is transformed into a variety of sulfur free radical species. S-centered Radicals deals with the organic radicals containing sulfur atoms, RS*, RSO*, RSO_2* and R_3S and the inorganic radicals, *SH and SO_x*. This is the book to bring together all the recent developments of S-centered radical chemistry. This area is extremely important to organic synthetic chemists and environmentalists. S-centered radicals are of increasing interest in biochemistry and medicine due to S-containing amino-acids and S-S bonds in proteins. Sulfur radicals are also involved in polymer chemistry and photonic materials as well as in radiation protection and nutrition. This title is the essential volume for anyone working in sulfur chemistry.
Author : R.A. Abramovitch
Publisher : Springer Science & Business Media
ISBN 13 : 1461331927
Total Pages : 609 pages
Book Rating : 4.4/5 (613 download)
Download or read book Reactive Intermediates written by R.A. Abramovitch and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 609 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of reactive intermediates has been blossoming at a rapid rate in recent years and its impact on chemistry, both "pure" and "applied," as well as on biology, astronomy, and other areas of science, is enormous. Several books have been published which cover the area; one, edited by McManus, * surveys the subject in general at the senior undergraduate or beginning graduate level. In addition, a number of monographs have appeared which deal with individual topics such as carbenes, nitrenes, free radicals, carbanions, carbenium ions, and so on, in great depth. Our objective is somewhat different. We hope that these Advances in . . . type of volumes will appear at irregular intervals of a year to 18 months each. We intend to publish up-to-date reviews in relatively new areas of the chemistry of reactive intermediates. These will be written by world authorities in the field, each one of whom will give the reader a current in-depth review of all aspects of the chemistry of each of these species. It is our plan that the subjects to be reviewed will cover not only organic chemistry but also inorganic, physical, bio-, industrial, and atmospheric chemistry. The volumes themselves, we hope, will end up being reasonably interdisciplinary, though this need not and probably will not be the case for the individual reviews.
Author :
Publisher :
ISBN 13 :
Total Pages : 874 pages
Book Rating : 4.:/5 (318 download)
Download or read book Journal of Organic Chemistry of the USSR. written by and published by . This book was released on 1986 with total page 874 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : James Christie Robb
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (911 download)
Download or read book Investigations of Free Radical Reactions written by James Christie Robb and published by . This book was released on 1954 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Judit E. Puskas
Publisher : Springer Science & Business Media
ISBN 13 : 1461501253
Total Pages : 214 pages
Book Rating : 4.4/5 (615 download)
Download or read book In Situ Spectroscopy of Monomer and Polymer Synthesis written by Judit E. Puskas and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a collection of selected papers presented at the symposium titled "In situ Spectroscopy in Monomer and Polymer Synthesis," held at the April, 2001 ACS National Meeting in San Diego, California, USA. The co-organizers of this symposium were Timothy Long, Judit E. Puskas, Robson F. Storey, and J. Andrews. In situ spectroscopic monitoring is gaining popularity both in academia and industry. FfIR monitoring is used most frequently, but UV-visible, raman, and NMR spectroscopy are also important. This book concentrates mostly on FfIR monitoring, both in the near and mid-infrared ranges. The first chapter is a short general overview of FfIR spectroscopy, followed by the symposium contribu tions. We thought that this would be especially useful for student readers. We hope that the book will present a state-of-the-art overview of research related to in situ spectroscopic monitoring. -Judit E. Puskas ix Acknowledgments This book would not have been possible without the dedicated effort of the chapter contributors and the symposium committee: Professor Judit E. Puskas Professor Timothy Long Professor Robson F. Storey Professor J. Andrews The symposium was financially supported by: ACS-Petroleum Research Fund REMSPEC Co. Wyatt Technology Co.
Author : Augustine Ong Soon Hock
Publisher :
ISBN 13 :
Total Pages : 482 pages
Book Rating : 4.:/5 (731 download)
Download or read book Aspects of Free Radical Addition Reactions written by Augustine Ong Soon Hock and published by . This book was released on 1963 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt:
