Reactive Intermediates

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Publisher : John Wiley & Sons
ISBN 13 : 9783527628735
Total Pages : 341 pages
Book Rating : 4.6/5 (287 download)

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Book Synopsis Reactive Intermediates by : Leonardo S. Santos

Download or read book Reactive Intermediates written by Leonardo S. Santos and published by John Wiley & Sons. This book was released on 2009-11-04 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the last two decades there has been considerable growth in the development of electrospray ionization mass spectrometry (ESI-MS) as a practical method in the study of reaction mechanisms. This method allows the interception and characterization of key intermediates, either as transient species or as protonated/deprotonated forms of neutral species by API-MS. The outstanding features and advantages of ESI-MS make it one of the most suitable tools for the fast screening of intermediates directly from solution, providing hitherto unavailable chemical information to organic chemists. This monograph provides an overview of the mechanisms involved in ESI-MS, the historical perspectives before looking further in-depth at specific reactions and intermediates. Written by researchers in the field, this book is an unique resource for the understanding of this cutting-edge technique.

Investigations of Ion-molecule Reactions in the Gas Phase by Ion Cyclotron Resonance Mass Spectrometry

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Publisher :
ISBN 13 :
Total Pages : 476 pages
Book Rating : 4.3/5 (9 download)

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Book Synopsis Investigations of Ion-molecule Reactions in the Gas Phase by Ion Cyclotron Resonance Mass Spectrometry by : Jeffrey P. Kiplinger

Download or read book Investigations of Ion-molecule Reactions in the Gas Phase by Ion Cyclotron Resonance Mass Spectrometry written by Jeffrey P. Kiplinger and published by . This book was released on 1984 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Journal of Research of the National Bureau of Standards

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Publisher :
ISBN 13 :
Total Pages : 554 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Journal of Research of the National Bureau of Standards by : United States. National Bureau of Standards

Download or read book Journal of Research of the National Bureau of Standards written by United States. National Bureau of Standards and published by . This book was released on 1975 with total page 554 pages. Available in PDF, EPUB and Kindle. Book excerpt:

ERDA Energy Research Abstracts

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Publisher :
ISBN 13 :
Total Pages : 724 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis ERDA Energy Research Abstracts by :

Download or read book ERDA Energy Research Abstracts written by and published by . This book was released on 1977 with total page 724 pages. Available in PDF, EPUB and Kindle. Book excerpt:

ERDA Energy Research Abstracts

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Publisher :
ISBN 13 :
Total Pages : 1680 pages
Book Rating : 4.3/5 (129 download)

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Book Synopsis ERDA Energy Research Abstracts by : United States. Energy Research and Development Administration. Technical Information Center

Download or read book ERDA Energy Research Abstracts written by United States. Energy Research and Development Administration. Technical Information Center and published by . This book was released on 1977 with total page 1680 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Quantum Systems in Chemistry and Physics

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Publisher : Springer Science & Business Media
ISBN 13 : 0306481456
Total Pages : 400 pages
Book Rating : 4.3/5 (64 download)

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Book Synopsis Quantum Systems in Chemistry and Physics by : Alfonso Hernández-Laguna

Download or read book Quantum Systems in Chemistry and Physics written by Alfonso Hernández-Laguna and published by Springer Science & Business Media. This book was released on 2006-04-11 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: These two volumes collect forty-four selected papers from the scientific contributions presented at the Third European Workshop on Quantum Systems in Chemistry and Physics, held in Granada (Spain), April 19–22, 1998. Ninety-nine scientists from Bulgaria, Columbia, Cuba, Denmark, Finland, France, Germany, Hungary, Israel, Italy, Mexico, Netherlands, Norway, Poland, Russia, Slovakia, Spain, Sweden, United Ki- dom, Uruguay and Venezuela attended the workshop, discussing the state of the art, new trends, and future evolution of the methods and applications. The workshop took place at the ‘Los Alixares’ Hotel, where 45 lectures were given by prominent members of the scientific community; in addition, 49 posters were presented in two very animated sessions. The success of this workshop is due, without doubt, to the excellent tradition initiated at the previous workshops, organised by Prof. R. McWeeny in San Miniato, Pisa (Italy), 1996, and by Prof. S. Wilson in Oxford (United Kingdom), 1997. These workshops create occasions for meetings and disc- sions on the current state of the art, emerging methods and applications and new trends in this area of science. The three meetings were sponsored and partially supported by the European Union (EU) in the frame of the Cooperation in Science and Technology (COST) chemistry actions.

Mechanistic Studies on Transition Metal-Catalyzed C–H Activation Reactions Using Combined Mass Spectrometry and Theoretical Methods

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Publisher : Springer
ISBN 13 : 9811045216
Total Pages : 140 pages
Book Rating : 4.8/5 (11 download)

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Book Synopsis Mechanistic Studies on Transition Metal-Catalyzed C–H Activation Reactions Using Combined Mass Spectrometry and Theoretical Methods by : Gui-Juan Cheng

Download or read book Mechanistic Studies on Transition Metal-Catalyzed C–H Activation Reactions Using Combined Mass Spectrometry and Theoretical Methods written by Gui-Juan Cheng and published by Springer. This book was released on 2017-06-07 with total page 140 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis presents detailed mechanistic studies on a series of important C-H activation reactions using combined computational methods and mass spectrometry experiments. It also provides guidance on the design and improvement of catalysts and ligands. The reactions investigated include: (i) a nitrile-containing template-assisted meta-selective C-H activation, (ii) Pd/mono-N-protected amino acid (MPAA) catalyzed meta-selective C-H activation, (iii) Pd/MPAA catalyzed asymmetric C-H activation reactions, and (iv) Cu-catalyzed sp3 C-H cross-dehydrogenative-coupling reaction. The book reports on a novel dimeric Pd-M (M = Pd or Ag) model for reaction (i), which successfully explains the meta-selectivity observed experimentally. For reaction (ii), with a combined DFT/MS method, the author successfully reveals the roles of MPAA ligands and a new C-H activation mechanism, which accounts for the improved reactivity and high meta-selectivity and opens new avenues for ligand design. She subsequently applies ion-mobility mass spectrometry to capture and separate the [Pd(MPAA)(substrate)] complex at different stages for the first time, providing support for the internal-base model for reaction (iii). Employing DFT studies, she then establishes a chirality relay model that can be widely applied to MPAA-assisted asymmetric C-H activation reactions. Lastly, for reaction (iv) the author conducts detailed computational studies on several plausible pathways for Cu/O2 and Cu/TBHP systems and finds a reliable method for calculating the single electron transfer (SET) process on the basis of benchmark studies.

Reviews of Reactive Intermediate Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 0470120819
Total Pages : 492 pages
Book Rating : 4.4/5 (71 download)

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Book Synopsis Reviews of Reactive Intermediate Chemistry by : Matthew S. Platz

Download or read book Reviews of Reactive Intermediate Chemistry written by Matthew S. Platz and published by John Wiley & Sons. This book was released on 2007-04-20 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of reactive intermediates is central to a modern mechanistic and quantitative understanding of organic chemistry. Moreover, it underlies a significant portion of modern synthetic chemistry and is integral to a molecular view of biological chemistry. Reviews in Reactive Intermediate Chemistry presents an up-to-date, authoritative guide to this fundamental topic. Although it follows Reactive Intermediate Chemistry by the same authors, it serves as a free-standing resource for the entire chemical and biochemical community. The book includes: Relevant, practical applications Coverage of such topics as mass spectrometry methods, reactive intermediates in interstellar medium, quantum mechanical tunnelling, solvent effects, reactive intermediates in biochemical processes, and excited state surfaces Discussions of emerging areas, particularly those involving dynamics and theories Concluding sections identifying key directions for future research are provided at the end of each chapter

Photochemical Studies of Reactive Intermediates Involved in Gas Phase Ion-neutral Reactions

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Publisher :
ISBN 13 :
Total Pages : 368 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Photochemical Studies of Reactive Intermediates Involved in Gas Phase Ion-neutral Reactions by : Thomas H. Osterheld

Download or read book Photochemical Studies of Reactive Intermediates Involved in Gas Phase Ion-neutral Reactions written by Thomas H. Osterheld and published by . This book was released on 1992 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Scientific and Technical Aerospace Reports

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ISBN 13 :
Total Pages : 542 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis Scientific and Technical Aerospace Reports by :

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1995 with total page 542 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Energy Research Abstracts

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Publisher :
ISBN 13 :
Total Pages : 1224 pages
Book Rating : 4.U/5 (183 download)

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Book Synopsis Energy Research Abstracts by :

Download or read book Energy Research Abstracts written by and published by . This book was released on 1988 with total page 1224 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Amide Linkage

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Publisher : John Wiley & Sons
ISBN 13 : 9780471420255
Total Pages : 672 pages
Book Rating : 4.4/5 (22 download)

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Book Synopsis The Amide Linkage by : Arthur Greenberg

Download or read book The Amide Linkage written by Arthur Greenberg and published by John Wiley & Sons. This book was released on 2002-11-11 with total page 672 pages. Available in PDF, EPUB and Kindle. Book excerpt: An authoritative reference to an important and ubiquitous chemical linkage The amide linkage is one of the most fundamental and widespread chemical bonds in nature, underlying the properties of a vast array of organic molecules, polymers, and materials, including peptides and proteins. Arthur Greenberg, Curt Breneman, and Joel Liebman's peerless text provides comprehensive coverage of the experimental, structural, and computational findings that shed light on the chemical and physical properties of the amide linkage, as well as its emerging applications in materials and biotechnology. Chapters in The Amide Linkage highlight how this chemical bond factors in the design of enzyme inhibitors, cyclic peptides, antibacterial agents, and emerging nanotechnology applications. This one-of-a-kind study also: * Discusses selected aspects of chemical reactions, structure, bonding, and energetics of the amide bond, including amide rotational barriers, stereochemistry, complexation, spectroscopy, and thermochemistry * Presents specific applications to supramolecular and stereospecific synthesis * Discusses key aspects of peptide and protein chemistry-such as molecular recognition, conformation, and folding-in terms of the amide linkage * Includes chapters contributed by numerous eminent chemists and biochemists Organic, medicinal, polymer, and physical chemists, as well as biochemists and materials scientists, will find The Amide Linkage to be an invaluable addition to their professional libraries.

Grants and Awards for the Fiscal Year Ended ...

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Publisher :
ISBN 13 :
Total Pages : 260 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Grants and Awards for the Fiscal Year Ended ... by : National Science Foundation (U.S.)

Download or read book Grants and Awards for the Fiscal Year Ended ... written by National Science Foundation (U.S.) and published by . This book was released on 1980 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Gold Clusters, Colloids and Nanoparticles II

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Publisher : Springer
ISBN 13 : 3319078453
Total Pages : 242 pages
Book Rating : 4.3/5 (19 download)

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Book Synopsis Gold Clusters, Colloids and Nanoparticles II by : D. Michael P. Mingos

Download or read book Gold Clusters, Colloids and Nanoparticles II written by D. Michael P. Mingos and published by Springer. This book was released on 2014-10-31 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors. Readership: research scientists at universities or in industry, graduate students Special offer For all customers who have a standing order to the print version of Structure and Bonding, we offer free access to the electronic volumes of the Series published in the current year via SpringerLink.com

Research in Progress

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Publisher :
ISBN 13 :
Total Pages : 604 pages
Book Rating : 4.:/5 (334 download)

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Book Synopsis Research in Progress by :

Download or read book Research in Progress written by and published by . This book was released on 1984 with total page 604 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organic Reaction Mechanisms 1981

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Publisher : John Wiley & Sons
ISBN 13 : 0470066679
Total Pages : 662 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis Organic Reaction Mechanisms 1981 by : A. C. Knipe

Download or read book Organic Reaction Mechanisms 1981 written by A. C. Knipe and published by John Wiley & Sons. This book was released on 2008-04-30 with total page 662 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 1981 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 1981. The 17th annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.

Biomedical Index to PHS-supported Research

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Publisher :
ISBN 13 :
Total Pages : 1200 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Biomedical Index to PHS-supported Research by :

Download or read book Biomedical Index to PHS-supported Research written by and published by . This book was released on 1993 with total page 1200 pages. Available in PDF, EPUB and Kindle. Book excerpt: