Supercritical Fluids

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Publisher : Springer Science & Business Media
ISBN 13 : 9401139296
Total Pages : 602 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Supercritical Fluids by : E. Kiran

Download or read book Supercritical Fluids written by E. Kiran and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 602 pages. Available in PDF, EPUB and Kindle. Book excerpt: Supercritical fluids are neither gas nor liquid, but can be compressed gradually from low to high density and they are therefore interesting and important as tunable solvents and reaction media in the chemical process industry. By adjusting the density the properties of these fluids can be customised and manipulated for a given process - physical or chemical transformation. Separation and processing using supercritical solvents such as CO2 are currently on-line commercially in the food, essential oils and polymer industries. Many agencies and industries are considering the use of supercritical water for waste remediation. Supercritical fluid chromatography represents another, major analytical application. Significant advances have recently been made in materials processing, ranging from particle formation to the creation of porous materials. The chapters in this book provide tutorial accounts of topical areas centred around: (1) phase equilibria, thermodynamics and equations of state; (2) critical behaviour, crossover effects; (3) transport and interfacial properties; (4) molecular modelling, computer simulation; (5) reactions, spectroscopy; (6) phase separation kinetics; (7) extractions; (8) applications to polymers, pharmaceuticals, natural materials and chromatography; (9) process scale-up.

Introduction to Supercritical Fluids

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Author :
Publisher : Newnes
ISBN 13 : 0080931308
Total Pages : 764 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Introduction to Supercritical Fluids by : Richard Smith

Download or read book Introduction to Supercritical Fluids written by Richard Smith and published by Newnes. This book was released on 2013-12-08 with total page 764 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text provides an introduction to supercritical fluids with easy-to-use Excel spreadsheets suitable for both specialized-discipline (chemistry or chemical engineering student) and mixed-discipline (engineering/economic student) classes. Each chapter contains worked examples, tip boxes and end-of-the-chapter problems and projects. Part I covers web-based chemical information resources, applications and simplified theory presented in a way that allows students of all disciplines to delve into the properties of supercritical fluids and to design energy, extraction and materials formation systems for real-world processes that use supercritical water or supercritical carbon dioxide. Part II takes a practical approach and addresses the thermodynamic framework, equations of state, fluid phase equilibria, heat and mass transfer, chemical equilibria and reaction kinetics of supercritical fluids. Spreadsheets are arranged as Visual Basic for Applications (VBA) functions and macros that are completely (source code) accessible for students who have interest in developing their own programs. Programming is not required to solve problems or to complete projects in the text. Property worksheets/spreadsheets that are easy to use in learning environments Worked examples with Excel VBA Worksheet functions allow users to design their own processes Fluid phase equilibria and chemical equilibria worksheets allow users to change conditions, study new solutes, co-solvents, chemical systems or reactions

Gas Extraction

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Publisher : Springer Science & Business Media
ISBN 13 : 3662073803
Total Pages : 396 pages
Book Rating : 4.6/5 (62 download)

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Book Synopsis Gas Extraction by : Gerd Brunner

Download or read book Gas Extraction written by Gerd Brunner and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: Application of compressed gases as solvents has found widespread interest within the scientific community. Its processes have industrial applications. Gas Extraction deals with the possibilities of supercritical gases as solvents for separation processes. The volume combines physico-chemical aspects with chemical engineering methods. The text generalizes as far as possible, and treats examples in detail. Gas Extraction covers, for the first time, the subject in textbook form. Most of the examples provide new results that will be helpful for practicing scientists, engineers, and students who want to make use of the techniques.

Supercritical Fluid Methods and Protocols

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Publisher : Springer Science & Business Media
ISBN 13 : 1592590306
Total Pages : 253 pages
Book Rating : 4.5/5 (925 download)

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Book Synopsis Supercritical Fluid Methods and Protocols by : John R. Williams

Download or read book Supercritical Fluid Methods and Protocols written by John R. Williams and published by Springer Science & Business Media. This book was released on 2008-02-05 with total page 253 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last 15 years, there has been renewed interest in supercritical fluids owing to their unique properties and relatively low environmental impact. Greatest attention has been given to the extraction and separation of organic compounds. Supercritical fluids have also been successfully used for particle production, as reaction media, and for the destruction of toxic waste. Supercritical carbon dioxide has been the most widely used supercritical fluid, mainly because it is cheap, relatively nontoxic, and has convenient critical values. Supercritical fluids have also been used on analytical and preparative scales for many biological and other applications. Many papers have been published on the use of supercritical fluids. However, few have acted as a detailed instruction manual for those wanting to use the techniques for the first time. We anticipate that this Methods in Biotechnology volume, Supercritical Fluid Methods and Protocols will s- isfy the need for such a book. Every chapter has been written by experienced workers and should, if closely followed, enable workers with some or no previous experience of supercritical fluids to conduct experiments successfully at the first attempt.

Supercritical Fluids

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 9401582955
Total Pages : 775 pages
Book Rating : 4.4/5 (15 download)

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Book Synopsis Supercritical Fluids by : E. Kiran

Download or read book Supercritical Fluids written by E. Kiran and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 775 pages. Available in PDF, EPUB and Kindle. Book excerpt: Supercritical fluids which are neither gas nor liquid, but can be compressed gradually from low to high density, are gaining increasing importance as tunable solvents and reaction media in the chemical process industry. By adjusting the pressure, or more strictly the density, the properties of these fluids are customized and manipulated for the particular process at hand, be it a physical transformation, such as separation or solvation, or a chemical transformation, such as a reaction or reactive extraction. Supercritical fluids, however, differ from both gases and liquids in many respects. In order to properly understand and describe their properties, it is necessary to know the implications of their nearness to criticality, to be aware of the complex types of phase separation (including solid phases) that occur when the components of the fluid mixture are very different from each other, and to develop theories that can cope with the large differences in molecular size and shape of the supercritical solvent and the solutes that are present.

Supercritical Fluid Extraction

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Author :
Publisher : Butterworth-Heinemann
ISBN 13 :
Total Pages : 528 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Supercritical Fluid Extraction by : Mark A. McHugh

Download or read book Supercritical Fluid Extraction written by Mark A. McHugh and published by Butterworth-Heinemann. This book was released on 1986 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: Supercritical Fluid Extraction is a technique in which CO2 is used under extremely high pressure to separate solutions. Separations is basic to all process industries & supercritical fluid extraction is a specific type which is receiving a high level of attention, The book will combine basic fundamentals with industrial applications.

Analysis with Supercritical Fluids: Extraction and Chromatography

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Publisher : Springer Science & Business Media
ISBN 13 : 3642774741
Total Pages : 225 pages
Book Rating : 4.6/5 (427 download)

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Book Synopsis Analysis with Supercritical Fluids: Extraction and Chromatography by : Bernd Wenclawiak

Download or read book Analysis with Supercritical Fluids: Extraction and Chromatography written by Bernd Wenclawiak and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 225 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of supercritical fluids in analytical chemistry is still grow ing. More and more analysts are discovering the favorable advan tages for a number of applications. Especially supercritical fluid extraction (SFE) has attracted a lot of interest in recent years due to its simplicity. Supercritical fluid chromatography (SFC) has become better established and the development of this technique has been accelerated by the many applications with capillary col umns which have been published in the literature. At first SFC equipment was based on instruments commonly used for liquid chromatography, and the first commercial in struments were derived from this technology. However, capillary columns can be much more easily interfaced to gas chromatogra phy equipment especially to the detectors commonly used for Oc. Many stationary phases both for packed micro columns and capillary columns have been designed for SFC purposes extending this technology to LC and OC. The most common fluid applied in SFC and SFE is carbon dioxide. The advantages of supercritical CO , such as having dif 2 fusivity like a gas and solvating power depending on temperature and pressure, are also valid for other fluids and modified fluids. Both properties are valuable for sample extraction and extraction selectivity.

Applications of Supercritical Fluids in Industrial Analysis

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 940112146X
Total Pages : 238 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Applications of Supercritical Fluids in Industrial Analysis by : J.R. Dean

Download or read book Applications of Supercritical Fluids in Industrial Analysis written by J.R. Dean and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 238 pages. Available in PDF, EPUB and Kindle. Book excerpt: The continued search for rapid, efficient and cost-effective means of analytical measurement has introduced supercritical fluids into the field of analytical chemistry. Two areas are common: supercritical fluid chroma tography and supercritical fluid extraction. Both seek to exploit the unique properties of a gas at temperatures and pressures above the critical point. The most common supercritical fluid is carbon dioxide, employed because of its low critical temperature (31 °C), inertness, purity, non-toxicity and cheapness. Alternative supercritical fluids are also used and often in conjunction with modifiers. The combined gas-like mass transfer and liquid-like solvating characteristics have been used for improved chroma tographic separation and faster sample preparation. Supercritical fluid chromatography (SFC) is complementary to gas chro matography ( GC) and high performance liquid chromatography (HPLC), providing higher efficiency than HPLC, together with the ability to analyse thermally labile and high molecular weight analytes. Both packed and open tubular columns can be employed, providing the capability to analyse a wide range of sample types. In addition, flame ionization detection can be used, thus providing 'universal' detection.

The Application of Green Solvents in Separation Processes

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Publisher : Elsevier
ISBN 13 : 0128054433
Total Pages : 560 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis The Application of Green Solvents in Separation Processes by : Francisco Pena-Pereira

Download or read book The Application of Green Solvents in Separation Processes written by Francisco Pena-Pereira and published by Elsevier. This book was released on 2017-02-28 with total page 560 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Application of Green Solvents in Separation Processes features a logical progression of a wide range of topics and methods, beginning with an overview of green solvents, covering everything from water and organic solvents, to ionic liquids, switchable solvents, eutectic mixtures, supercritical fluids, gas-expanded solvents, and more. In addition, the book outlines green extraction techniques, such as green membrane extraction, ultrasound-assisted extraction, and surfactant-mediated extraction techniques. Green sampling and sample preparation techniques are then explored, followed by green analytical separations, including green gas and liquid capillary chromatography, counter current chromatography, supercritical fluid chromatography, capillary electrophoresis, and other electrical separations. Applications of green chemistry techniques that are relevant for a broad range of scientific and technological areas are covered, including the benefits and challenges associated with their application. Provides insights into recent advances in greener extraction and separation processes Gives an understanding of alternatives to harmful solvents commonly used in extraction and separation processes, as well as advanced techniques for such processes Written by a multidisciplinary group of internationally recognized scientists

Introduction to Supercritical Fluids

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Author :
Publisher : Elsevier Inc. Chapters
ISBN 13 : 0128076895
Total Pages : 752 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Introduction to Supercritical Fluids by : Richard Smith

Download or read book Introduction to Supercritical Fluids written by Richard Smith and published by Elsevier Inc. Chapters. This book was released on 2013-12-08 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Introduction to Supercritical Fluids

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Author :
Publisher : Elsevier Inc. Chapters
ISBN 13 : 012807695X
Total Pages : 752 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Introduction to Supercritical Fluids by : Richard Smith

Download or read book Introduction to Supercritical Fluids written by Richard Smith and published by Elsevier Inc. Chapters. This book was released on 2013-12-08 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Advanced Supercritical Fluids Technologies

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Author :
Publisher : BoD – Books on Demand
ISBN 13 : 183880708X
Total Pages : 224 pages
Book Rating : 4.8/5 (388 download)

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Book Synopsis Advanced Supercritical Fluids Technologies by : Igor Pioro

Download or read book Advanced Supercritical Fluids Technologies written by Igor Pioro and published by BoD – Books on Demand. This book was released on 2020-05-20 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt: Using SuperCritical Fluids (SCFs) in various processes is not new, because Mother Nature has been processing minerals in aqueous solutions at critical and supercritical pressures for billions of years. Somewhere in the 20th century, SCFs started to be used in various industries as working fluids, coolants, chemical agents, etc. Written by an international team of experts and complete with the latest research, development, and design, Advanced Supercritical Fluids Technologies is a unique technical book, completely dedicated to modern and advanced applications of supercritical fluids in various industries.Advanced Supercritical Fluids Technologies provides engineers and specialists in various industries dealing with SCFs as well as researchers, scientists, and students of the corresponding departments with a comprehensive overview of the current status, latest trends and developments of these technologies.Dr Igor Pioro is a professor at the University of Ontario Institute of Technology, Canada, and the Founding Editor of the ASME Journal of Nuclear Engineering and Radiation Science.

The Liquid and Supercritical Fluid States of Matter

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Publisher : CRC Press
ISBN 13 : 0429957912
Total Pages : 287 pages
Book Rating : 4.4/5 (299 download)

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Book Synopsis The Liquid and Supercritical Fluid States of Matter by : John E. Proctor

Download or read book The Liquid and Supercritical Fluid States of Matter written by John E. Proctor and published by CRC Press. This book was released on 2020-09-15 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses graduate students and researchers wishing to better understand the liquid and supercritical fluid states of matter, presenting a single cohesive treatment of the liquid and supercritical fluid states using the gas-like and solid-like approaches. Bringing this information together into one comprehensive text, this book outlines how our understanding of the liquid and supercritical fluid states is applied and explores the use of supercritical fluids in daily life and in research, for example in power generation, and their existence in planetary interiors. Presents a single coherent treatment of the key knowledge about the liquid and supercritical fluid states Provides comprehensive survey of key fluid properties from the latest experiments and applies our theoretical knowledge to understand the behaviour of these real fluids Explores the consequences of recent advances in the field on our understanding in industry, nature, and in interdisciplinary research, including planetary science

Natural Extracts Using Supercritical Carbon Dioxide

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Publisher : CRC Press
ISBN 13 : 142004169X
Total Pages : 362 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Natural Extracts Using Supercritical Carbon Dioxide by : Mamata Mukhopadhyay

Download or read book Natural Extracts Using Supercritical Carbon Dioxide written by Mamata Mukhopadhyay and published by CRC Press. This book was released on 2000-06-27 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt: Synthesizing research from a wide variety of sources, this work offers a convenient guide to a clean, safe, inexpensive, non-toxic, non-polluting solvent that performs better than most conventional solvents. Natural Extracts Using Supercritical Carbon Dioxide reviews recent development in the technology and its applications to the food, flavor, fra

Hydrothermal and Supercritical Water Processes

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Publisher : Elsevier
ISBN 13 : 0444594183
Total Pages : 683 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Hydrothermal and Supercritical Water Processes by : Gerd Brunner

Download or read book Hydrothermal and Supercritical Water Processes written by Gerd Brunner and published by Elsevier. This book was released on 2014-04-04 with total page 683 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrothermal and Supercritical Water Processes presents an overview on the properties and applications of water at elevated temperatures and pressures. It combines fundamentals with production process aspects. Water is an extraordinary substance. At elevated temperatures (and pressures) its properties change dramatically due to the modifications of the molecular structure of bulk water that varies from a stable three-dimensional network, formed by hydrogen bonds at low and moderate temperatures, to an assembly of separated polar water molecules at high and supercritical temperatures. With varying pressure and temperature, water is turned from a solvent for ionic species to a solvent for polar and non-polar substances. This variability and an enhanced reactivity of water have led to many practical applications and to even more research activities, related to such areas as energy transfer, extraction of functional molecules, unique chemical reactions, biomass conversion and fuel materials processing, destruction of dangerous compounds and recycling of useful ones, growth of monolithic crystals, and preparation of metallic nanoparticles. This book provides an introduction into the wide range of activities that are possible in aqueous mixtures. It is organized to facilitate understanding of the main features, outlines the main applications, and gives access to further information Summarizes fundamental properties of water for engineering applications Compares process and reactor designs Evaluates processes from thermodynamic, economic, and social impact viewpoints

Supercritical Fluid Technology in Materials Science and Engineering

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Author :
Publisher : CRC Press
ISBN 13 : 0824744713
Total Pages : 597 pages
Book Rating : 4.8/5 (247 download)

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Book Synopsis Supercritical Fluid Technology in Materials Science and Engineering by : Ya-Ping Sun

Download or read book Supercritical Fluid Technology in Materials Science and Engineering written by Ya-Ping Sun and published by CRC Press. This book was released on 2002-03-26 with total page 597 pages. Available in PDF, EPUB and Kindle. Book excerpt: This title analyzes the chemical reactions, structures and fundamental properties of supercritical fluid systems for the production of new compounds, nanomaterials, fibers, and films. It complies contemporary research and technological advances for increased selectivity and reduced waste in chemical, industrial, pharmaceutical, and biomedical applications. Topics include fluid dynamics, catalysis, hydrothermal synthesis, surfactants, conducting polymers, crystal growth, and other aspects and applications of supercritical fluids.

Supercritical Fluid Science and Technology

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Publisher :
ISBN 13 :
Total Pages : 568 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Supercritical Fluid Science and Technology by : Keith P. Johnston

Download or read book Supercritical Fluid Science and Technology written by Keith P. Johnston and published by . This book was released on 1989 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: New directions in supercritical fluids science and technology, fluorescence spectroscopy studies of intermolecular interactions in supercritical fluids, solvation structure in supercritical fluid mixtures based on molecular distribution functions, gibbs-ensemble Monte Carlo simulations of phase equilibria in supercritical fluid mixtures, spectroscopic determination of solvent strength and structure in supercritical fluid mixtures, partition coefficients of polyethyle glycols in super critical carbon dioxide, experimental measurement of supercritical fluid-liquid phase equilibrium, vapor-liquid equilibria of fatty acid esters in supercritical fluids, four-phase equilibrium of two ternary organic systems with carbon dioxide, direct viscosity enhancement of carbon dioxide, inverse emulsion polymerization of acrylamide, interaction of polymers with near-critical carbon dioxide, fundamental kinetics of methanol oxidation in supercritical fluids, thermodynamic analysis of corrosion of iron alloys in supercritical water, electrochemical measurements of corrosion of iron alloys in supercritical water, phase and reaction equilibria considerations in the evaluation and operation of supercritical fluid reaction processes, kinetic model for supercritical delignification of wood, gas antisolvent recrystallization solids formation after the expansion of supercritical mixtures, food, pharmaceutical, and environmental applications, design of commercial plant.