Infrared Probes Of Metal Cluster Structure And Bonding

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Metal Clusters

Author : Frank Träger
Publisher : Springer Science & Business Media
ISBN 13 : 3642715710
Total Pages : 230 pages
Book Rating : 4.6/5 (427 download)

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Book Synopsis Metal Clusters by : Frank Träger

Download or read book Metal Clusters written by Frank Träger and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains papers which have been presented at the International Sym posium on Metal Clusters in Heidelberg from April 7-11, 1986. Clusters, and in particular metal clusters, have been the topic of fa~t growing scientific interest. Indeed, clusters constitute a field of interdisciplinary nature where both physical and chemical questions have to be addressed. Clusters are offundamental importance for the deeper understanding of the transition from atoms via molecules and larger aggregates of particles to the properties of solid materials. Moreover, metal clusters and their character istics are of vital significance for such applied topics as catalysis or photography. Experimentally, the field exhibited rapid progress in the last years. Different sources for clusters have been developed. Intense beams made possible the investigation of free neutral clusters and cluster ions as well. Even though a number of issues concerning metal clusters is still discussed controversially, the present volume tries to give an overview of current work in this field and to illustrate the large variety of experiments as well as the advances made possible by modern theoretical methods. Looking at the many interesting questions still to be addressed it is fair to propose a rapid further growth of this field.

Cluster Assembled Materials

Author : Klaus Sattler
Publisher : CRC Press
ISBN 13 : 9780878497478
Total Pages : 318 pages
Book Rating : 4.4/5 (974 download)

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Book Synopsis Cluster Assembled Materials by : Klaus Sattler

Download or read book Cluster Assembled Materials written by Klaus Sattler and published by CRC Press. This book was released on 1996 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is now some 15 years since atomic clusters were first produced and investigated in laboratories. Since then, knowledge concerning clusters has enjoyed rapid and sustained growth, and cluster research has become a new branch of science.

Clusters

Author : Minh Tho Nguyen
Publisher : Springer
ISBN 13 : 3319489186
Total Pages : 372 pages
Book Rating : 4.3/5 (194 download)

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Book Synopsis Clusters by : Minh Tho Nguyen

Download or read book Clusters written by Minh Tho Nguyen and published by Springer. This book was released on 2017-01-31 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of atomic clusters continues to attract great interest amongst physicists and chemists alike. This is in part due to their intrinsic properties and potential industrial applications. The first part of Binary Clusters is devoted to recent developments in experimental techniques, the second part covers a variety of theoretical approaches. Different theoretical methods based on group/graph theories and quantum chemical computational methods as well as various spectroscopy techniques (such as mass, laser, infrared, photoelectron etc.) are applied to the determination of the existence of geometrical and electronic structures, chemical bonding phenomena, and the thermodynamic stabilities of several classes of binary clusters. All chapters within this review volume have been contributed by experts in chemistry, physics, and material sciences based at the University of Leuven, Belgium. This book is aimed at professionals and students working in cluster science.

Functional Nanometer-Sized Clusters of Transition Metals

Author : Wei Chen
Publisher : Royal Society of Chemistry
ISBN 13 : 1782628517
Total Pages : 465 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Functional Nanometer-Sized Clusters of Transition Metals by : Wei Chen

Download or read book Functional Nanometer-Sized Clusters of Transition Metals written by Wei Chen and published by Royal Society of Chemistry. This book was released on 2014-08-14 with total page 465 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal nanoclusters, which bridge metal atoms and nanocrystals, are gaining attention due to their unique chemical and physical properties which differ greatly from their corresponding large nanoparticles and molecular compounds. Their electronic and optical properties are of particular interest for their use in sensing, optoelectronics, photovoltaics and catalysis. The book highlights recent progress and challenges in size-controlled synthesis, size-dependent properties, characterization and applications of metal nanoclusters. Specific topics include organochalcogenolate-stabilized metal nanoparticles, water-soluble fluorescent silver nanoclusters, thiolate-protected Au and Ag nanoclusters, DNA-templated metal nanoclusters, fluorescent platinum nanoclusters and janus nanoparticles by interfacial engineering. Edited by active researchers in the area, the book provides a valuable reference for researchers in the area of functional nanomaterials. It also provides a guide for graduate students, academic and industrial researchers interested in the fundamentals of the materials or their applications.

Atomic Clusters with Unusual Structure, Bonding and Reactivity

Author : Pratim Kumar Chattaraj
Publisher : Elsevier
ISBN 13 : 0128231017
Total Pages : 446 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Atomic Clusters with Unusual Structure, Bonding and Reactivity by : Pratim Kumar Chattaraj

Download or read book Atomic Clusters with Unusual Structure, Bonding and Reactivity written by Pratim Kumar Chattaraj and published by Elsevier. This book was released on 2022-10-06 with total page 446 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomic Clusters with Unusual Structure, Bonding and Reactivity: Theoretical Approaches, Computational Assessment and Applications reviews the latest computational tools and approaches available for accurately assessing the properties of a cluster, while also highlighting how such clusters can be adapted and utilized for the development of novel materials and applications. Sections provide an introduction to the computational methods used to obtain global minima for clusters and effectively analyze bonds, outline experimental approaches to produce clusters, discuss specific applications, and explore cluster reactivity and usage across a number of fields.Drawing on the knowledge of its expert editors and contributors, this book provides a detailed guide to ascertaining the stability, bonding and properties of atomic clusters. Atomic clusters, which exhibit unusual properties, offer huge potential as building blocks for new materials and novel applications, but understanding their properties, stability and bonding is essential in order to accurately understand, characterize and manipulate them for further use. Searching for the most stable geometry of a given cluster is difficult and becomes even more so for clusters of medium and large sizes, where the number of possible isomers sharply increase, hence this book provides a unique and comprehensive approach to the topic and available techniques and applications. - Introduces readers to the vast structural and bonding diversity that clusters show and reflects on their potential for novel application and material development - Highlights the latest computational methods and theoretical tools available for identification of the most stable isomers and accurate analysis of bonding in the clusters - Focuses on clusters which violate the rules established in traditional chemistry and exhibit unusual structure, bonding and reactivity

Clusters and Colloids

Author : Günter Schmid
Publisher : John Wiley & Sons
ISBN 13 : 3527616063
Total Pages : 570 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Clusters and Colloids by : Günter Schmid

Download or read book Clusters and Colloids written by Günter Schmid and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive overview of the rapidly developing field of cluster science. In an interdisciplinary approach, basic concepts as well as recent developments in research and practical applications are authoritatively discussed by leading authors. Topics covered include 'naked' metal clusters, clusters stabilized by ligands, clusters in solids, and colloids. The reader will find answers to questions like: * How many metal atoms must a particle have to exhibit metallic properties? * How can the large specific surface of clusters and colloids be employed in catalysts? * How can metal clusters be introduced into solid hosts? * Which effects are responsible for the transition from isolated to condensed clusters? The editor has succeeded in bringing the contributions of various authors together into a homogeneous, readable book, which will be useful for the academic and industrial reader alike.

Chemisorption of Probe Molecules

Author :
Publisher : Elsevier
ISBN 13 : 0080887473
Total Pages : 409 pages
Book Rating : 4.0/5 (88 download)

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Book Synopsis Chemisorption of Probe Molecules by :

Download or read book Chemisorption of Probe Molecules written by and published by Elsevier. This book was released on 1990-07-19 with total page 409 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume concentrates on catalyst surfaces. The interaction of adsorbed molecules, mostly on heterogenous catalysts, although some reference to model catalysts is also made, is discussed here. Vibrational (infrared and electron energy loss spectroscopies, magnetic resonances (nuclear and electron spin) and thermal desorption methods have been included in this latter category. The reader will find also a comparison of these well established methods with their recent developments which make them much more attractive. Therefore, researchers working in the catalysis field will find much to interest them in this book.

Microclusters

Author : Satoru Sugano
Publisher : Springer Science & Business Media
ISBN 13 : 3642830641
Total Pages : 299 pages
Book Rating : 4.6/5 (428 download)

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Book Synopsis Microclusters by : Satoru Sugano

Download or read book Microclusters written by Satoru Sugano and published by Springer Science & Business Media. This book was released on 2013-03-12 with total page 299 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains the proceedings of the first in a series of biennial NEC Symposia on Fundamental Approaches to New Material Phases sponsored by the NEC Corporation, Tokyo, Japan. The symposium was held Octo ber 20-22, 1986, at Hakone Kanko Hotel in Hakone near Mt. Fuji, and on October 23 at NEC Laboratories in Kawasaki, Japan. About 40 partic ipants stayed together at the symposium sites during this period. They enjoyed intense and wide-ranging discussions in a conference room facing Mt. Fuji and the beautiful lake Ashinoko extending from the foot of the slope in the old crater. The title of the volume, Microclusters, means microscopic aggregates consisting of a few tens through a few hundreds of atoms. Microclusters, which are too big to be described as inorganic molecules but too small to have translational symmetry, are expected to show exotic properties which can be found in neither molecules nor solids. In the past few years the research field of microclusters has shown rapid and epoch-making de velopment. This is partly due to rapid development of the experimental techniques which have enabled the production of relatively dense, non interacting microclusters of various sizes in the form of cluster beams, thus allowing measurement of the properties of a free microcluster of a given size.

Elemental and Molecular Clusters

Author : Giorgio Benedek
Publisher : Springer
ISBN 13 :
Total Pages : 396 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Elemental and Molecular Clusters by : Giorgio Benedek

Download or read book Elemental and Molecular Clusters written by Giorgio Benedek and published by Springer. This book was released on 1988 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Aromaticity and Metal Clusters

Author : Pratim Kumar Chattaraj
Publisher : CRC Press
ISBN 13 : 9781439813355
Total Pages : 466 pages
Book Rating : 4.8/5 (133 download)

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Book Synopsis Aromaticity and Metal Clusters by : Pratim Kumar Chattaraj

Download or read book Aromaticity and Metal Clusters written by Pratim Kumar Chattaraj and published by CRC Press. This book was released on 2010-10-15 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal clusters, an intermediate state between molecules and the extended solid, show peculiar bonding and reactivity patterns. Their significance is critical to many areas, including air pollution, interstellar matter, clay minerals, photography, catalysis, quantum dots, and virus crystals. In Aromaticity and Metal Clusters, dozens of international experts explore not only the basic aspects of aromaticity, but also the structures, properties, reactivity, stability, and other consequences of the aromaticity of a variety of metal clusters. Although the concept of aromaticity has been known for nearly two centuries, there is no way to measure it experimentally and no theoretical formula to calculate it. In order to gain insight into its exact nature, the authors of this volume examine various indirect characteristics such as geometrical, electronic, magnetic, thermodynamic, and reactivity considerations. The book begins by discussing the evolution of aromaticity from benzene to atomic clusters. Next, more specialized chapters focus on areas of significant interest. Topics discussed include: Computational studies on molecules with unusual aromaticity Electronic shells and magnetism in small metal clusters A density functional investigation on the structures, energetics, and properties of sodium clusters through electrostatic guidelines and molecular tailoring The correlation between electron delocalization and ring currents in all metallic aromatic compounds Phenomenological shell model and aromaticity in metal clusters Rationalizing the aromaticity indexes used to describe the aromatic behavior of metal clusters 5f orbital successive aromatic and antiaromatic zones in triangular uranium cluster chemistry This collection of diverse contributions, composed of the work of scientists worldwide, is destined to not only answer puzzling questions about the nature of aromaticity, but also to provoke further inquiry in the minds of researchers.

The Chemical Bond I

Author : D. Michael P. Mingos
Publisher : Springer
ISBN 13 : 331933543X
Total Pages : 257 pages
Book Rating : 4.3/5 (193 download)

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Book Synopsis The Chemical Bond I by : D. Michael P. Mingos

Download or read book The Chemical Bond I written by D. Michael P. Mingos and published by Springer. This book was released on 2016-09-09 with total page 257 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors

Gold Clusters, Colloids and Nanoparticles I

Author : D. Michael P. Mingos
Publisher : Springer
ISBN 13 : 3319078488
Total Pages : 287 pages
Book Rating : 4.3/5 (19 download)

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Book Synopsis Gold Clusters, Colloids and Nanoparticles I by : D. Michael P. Mingos

Download or read book Gold Clusters, Colloids and Nanoparticles I written by D. Michael P. Mingos and published by Springer. This book was released on 2014-09-27 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors. Readership: research scientists at universities or in industry, graduate students Special offer For all customers who have a standing order to the print version of Structure and Bonding, we offer free access to the electronic volumes of the Series published in the current year via SpringerLink.

Organometallic Chemistry

Author : E W Abel
Publisher : Royal Society of Chemistry
ISBN 13 : 1847554075
Total Pages : 494 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Organometallic Chemistry by : E W Abel

Download or read book Organometallic Chemistry written by E W Abel and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 494 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Handbook of Nanophysics

Author : Klaus D. Sattler
Publisher : CRC Press
ISBN 13 : 1420075551
Total Pages : 912 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Handbook of Nanophysics by : Klaus D. Sattler

Download or read book Handbook of Nanophysics written by Klaus D. Sattler and published by CRC Press. This book was released on 2010-09-17 with total page 912 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of nanoscience was pioneered in the 1980s with the groundbreaking research on clusters, which later led to the discovery of fullerenes. Handbook of Nanophysics: Clusters and Fullerenes focuses on the fundamental physics of these nanoscale materials and structures. Each peer-reviewed chapter contains a broad-based introduction and enhances

Gas Phase Inorganic Chemistry

Author : David H. Russell
Publisher : Springer Science & Business Media
ISBN 13 : 146845529X
Total Pages : 422 pages
Book Rating : 4.4/5 (684 download)

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Book Synopsis Gas Phase Inorganic Chemistry by : David H. Russell

Download or read book Gas Phase Inorganic Chemistry written by David H. Russell and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of gas phase inorganic ion chemistry is relatively new; the early studies date back approximately twenty years, but there has been intense interest and development in the field in the last ten years. As with much of modern chemistry, the growth in gas phase inorganic ion chemistry can be traced to the development of instrumentation and new experimental methods. Studies in this area require sophisticated instruments and sample introduc tion/ ionization methods, and often these processes are complicated by the need for state-selecting (or collisionally stabilizing) the reactive species in order to assign the chemistry unequivocally. At the present level of experimental development, a wide range of experiments on diverse ionic systems are possible and many detailed aspects of the chemistry can be studied. Gas Phase Inorganic Chemistry focuses on the reactions of metal ions and metal clusters, and on the study of these species using the available modern spectroscopic methods. Three of the twelve chapters cover the chemistry of ionic monometal transition metal ions and the chemistry of these species with small diatomics and model organics. Two of the chapters focus on the studies of the chemical and physical properties of (primarily) transition metal clusters, and these chapters review experimental methods and capabilities. Two chapters also deal with the chemistry of transition metal carbonyl clusters, and these chapters address issues important to cluster growth and activation as well as the characterization of such species.

Vibrational Spectra of Organometallics

Author : Edward Maslowsky, Jr.
Publisher : John Wiley & Sons
ISBN 13 : 1119404665
Total Pages : 736 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Vibrational Spectra of Organometallics by : Edward Maslowsky, Jr.

Download or read book Vibrational Spectra of Organometallics written by Edward Maslowsky, Jr. and published by John Wiley & Sons. This book was released on 2018-12-10 with total page 736 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive compilation of the available experimental and theoretical vibrational data for organometallic compounds and its role in evaluating the structures, bonding, and properties of these key compounds This unique book offers a thorough review of the literature dealing with vibrational data obtained using various phases, including matrices, reported for organometallic compounds from infrared spectra, Raman spectra, and several other techniques. It is the only one that compiles the available experimental and theoretical vibrational data on these compounds, and which discusses the importance of this information and its role in evaluating structures, bonding, and other important properties. It also treats the use of DFT and other theoretical calculations to analyze the vibrational data and to predict properties associated with these compounds. The book also includes vibrational data for organic species that form on metal and other surfaces. Vibrational Spectra of Organometallics: Theoretical and Experimental Data offers complete coverage of: Carbide, Alkylidyne, Alkylidene, Alkyl, and Alkane Derivatives; Noncyclic Carbon Clusters and Unsaturated Hydrocarbon Derivatives; and Cyclic, Unsaturated Organometallic Derivatives. By summarizing work that has already been done on organometallic compounds, it serves as an important reference for those studying their vibrational spectra and will, in the end, lead to a clearer understanding of other research that needs to be done in order to help researchers determine new research directions. An important reference for those studying the vibrational spectra of organometallic compounds Gathers the existing experimental and theoretical vibrational data and discusses its significance in assessing structures, bonding, and other principle properties Includes DFT methods for the interpretation of spectra, which has been one of the major developments of the last two decades Vibrational Spectra of Organometallics: Theoretical and Experimental Data is an important reference for researchers and practitioners in the areas of inorganic, organometallic, organic, and surface chemistry who have an interest in using vibrational data to characterize the bonding, composition, reactions, and structures of organometallic compounds, and organic species that are formed on various surfaces.

Organometallic Chemistry

Author : M. Green
Publisher : Royal Society of Chemistry
ISBN 13 : 0854043438
Total Pages : 504 pages
Book Rating : 4.8/5 (54 download)

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Book Synopsis Organometallic Chemistry by : M. Green

Download or read book Organometallic Chemistry written by M. Green and published by Royal Society of Chemistry. This book was released on 2005 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis, synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests, reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Volume 31 covers literature published during 2002. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.