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Hydrogen Production By Aqueous Phase Reforming Of Oxygenated Hydrocarbons Over Supported Metal Catalysts
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Book Synopsis Hydrogen Production by Aqueous-phase Reforming of Oxygenated Hydrocarbons Over Supported Metal Catalysts by : Rupali R. Davda
Download or read book Hydrogen Production by Aqueous-phase Reforming of Oxygenated Hydrocarbons Over Supported Metal Catalysts written by Rupali R. Davda and published by . This book was released on 2004 with total page 144 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Hydrogen Production by Aqueous Phase Reforming of Light Oxygenated Hydrocarbons by : John W. Shabaker
Download or read book Hydrogen Production by Aqueous Phase Reforming of Light Oxygenated Hydrocarbons written by John W. Shabaker and published by . This book was released on 2004 with total page 196 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Selective Synthesis of Hydrogen from Aqueous-phase Reforming of Glycerol Over Supported Metal Catalysts by : Mohammad Mizanur Rahman
Download or read book Selective Synthesis of Hydrogen from Aqueous-phase Reforming of Glycerol Over Supported Metal Catalysts written by Mohammad Mizanur Rahman and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Steam Reforming of Oxygenated Hydrocarbons for Hydrogen Production Over Metal Catalysts by : Sushil Adhikari
Download or read book Steam Reforming of Oxygenated Hydrocarbons for Hydrogen Production Over Metal Catalysts written by Sushil Adhikari and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: With the increase in production of biodiesel, a glut of glycerol has resulted in the world market. Glycerol, once a valuable chemical, has become a recalcitrant byproduct. It is also a potential renewable feedstock for hydrogen production. This study is focused on hydrogen production from glycerol steam reforming. During the initial stage, effect of process variables, such as system pressure (1-5 atm), temperature (327-727 °C) were calculated by the method of Gibbs free energy minimization. The study revealed that the best conditions for producing hydrogen is at temperature> 627 °C, atmospheric pressure, and water/glycerol molar ratio (WGMR) 9:1. As a part of catalysts screening, 14 catalysts were prepared on monoliths and tested for their activity. Effects of those catalysts on hydrogen selectivity and glycerol conversion in temperatures ranging from 600-900 °C were discussed. Ni/Al2O3 and Rh/CeO2/Al2O3 were found to be the best performing catalysts based on hydrogen selectivity and glycerol conversion under the conditions investigated in this study. Also, the effect of WGMR, metal loading, and feed flow rate (FFR) were analyzed for the two best performing catalysts. Subsequently, effect of CeO2, MgO, and TiO2 supported Ni catalysts on hydrogen production from glycerol was studied. Effects of reaction temperature, FFR, and WGMR on hydrogen selectivity and glycerol conversion were also analyzed. Ni/CeO2 was found to be the best performing catalyst when compared to Ni/MgO and Ni/TiO2 under the experimental conditions investigated. The activation energy of glycerol reforming reaction was found to be 103 kJ/mol, and the reaction order with respect to glycerol was 0.23 over Ni/CeO2 catalysts based on the power law.
Book Synopsis Hydrogen Production from Aqueous Phase Reforming Over Carbon Nanotube Supported Catalysts by : Xiaoming Wang
Download or read book Hydrogen Production from Aqueous Phase Reforming Over Carbon Nanotube Supported Catalysts written by Xiaoming Wang and published by . This book was released on 2011 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis STEAM REFORMING OF OXYGENATED HYDROCARBONS FOR HYDROGEN PRODUCTION OVER METAL CATALYSTS. by :
Download or read book STEAM REFORMING OF OXYGENATED HYDROCARBONS FOR HYDROGEN PRODUCTION OVER METAL CATALYSTS. written by and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: With the increase in production of biodiesel, a glut of glycerol has resulted in the world market. Glycerol, once a valuable chemical, has become a recalcitrant byproduct. It is also a potential renewable feedstock for hydrogen production. This study is focused on hydrogen production from glycerol steam reforming. During the initial stage, effect of process variables, such as system pressure (1-5 atm), temperature (327 727 oC), and water/glycerol molar ratio of (1:1-9:1) on hydrogen yield was investigated using a thermodynamic analysis. The equilibrium concentrations of different compounds were calculated by the method of Gibbs free energy minimization. The study revealed that the best conditions for producing hydrogen is at temperature> 627 oC, atmospheric pressure, and water/glycerol molar ratio (WGMR) 9:1. As a part of catalysts screening, 14 catalysts were prepared on monoliths and tested for their activity. Effects of those catalysts on hydrogen selectivity and glycerol conversion in temperatures ranging from 600-900 oC were discussed. Ni/Al2O3 and Rh/CeO2/Al2O3 were found to be the best performing catalysts based on hydrogen selectivity and glycerol conversion under the conditions investigated in this study. Also, the effect of WGMR, metal loading, and feed flow rate (FFR) were analyzed for the two best performing catalysts. Subsequently, effect of CeO2, MgO, and TiO2 supported Ni catalysts on hydrogen production from glycerol was studied. Effects of reaction temperature, FFR, and WGMR on hydrogen selectivity and glycerol conversion were also analyzed. Ni/CeO2 was found to be the best performing catalyst when compared to Ni/MgO and Ni/TiO2 under the experimental conditions investigated. The activation energy of glycerol reforming reaction was found to be 103 kJ/mol, and the reaction order with respect to glycerol was 0.23 over Ni.
Book Synopsis Basic Principles in Applied Catalysis by : Manfred Baerns
Download or read book Basic Principles in Applied Catalysis written by Manfred Baerns and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a team of internationally recognized experts, this book addresses the most important types of catalytic reactions and catalysts as used in industrial practice. Both applied aspects and the essential scientific principles are described. The main topics can be summarized as follows: heterogeneous, homogeneous and biocatalysis, catalyst preparation and characterization, catalytic reaction engineering and kinetics, catalyst deactivation and industrial perspective.
Book Synopsis Aqueous-phase Reforming of Renewables for Selective Hydrogen Production in the Presence of Supported Platinum Catalysts by : Alexey V. Kirilin
Download or read book Aqueous-phase Reforming of Renewables for Selective Hydrogen Production in the Presence of Supported Platinum Catalysts written by Alexey V. Kirilin and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Aqueous-phase Catalytic Conversions of Renewable Feedstocks for Sustainable Biorefineries by : Georgios Papadogianakis
Download or read book Aqueous-phase Catalytic Conversions of Renewable Feedstocks for Sustainable Biorefineries written by Georgios Papadogianakis and published by Frontiers Media SA. This book was released on 2024-08-23 with total page 196 pages. Available in PDF, EPUB and Kindle. Book excerpt: Today, there is growing interest in aqueous-phase catalytic conversions for the valorization of renewable biomass-based feedstocks for biorefineries to produce, in a sustainable way, biofuels, chemicals, power, energy, materials, pharmaceuticals and food. This is because of the highly polar nature of water which makes it an ideal medium to convert polar biomass-based lignocellulose (cellulose, hemicellulose, lignin), with high oxygen content, and their upgraded products such as hydrophilic carbohydrates, platform chemicals and their derivatives. Another reason which makes water the solvent of choice is that water itself is involved either as a reagent or as a byproduct even in large amounts in typical conversions for the valorization of biomass. The obtained intermediates further react in the aqueous medium, often without any separation and purification, to manufacture more valuable products. This results in substantial energy savings, lower emissions and economic benefits. Furthermore, water could act as a catalyst in conversions of biomass-based feedstocks such as in liquefaction reactions under subcritical conditions. Moreover, novel types of catalytic reactivity have been observed in the aqueous solvent, not only with water-soluble transition metal catalytic complexes, but also with conventional heterogeneous catalysts and catalytic nanoparticles in a broad spectrum of different reactions such as, inter alia, aldol condensations and hydrogenation reactions. For example, in the aqueous-phase hydrogenation of the biomass-based key platform chemical levulinic acid into γ-valerolactone and beyond, employing heterogeneous catalysts and nanoparticles the presence of water has a beneficial effect and accelerates the reaction rates, whereas in organic solvents much lower activities were observed. This promotional effect of water in the hydrogenation of levulinic acid was proved by many experimental and theoretical studies using a broad spectrum of different types of catalytic systems.
Download or read book Hydrogen Fuel written by Ram B. Gupta and published by CRC Press. This book was released on 2008-07-30 with total page 626 pages. Available in PDF, EPUB and Kindle. Book excerpt: From Methane to Hydrogen-Making the Switch to a Cleaner Fuel Source The world's overdependence on fossil fuels has created environmental problems, such as air pollution and global warming, as well as political and economic unrest. With water as its only by-product and its availability in all parts of the world, hydrogen promises to be the next grea
Download or read book Biohydrogen written by Thallada Bhaskar and published by Elsevier Inc. Chapters. This book was released on 2013-06-11 with total page 57 pages. Available in PDF, EPUB and Kindle. Book excerpt: Concerns over energy supply security, climate change as well as local air pollution and the increasing prices of energy services are having a growing impact on policy making throughout the world. Today’s energy and transport system, which is based mainly on fossil energy carriers, can in no way be evaluated as sustainable. Increasingly, hydrogen is being promoted as an alternative energy carrier for a sustainable future. For biological H2 systems to become commercially competitive, they must be able to synthesize H2 at rates that are sufficient for practical application. Thermochemical platform provides various efficient methods for conversion of residual biomass (agriculture, forest, and algal) into hydrogen in a single or two stage processes. The processes (gasification, pyrolysis, hydrothermal) and materials/catalysts employed for these processes can be modified to improve the efficiencies for stationary applications/transportation fuel. Integration of various technologies would help in the realisation of hydrogen economy in the future.
Book Synopsis Renewable Hydrogen Technologies by : Luis M Gandia
Download or read book Renewable Hydrogen Technologies written by Luis M Gandia and published by Newnes. This book was released on 2013-05-03 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fields covered by the hydrogen energy topic have grown rapidly, and now it has become clearly multidisciplinary. In addition to production, hydrogen purification and especially storage are key challenges that could limit the use of hydrogen fuel. In this book, the purification of hydrogen with membrane technology and its storage in "solid" form using new hydrides and carbon materials are addressed. Other novelties of this volume include the power conditioning of water electrolyzers, the integration in the electric grid of renewable hydrogen systems and the future role of microreactors and micro-process engineering in hydrogen technology as well as the potential of computational fluid dynamics to hydrogen equipment design and the assessment of safety issues. Finally, and being aware that transportation will likely constitute the first commercial application of hydrogen fuel, two chapters are devoted to the recent advances in hydrogen fuel cells and hydrogen-fueled internal combustion engines for transport vehicles. Hydrogen from water and biomass considered Holistic approach to the topic of renewable hydrogen production Power conditioning of water electrolyzers and integration of renewable hydrogen energy systems considered Subjects not included in previous books on hydrogen energy Micro process technology considered Subject not included in previous books on hydrogen energy Applications of CFD considered Subject not included in previous books on hydrogen energy Fundamental aspects will not be discussed in detail consciously as they are suitably addressed in previous books Emphasis on technological advancements Chapters written by recognized experts Up-to date approach to the subjects and relevant bibliographic references
Book Synopsis Advances in Clean Hydrocarbon Fuel Processing by : M. Rashid Khan
Download or read book Advances in Clean Hydrocarbon Fuel Processing written by M. Rashid Khan and published by Elsevier. This book was released on 2011-09-23 with total page 577 pages. Available in PDF, EPUB and Kindle. Book excerpt: Conventional coal, oil and gas resources used worldwide for power production and transportation are limited and unsustainable. Research and development into clean, alternative hydrocarbon fuels is therefore aimed at improving fuel security through exploring new feedstock conversion techniques, improving production efficiency and reducing environmental impacts. Advances in clean hydrocarbon fuel processing provides a comprehensive and systematic reference on the range of alternative conversion processes and technologies. Following introductory overviews of the feedstocks, environmental issues and life cycle assessment for alternative hydrocarbon fuel processing, sections go on to review solid, liquid and gaseous fuel conversion. Solid fuel coverage includes reviews of liquefaction, gasification, pyrolysis and biomass catalysis. Liquid fuel coverage includes reviews of sulfur removal, partial oxidation and hydroconversion. Gaseous fuel coverage includes reviews of Fischer-Tropsch synthesis, methanol and dimethyl ether production, water-gas shift technology and natural gas hydrate conversion. The final section examines environmental degradation issues in fuel processing plants as well as automation, advanced process control and process modelling techniques for plant optimisation Written by an international team of expert contributors, Advances in clean hydrocarbon fuel processing provides a valuable reference for fuel processing engineers, industrial petrochemists and energy professionals, as well as for researchers and academics in this field. A comprehensive reference on the range of alternative conversion processes and technologies Provides an overview of the feedstocks, environmental issues and life cycle assessments for alternative hydrocarbon fuel processing, including a review of the key issues in solid, liquid and gaseous fuel conversion Examines automation, advanced process control and process modelling techniques for plant optimisation
Book Synopsis Current Trends and Future Developments on (Bio-) Membranes by : Angelo Basile
Download or read book Current Trends and Future Developments on (Bio-) Membranes written by Angelo Basile and published by Elsevier. This book was released on 2020-03-20 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Membrane Systems for Hydrogen Production offers an overview of advanced technologies in the field of both catalysts and membrane technologies for hydrogen productions and energy saving. Catalysts play an irreplaceable role in chemical engineering for carrying out reaction at industrial level. Membrane processes are today well-recognized technologies in many fields, such as water and wastewater treatment, gas separation and purification, etc. This book relates these two fields and their role in electrochemical hydrogen production by presenting 5 specific chapters where the catalysts are compared to the membrane technology. The purpose of this book is to provide an overview on recently developed catalysts which work in combination with membrane operations for energy savings. This combination provides an example of strategies for engineering development and process intensification of interest for both industrial and developing countries. Provides an overview of the interconnections between membrane technology and catalysts related to the electrochemical hydrogen production Provides a comprehensive review of advanced research on the catalysts used in electrochemical processes and the use of related membrane processes Addresses the key issues to introduce considerable process intensification in the hydrogen production
Book Synopsis Hydrogen Production Technologies by : Mehmet Sankir
Download or read book Hydrogen Production Technologies written by Mehmet Sankir and published by John Wiley & Sons. This book was released on 2017-03-20 with total page 653 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.
Book Synopsis Nanocatalysis by : Vivek Polshettiwar
Download or read book Nanocatalysis written by Vivek Polshettiwar and published by John Wiley & Sons. This book was released on 2013-09-06 with total page 670 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exhibiting both homogeneous and heterogeneous catalytic properties, nanocatalysts allow for rapid and selective chemical transformations, with the benefits of excellent product yield and ease of catalyst separation and recovery. This book reviews the catalytic performance and the synthesis and characterization of nanocatalysts, examining the current state of the art and pointing the way towards new avenues of research. Moreover, the authors discuss new and emerging applications of nanocatalysts and nanocatalysis, from pharmaceuticals to fine chemicals to renewable energy to biotransformations. Nanocatalysis features contributions from leading research groups around the world. These contributions reflect a thorough review of the current literature as well as the authors’ first-hand experience designing and synthesizing nanocatalysts and developing new applications for them. The book’s nineteen chapters offer a broad perspective, covering: Nanocatalysis for carbon-carbon and carbon-heteroatom coupling reactions Nanocatalysis for various organic transformations in fine chemical synthesis Nanocatalysis for oxidation, hydrogenation, and other related reactions Nanomaterial-based photocatalysis and biocatalysis Nanocatalysts to produce non-conventional energy such as hydrogen and biofuels Nanocatalysts and nano-biocatalysts in the chemical industry Readers will also learn about the latest spectroscopic and microscopy tools used in advanced characterization methods that shed new light on nanocatalysts and nanocatalysis. Moreover, the authors offer expert advice to help readers develop strategies to improve catalytic performance. Summarizing and reviewing all the most important advances in nanocatalysis over the last two decades, this book explains the many advantages of nanocatalysts over conventional homogeneous and heterogeneous catalysts, providing the information and guidance needed for designing green, sustainable catalytic processes.
Book Synopsis Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals by : Charles E. Wyman
Download or read book Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals written by Charles E. Wyman and published by John Wiley & Sons. This book was released on 2013-03-27 with total page 597 pages. Available in PDF, EPUB and Kindle. Book excerpt: Plant biomass is attracting increasing attention as a sustainable resource for large-scale production of renewable fuels and chemicals. However, in order to successfully compete with petroleum, it is vital that biomass conversion processes are designed to minimize costs and maximize yields. Advances in pretreatment technology are critical in order to develop high-yielding, cost-competitive routes to renewable fuels and chemicals. Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals presents a comprehensive overview of the currently available aqueous pretreatment technologies for cellulosic biomass, highlighting the fundamental chemistry and biology of each method, key attributes and limitations, and opportunities for future advances. Topics covered include: • The importance of biomass conversion to fuels • The role of pretreatment in biological and chemical conversion of biomass • Composition and structure of biomass, and recalcitrance to conversion • Fundamentals of biomass pretreatment at low, neutral and high pH • Ionic liquid and organosolv pretreatments to fractionate biomass • Comparative data for application of leading pretreatments and effect of enzyme formulations • Physical and chemical features of pretreated biomass • Economics of pretreatment for biological processing • Methods of analysis and enzymatic conversion of biomass streams • Experimental pretreatment systems from multiwell plates to pilot plant operations This comprehensive reference book provides an authoritative source of information on the pretreatment of cellulosic biomass to aid those experienced in the field to access the most current information on the topic. It will also be invaluable to those entering the growing field of biomass conversion.
