Homogenous Catalysis By Metal Complexes

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Homogeneous Catalysis with Metal Complexes

Author : Gheorghe Duca
Publisher : Springer Science & Business Media
ISBN 13 : 364224629X
Total Pages : 484 pages
Book Rating : 4.6/5 (422 download)

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Book Synopsis Homogeneous Catalysis with Metal Complexes by : Gheorghe Duca

Download or read book Homogeneous Catalysis with Metal Complexes written by Gheorghe Duca and published by Springer Science & Business Media. This book was released on 2012-06-15 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book about homogeneous catalysis with metal complexes deals with the description of the reductive-oxidative, metal complexes in a liquid phase (in polar solvents, mainly in water, and less in nonpolar solvents). The exceptional importance of the redox processes in chemical systems, in the reactions occuring in living organisms, the environmental processes, atmosphere, water, soil, and in industrial technologies (especially in food-processing industries) is discussed. The detailed practical aspects of the established regularities are explained for solving the specific practical tasks in various fields of industrial chemistry, biochemistry, medicine, analytical chemistry and ecological chemistry. The main scope of the book is the survey and systematization of the latest advances in homogeneous catalysis with metal complexes. It gives an overview of the research results and practical experience accumulated by the author during the last decade.

Homogeneous Catalysis with Metal Complexes

Author : Oleg N. Temkin
Publisher : John Wiley & Sons
ISBN 13 : 1119966825
Total Pages : 963 pages
Book Rating : 4.1/5 (199 download)

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Book Synopsis Homogeneous Catalysis with Metal Complexes by : Oleg N. Temkin

Download or read book Homogeneous Catalysis with Metal Complexes written by Oleg N. Temkin and published by John Wiley & Sons. This book was released on 2012-02-08 with total page 963 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous catalysis by soluble metal complexes has gained considerable attention due to its unique applications and features such as high activity and selectivity. Catalysis of this type has demonstrated impressive achievements in synthetic organic chemistry and commercial chemical technology. Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms presents a comprehensive summary of the results obtained over the last sixty years in the field of the kinetics and mechanisms of organic and inorganic reactions catalyzed with metal complexes. Topics covered include: Specific features of catalytic reaction kinetics in the presence of various mono- and polynuclear metal complexes and nanoclusters Multi-route mechanisms and the methods of their identification, as well as approaches to the kinetics of polyfunctional catalytic systems Principles and features of the dynamic behavior of nonlinear kinetic models The potential, achievements, and limitations of applying the kinetic approach to the identification of complex reaction mechanisms The development of a rational strategy for designing kinetic models The kinetic models and mechanisms of many homogeneous catalytic processes employed in synthetic and commercial chemistry Written for specialists in the field of kinetics and catalysis, this book is also relevant for post-graduates engaged in the study

Computational Modeling of Homogeneous Catalysis

Author : Feliu Maseras
Publisher : Springer Science & Business Media
ISBN 13 : 0306477181
Total Pages : 373 pages
Book Rating : 4.3/5 (64 download)

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Book Synopsis Computational Modeling of Homogeneous Catalysis by : Feliu Maseras

Download or read book Computational Modeling of Homogeneous Catalysis written by Feliu Maseras and published by Springer Science & Business Media. This book was released on 2006-04-11 with total page 373 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent results on a wide array of catalytic processes are collected in this volume. The book illustrates the importance of computational modelling in homogeneous catalysis by providing up-to-date reviews of its application to a variety of reactions of industrial interest.

Homogeneous Catalysis

Author : Piet W.N.M. van Leeuwen
Publisher : Springer Science & Business Media
ISBN 13 : 1402020007
Total Pages : 413 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Homogeneous Catalysis by : Piet W.N.M. van Leeuwen

Download or read book Homogeneous Catalysis written by Piet W.N.M. van Leeuwen and published by Springer Science & Business Media. This book was released on 2006-08-02 with total page 413 pages. Available in PDF, EPUB and Kindle. Book excerpt: No available as softcover No other book available that gives insight into so many reactions of importance, while the field of homogeneous catalysis is becoming more and more important to organic chemists, industrial chemists, and academia. Gives real insight in the many new and old reactions of importance, based on the author's extensive experience in both teaching and industrial practice. Provide background to chemists trained in a different discipline and graduate and masters students who take catalysis as a main or secondary topic.

Heterogenized Homogeneous Catalysts for Fine Chemicals Production

Author : Pierluigi Barbaro
Publisher : Springer Science & Business Media
ISBN 13 : 9048136962
Total Pages : 470 pages
Book Rating : 4.0/5 (481 download)

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Book Synopsis Heterogenized Homogeneous Catalysts for Fine Chemicals Production by : Pierluigi Barbaro

Download or read book Heterogenized Homogeneous Catalysts for Fine Chemicals Production written by Pierluigi Barbaro and published by Springer Science & Business Media. This book was released on 2010-09-02 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: Table 1 E factors (tonnes of waste generated per tonne of product manufactured [7] Industry segment Annual product tonnage E factor 6 8 Oil refining 10 –10 Approx. 0. 1 4 6 Bulk chemicals 10 –10

Homogeneous Catalysis with Metal Phosphine Complexes

Author : Louis M. Pignolet
Publisher : Springer Science & Business Media
ISBN 13 : 1461336236
Total Pages : 494 pages
Book Rating : 4.4/5 (613 download)

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Book Synopsis Homogeneous Catalysis with Metal Phosphine Complexes by : Louis M. Pignolet

Download or read book Homogeneous Catalysis with Metal Phosphine Complexes written by Louis M. Pignolet and published by Springer Science & Business Media. This book was released on 2013-11-21 with total page 494 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of transition metal catalysis has experienced incredible growth during the past decade. The reasons for this are obvious when one considers the world's energy problems and the need for new and less energy demanding syntheses of important chemicals. Heterogeneous catalysis has played a major industrial role; however, such reactions are generally not selective and are exceedingly difficult to study. Homogeneous catalysis suffers from on-site engineering difficulties; however, such reactions usually provide the desired selectivity. For example, Monsanto's synthesis of optically-active amino acids employs a chiral homogeneous rhodium diphosphine catalyst. Industrial uses of homogeneous catalyst systems are increasing. It is not by accident that many homogeneous catalysts contain tertiary phosphine ligands. These ligands possess the correct steric and electronic properties that are necessary for catalytic reactivity and selectivity. This point will be emphasized throughout the book. Thus the stage is set for a comprehensive be treatment of the many ways in which phosphine catalyst systems can designed, synthesized, and studied.

Supported Metal Complexes

Author : F.R. Hartley
Publisher : Springer Science & Business Media
ISBN 13 : 9400952473
Total Pages : 331 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Supported Metal Complexes by : F.R. Hartley

Download or read book Supported Metal Complexes written by F.R. Hartley and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 331 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is now IS years since the first patents in polymer supported metal complex catalysts were taken out. In the early days ion-exchange resins were used to support ionic metal complexes. Soon covalent links were developed, and after an initially slow start there was a period of explosive growth in the mid to late 1970s during which virtually every homogeneous metal complex catalyst ever reported was also studied bound to a support. Both polymers and inorganic oxides were studied as supports, although the great preponderance of workers studied polymeric supports, and of these polystyrene was by far the commonest used. This period served to show that by very careful design polymer-supported metal complex catalysts could have specific advantages over homogeneous metal complex catalysts. However the subject was a complicated one. Merely immobilising a successful metal complex catalyst to a functionalised support rarely yielded other than an inferior version of the catalyst. Amongst the many discouraging results of the 1970s, there were more than enough results that were sufficiently encouraging to demonstrate that, by careful design, supported metal complex catalysts could be prepared in which both the metal complex and the support combined together to produce an active catalyst which, due to the combination of support and complex, had advantages of activity, selectivity and specificity not found in homogeneous catalysts. Thus a new generation of catalysts was being developed.

Industrial Applications of Homogeneous Catalysis

Author : A. Mortreux
Publisher : Springer Science & Business Media
ISBN 13 : 9400938977
Total Pages : 371 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Industrial Applications of Homogeneous Catalysis by : A. Mortreux

Download or read book Industrial Applications of Homogeneous Catalysis written by A. Mortreux and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysts are now widely used in both laboratory and industrial-scale chemistry. Indeed, it is hard to find any complex synthesis or industrial process that does not, at some stage, utilize a catalytic reaction. The development of homogeneous transition metal catalysts on the laboratory scale has demonstrated that these systems can be far superior to the equivalent heterogeneous systems, at least in terms of selectivity. is an increasing interest in this field of research from both an Thus, there academic and industrial point of view. In connection with the rapid developments in this area, four universities from the E.E.C (Aachen, FRG; Liege, Belgium; Milan, Italy; and Lille, France) have collaborated to organise a series of seminars for high-level students and researchers. These meetings have been sponsored by the Commission of the E.E.C and state organizations. The most recent of these meetings was held in Lille in September 1985 and this book contains updated and expanded presentations of most of the lectures given there. These lectures are concerned with the field of homogeneous transition metal catalysis and its application to the synthesis of organic intermediates and fine chemicals from an academic and industrial viewpoint. The continuing petroleum crisis which began in the early 1970s has given rise to the need to develop new feedstocks for the chemical industry.

Theoretical Aspects of Homogeneous Catalysis

Author : Piet W.N.M. van Leeuwen
Publisher : Springer Science & Business Media
ISBN 13 : 9401104751
Total Pages : 219 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Theoretical Aspects of Homogeneous Catalysis by : Piet W.N.M. van Leeuwen

Download or read book Theoretical Aspects of Homogeneous Catalysis written by Piet W.N.M. van Leeuwen and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: This publication is the first to present the quantitative application of quantum chemistry to organometallic reactions. Great progress has been made in recent years in the calculation of transition states of organometallic conversions in both homo and heterogeneous catalysis. This volume, which contains seven contributions by leading scientists, deals with key reactions of homogeneous catalysis including oxidative addition, migratory insertions, 2+2 additions, the Wacker reaction, and epoxidation. The book provides experimental chemists with an up-to-date overview of the state of the art in this field, and will stimulate an adjustment of views previously based on semiempirical calculations. For researchers and advanced graduate students whose work involves organometallics and catalysis.

Homogeneous Catalysis

Author : George William Parshall
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 262 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Homogeneous Catalysis by : George William Parshall

Download or read book Homogeneous Catalysis written by George William Parshall and published by John Wiley & Sons. This book was released on 1980 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contains a balanced discussion of homogeneous catalytic reactions that are used in industry, featuring every documented example employed in a current commercial process, or that have a broad application in the organic synthesis laboratory. Incorporates synthesis with chiral catalysts in chapters on hydrogenation, CO chemistry and olefin oxidation. New additions include Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol process for dimerizing propylene as well as major changes in the areas on pharmaceuticals, flavors, fragrances, agricultural and electronic chemicals.

Homogeneous Catalysis

Author : George William Parshall
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 262 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Homogeneous Catalysis by : George William Parshall

Catalyst Separation, Recovery and Recycling

Author : David J. Cole-Hamilton
Publisher : Springer Science & Business Media
ISBN 13 : 9781402040863
Total Pages : 270 pages
Book Rating : 4.0/5 (48 download)

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Book Synopsis Catalyst Separation, Recovery and Recycling by : David J. Cole-Hamilton

Download or read book Catalyst Separation, Recovery and Recycling written by David J. Cole-Hamilton and published by Springer Science & Business Media. This book was released on 2006-01-13 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book looks at new ways of tackling the problem of separating reaction products from homogeneous catalytic solutions. The new processes involve low leaching supported catalysts, soluble supports such as polymers and dendrimers and unusual solvents such as water, fluorinated organics, ionic liquids and supercritical fluids. The advantages of the different possibilities are discussed alongside suggestions for further research that will be required for commercialisation. Unlike other books, in addition to the chemistry involved, the book looks at the process design that would be required to bring the new approaches to fruition. Comparisons are given with existing processes that have already been successfully applied and examples are given where these approaches are not suitable. The book includes: - New processes for the separation of products from solutions containing homogeneous catalysts - Catalysts on insoluble or soluble supports – fixed bed catalysts - continuous flow or ultrafiltration - Biphasic systems: water - organic, fluorous - organic, ionic liquid – organic, supercritical fluids (monophasic or biphasic with water, organic or ionic liquid) - Comparisons with current processes involving atmospheric or low temperature distillation - Consideration of Chemistry and Process Design - Advantages and disadvantages of each process exposed - Consideration of what else is need for commercialisation

Homogeneous Catalysis

Author : George W. Parshall
Publisher : Wiley-Interscience
ISBN 13 :
Total Pages : 368 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Homogeneous Catalysis by : George W. Parshall

Download or read book Homogeneous Catalysis written by George W. Parshall and published by Wiley-Interscience. This book was released on 1992-08-07 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt: The broadening technical advances in the production of pharmaceuticals, flavors, and fragrances have more than doubled the industrial applications of soluble transition metal catalysts. Indeed, transition metal catalysts have become an ascendant feature of a heightened academic interest in organometallic chemistry. This Second Edition of the landmark text offers a clear, systematic look at the state-of-the-science of homogeneous catalytic reactions. Focusing on specific processes, rather than principles of coordination or organometallic chemistry, this updated edition is an A-to-Z compilation of the homogeneous catalytic reactions commonly used in industry or that have broad application in the organic synthesis laboratory. Documenting examples of homogeneous catalytic reactions used in current commercial processes, this newest edition features Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol processes for dimerizing propylene as well as Du Pont's hydrocyanation process. Detailed coverage also includes isomerization of simple olefins, mechanism of olefin hydrogenation, oligomerization of olefins, chain transfer catalysis, reactions of carbon monoxide, specialty chemicals, reactions of acetylenes, esterification, polycondensation, and related processes. Featuring the latest findings in its existing coverage on pharmaceuticals, agricultural chemicals, flavors, fragrances, and electronic chemicals, this Second Edition clearly details the science's growing influence and practicality in industry and the lab. Organic and inorganic chemists, instructors, and students will find Homogeneous Catalysis, Second Edition a clear, up-to-date compendium of the catalytic reactionssharpening chemistry's cutting edge.

Alkane C-H Activation by Single-Site Metal Catalysis

Author : Pedro J. Pérez
Publisher : Springer Science & Business Media
ISBN 13 : 9048136989
Total Pages : 277 pages
Book Rating : 4.0/5 (481 download)

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Book Synopsis Alkane C-H Activation by Single-Site Metal Catalysis by : Pedro J. Pérez

Download or read book Alkane C-H Activation by Single-Site Metal Catalysis written by Pedro J. Pérez and published by Springer Science & Business Media. This book was released on 2012-09-15 with total page 277 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C−H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds. Alkane C-H Activation by Single-Site Metal Catalysis presents the current state-of-the-art development in the catalytic systems for the catalytic trans-formations of alkanes under homogeneous conditions. Chapter 1 offers a comprehensive summary of the main discoveries realized so far. Chapter 2 reviews the so-called electrophilic activation, initiated by Shulpín in the late 60s, and the base for the Catalytica system. Chapter 3 examines the catalytic borylation of alkanes, discovered by Hartwig, whereas chapter 4 provides an updated vision of the alkane dehydrogenation reaction. Chapter 5 covers the oxygenation of C-H bonds, a field of enormous interest with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. The history of C-H bond activation, and the current research described in this book, highlight the current research and present the reader with an outlook of this field which continues to be explored by an increasingly visionary and enthusiastic group of organic, organometallic, biological and physical chemists.

Homogeneous Catalysis with Compounds of Rhodium and Iridium

Author : R. Dickson
Publisher : Springer Science & Business Media
ISBN 13 : 9400952678
Total Pages : 293 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Homogeneous Catalysis with Compounds of Rhodium and Iridium by : R. Dickson

Download or read book Homogeneous Catalysis with Compounds of Rhodium and Iridium written by R. Dickson and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Some years ago, I agreed to contribute a volume to the Academic Press 'Organo metallic Chemistry' series - the metals to be covered were rhodium and iridium. Initially, my plan was to discuss both the fundamental organometallic chemistry and applications in organic synthesis. When the first draft of the manuscript was complete, it was apparent that I had exceeded my allowance of pages by a huge amount. It was then that I decided that the catalysis section warranted separate treatment. I am grateful to Reidel for agreeing to publish this volume on Homogeneous Catalysis with Compounds of Rhodium and Iridium as part of their 'Catalysis by Metal Complexes' series. The material I had for the original Academic Press project covered the litera ture to the end of 1978. I decided to update this to the end of 1982 with a few key references from 1983. It is some measure of the rate of progress in this field that the number of references almost doubled during this revision.

Advances in Catalytic Activation of Dioxygen by Metal Complexes

Author : László I. Simándi
Publisher : Springer Science & Business Media
ISBN 13 : 0306478161
Total Pages : 349 pages
Book Rating : 4.3/5 (64 download)

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Book Synopsis Advances in Catalytic Activation of Dioxygen by Metal Complexes by : László I. Simándi

Download or read book Advances in Catalytic Activation of Dioxygen by Metal Complexes written by László I. Simándi and published by Springer Science & Business Media. This book was released on 2006-04-11 with total page 349 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject of dioxygen activation and homogeneous catalytic oxidation by metal complexes has been in the focus of attention over the last 20 years. The widespread interest is illustrated by its recurring presence among the sessions and subject areas of important international conferences on various aspects of bioinorganic and coordination chemistry as well as catalysis. The most prominent examples are ICCC, ICBIC, EUROBIC, ISHC, and of course the ADHOC series of meetings focusing on the subject itself. Similarly, the number of original and review papers devoted to various aspects of dioxygen activation are on the rise. This trend is due obviously to the relevance of catalytic oxidation to biological processes such as dioxygen transport, and the action of oxygenase and oxidase enzymes related to metabolism. The structural and functional modeling of metalloenzymes, particularly of those containing iron and copper, by means of low-molecular complexes of iron, copper, ruthenium, cobalt, manganese, etc., have provided a wealth of indirect information helping to understand how the active centers of metalloenzymes may operate. The knowledge gained from the study of metalloenzyme models is also applicable in the design of transition metal complexes as catalytsts for specific reactions. This approach has come to be known as biomimetic or bioinspired catalysis and continues to be a fruitful and expanding area of research.

Homogeneous Hydrogenation

Author : P.A. Chaloner
Publisher : Springer Science & Business Media
ISBN 13 : 9401717915
Total Pages : 293 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Homogeneous Hydrogenation by : P.A. Chaloner

Download or read book Homogeneous Hydrogenation written by P.A. Chaloner and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous hydrogenation is one of the most thoroughly studied fields of homogeneous catalysis. The results of these studies have proved to be most important for an understanding of the underlying principles of the activation of small molecules by transition metal complexes. During the past three decades homogeneous hydrogenation has found widespread application in organic chemistry, including the production of important pharmaceuticals, especially where a sophisticated degree of selectivity is required. This volume presents a general account of the main principles and applications of homogeneous hydrogenation by transition metal complexes. Special attention is devoted to the mechanisms by which these processes occur, and the role of the recently discovered complexes of molecular hydrogen is described. Sources of hydrogen, other than H2, are also considered (transfer hydrogenation). The latest achievements in highly stereoselective hydrogenations have made possible many new applications in organic synthesis. These applications are documented by giving details of the reduction of important unsaturated substrates (alkenes, alkynes, aldehydes and ketones, nitrocompounds, etc.). Hydrogenation in biphasic and phase transfer catalyzed systems is also described. Finally, a discussion of the biochemical routes of H2 activation highlights the similarities and differences in performing hydrogenation in both natural and synthetic systems. For researchers working in the fields of homogeneous catalysis, especially in areas such as pharmaceuticals, plastics and fine chemicals.