Growth And Characterization Of Metal Polymer Interfaces

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Growth and Characterization of Metal/polymer Interfaces

Author : Kabul S. Sengupta
Publisher :
ISBN 13 :
Total Pages : 330 pages
Book Rating : 4.:/5 (261 download)

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Book Synopsis Growth and Characterization of Metal/polymer Interfaces by : Kabul S. Sengupta

Download or read book Growth and Characterization of Metal/polymer Interfaces written by Kabul S. Sengupta and published by . This book was released on 1991 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: A number of metal/polyimide interfaces such as Ti, Al, and Ni/Polyimide systems were studied to determine their chemistry, structure, and stability in various environments. The Au/Cu/Ti/Polyimide (sputtered) system delaminated in a hydrogen environment at elevated temperatures. The delaminated planes were characterized and the failure loci were found to be at the Ti-Polyimide interdiffusion zone/polyimide interface. Precipitation of titanium hydride during anneals in hydrogen atmospheres caused large interfacial stresses which lead to failure. No delamination was observed when the metallization was done on an unsputtered polyimide substrate. The effects of ion bombardment on the structure and chemistry of the polyimide were studied using X-ray Photoelectron Spectroscopy. The surface chemistry of the polyimide was severely altered by the ion bombardment. In addition to a decrease in the oxygen concentration (particularly from the carbonyl) and amorphous carbon formation due to dehydrogenation and bond scission, a net negative surface charge was found due to unbonded anions created on the surface. Aluminum and nickel were deposited in situ in the X-ray Photoelectron Spectrometer on the polyimide and the chemistry of the developing interface was studied as a function of metal film thickness. Aluminum was found to interact with the carbonyl group by charge transfer followed by Al-O-C formation. The chemical interaction of nickel was limited to a thermally reversible charge transfer process with PMDA, carbonyl and the ODA groups. Unlike aluminum, nickel diffused into the polyimide at 600 K. Both metals exhibit island or Volmer-Weber type of growth on the polyimide.

Polymer Surfaces and Interfaces: Characterization, Modification and Application

Author : Kash L. Mittal
Publisher : CRC Press
ISBN 13 : 1466563702
Total Pages : 435 pages
Book Rating : 4.4/5 (665 download)

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Book Synopsis Polymer Surfaces and Interfaces: Characterization, Modification and Application by : Kash L. Mittal

Download or read book Polymer Surfaces and Interfaces: Characterization, Modification and Application written by Kash L. Mittal and published by CRC Press. This book was released on 2023-01-06 with total page 435 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymeric materials are used for a legion of applications in a wide array of technological areas, and their proper surface/interface characteristics are of cardinal importance for their applications. Therefore, the need to characterize polymer surfaces/interfaces and their suitable modification to impart desired characteristics is quite patent. This book chronicles the proceedings of the Symposium on Polymer Surfaces and Interfaces: Characterization, Modification and Application held as a part of the Society of Plastics Engineers Annual Technical Conference, Boston, May 7--11, 1995. The articles in this book address many aspects of polymer surfaces and interfaces. Topics covered include: various ways (chemical, photochemical, laser, flame, corona) to modify polymer surfaces; modification of contact lens surfaces; various ways to analyze/characterize polymer surfaces; metal/polymer interfaces; metal/polyimide adhesion; metal/self-assembled organic monolayer interfaces; polymer alignment layers for liquid crystals; alignment of liquid crystal surfaces; polyimide alignment layers; molecular re-orientation of polymer surfaces; plasma polymerized organic coatings; epoxy/fiber interphase; epoxy underfill materials for packaging integrated circuits; transport in polymers; polymer miscibility; and cell adhesion.

Molecular-Level Synthesis and Characterization of Metal-Polymer Interfaces

Author : Shaw L. Ling
Publisher :
ISBN 13 :
Total Pages : 17 pages
Book Rating : 4.:/5 (227 download)

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Book Synopsis Molecular-Level Synthesis and Characterization of Metal-Polymer Interfaces by : Shaw L. Ling

Download or read book Molecular-Level Synthesis and Characterization of Metal-Polymer Interfaces written by Shaw L. Ling and published by . This book was released on 1987 with total page 17 pages. Available in PDF, EPUB and Kindle. Book excerpt: Two separate, but interacting research groups began a program entailing molecular level syntheses and characterization of metal-polymer interfaces. Two general synthetic routes were followed: In one case, a metal surface (platinum) was cleaned of its oxide layer by carrying out a hydrogenation reaction (hexene or cyclohexene) using the metal surface as the catalyst. Under these conditions, platinum oxide is unstable and is reduced to platinum(0) and water. The reaction was then deliberately poisoned with 4-picoline. Monitoring the kinetics of hydrogenation before and after the addition of the poison allowed us to determine that approx. 70% of the hydrogenation sites were ligated. The amount of 4-picoline that adsorbed was determined by elemental analysis, gravimetric analysis and UV-vis analysis of the solution. The surface-confined picoline was then deprotonated to render the ligated lithium reagent which was used to initiate the polymerization of styrene. The thin film of polystyrene prepared in this manner was irreversibly attached to the platinum surface. The platinum-polystyrene interface was studied by a range of analytical techniques. The platinum-polystyrene interface was studied by a range of analytical techniques. In the other case, a metal-polymer interface was prepared by polymer adsorption: Polystyrene containing one terminal thiol group and styrene-propylene sulfide block copolymers were allowed to adsorb on evaporated gold films supported on glass. The resulting supported films were characterized by x-ray photoelectron spectroscopy, external reflectance infrared spectroscopy and scintillation counting of radioisotope-labeled polymers.

Characterization of Metal and Polymer Surfaces V2

Author : Lieng-Huang Lee
Publisher : Elsevier
ISBN 13 : 0323148700
Total Pages : 482 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Characterization of Metal and Polymer Surfaces V2 by : Lieng-Huang Lee

Download or read book Characterization of Metal and Polymer Surfaces V2 written by Lieng-Huang Lee and published by Elsevier. This book was released on 2012-12-02 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: Characterization of Metal and Polymer Surfaces, Volume 2: Polymer Surfaces presents the proceedings of the Symposium on Advances in Characterization of Metal and Polymer Surfaces, held in New York, on April 5–8, 1976. This book provides information pertinent to surface science and discusses the applications of surface analyses to polymer technology. Organized into four parts encompassing 21 chapters, this volume starts with an overview of the measurement of binding energies and chemical shifts, which remain a relevant aspect of electron microscopy for organic and inorganic compounds. This text then explores the capability of electron spectroscopy for chemical analysis (ESCA) as a spectroscopic tool that enables the features of structure and bonding in surface, subsurface, and bulk regions of polymer systems to be elaborated. Other chapters consider the surface and interfacial properties of polymers, which are significant in various biomedical applications. This book is a valuable resource for analytical and polymer chemists.

Metal-polymer Interfaces

Author : Jan M. Stouffer
Publisher :
ISBN 13 :
Total Pages : 286 pages
Book Rating : 4.:/5 (188 download)

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Book Synopsis Metal-polymer Interfaces by : Jan M. Stouffer

Download or read book Metal-polymer Interfaces written by Jan M. Stouffer and published by . This book was released on 1988 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Polymer Surface Characterization

Author : Luigia Sabbatini
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 311070109X
Total Pages : 403 pages
Book Rating : 4.1/5 (17 download)

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Book Synopsis Polymer Surface Characterization by : Luigia Sabbatini

Download or read book Polymer Surface Characterization written by Luigia Sabbatini and published by Walter de Gruyter GmbH & Co KG. This book was released on 2022-01-19 with total page 403 pages. Available in PDF, EPUB and Kindle. Book excerpt: This fully updated edition provides a broad approach to the surface analysis of polymers being of high technological interest. Modern analytical techniques, potential applications and recent advances in instrumental apparatus are discussed. The self-consistent chapters are devoted to techniques from photoelectron spectroscopy to electron microscopies and wettability.

Properties and Characterization of Modern Materials

Author : Andreas Öchsner
Publisher : Springer
ISBN 13 : 981101602X
Total Pages : 450 pages
Book Rating : 4.8/5 (11 download)

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Book Synopsis Properties and Characterization of Modern Materials by : Andreas Öchsner

Download or read book Properties and Characterization of Modern Materials written by Andreas Öchsner and published by Springer. This book was released on 2016-07-30 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on robust characterization and prediction methods for materials in technical applications as well as the materials’ safety features during operation. In particular, it presents methods for reliably predicting material properties, an aspect that is becoming increasingly important as engineering materials are pushed closer and closer to their limits to boost the performance of machines and structures. To increase their engineering value, components are now designed under the consideration of their multiphysical properties and functions, which requires much more intensive investigation and characterization of these materials. The materials covered in this monograph range from metal-based groups such as lightweight alloys, to advanced high-strength steels and modern titanium alloys. Furthermore, a wide range of polymers and composite materials (e.g. with micro- and nanoparticles or fibres) is covered. The book explores methods for property prediction from classical mechanical characterization-related fields of application, for example, from wear, creep, fatigue and crack growth, to specific surface properties, to dielectric and electrochemical values. As in all fields of modern engineering, the process is often accompanied by numerical simulation and optimization.

Molecular Soft-Interface Science

Author : Mizuo Maeda
Publisher : Springer
ISBN 13 : 4431568778
Total Pages : 219 pages
Book Rating : 4.4/5 (315 download)

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Book Synopsis Molecular Soft-Interface Science by : Mizuo Maeda

Download or read book Molecular Soft-Interface Science written by Mizuo Maeda and published by Springer. This book was released on 2019-05-09 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive treatment of the molecular design, characterization, and physical chemistry of soft interfaces. At the same time, the book aims to encourage the fabrication of functional materials including biomaterials. During the past few decades there has been steady growth in soft-interface science, and that growth has been especially rapid in the twenty-first century. The field is interdisciplinary because it involves chemistry, polymer science, materials science, physical chemistry, and biology. Based on the increasing interdisciplinary nature of undergraduate and graduate programs, the primary goal of this present work is to serve as a comprehensive resource for senior-level undergraduates and for graduate students, particularly in polymer chemistry, materials science, bioconjugate chemistry, bioengineering, and biomaterials. Additionally, with the growing interest in the fabrication of functional soft materials, this book provides essential fundamental information for researchers not only in academia but also in industry.

Scientific and Technical Aerospace Reports

Author :
Publisher :
ISBN 13 :
Total Pages : 704 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Scientific and Technical Aerospace Reports by :

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1995 with total page 704 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Handbook of Surfaces and Interfaces of Materials, Five-Volume Set

Author : Hari Singh Nalwa
Publisher : Elsevier
ISBN 13 : 0080533825
Total Pages : 1915 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Handbook of Surfaces and Interfaces of Materials, Five-Volume Set by : Hari Singh Nalwa

Download or read book Handbook of Surfaces and Interfaces of Materials, Five-Volume Set written by Hari Singh Nalwa and published by Elsevier. This book was released on 2001-10-26 with total page 1915 pages. Available in PDF, EPUB and Kindle. Book excerpt: This handbook brings together, under a single cover, all aspects of the chemistry, physics, and engineering of surfaces and interfaces of materials currently studied in academic and industrial research. It covers different experimental and theoretical aspects of surfaces and interfaces, their physical properties, and spectroscopic techniques that have been applied to a wide class of inorganic, organic, polymer, and biological materials. The diversified technological areas of surface science reflect the explosion of scientific information on surfaces and interfaces of materials and their spectroscopic characterization. The large volume of experimental data on chemistry, physics, and engineering aspects of materials surfaces and interfaces remains scattered in so many different periodicals, therefore this handbook compilation is needed.The information presented in this multivolume reference draws on two decades of pioneering research on the surfaces and interfaces of materials to offer a complete perspective on the topic. These five volumes-Surface and Interface Phenomena; Surface Characterization and Properties; Nanostructures, Micelles, and Colloids; Thin Films and Layers; Biointerfaces and Applications-provide multidisciplinary review chapters and summarize the current status of the field covering important scientific and technological developments made over past decades in surfaces and interfaces of materials and spectroscopic techniques with contributions from internationally recognized experts from all over the world. Fully cross-referenced, this book has clear, precise, and wide appeal as an essential reference source long due for the scientific community. The complete reference on the topic of surfaces and interfaces of materialsThe information presented in this multivolume reference draws on two decades of pioneering researchProvides multidisciplinary review chapters and summarizes the current status of the fieldCovers important scientific and technological developments made over past decades in surfaces and interfaces of materials and spectroscopic techniquesContributions from internationally recognized experts from all over the world

Chemical Characterization of Steel/polymer Interfaces

Author : Octavio Cervantes
Publisher :
ISBN 13 :
Total Pages : 144 pages
Book Rating : 4.:/5 (515 download)

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Book Synopsis Chemical Characterization of Steel/polymer Interfaces by : Octavio Cervantes

Download or read book Chemical Characterization of Steel/polymer Interfaces written by Octavio Cervantes and published by . This book was released on 2002 with total page 144 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Polymer Surfaces and Interfaces II

Author : W. J. Feast
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 328 pages
Book Rating : 4.:/5 (44 download)

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Book Synopsis Polymer Surfaces and Interfaces II by : W. J. Feast

Download or read book Polymer Surfaces and Interfaces II written by W. J. Feast and published by John Wiley & Sons. This book was released on 1993-04-28 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: A collection of review papers which give an up-to-date interdisciplinary view of current technology and research on polymer surfaces. Contributors are drawn from both academia and industry, and represent a cross-section of subject interests.

Polymer Interface and Adhesion

Author : Wu
Publisher : Routledge
ISBN 13 : 1351423525
Total Pages : 654 pages
Book Rating : 4.3/5 (514 download)

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Book Synopsis Polymer Interface and Adhesion by : Wu

Download or read book Polymer Interface and Adhesion written by Wu and published by Routledge. This book was released on 2017-11-22 with total page 654 pages. Available in PDF, EPUB and Kindle. Book excerpt: Poly mer Interface and Adhesion provides the critical basis for further advancement in thisfield. Combining the principles of interfacial science, rheology, stress analysis, and fracturemechanics, the book teaches a new approach to the analysis of long standing problemssuch as: how is the interface formed; what are its physical and mechanical properties;and how does the interface modify the stress field and fracture strength of the material.The book offers many outstanding features, including extensive listings of pertinent references,exhaustive tabulations of the interfacial properties of polymers, critical reviews ofthe many conflicting theories, and complete discussions of coupling agents, adhesion promotion,and surface modifications. Emphasis is placed on physical concepts and mechanisms,using clear, understandable mathematics.Polymer Interface and Adhesion promotes a more thorough understanding of the physical,mechanical, and adhesive properties of multiphase, polymer systems. Polymer scientistsand engineers, surface chemists, materials scientists, rheologists, as well as chemical andmechanical engineers interested in the research, development or industrial applications ofpolymers, plastics, fibers, coatings, adhesives, and composites need this important newsource book.

Development of Surface Interactions at Polymer-Metal Interfaces

Author : J. S. Solomon
Publisher :
ISBN 13 :
Total Pages : 139 pages
Book Rating : 4.:/5 (227 download)

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Book Synopsis Development of Surface Interactions at Polymer-Metal Interfaces by : J. S. Solomon

Download or read book Development of Surface Interactions at Polymer-Metal Interfaces written by J. S. Solomon and published by . This book was released on 1979 with total page 139 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: Introduction; Metal Adherend Surfaces -- Aluminum Alloys - Oxide Characterization; Elemental Distribution - Phosphorus, Copper, Magnesium; Titanium Alloys; Graphite Fibers; Bond Joint Characterization; Instrumental Modification -- Secondary Ion Mass Spectroscopy, and Auger Electron Spectroscopy.

Metallization of Polymers 2

Author : Edward Sacher
Publisher : Springer Science & Business Media
ISBN 13 : 1461505631
Total Pages : 208 pages
Book Rating : 4.4/5 (615 download)

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Book Synopsis Metallization of Polymers 2 by : Edward Sacher

Download or read book Metallization of Polymers 2 written by Edward Sacher and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: As the demands put on the polymer/metal interface, particularly by the microelectronics industry, become more and more severe, the necessity for understanding this interface, its properties and its limitations, becomes more and more essential. This requires a broad knowledge of, and a familiarity with, the latest findings in this rapidly advancing field. At the very least, such familiarity requires an exchange of infonnation, particularly among those intimately involved in this field. Communications among many of us in this area have made one fact quite obvious: the facilities provided by existing organizations, scientific and otherwise, do not offer the forum necessary to accomplish this exchange of infonnation. It was for this reason that Jean-Jacques Pireaux, Steven Kowalczyk and I organized the first Metallization of Polymers, a symposium sponsored by the American Chemical Society, which took place in Montreal, September 25-28, 1989; the Proceedings from that symposium were published as ACS Symposium Series 440, (1990). It is this same per ceived lack of a proper forum, and the encouragement of my colleagues, that prompted me to organize this meeting, so as to bring to the attention of the participants new instruments, materials, methods, advances, and, particularly, thoughts in the field of polymer metalliza tion. The meeting was designed as a workshop, with time being made available throughout for discussion and for the consideration of new findings.

Polymer/Metal Interfaces and Defect Mediated Phenomena in Ordered Polymers: Volume 734

Author : Evangelos D. Manias
Publisher : Mrs Proceedings
ISBN 13 :
Total Pages : 488 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Polymer/Metal Interfaces and Defect Mediated Phenomena in Ordered Polymers: Volume 734 by : Evangelos D. Manias

Download or read book Polymer/Metal Interfaces and Defect Mediated Phenomena in Ordered Polymers: Volume 734 written by Evangelos D. Manias and published by Mrs Proceedings. This book was released on 2003-04-10 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.

Advanced Materials Interfaces

Author : Ashutosh Tiwari
Publisher : John Wiley & Sons
ISBN 13 : 1119242746
Total Pages : 528 pages
Book Rating : 4.1/5 (192 download)

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Book Synopsis Advanced Materials Interfaces by : Ashutosh Tiwari

Download or read book Advanced Materials Interfaces written by Ashutosh Tiwari and published by John Wiley & Sons. This book was released on 2016-07-15 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Material Interfaces is a state-of-the-art look at innovative methodologies and strategies adopted for interfaces and their applications. The 13 chapters are written by eminent researchers not only elaborate complex interfaces fashioned of solids, liquids, and gases, but also ensures cross-disciplinary mixture and blends of physics, chemistry, materials science, engineering and life sciences. Advanced interfaces operate fundamental roles in essentially all integrated devices. It is therefore of the utmost urgency to focus on how newly-discovered fundamental constituents and interfacial progressions can be materialized and used for precise purposes. Interfaces are associated in wide multiplicity of application spectrum from chemical catalysis to drug functions and the advancement is funnelled by fine-tuning of our fundamental understanding of the interface effects.