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Functional Materials Based On Redox Active Components
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Book Synopsis Functional Materials Based on Redox-active Components by : Kristen M. Milum
Download or read book Functional Materials Based on Redox-active Components written by Kristen M. Milum and published by . This book was released on 2010 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: Conducting polymers have been extensively investigated in a wide range of applications due to their ability to achieve near metallic conductivity while possessing the flexibility and processability of traditional polymers. However, interchain and solid-state effects have made direct investigation of the polymer systems difficult. A series of systematically varied model compounds have been designed to provide detailed information about through-chain charge transport in well-defined oligothiophenes. Our design incorporates two metal binding pockets at either end of an oligothiophene bridge to investigate the interaction of redox centers and charge transport properties between conducting polymers and bound transition metal centers. Synthesis, characterization, electrochemistry, and detailed EPR investigations of this new series of oligothiophene model compounds and the analogous mononuclear compounds will be discussed herein. Conjugated polymer matrices possess a large number of available oxidation states making them an attractive choice for use as redox-active ligands. This variety of oxidation states offers a means to easily tune the amount of electron density on a metal center and consequently affect the binding of an additional ligand. Our approach utilizes conducting metallopolymers with metal complexes synthetically incorporated directly into the conducting polymer backbone. The redox-dependent properties of this class of materials and their development as small molecule storage and delivery systems have been explored utilizing a variety of novel electropolymerizable transition metal complexes. The design, synthesis, characterization, and redox-affected properties of the monomers, corresponding conducting metallopolymers, and model complexes are discussed. The tub-shaped dibenzo[a, e]cyclooctatetraene molecule undergoes a large change in geometry upon reduction to form the planar aromatic species. Herein, we seek to prepare and investigate a supramolecular assembly utilizing this redox-active molecule. In contrast to electrochemically active frameworks where redox changes occur at the metal centers, incorporation of a functionalized dibenzo[a, e]cyclooctatetraene ligand into an assembly has the potential to result in a redox-active framework. Not only would the redox-activity occur at the organic bridge, but reduction of the system should result in a large geometry change.
Book Synopsis Advanced Functional Materials Based on Metal-organic Frameworks by : Olesia Kozachuk
Download or read book Advanced Functional Materials Based on Metal-organic Frameworks written by Olesia Kozachuk and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Redox Systems Under Nano-Space Control by : Toshikazu Hirao
Download or read book Redox Systems Under Nano-Space Control written by Toshikazu Hirao and published by Springer Science & Business Media. This book was released on 2006-08-02 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: The generation of novel redox systems under nano-space control is one of the most exciting fields in present organic, inorganic, and supramolecular chemistry. The authors have drawn together the newest information on the construction of such novel redox systems using nano-space control of complexation or molecular chain-induced spaces and metal- or self-assembled spaces through combining techniques in coordination, supramolecular, and bio-inspired chemistry. Such design on the nano level produces hybrid conjugated systems composed of transition and synthetic metals, metallohosts, redox-active self-assembled monolayers of helical peptides, DNA-directed metal arrays, photoactive antibody systems, chiral rotaxanes, and redox-active imprinted polymers. In the future, these systems will be the basis for novel selective electron-transfer reactions as well as new functional materials and catalysts.
Book Synopsis Polyoxometalate-Based Assemblies and Functional Materials by : Yu-Fei Song
Download or read book Polyoxometalate-Based Assemblies and Functional Materials written by Yu-Fei Song and published by Springer. This book was released on 2018-03-24 with total page 168 pages. Available in PDF, EPUB and Kindle. Book excerpt: The authors of this volume concentrate on the recent progress of novel polyoxometalate (POM) syntheses, as well as advances made in catalytic, electrochemical, and sensing systems. The state-of-the-art techniques such as flow system and gel-electrophoresis for the discovery of POMs are covered with a detailed discussion. Of particular importance, the application of POM-based materials in photo-sensing, heterogeneous catalysis, energy conservation and storage, and gas separation is reviewed. Over the past few years, POM chemistry has witnessed a remarkable progress with more than 1500 papers published each year. Due to their intrinsic structural features, POMs are considered as versatile building blocks for the construction of sophisticated complex assemblies and advanced multi-functional materials. Various strategies, methods, and techniques have been adopted to develop POM-based materials with intriguing properties and excellent performance. All the contributors to this volume are young, vibrant chemists in this research field and all the works are carefully collected from the authors’ years of experience. This volume serves as an essential reference for every POM chemist and is of great interest to new researchers who wish to learn more about this area.
Book Synopsis Electrochromism by : Paul M. S. Monk
Download or read book Electrochromism written by Paul M. S. Monk and published by John Wiley & Sons. This book was released on 2008-09-26 with total page 239 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochromic devices have a number of important commercial applications, for instance in displays, as optical shutters, and as modulators for mirrors, windows, and sun-glasses. Electrochromism - Fundamentals and Applications is the first in-depth treatise on the topic. Written by leading scientists in the field, it is a state-of-the-art account of all aspects of electrochromism, presented at a level accessible to chemists, physicists, materials scientists and engineers. Both the physical and chemical background of electrochromic phenomena are described and a comprehensive survey of both organic and inorganic compounds and systems is given. Special emphasis is placed on providing detailed, hands-on information on applications and potential uses of electrochromic systems. This book is essential reading for scientists active in the field and for anyone wishing to enter the field. An extensive list of carefully chosen references rounds off this valuable reference source.
Book Synopsis Functional Molecular Materials by : Matteo Atzori
Download or read book Functional Molecular Materials written by Matteo Atzori and published by CRC Press. This book was released on 2018-04-17 with total page 351 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of molecular materials represents an exciting playground for the design, tailoring, and combination of chemical building blocks as carriers of physical properties and aims at the understanding and development of novel functional molecular devices. Within this extraordinarily widespread framework, the realization of materials with the desired functionalities can only be achieved through a rational design strategy based on a solid understanding of the chemical and physical features of each constituting building block. This book provides a general overview of molecular materials, discussing their key features in a simple and organic way by focusing more on basic concepts rather than on specialized descriptions, in order to supply the non-expert reader with the immediate fundamental tools and hints to understand and develop research in this field. With this view, it is a step-by-step guide toward the preparation of functional molecular materials, where the knowledge and understanding so far attained by the scientific community through the investigation of significant archetypical examples is deconstructed down to the fundamental basis and then presented in reverse, from the base to the top.
Book Synopsis Sustainable and Functional Redox Chemistry by : Shinsuke Inagi
Download or read book Sustainable and Functional Redox Chemistry written by Shinsuke Inagi and published by Royal Society of Chemistry. This book was released on 2022-04-29 with total page 403 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mimicking nature's efficiency and sustainability in organic chemistry is a major goal for future chemists; redox reactions are a key element in a variety of fields ranging from synthesis and catalysis to materials chemistry and analytical applications. Sustainability is increasingly becoming a consideration in synthesis and functional chemistry and an essential element for the next generation of chemistry in academia and industry. This book represents a compilation of the latest advancements in functional redox chemistry and demonstrates its importance in achieving a more sustainable future. This book is an ideal companion for any postgraduate students or researchers interested in sustainability in academia and industry.
Book Synopsis Organic Redox Systems by : Tohru Nishinaga
Download or read book Organic Redox Systems written by Tohru Nishinaga and published by John Wiley & Sons. This book was released on 2015-11-25 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing a thorough overview of leading research from internationally-recognized contributing authors, this book describes methods for the preparation and application of redox systems for organic electronic materials like transistors, photovoltaics, and batteries. Covers bond formation and cleavage, supramolecular systems, molecular design, and synthesis and properties Addresses preparative methods, unique structural features, physical properties, and material applications of redox active p-conjugated systems Offers a useful guide for both academic and industrial chemists involved with organic electronic materials Focuses on the transition-metal-free redox systems composed of organic and organo main group compounds
Book Synopsis Applications of Porphyrinoids as Functional Materials by : Heinrich Lang
Download or read book Applications of Porphyrinoids as Functional Materials written by Heinrich Lang and published by Royal Society of Chemistry. This book was released on 2021-08-10 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt: Porphyrinoids are pyrrole-containing macrocycles with varied core sizes, which have found many applications beyond the original chemical and biological aspects. Porphyrin research has a long history, covering a wide variety of disciplines of natural sciences, including photosynthesis, P450-related biocatalysis, organic photovoltaic cells, photodynamic therapeutic agents, bioimaging probes, chemosensors, conductive organic materials, light-emitting materials, near-infrared dyes, nonlinear optical materials, information storage, molecular wires, and metal ligands. This book gives an overview of the applications and potential applications of porphyrins and related macrocycles as smart or functional materials. Chapters cover applications in fields such as energy storage and transfer, water purification, molecular electronics and imaging. With contributions from leading global researchers, this title will be of interest to graduate students and researchers across materials science, chemistry, physics and medicine.
Book Synopsis Organic Redox Systems by : Tohru Nishinaga
Download or read book Organic Redox Systems written by Tohru Nishinaga and published by John Wiley & Sons. This book was released on 2015-11-25 with total page 627 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing a thorough overview of leading research from internationally-recognized contributing authors, this book describes methods for the preparation and application of redox systems for organic electronic materials like transistors, photovoltaics, and batteries. Covers bond formation and cleavage, supramolecular systems, molecular design, and synthesis and properties Addresses preparative methods, unique structural features, physical properties, and material applications of redox active p-conjugated systems Offers a useful guide for both academic and industrial chemists involved with organic electronic materials Focuses on the transition-metal-free redox systems composed of organic and organo main group compounds
Book Synopsis Sustainable and Functional Redox Chemistry by : Shinsuke Inagi
Download or read book Sustainable and Functional Redox Chemistry written by Shinsuke Inagi and published by Royal Society of Chemistry. This book was released on 2022-04-29 with total page 403 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mimicking nature's efficiency and sustainability in organic chemistry is a major goal for future chemists; redox reactions are a key element in a variety of fields ranging from synthesis and catalysis to materials chemistry and analytical applications. Sustainability is increasingly becoming a consideration in synthesis and functional chemistry and an essential element for the next generation of chemistry in academia and industry. This book represents a compilation of the latest advancements in functional redox chemistry and demonstrates its importance in achieving a more sustainable future. This book is an ideal companion for any postgraduate students or researchers interested in sustainability in academia and industry.
Book Synopsis Functional Materials in Amperometric Sensing by : Renato Seeber
Download or read book Functional Materials in Amperometric Sensing written by Renato Seeber and published by Springer. This book was released on 2014-12-29 with total page 235 pages. Available in PDF, EPUB and Kindle. Book excerpt: Amperometric sensors, biosensors included, particularly rely on suitable electrode materials. Progress in material science has led to a wide variety of options that are available today. For the first time, these novel functional electrode coating materials are reviewed in this monograph, written by and for electroanalytical chemists. This includes intrinsically conducting, redox and ion-exchange polymers, metal and carbon nanostructures, silica based materials. Monolayers and relatively thick films are considered. The authors critically discuss preparation methods, in addition to chemical and physical characteristics of these new materials. They present various examples of emerging applications in electroanalysis. Due to its comprehensive coverage, the book will become an indispensable source for researchers working on the development and even proper use of new amperometric sensor systems.
Book Synopsis Recent Advances in Redox Active Plant and Microbial Products by : Claus Jacob
Download or read book Recent Advances in Redox Active Plant and Microbial Products written by Claus Jacob and published by Springer. This book was released on 2014-11-25 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nature endows us with a treasure chest of Green Gold full of amazing ‘redox-active’ substances which interfere with numerous biological processes in our own body, in animals, bacteria, fungi and plants. Whilst such natural products are all around and also in us, we still do not fully understand how these compounds actually work. This book attempts to resolve some of the mysteries and riddles associated with such products. Written by more than thirty international experts from academia and industry, it places a focus on modern developments in this field and considers such natural products from various angles, from their isolation and characterization all along to product development and commercialization. Throughout, the reader will be confronted with modern approaches which enable the efficient identification and isolation of new natural products, help to elucidate their mode(s) of action and permit practical uses in Medicine, Cosmetics, Agriculture, Industry and as functional foods.
Book Synopsis Redox Polymers for Energy and Nanomedicine by : Nerea Casado
Download or read book Redox Polymers for Energy and Nanomedicine written by Nerea Casado and published by Royal Society of Chemistry. This book was released on 2020-10-20 with total page 575 pages. Available in PDF, EPUB and Kindle. Book excerpt: Redox Polymers for Energy and Nanomedicine highlights trends in the chemistry, characterization and application of polymers with redox properties.
Book Synopsis Metal–Molecular Assembly for Functional Materials by : Yutaka Matsuo
Download or read book Metal–Molecular Assembly for Functional Materials written by Yutaka Matsuo and published by Springer Science & Business Media. This book was released on 2013-09-03 with total page 94 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on modern coordination chemistry, covering porous coordination polymers, metalloproteins, metallopeptides, nanoclusters, nanocapsules, aligned polymers, and fullerenes. As well, it deals with applications to electronic devices and surface characterization. These wide-ranging topics are integrally described from the perspectives of dimensionality (one-, two-, and three-dimension), new materials design, synthesis, molecular assembly, function and application. The nine chapters making up this book have been authored by scientists who are at the cutting edge of research in this particular field. The level is appropriate for graduate students, post-doc researchers, and new faculty members whose aim is to become familiar with modern coordination chemistry from its basics to applications.
Book Synopsis Functional Materials for Sustainable Energy Applications by : J A Kilner
Download or read book Functional Materials for Sustainable Energy Applications written by J A Kilner and published by Elsevier. This book was released on 2012-09-28 with total page 715 pages. Available in PDF, EPUB and Kindle. Book excerpt: Global demand for low cost, efficient and sustainable energy production is ever increasing. Driven by recent discoveries and innovation in the science and technology of materials, applications based on functional materials are becoming increasingly important. Functional materials for sustainable energy applications provides an essential guide to the development and application of these materials in sustainable energy production. Part one reviews functional materials for solar power, including silicon-based, thin-film, and dye sensitized photovoltaic solar cells, thermophotovoltaic device modelling and photoelectrochemical cells. Part two focuses on functional materials for hydrogen production and storage. Functional materials for fuel cells are then explored in part three where developments in membranes, catalysts and membrane electrode assemblies for polymer electrolyte and direct methanol fuel cells are discussed, alongside electrolytes and ion conductors, novel cathodes, anodes, thin films and proton conductors for solid oxide fuel cells. Part four considers functional materials for demand reduction and energy storage, before the book concludes in part five with an investigation into computer simulation studies of functional materials. With its distinguished editors and international team of expert contributors, Functional materials for sustainable energy applications is an indispensable tool for anyone involved in the research, development, manufacture and application of materials for sustainable energy production, including materials engineers, scientists and academics in the rapidly developing, interdisciplinary field of sustainable energy. An essential guide to the development and application of functional materials in sustainable energy production Reviews functional materials for solar power Focuses on functional materials for hydrogen production and storage, fuel cells, demand reduction and energy storage
Book Synopsis Functional Organic Materials by : Thomas J. J. Müller
Download or read book Functional Organic Materials written by Thomas J. J. Müller and published by John Wiley & Sons. This book was released on 2007-02-12 with total page 622 pages. Available in PDF, EPUB and Kindle. Book excerpt: This timely overview of the syntheses for functional pi-systems focuses on target molecules that have shown interesting properties as materials or models in physics, biology and chemistry. The unique concept allows readers to select the right synthetic strategy for success, making it invaluable for a number of industrial applications. A "must have" for everyone working in this new and rapidly expanding field.