Fluidized Bed Steam Reforming Mineralization for High Organic and Nitrate Waste Streams for the Global Nuclear Energy Partnership

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (893 download)

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Book Synopsis Fluidized Bed Steam Reforming Mineralization for High Organic and Nitrate Waste Streams for the Global Nuclear Energy Partnership by :

Download or read book Fluidized Bed Steam Reforming Mineralization for High Organic and Nitrate Waste Streams for the Global Nuclear Energy Partnership written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Waste Forms Technology and Performance

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Publisher : National Academies Press
ISBN 13 : 0309187338
Total Pages : 308 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Waste Forms Technology and Performance by : National Research Council

Download or read book Waste Forms Technology and Performance written by National Research Council and published by National Academies Press. This book was released on 2011-09-05 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Department of Energy's Office of Environmental Management (DOE-EM) is responsible for cleaning up radioactive waste and environmental contamination resulting from five decades of nuclear weapons production and testing. A major focus of this program involves the retrieval, processing, and immobilization of waste into stable, solid waste forms for disposal. Waste Forms Technology and Performance, a report requested by DOE-EM, examines requirements for waste form technology and performance in the cleanup program. The report provides information to DOE-EM to support improvements in methods for processing waste and selecting and fabricating waste forms. Waste Forms Technology and Performance places particular emphasis on processing technologies for high-level radioactive waste, DOE's most expensive and arguably most difficult cleanup challenge. The report's key messages are presented in ten findings and one recommendation.

Materials for Nuclear Waste Immobilization

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Publisher : MDPI
ISBN 13 : 3039218468
Total Pages : 220 pages
Book Rating : 4.0/5 (392 download)

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Book Synopsis Materials for Nuclear Waste Immobilization by : Michael I. Ojovan

Download or read book Materials for Nuclear Waste Immobilization written by Michael I. Ojovan and published by MDPI. This book was released on 2020-01-09 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book outlines recent advances in nuclear wasteform materials including glasses, ceramics and cements and spent nuclear fuel. It focuses on durability aspects and contains data on performance of nuclear wasteforms as well as expected behavior in a disposal environment.

Radioactive Waste Management and Contaminated Site Clean-Up

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Publisher : Elsevier
ISBN 13 : 085709744X
Total Pages : 925 pages
Book Rating : 4.8/5 (57 download)

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Book Synopsis Radioactive Waste Management and Contaminated Site Clean-Up by : William E Lee

Download or read book Radioactive Waste Management and Contaminated Site Clean-Up written by William E Lee and published by Elsevier. This book was released on 2013-10-31 with total page 925 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radioactive waste management and contaminated site clean-up reviews radioactive waste management processes, technologies, and international experiences. Part one explores the fundamentals of radioactive waste including sources, characterisation, and processing strategies. International safety standards, risk assessment of radioactive wastes and remediation of contaminated sites and irradiated nuclear fuel management are also reviewed. Part two highlights the current international situation across Africa, Asia, Europe, and North America. The experience in Japan, with a specific chapter on Fukushima, is also covered. Finally, part three explores the clean-up of sites contaminated by weapons programmes including the USA and former USSR.Radioactive waste management and contaminated site clean-up is a comprehensive resource for professionals, researchers, scientists and academics in radioactive waste management, governmental and other regulatory bodies and the nuclear power industry. - Explores the fundamentals of radioactive waste including sources, characterisation, and processing strategies - Reviews international safety standards, risk assessment of radioactive wastes and remediation of contaminated sites and irradiated nuclear fuel management - Highlights the current international situation across Africa, Asia, Europe, and North America specifically including a chapter on the experience in Fukushima, Japan

Fluidized Bed Stream Reforming of Organic and Nitrate Containing Salt Supernate

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Publisher :
ISBN 13 :
Total Pages : 5 pages
Book Rating : 4.:/5 (684 download)

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Book Synopsis Fluidized Bed Stream Reforming of Organic and Nitrate Containing Salt Supernate by :

Download or read book Fluidized Bed Stream Reforming of Organic and Nitrate Containing Salt Supernate written by and published by . This book was released on 2004 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: A salt supernate waste (Tank 48H) generated at the Savannah River Site (SRS) during demonstration of In Tank Precipitation (ITP) process for Cs removal contains nitrates, nitrites, and sodium tetraphenyl borate (NaTPB). This slurry must be pre-processed in order to reduce the impacts of the nitrate and organic species on subsequent vitrification in the Defense Waste Processing Facility (DWPF). Fluidized Bed Steam Reforming (FBSR) is a candidate technology for destroying the nitrates, nitrites, and organics (NaTPB) prior to melting. Bench scale tests were designed and conducted at the Savannah River National Laboratory (SRNL) to demonstrate that bench scale testing can adequately reproduce the CO/CO2 and H2/H2O fugacities representative of the FBSR process and form the appropriate product phases. Carbonate and silicate product phases that were compatible with DWPF vitrification were achieved in the bench scale testing and test parameters were optimized for a pilot scale FBSR demonstration.

FLUIDIZED BED STEAM REFORMING TECHNOLOGY FOR ORGANIC AND NITRATE SALT SUPERNATE.

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis FLUIDIZED BED STEAM REFORMING TECHNOLOGY FOR ORGANIC AND NITRATE SALT SUPERNATE. by :

Download or read book FLUIDIZED BED STEAM REFORMING TECHNOLOGY FOR ORGANIC AND NITRATE SALT SUPERNATE. written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: About two decades ago a process was developed at the Savannah River Site (SRS) to remove Cs137 from radioactive high level waste (HLW) supernates so the supernates could be land disposed as low activity waste (LAW). Sodium tetraphenylborate (NaTPB) was used to precipitate Cs137 as CsTPB. The flowsheet called for destruction of the organic TPB by acid hydrolysis so that the Cs137 enriched residue could be mixed with other HLW sludge, vitrified, and disposed of in a federal geologic repository. The precipitation process was demonstrated full scale with actual HLW waste and a 2.5 wt% Cs137 rich precipitate containing organic TPB was produced admixed with 240,000 gallons of salt supernate. Organic destruction by acid hydrolysis proved to be problematic and other disposal technologies were investigated. Fluidized Bed Steam Reforming (FBSR), which destroys organics by pyrolysis, is the current baseline technology for destroying the TPB and the waste nitrates prior to vitrification. Bench scale tests were designed and conducted at the Savannah River National Laboratory (SRNL) to reproduce the pyrolysis reactions. The formation of alkali carbonate phases that are compatible with DWPF waste pre-processing and vitrification were demonstrated in the bench scale tests. Test parameters were optimized for a pilot scale FBSR demonstration that was performed at the SAIC Science & Technology Application Research (STAR) Center in Idaho Falls, ID by Idaho National Laboratory (INL) and SRNL in 2003. An engineering scale demonstration was completed by THOR{reg_sign} Treatment Technologies (TTT) and SRNL in 2006 at the Hazen Research, Inc. test facility in Golden, CO. The same mineral carbonate phases, the same organic destruction (& gt;99.99%) and the same nitrate/nitrite destruction (>99.99%) were produced at the bench scale, pilot scale, and engineering scale although different sources of carbon were used during testing.

FLUIDIZED BED STEAM REFORMER MONOLITH FORMATION.

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (316 download)

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Book Synopsis FLUIDIZED BED STEAM REFORMER MONOLITH FORMATION. by : C. Jantzen

Download or read book FLUIDIZED BED STEAM REFORMER MONOLITH FORMATION. written by C. Jantzen and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Fluidized Bed Steam Reforming (FBSR) is being considered as an alternative technology for the immobilization of a wide variety of aqueous high sodium containing radioactive wastes at various DOE facilities in the United States. The addition of clay, charcoal, and a catalyst as co-reactants converts aqueous Low Activity Wastes (LAW) to a granular or ''mineralized'' waste form while converting organic components to CO{sub 2} and steam, and nitrate/nitrite components, if any, to N{sub 2}. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage-like structures that atomically bond radionuclides like Tc-99 and anions such as SO{sub 4}, I, F, and Cl. The granular product has been shown to be as durable as LAW glass. Shallow land burial requires that the mineralized waste form be able to sustain the weight of soil overburden and potential intrusion by future generations. The strength requirement necessitates binding the granular product into a monolith. FBSR mineral products were formulated into a variety of monoliths including various cements, Ceramicrete, and hydroceramics. All but one of the nine monoliths tested met the

MINERALIZING, STEAM REFORMING TREATMENT OF HANFORD LOW-ACTIVITY WASTE (a.k.a. INEEL/EXT-05-02526).

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (16 download)

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Book Synopsis MINERALIZING, STEAM REFORMING TREATMENT OF HANFORD LOW-ACTIVITY WASTE (a.k.a. INEEL/EXT-05-02526). by :

Download or read book MINERALIZING, STEAM REFORMING TREATMENT OF HANFORD LOW-ACTIVITY WASTE (a.k.a. INEEL/EXT-05-02526). written by and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The U.S. Department of Energy (DOE) documented, in 2002, a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years. A key element of the plan was acceleration of the tank waste program and completion of ''tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (WTP) and using supplemental technologies for waste treatment and immobilization.'' The plan identified steam reforming technology as a candidate for supplemental treatment of as much as 70% of the low-activity waste (LAW). Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was completed in a 15-cm-diameter reactor vessel. The pilot scale facility was equipped with a cyclone separator and heated sintered metal filters for particulate removal, a thermal oxidizer for reduced gas species and NOx destruction, and a packed activated carbon bed for residual volatile species capture. The pilot scale equipment is owned by the DOE, but located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Pilot scale testing was performed August 2-5, 2004. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory (INEEL), Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Science Application International Corporation, owners of the STAR Center, personnel performed actual pilot scale operation. The pilot scale test achieved a total of 68.4 hours of cumulative/continuous processing operation before termination in response to a bed de-fluidization condition. 178 kg of LAW surrogate were processed that resulted in 148 kg of solid product, a mass reduction of about 17%. The process achieved essentially complete bed turnover within approximately 40 hours. Samples of mineralized solid product materials were analyzed for chemical/physical properties. SRNL will report separately the results of product performance testing that were accomplished.

Radionuclide and Contaminant Immobilization in the Fluidized Bed Steam Reforming Waste Product

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (115 download)

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Book Synopsis Radionuclide and Contaminant Immobilization in the Fluidized Bed Steam Reforming Waste Product by : James J. Neeway

Download or read book Radionuclide and Contaminant Immobilization in the Fluidized Bed Steam Reforming Waste Product written by James J. Neeway and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Radionuclide and Contaminant Immobilization in the Fluidized Bed Steam Reforming Waste Product.

Radionuclide and Contaminant Immobilization in the Fluidized Bed Steam Reforming Waste Product

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Publisher :
ISBN 13 : 9789535105510
Total Pages : pages
Book Rating : 4.1/5 (55 download)

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Book Synopsis Radionuclide and Contaminant Immobilization in the Fluidized Bed Steam Reforming Waste Product by : James J. Neeway

Download or read book Radionuclide and Contaminant Immobilization in the Fluidized Bed Steam Reforming Waste Product written by James J. Neeway and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fluidized Bed Calcination Experience with Simulated Commercial High-level Nuclear Waste

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Publisher :
ISBN 13 :
Total Pages : 65 pages
Book Rating : 4.:/5 (543 download)

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Book Synopsis Fluidized Bed Calcination Experience with Simulated Commercial High-level Nuclear Waste by : William J. Bjorklund

Download or read book Fluidized Bed Calcination Experience with Simulated Commercial High-level Nuclear Waste written by William J. Bjorklund and published by . This book was released on 1976 with total page 65 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Cementitious Materials for Nuclear Waste Immobilization

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Publisher : John Wiley & Sons
ISBN 13 : 1118512006
Total Pages : 245 pages
Book Rating : 4.1/5 (185 download)

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Book Synopsis Cementitious Materials for Nuclear Waste Immobilization by : Rehab O. Abdel Rahman

Download or read book Cementitious Materials for Nuclear Waste Immobilization written by Rehab O. Abdel Rahman and published by John Wiley & Sons. This book was released on 2014-11-17 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cementitious materials are an essential part in any radioactive waste disposal facility. Conditioning processes such as cementation are used to convert waste into a stable solid form that is insoluble and will prevent dispersion to the surrounding environment. It is incredibly important to understand the long-term behavior of these materials. This book summarises approaches and current practices in use of cementitious materials for nuclear waste immobilisation. It gives a unique description of the most important aspects of cements as nuclear waste forms: starting with a description of wastes, analyzing the cementitious systems used for immobilization and describing the technologies used, and ending with analysis of cementitious waste forms and their long term behavior in an envisaged disposal environment. Extensive research has been devoted to study the feasibility of using cement or cement based materials in immobilizing and solidifying different radioactive wastes. However, these research results are scattered. This work provides the reader with both the science and technology of the immobilization process, and the cementitious materials used to immobilize nuclear waste. It summarizes current knowledge in the field, and highlights important areas that need more investigation. The chapters include: Introduction, Portland cement, Alternative cements, Cement characterization and testing, Radioactive waste cementation, Waste cementation technology, Cementitious wasteform durability and performance assessment.

Bulletin of the Atomic Scientists

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ISBN 13 :
Total Pages : 64 pages
Book Rating : 4./5 ( download)

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Book Synopsis Bulletin of the Atomic Scientists by :

Download or read book Bulletin of the Atomic Scientists written by and published by . This book was released on 1972-10 with total page 64 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Bulletin of the Atomic Scientists is the premier public resource on scientific and technological developments that impact global security. Founded by Manhattan Project Scientists, the Bulletin's iconic "Doomsday Clock" stimulates solutions for a safer world.

Industrial Environmental Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 1489923209
Total Pages : 310 pages
Book Rating : 4.4/5 (899 download)

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Book Synopsis Industrial Environmental Chemistry by : Donald T. Sawyer

Download or read book Industrial Environmental Chemistry written by Donald T. Sawyer and published by Springer Science & Business Media. This book was released on 2013-12-11 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph consists of manuscripts submitted by invited speakers who participated in the symposium "Industrial Environmental Chemistry: Waste Minimization in Industrial Processes and Remediation of Hazardous Waste," held March 24-26, 1992, at Texas A&M University. This meeting was the tenth annual international symposium sponsored by the Texas A&M Industry-University Cooperative Chemistry Program (IUCCP). The program was developed by an academic-industrial steering committee consisting of the co-chairmen, Professors Donald T. Sawyer and Arthur E. Martell of the Texas A&M University Chemistry Department, and members appointed by the sponsoring companies: Bernie A. Allen, Jr., Dow Chemical USA; Kirk W. Brown, Texas A&M University; Abraham Clearfield, Texas A&M University; Greg Leyes, Monsanto Company; Jay Warner, Hoechst-Celanese Corporation; Paul M. Zakriski, BF Goodrich Company; and Emile A. Schweikert, Texas A&M University (IUCCP Coordinator). The subject of this conference reflects the interest that has developed in academic institutions and industry for technological solutions to environmental contamination by industrial wastes. Progress is most likely with strategies that minimize waste production from industrial processes. Clearly the key to the protection and preservation of the environment will be through R&D that optimizes chemical processes to minimize or eliminate waste streams. Eleven of the papers are directed to waste minimization. An additional ten papers discuss chemical and biological remediation strategies for hazardous wastes that contaminate soils, sludges, and water.

New and Future Developments in Catalysis

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Publisher : Newnes
ISBN 13 : 0444538739
Total Pages : 493 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis New and Future Developments in Catalysis by : Steven L Suib

Download or read book New and Future Developments in Catalysis written by Steven L Suib and published by Newnes. This book was released on 2013-07-19 with total page 493 pages. Available in PDF, EPUB and Kindle. Book excerpt: New and Future Developments in Catalysis is a package of seven books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes.The use of solar energy during various catalytic chemical processes for the production of an array of chemical products is the theme of this volume. Photocatalysis is a topic of increasing importance due to its essential role in many of today's environmental and energy source problems. The use of solar energy for catalytic reactions results in a carbon dioxide–neutral process. All photocatalytic processes and the future developments in this area are discussed, including an economic analysis of the various processes. - Offers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areas - A clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular case - Outlines the catalytic processes applicable to energy generation and design of green processes

Applications of Biochar for Environmental Safety

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Publisher : BoD – Books on Demand
ISBN 13 : 178985895X
Total Pages : 278 pages
Book Rating : 4.7/5 (898 download)

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Book Synopsis Applications of Biochar for Environmental Safety by : Ahmed Abdelhafez

Download or read book Applications of Biochar for Environmental Safety written by Ahmed Abdelhafez and published by BoD – Books on Demand. This book was released on 2020-07-22 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biochar is a carbon-rich material produced from the pyrolysis of organic materials from agricultural and forestry biomass at a relatively low temperature in the absence of oxygen. As such, it has potential for solving many agricultural and environmental problems.This book is divided into five sections: “Introduction,” “Production and Legislation of Biochar,” “Applications of Biochar for Soil Fertility Improvement,” “Role of Biochar for Soil Remediation and Ameliorating Salinity Effects” and “Applications of Biochar for Water Treatment.” Chapters address topics such as the pros and cons of biochar, its production, and its role in remediating and treating contaminated soils and water.

Water Recycling and Resource Recovery in Industry

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Publisher : IWA Publishing
ISBN 13 : 9781843390053
Total Pages : 736 pages
Book Rating : 4.3/5 (9 download)

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Book Synopsis Water Recycling and Resource Recovery in Industry by : Piet Lens

Download or read book Water Recycling and Resource Recovery in Industry written by Piet Lens and published by IWA Publishing. This book was released on 2002-03-31 with total page 736 pages. Available in PDF, EPUB and Kindle. Book excerpt: Water Recycling and Resource Recovery in Industry: Analysis, Technologies and Implementation provides a definitive and in-depth discussion of the current state-of-the-art tools and technologies enabling the industrial recycling and reuse of water and other resources. The book also presents in detail how these technologies can be implemented in order to maximize resource recycling in industrial practice, and to integrate water and resource recycling in ongoing industrial production processes. Special attention is given to non-process engineering aspects such as systems analysis, software tools, health, regulations, life-cycle analysis, economic impact and public participation. Case studies illustrate the huge potential of environmental technology to optimise resource utilisation in industry. The large number of figures, tables and case studies, together with the book's multidisciplinary approach, makes Water Recycling and Resource Recovery in Industry: Analysis, Technologies and Implementation the perfect reference work for academics, professionals and consultants dealing with industrial water resources recovery. Contents Part I: Industrial reuse for environmental protection Part II: System analysis to assist in closing industrial resource cycles Part III: Characterisation of process water quality Part IV: Technological aspects of closing industrial cycles Part V: Examples of closed water cycles in industrial processes Part VI: Resource protection policies in industry