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Experimental Studies Of Bimolecular Reaction Dynamics Using Pulsed Tabletop Vacuum Ultraviolet Photoionization Detection
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Book Synopsis Experimental Studies of Bimolecular Reaction Dynamics Using Pulsed Tabletop Vacuum Ultraviolet Photoionization Detection by : Daniel Russell Albert
Download or read book Experimental Studies of Bimolecular Reaction Dynamics Using Pulsed Tabletop Vacuum Ultraviolet Photoionization Detection written by Daniel Russell Albert and published by . This book was released on 2013 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development and application of pulsed photoionization detection employing high intensity vacuum-ultraviolet (VUV) radiation produced by tabletop light sources has been utilized to study bimolecular reaction dynamics of phenyl radical reactions. This method employs four-wave mixing of unfocussed commercial nanosecond dye lasers in mercury vapor to generate light at 9.9 eV. Using two or three commercial pulsed nanosecond dye lasers pumped by a single 30 Hz Nd:YAG laser, generation of 0.10 mJ pulses at 125 nm (6 x 1013 photons/pulse) has been demonstrated. The VUV light source has been used as an alternative to the use of synchrotron light sources, for sensitive universal photoionization detection of products from crossed molecular beam reactions employing pulsed beam sources. In the reaction of phenyl radicals with molecular oxygen at collision energies of 64 and 97 kJ/mol, the reaction C6H5 + O2 [RIGHTWARDS ARROW] C6H5O + O was found to occur via the formation of long-lived phenylperoxy collision complexes at all collision energies. The reaction of phenyl radicals with propene has also been studied at collision energies of 84 and 108 kJ/mol. The branching ratios between methyl radical elimination, forming C8H8, and H-atom elimination, forming C9H10, were found to be 10:1 at 84 kJ/mol and 3:1 at 108 kJ/mol. By using "soft" vacuum ultraviolet photoionization at 9.9 eV for product detection, we were able to observe both product channels with negligible fragmentation. As a comparison the reaction of phenyl radicals with trans-2-butene has been studied at a collision energy of 97 kJ/mol. We only observe methyl elimination in the reaction with 2-butene and do not observe H-atom elimination.
Book Synopsis Vacuum Ultraviolet Photoionization And Photodissociation Of Molecules And Clusters by : Cheuk-yiu Ng
Download or read book Vacuum Ultraviolet Photoionization And Photodissociation Of Molecules And Clusters written by Cheuk-yiu Ng and published by World Scientific. This book was released on 1991-06-25 with total page 582 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph reviews the recent progress in vacuum ultraviolet (VUV) photoionization and photodissociation processes. Photoionization, photoelectron, and fluorescence spectroscopic techniques have played an important role in revealing the photoionization and photodissociation dynamics of molecules in the vacuum ultraviolet region and in providing accurate energetic and spectroscopic information of ions as well as neutral molecules. The book represents the first detailed review of major experimental developments in the studies of single vacuum ultraviolet photon ionization and dissociation processes of gaseous molecules and clusters.
Book Synopsis Dynamics of Molecular Photodissociation Studied Using Coherent Vacuum Ultraviolet by : Michael Aaron Todt
Download or read book Dynamics of Molecular Photodissociation Studied Using Coherent Vacuum Ultraviolet written by Michael Aaron Todt and published by . This book was released on 2017 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Ultrafast Molecular Dynamics Studied with Vacuum Ultraviolet Pulses by : Travis William Wright
Download or read book Ultrafast Molecular Dynamics Studied with Vacuum Ultraviolet Pulses written by Travis William Wright and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Studying the ultrafast dynamics of small molecules can serve as the first step in understanding the dynamics in larger chemically and biologically relevant molecules. To make direct comparisons with existing computational techniques, the photons used in pump-probe spectroscopy must make perturbative transitions between the electronic states of isolated small molecules. In this dissertation experimental investigations of ultrafast dynamics in electronic excitations of neutral ethylene and carbon dioxide are discussed. These experiments are performed using VUV/XUV femtosecond pulses as pump and probe. To make photons with sufficient energy for single photon transitions, VUV and XUV light is generated by high harmonic generation (HHG) using a high pulse energy ([approximately] 30 - 40 mJ) Ti:sapphire femtosecond laser. Sufficient flux must be generated to enable splitting of the HHG light into pump and probe arms. The system produces > 1010 photons per shot, corresponding to nearly 10 MW of peak power in the XUV. Using a high flux of high energy photons creates a unique set of challenges when designing a detector capable of performing pump-probe experiments. A velocity map imaging (VMI) detector has been designed to address these challenges, and has become a successful tool facilitating studies into molecular dynamics that were not possible before its implementation. The emphasis on using high energy, single photon transitions allowed theoretical calculations to be directly compared to experimental yields for the first time. This comparison resolved a long standing issue in the excited state lifetime of ethylene, and provided a confirmation of the branching ratio between the two nonadiabatic relaxation pathways that return ethylene back to its ground state from the [pi]*. The participation of the 3s Rydberg state has also been measured by collecting the time resolved photoelectron spectrum during the dynamics on ethylene [pi]* excited state, confirming calculations predicting the effect of the 3s. In carbon dioxide the first time resolved measurement in the lowest electronic excitation of carbon dioxide has been performed. A high kinetic energy release channel shows the signature of wavepacket dynamics within the excited state manifold. Deviation from the direct dissociation predicted for the pumped state provides experimental evidence confirming theoretical predictions of nonadiabatic transitions within the lowest lying electronically excited states.
Book Synopsis Femtosecond Molecular Dynamics Studied with Vacuum Ultraviolet Pulse Pairs by : Thomas K. Allison III
Download or read book Femtosecond Molecular Dynamics Studied with Vacuum Ultraviolet Pulse Pairs written by Thomas K. Allison III and published by . This book was released on 2010 with total page 238 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atoms and molecules have most of their oscillator strength in the vacuum ultraviolet (VUV) and extreme ultraviolet (XUV), between the wavelengths of 200 nm and 30 nm. However, most femtosecond spectroscopy has been restricted to the visible and infrared due to a lack of sufficiently intense VUV and XUV femtosecond light sources. This thesis discusses extensions of pump/probe spectroscopy to the VUV and XUV, and its application to the dynamics of ethylene and oxygen molecules excited at 161 nm. I begin with a detailed discussion of the short wavelength light source used in this work. The source is based on the high order harmonics of a near infrared laser and can deliver> 1010 photons per shot in femtosecond pulses, corresponding to nearly 10 MW peak power in the XUV. Measurements of the harmonic yields as a function of the generation conditions reveal the roles of phase matching and ionization gating in the high order harmonic generation process. Pump/probe measurements are conducted using a unique VUV interferometer, capable of combining two different harmonics at a focus with variable delay. Measurements of VUV multiphoton ionization allows for characterization of the source and the interferometer. In molecules, time resolved measurements of fragment ion yields reveal the femtosecond dynamics of the system. The range of wavelengths available for pump and probe allows the dynamics to be followed from photo-excitation all the way to dissociation without detection window effects. The dynamics in ethylene upon [pi] 2![pi]* excitation are protypical of larger molecules and have thus served as an important test case for advanced ab initio molecular dynamics theories. Femtosecond measurements to date, however, have been extremely lacking. In the present work, through a series of pump probe experiments using VUV and XUV pulses, time scales for the non-adiabatic relaxation of the electronic excitation, hydrogen migration across the double bond, and H2 molecule elimination are measured and compared to theory. In the simpler oxygen molecule, excitation in the Schuman-Runge continuum leads to direct dissociation along the B 3[Sigma]u- potential energy curve. The time resolved photoion spectra show that the total photoionization cross section of the molecule resembles two oxygen atoms within 50 fs after excitation.
Book Synopsis Applied Combustion Diagnostics by : Katharina Kohse-Hoinghaus
Download or read book Applied Combustion Diagnostics written by Katharina Kohse-Hoinghaus and published by CRC Press. This book was released on 2002-04-26 with total page 734 pages. Available in PDF, EPUB and Kindle. Book excerpt: The editors have assembled a world-class group of contributors who address the questions the combustion diagnostic community faces. They are chemists who identify the species to be measured and the interfering substances that may be present; physicists, who push the limits of laser spectroscopy and laser devices and who conceive suitable measuremen
Book Synopsis Nanoscale Photonic Imaging by : Tim Salditt
Download or read book Nanoscale Photonic Imaging written by Tim Salditt and published by Springer Nature. This book was released on 2020-06-09 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt: This open access book, edited and authored by a team of world-leading researchers, provides a broad overview of advanced photonic methods for nanoscale visualization, as well as describing a range of fascinating in-depth studies. Introductory chapters cover the most relevant physics and basic methods that young researchers need to master in order to work effectively in the field of nanoscale photonic imaging, from physical first principles, to instrumentation, to mathematical foundations of imaging and data analysis. Subsequent chapters demonstrate how these cutting edge methods are applied to a variety of systems, including complex fluids and biomolecular systems, for visualizing their structure and dynamics, in space and on timescales extending over many orders of magnitude down to the femtosecond range. Progress in nanoscale photonic imaging in Göttingen has been the sum total of more than a decade of work by a wide range of scientists and mathematicians across disciplines, working together in a vibrant collaboration of a kind rarely matched. This volume presents the highlights of their research achievements and serves as a record of the unique and remarkable constellation of contributors, as well as looking ahead at the future prospects in this field. It will serve not only as a useful reference for experienced researchers but also as a valuable point of entry for newcomers.
Book Synopsis Introduction to Biophotonics by : Paras N. Prasad
Download or read book Introduction to Biophotonics written by Paras N. Prasad and published by John Wiley & Sons. This book was released on 2004-01-16 with total page 622 pages. Available in PDF, EPUB and Kindle. Book excerpt: Paras Prasad’s text provides a basic knowledge of a broad range of topics so that individuals in all disciplines can rapidly acquire the minimal necessary background for research and development in biophotonics. Introduction to Biophotonics serves as both a textbook for education and training as well as a reference book that aids research and development of those areas integrating light, photonics, and biological systems. Each chapter contains a topic introduction, a review of key data, and description of future directions for technical innovation. Introduction to Biophotonics covers the basic principles of Optics Optical spectroscopy Microscopy Each section also includes illustrated examples and review questions to test and advance the reader’s knowledge. Sections on biosensors and chemosensors, important tools for combating biological and chemical terrorism, will be of particular interest to professionals in toxicology and other environmental disciplines. Introduction to Biophotonics proves a valuable reference for graduate students and researchers in engineering, chemistry, and the life sciences.
Book Synopsis Electronic Processes in Organic Semiconductors by : Anna Köhler
Download or read book Electronic Processes in Organic Semiconductors written by Anna Köhler and published by John Wiley & Sons. This book was released on 2015-06-08 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first advanced textbook to provide a useful introduction in a brief, coherent and comprehensive way, with a focus on the fundamentals. After having read this book, students will be prepared to understand any of the many multi-authored books available in this field that discuss a particular aspect in more detail, and should also benefit from any of the textbooks in photochemistry or spectroscopy that concentrate on a particular mechanism. Based on a successful and well-proven lecture course given by one of the authors for many years, the book is clearly structured into four sections: electronic structure of organic semiconductors, charged and excited states in organic semiconductors, electronic and optical properties of organic semiconductors, and fundamentals of organic semiconductor devices.
Book Synopsis Lanthanide Luminescence by : Pekka Hänninen
Download or read book Lanthanide Luminescence written by Pekka Hänninen and published by Springer Science & Business Media. This book was released on 2011-06-21 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lanthanides have fascinated scientists for more than two centuries now, and since efficient separation techniques were established roughly 50 years ago, they have increasingly found their way into industrial exploitation and our everyday lives. Numerous applications are based on their unique luminescent properties, which are highlighted in this volume. It presents established knowledge about the photophysical basics, relevant lanthanide probes or materials, and describes instrumentation-related aspects including chemical and physical sensors. The uses of lanthanides in bioanalysis and medicine are outlined, such as assays for in vitro diagnostics and research. All chapters were compiled by renowned scientists with a broad audience in mind, providing both beginners in the field and advanced researchers with comprehensive information on on the given subject.
Book Synopsis Photochemical oxidants and air pollution by : Air Pollution Technical Information Center
Download or read book Photochemical oxidants and air pollution written by Air Pollution Technical Information Center and published by . This book was released on 1971 with total page 824 pages. Available in PDF, EPUB and Kindle. Book excerpt: About 1900 references, intended as a balanced sample of available literature mostly from the period 1959-1970. Foreign literature is included. Entries are arranged under topics. Author, title, subject, and geographic location indexes.
Author :Harald Siegfried Friedrich Publisher :Springer Science & Business Media ISBN 13 :3662037041 Total Pages :426 pages Book Rating :4.6/5 (62 download)
Book Synopsis Theoretical Atomic Physics by : Harald Siegfried Friedrich
Download or read book Theoretical Atomic Physics written by Harald Siegfried Friedrich and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new edition presents the recent developments in atomic physics. Beginning with a review of quantum mechanics, the book covers important areas of theoretical atomic physics, including semiclassical theory, periodic orbit theory, scaling properties for atoms in external fields, threshold behavior of ionization cross sections, and classical quantum dynamics of two-electron atoms.
Download or read book Astromag written by and published by . This book was released on 1988 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Photochemistry and Reaction Kinetics by : T. M. Sugden
Download or read book Photochemistry and Reaction Kinetics written by T. M. Sugden and published by Cambridge University Press. This book was released on 2010-06-24 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book examines very simple atomic reactions to more complex chain reactions involving combustion, flame and the production of polymers.
Book Synopsis Introduction to THz Wave Photonics by : Xi-Cheng Zhang
Download or read book Introduction to THz Wave Photonics written by Xi-Cheng Zhang and published by Springer Science & Business Media. This book was released on 2009-12-01 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt: Terahertz (THz) radiation, which is electromagnetic radiation in a frequency int- val from 0.3 to 10 THz (1 mm–30 ?m wavelength), is the next frontier in science and technology. This band occupies a large portion of the electromagnetic sp- trum between the infrared and microwave bands. Basic research, new initiatives, and developments in advanced sensing and imaging technology with regard to the THz band remain unexplored compared to the relatively well-developed science and technology in the microwave and optical frequencies. Historically, THz technologies were used mainly within the astronomy c- munity for studying the background of cosmic far-infrared radiation, and by the laser-fusion community for the diagnostics of plasmas. Since the ?rst demonstration of THz wave time-domain spectroscopy in the late 1980s, there has been a series of signi?cant advances (particularly in recent years) as more intense THz sources and higher sensitivity detectors provide new opportunities for understanding the basic science in the THz frequency range.
Book Synopsis Metal Sites in Proteins and Models by : H.A.O. Hill
Download or read book Metal Sites in Proteins and Models written by H.A.O. Hill and published by Springer Science & Business Media. This book was released on 1999-04-01 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biological chemistry is a major frontier of inorganic chemistry. Three special volumes devoted to Metal Sites in Proteins and Models address the questions: how unusual ("entatic") are metal sites in metalloproteins and metalloenzymes compared to those in small coordination complexes? and if they are special, how do polypeptide chains and co-factors control this? The chapters deal with iron, with metal centres acting as Lewis acids, metals in phosphate enzymes, with vanadium, and with the wide variety of transition metal ions which act as redox centres. They illustrate in particular how the combined armoury of genetics and structure determination at the molecular level are providing unprecedented new tools for molecular engineering.
Book Synopsis Molecular Reaction Dynamics by : Raphael D. Levine
Download or read book Molecular Reaction Dynamics written by Raphael D. Levine and published by Cambridge University Press. This book was released on 2009-06-04 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular reaction dynamics is the study of chemical and physical transformations of matter at the molecular level. The understanding of how chemical reactions occur and how to control them is fundamental to chemists and interdisciplinary areas such as materials and nanoscience, rational drug design, environmental and astrochemistry. This book provides a thorough foundation to this area. The first half is introductory, detailing experimental techniques for initiating and probing reaction dynamics and the essential insights that have been gained. The second part explores key areas including photoselective chemistry, stereochemistry, chemical reactions in real time and chemical reaction dynamics in solutions and interfaces. Typical of the new challenges are molecular machines, enzyme action and molecular control. With problem sets included, this book is suitable for advanced undergraduate and graduate students, as well as being supplementary to chemical kinetics, physical chemistry, biophysics and materials science courses, and as a primer for practising scientists.
