Reconstructive Phase Transitions: In Crystals And Quasicrystals

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Author :
Publisher : World Scientific
ISBN 13 : 981450002X
Total Pages : 416 pages
Book Rating : 4.8/5 (145 download)

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Book Synopsis Reconstructive Phase Transitions: In Crystals And Quasicrystals by : Vladimir Dmitriev

Download or read book Reconstructive Phase Transitions: In Crystals And Quasicrystals written by Vladimir Dmitriev and published by World Scientific. This book was released on 1996-09-30 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with the phenomenological theory of first-order structural phase transitions, with a special emphasis on reconstructive transformations in which a group-subgroup relationship between the symmetries of the phases is absent. It starts with a unified presentation of the current approach to first-order phase transitions, using the more recent results of the Landau theory of phase transitions and of the theory of singularities. A general theory of reconstructive phase transitions is then formulated, in which the structures surrounding a transition are expressed in terms of density-waves, providing a natural definition of the transition order-parameters, and a description of the corresponding phase diagrams and relevant physical properties. The applicability of the theory is illustrated by a large number of concrete examples pertaining to the various classes of reconstructive transitions: allotropic transformations of the elements, displacive and order-disorder transformations in metals, alloys and related structures, crystal-quasicrystal transformations.

The Physics of Structural Phase Transitions

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 9780387407166
Total Pages : 304 pages
Book Rating : 4.4/5 (71 download)

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Book Synopsis The Physics of Structural Phase Transitions by : Minoru Fujimoto

Download or read book The Physics of Structural Phase Transitions written by Minoru Fujimoto and published by Springer Science & Business Media. This book was released on 2004-09-01 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase transitions in which crystalline solids undergo structural changes present an interesting problem in the interplay between the crystal structure and the ordering process. This text, intended for readers with some prior knowledge of condensed-matter physics, emphasizes the basic physics behind such spontaneous structural changes in crystals. Starting with the relevant thermodynamic principles, the book discusses the nature of order variables and their collective motion in a crystal lattice; in a structural phase transition a singularity in such a collective mode is responsible for the lattice instability, as revealed by soft phonons. This mechanism is analogous to the interplay of a charge-density wave and a periodically deformed lattice in low-dimensional conductors. The text also describes experimental methods for modulated crystal structures and gives examples of structural changes in representative systems. The book is divided into two parts. The first, theoretical, part includes such topics as: the Landau theory of phase transitions; statistics, correlations and the mean-field approximation; pseudospins and their collective modes; soft lattice modes and pseudospin condensates; lattice imperfections and their role in the phase transitions of real crystals. The second part discusses experimental studies of modulated crystals using x-ray diffraction, neutron inelastic scattering, light scattering, dielectric measurements, and magnetic resonance spectroscopy.