Environmentally Sustainable Catalytic Asymmetric Oxidations

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Environmentally Sustainable Catalytic Asymmetric Oxidations

Author : Konstantin Bryliakov
Publisher : CRC Press
ISBN 13 : 1466588578
Total Pages : 166 pages
Book Rating : 4.4/5 (665 download)

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Book Synopsis Environmentally Sustainable Catalytic Asymmetric Oxidations by : Konstantin Bryliakov

Download or read book Environmentally Sustainable Catalytic Asymmetric Oxidations written by Konstantin Bryliakov and published by CRC Press. This book was released on 2014-09-17 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis plays a vital role in chemical, petroleum, agriculture, polymer, electronics, pharmaceutical, and other industries. Over 90 percent of chemicals originate from catalytic processes. Toughening economic and environmental constraints have proven to be a challenge for meeting the demand of novel efficient and sustainable regio- and stereoselective catalyst systems. Environmentally Sustainable Catalytic Asymmetric Oxidations provides a comprehensive overview of existing ecologically friendly catalyst systems for various asymmetric oxidation processes. Topics include: A survey of existing transition metal-based catalyst systems for asymmetric epoxidations (AEs) with O2 and H2O2 Asymmetric sulfoxidations with H2O2 on chiral metal complexes An overview of various transition metal-catalyzed oxidative transformations with H2O2 or O2 used as the terminal oxidant Organocatalytic asymmetric oxidations Catalytic processes of stereospecific oxidations of C-H functional groups The role that oxoiron(V) intermediates play in chemo- and stereoselective oxidations catalyzed by non-heme iron complexes The book concludes with a discussion of the opportunities and problems associated with the industrial application of stereoselective processes of catalytic oxidation with H2O2 and O2. It also provides examples of processes with industrial potential. Some of the catalysts presented in this book may serve as promising alternatives for existing catalysts—progressively replacing them in manufacturing processes and ultimately making the chemical industry greener and cleaner.

Frontiers of Green Catalytic Selective Oxidations

Author : Konstantin P. Bryliakov
Publisher : Springer Nature
ISBN 13 : 9813297514
Total Pages : 295 pages
Book Rating : 4.8/5 (132 download)

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Book Synopsis Frontiers of Green Catalytic Selective Oxidations by : Konstantin P. Bryliakov

Download or read book Frontiers of Green Catalytic Selective Oxidations written by Konstantin P. Bryliakov and published by Springer Nature. This book was released on 2019-10-02 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: The demand for novel efficient and environmentally sustainable chemo, regio- and stereoselective catalyst systems for the oxidation of organic substrates is continuously growing in line with toughening economic and environmental constraints. This book addresses these issues; it consists of eleven chapters written by world-recognized experts in green and sustainable oxidation catalysis. The most urgent and challenging topics, in the judgment of the editor, such as green asymmetric epoxidations, sulfoxidatiuons, C–H oxidations; oxidation catalysis by polyoxometalates and oxidations in non-conventional solvents, etc. have been critically reviewed in this book. Both fundamental aspects, such as catalysts design, catalytic properties, nature of catalytically active sites and reaction mechanisms, and practical outlook of the oxidations have been addressed by the authors. The book appeals to a broad readership, particularly graduate students, employees of universities and research organizations, and industrial researchers, particularly those working in the areas of homogeneous oxidation catalysis, asymmetric synthesis, organocatalysis, sustainable catalytic processes and green chemistry, mechanisms of catalytic reactions, synthesis of bioactive compounds, biomimetic chemistry, etc. Konstantin Bryliakov is Leading Researcher at the Boreskov Institute of Catalysis. In 2016, he was elected Honorary Professor of the Russian Academy of Sciences.

Frontiers of Green Catalytic Selective Oxidations

Author : Konstantin P. Bryliakov
Publisher :
ISBN 13 : 9789813297524
Total Pages : 295 pages
Book Rating : 4.2/5 (975 download)

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Book Synopsis Frontiers of Green Catalytic Selective Oxidations by : Konstantin P. Bryliakov

Download or read book Frontiers of Green Catalytic Selective Oxidations written by Konstantin P. Bryliakov and published by . This book was released on 2019 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: The demand for novel efficient and environmentally sustainable chemo, regio- and stereoselective catalyst systems for the oxidation of organic substrates is continuously growing in line with toughening economic and environmental constraints. This book addresses these issues; it consists of eleven chapters written by world-recognized experts in green and sustainable oxidation catalysis. The most urgent and challenging topics, in the judgment of the editor, such as green asymmetric epoxidations, sulfoxidatiuons, C-H oxidations; oxidation catalysis by polyoxometalates and oxidations in non-conventional solvents, etc. have been critically reviewed in this book. Both fundamental aspects, such as catalysts design, catalytic properties, nature of catalytically active sites and reaction mechanisms, and practical outlook of the oxidations have been addressed by the authors. The book appeals to a broad readership, particularly graduate students, employees of universities and research organizations, and industrial researchers, particularly those working in the areas of homogeneous oxidation catalysis, asymmetric synthesis, organocatalysis, sustainable catalytic processes and green chemistry, mechanisms of catalytic reactions, synthesis of bioactive compounds, biomimetic chemistry, etc. Konstantin Bryliakov is Leading Researcher at the Boreskov Institute of Catalysis. In 2016, he was elected Honorary Professor of the Russian Academy of Sciences.

Environmentally Sustainable Catalytic Asymmetric Oxidations

Author : Konstantin Bryliakov
Publisher : CRC Press
ISBN 13 : 1466588594
Total Pages : 160 pages
Book Rating : 4.4/5 (665 download)

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Book Synopsis Environmentally Sustainable Catalytic Asymmetric Oxidations by : Konstantin Bryliakov

Catalysis for Sustainability

Author : Thomas P. Umile
Publisher : CRC Press
ISBN 13 : 1466586869
Total Pages : 210 pages
Book Rating : 4.4/5 (665 download)

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Book Synopsis Catalysis for Sustainability by : Thomas P. Umile

Download or read book Catalysis for Sustainability written by Thomas P. Umile and published by CRC Press. This book was released on 2015-08-05 with total page 210 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis for Sustainability: Goals, Challenges, and Impacts explores the intersection between catalytic science and sustainable technologies as a means to addressing current economic, social, and environmental problems. These problems include harnessing alternative energy sources, pollution prevention and remediation, and the manufacturing of comm

Liquid Phase Oxidation via Heterogeneous Catalysis

Author : Mario G. Clerici
Publisher : John Wiley & Sons
ISBN 13 : 1118356756
Total Pages : 438 pages
Book Rating : 4.1/5 (183 download)

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Book Synopsis Liquid Phase Oxidation via Heterogeneous Catalysis by : Mario G. Clerici

Download or read book Liquid Phase Oxidation via Heterogeneous Catalysis written by Mario G. Clerici and published by John Wiley & Sons. This book was released on 2013-04-26 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.

Supramolecular Chirogenesis in Chemical and Related Sciences

Author : Victor Borovkov
Publisher : Frontiers Media SA
ISBN 13 : 2889668339
Total Pages : 179 pages
Book Rating : 4.8/5 (896 download)

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Book Synopsis Supramolecular Chirogenesis in Chemical and Related Sciences by : Victor Borovkov

Download or read book Supramolecular Chirogenesis in Chemical and Related Sciences written by Victor Borovkov and published by Frontiers Media SA. This book was released on 2021-06-01 with total page 179 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Catalytic Aerobic Oxidations

Author : Esteban Mejía
Publisher : Royal Society of Chemistry
ISBN 13 : 1839160349
Total Pages : 349 pages
Book Rating : 4.8/5 (391 download)

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Book Synopsis Catalytic Aerobic Oxidations by : Esteban Mejía

Download or read book Catalytic Aerobic Oxidations written by Esteban Mejía and published by Royal Society of Chemistry. This book was released on 2020-07-14 with total page 349 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidation reactions are an important chemical transformation in both academia and industry. Among the major advances in the field has been the development of catalytic processes, which are not only selective and efficient, but also allow the replacement of common stoichiometric oxidants with molecular oxygen, ideally from air at atmospheric pressure. This results in processes with higher atom efficiency, where water is the only side product in line with the principles of green chemistry. Focusing on the use of molecular oxygen as the terminal oxidant, this book covers recent advances in both heterogeneous and homogeneous systems, with and without metals and on the “taming” of the highly reactive oxygen gas by use of micro-flow reactors and membranes. A useful reference for industrial and academic chemists working on oxidation processes, as well as green chemists.

Sustainable Synthesis of Pharmaceuticals

Author : Mariette M Pereira
Publisher : Royal Society of Chemistry
ISBN 13 : 1788014413
Total Pages : 245 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Sustainable Synthesis of Pharmaceuticals by : Mariette M Pereira

Download or read book Sustainable Synthesis of Pharmaceuticals written by Mariette M Pereira and published by Royal Society of Chemistry. This book was released on 2018-03-26 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is a growing interest in the development of sustainable processes for the synthesis of pharmaceuticals and this book bridges the divide between industrial examples and the fundamental chemistry. It explains the basic principles of using transition metal catalysis with several green approaches for the synthesis of pharmaceuticals. The topic is an important one for green chemistry and the chapters in this book on hydroformylation, green oxidation and olefin metathesis will also be of interest to both medicinal and organic chemists. Written by leading experts in the field, it provides a valuable and easy tool for scientists and industrialists who require information regarding this topic.

Green Chemistry and Catalysis

Author : R. A. Sheldon
Publisher : John Wiley & Sons
ISBN 13 : 3527611010
Total Pages : 448 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Green Chemistry and Catalysis by : R. A. Sheldon

Download or read book Green Chemistry and Catalysis written by R. A. Sheldon and published by John Wiley & Sons. This book was released on 2007-06-27 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect: · Numerous catalytic reductions and oxidations methods · Solid-acid and solid-base catalysis · C-C bond formation reactions · Biocatalysis · Asymmetric catalysis · Novel reaction media like e.g. ionic liquids, supercritical CO2 · Renewable raw materials Written by Roger A. Sheldon -- without doubt one of the leaders in the field with much experience in academia and industry -- and his co-workers, the result is a unified whole, an indispensable source for every scientist looking to improve catalytic reactions, whether in the college or company lab.

Sustainable Catalysis

Author : Michael North
Publisher : Royal Society of Chemistry
ISBN 13 : 1782626395
Total Pages : 310 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Sustainable Catalysis by : Michael North

Download or read book Sustainable Catalysis written by Michael North and published by Royal Society of Chemistry. This book was released on 2016 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Focussing on catalysis through non-endangered metals, this book is an important reference for researchers working in catalysis and green chemistry.

Sustainable Catalysis

Author : Michael North
Publisher : Royal Society of Chemistry
ISBN 13 : 1782626409
Total Pages : 392 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Sustainable Catalysis by : Michael North

Download or read book Sustainable Catalysis written by Michael North and published by Royal Society of Chemistry. This book was released on 2016 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: Focussing on catalysis without metals or other endangered elements, this book is an important reference for researchers working in catalysis and green chemistry.

Polyoxomolybdates as Green Catalysts for Aerobic Oxidation

Author : Anjali Patel
Publisher : Springer
ISBN 13 : 3319129880
Total Pages : 63 pages
Book Rating : 4.3/5 (191 download)

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Book Synopsis Polyoxomolybdates as Green Catalysts for Aerobic Oxidation by : Anjali Patel

Download or read book Polyoxomolybdates as Green Catalysts for Aerobic Oxidation written by Anjali Patel and published by Springer. This book was released on 2014-11-22 with total page 63 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneously catalyzed selective oxidations of alcohols is a highly topical field. The first chapter of this brief describes the importance of the selective oxidation of alcohols and advantages of heterogeneous catalysts over conventional catalysts, use of environmentally benign oxidants, and the design of selective catalysts by tailoring of polyoxometalates at the molecular level. Chapter 2 describes synthesis, characterization 11-molybdophosphate based supported materials and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. ZrO2, Al2O3, MCM-41 and zeolite Hβ were used as supports. Chapter 3 describes synthesis, characterization of transition metals (Mn, Co, Ni, Cu)- substituted phosphomolybdates and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. Chapter 4 describes conclusive remarks for present catalytic systems.

Sustainable Chemistry

Author : Michael North
Publisher : Royal Society of Chemistry
ISBN 13 : 1782626387
Total Pages : 506 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Sustainable Chemistry by : Michael North

Download or read book Sustainable Chemistry written by Michael North and published by Royal Society of Chemistry. This book was released on 2016 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Focussing on catalysis through non-endangered metals, this book is an important reference for researchers working in catalysis and green chemistry.

Design And Applications Of Single-site Heterogeneous Catalysts: Contributions To Green Chemistry, Clean Technology And Sustainability

Download Design And Applications Of Single-site Heterogeneous Catalysts: Contributions To Green Chemistry, Clean Technology And Sustainability PDF Online Free

Author : John Meurig Thomas
Publisher : World Scientific Publishing Company
ISBN 13 : 1848169299
Total Pages : 324 pages
Book Rating : 4.8/5 (481 download)

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Book Synopsis Design And Applications Of Single-site Heterogeneous Catalysts: Contributions To Green Chemistry, Clean Technology And Sustainability by : John Meurig Thomas

Download or read book Design And Applications Of Single-site Heterogeneous Catalysts: Contributions To Green Chemistry, Clean Technology And Sustainability written by John Meurig Thomas and published by World Scientific Publishing Company. This book was released on 2012-04-16 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: For far too long chemists and industrialists have relied on the use of aggressive reagents such as nitric and sulphuric acids, permanganates and dichromates to prepare the massive quantities of both bulk and fine chemicals that are needed for the maintenance of civilised life — materials such as fuels, fabrics, foodstuffs, fertilisers and pharmaceuticals. Such aggressive reagents generate vast quantities of environmentally harmful and often toxic by-products, including the oxides of nitrogen, of metal oxides and carbon dioxide.Now, owing to recent advances made in the synthesis of nanoporous solids, it is feasible to design new solid catalysts that enable benign, mild oxidants to be used, frequently without utilising solvents, to manufacture the products that the chemical, pharmaceutical, agro- and bio-chemical industries require. These new solid agents are designated single-site heterogeneous catalysts (SSHCs). Their principal characteristics are that all the active sites present in the high-area solids are identical in their atomic environment and hence in their energy of interaction with reactants, just as in enzymes.Single-site heterogeneous catalysts now occupy a position of growing importance both academically and in their potential for commercial exploitation. This text, the only one devoted to such catalysts, dwells both on principles of design and on applications, such as the benign synthesis of nylon 6 and vitamin B3. It equips the reader with unifying insights required for future catalytic adventures in the quest for sustainability in the materials used by humankind.Anyone acquainted with the language of molecules, including undergraduates in the physical and biological sciences, as well as graduates in engineering and materials science, should be able to assimilate the principles and examples presented in this book. Inter alia, it describes how clean technology and ‘green’ processes may be carried out in an environmentally responsible manner.

Sustainable Catalytic Processes

Author : Basudeb Saha
Publisher : Newnes
ISBN 13 : 0444595791
Total Pages : 219 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Sustainable Catalytic Processes by : Basudeb Saha

Download or read book Sustainable Catalytic Processes written by Basudeb Saha and published by Newnes. This book was released on 2015-06-11 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of catalysts is the most sophisticated art in chemical sciences. It can be read like a story book when the critical scientific contents are presented in a chronological manner with short and simple sentences. This book will meets these criteria. To address the sustainability issues of existing chemical manufacturing processes or producing new chemicals, researchers are developing alternate catalysts to eliminate toxic chemicals use and by-products formation. Sustainable Catalytic Processes presents critical discussions of the progress of such catalytic development. This book of contemporary research results in sustainable catalysis area will benefit scientists in both industries and academia, and students to learn recent catalysts/process development. Reports the most recent developments in catalysis with a focus on environmentally friendly commercial processes, such as waste water treatment, alternate energy, etc Bridges the theory, necessary for the development of environmentally friendly processes, and their implementation through pilot plant and large scale Contains mainly laboratory scale data and encourages industrial scientists to test these processes on a pilot scale Includes work examples featuring the development of the new catalysts/processes using bio-renewable feedstock satisfactorily addressing environmental concerns Includes one chapter demonstrating real industrial examples motivating the industrial and academic researchers to pursue similar research

Comprehensive Inorganic Chemistry II

Author :
Publisher : Newnes
ISBN 13 : 0080965296
Total Pages : 7694 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Inorganic Chemistry II by :

Download or read book Comprehensive Inorganic Chemistry II written by and published by Newnes. This book was released on 2013-07-23 with total page 7694 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973