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Electron Transfer Reactions Of Carboxylatopenta Amminechromiumiii Complexes
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Book Synopsis Organic Reaction Mechanisms 1966 by : B. Capon
Download or read book Organic Reaction Mechanisms 1966 written by B. Capon and published by John Wiley & Sons. This book was released on 2008-05-27 with total page 481 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 1966 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 1966. The 2nd annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.
Book Synopsis Annual Review of Physical Chemistry: Volume 17 by :
Download or read book Annual Review of Physical Chemistry: Volume 17 written by and published by . This book was released on 1966 with total page 606 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Annual Review of Physical Chemistry by : Gerhard Krohn Rollefson
Download or read book Annual Review of Physical Chemistry written by Gerhard Krohn Rollefson and published by . This book was released on 1966 with total page 944 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides abstracts and review articles on topics in physical chemistry.
Book Synopsis Dissertation Abstracts International by :
Download or read book Dissertation Abstracts International written by and published by . This book was released on 1976 with total page 792 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Quarterly Journal of the Chemical Society of London by : Chemical Society (Great Britain)
Download or read book Quarterly Journal of the Chemical Society of London written by Chemical Society (Great Britain) and published by . This book was released on 1966 with total page 1236 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Dissertation Abstracts written by and published by . This book was released on with total page 1328 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Non-aqueous Solvent Systems by : Thomas Cudworth Waddington
Download or read book Non-aqueous Solvent Systems written by Thomas Cudworth Waddington and published by . This book was released on 1965 with total page 594 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Journal by : Chemical Society (Great Britain)
Download or read book Journal written by Chemical Society (Great Britain) and published by . This book was released on 1966 with total page 976 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Introduction to Inorganic Chemistry by : G.I. Brown
Download or read book Introduction to Inorganic Chemistry written by G.I. Brown and published by Longman Publishing Group. This book was released on 1985-01-01 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Electron Transfer Reactions of Complex Ions in Solution by : Henry Taube
Download or read book Electron Transfer Reactions of Complex Ions in Solution written by Henry Taube and published by Elsevier. This book was released on 2012-12-02 with total page 113 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electron Transfer Reactions of Complex Ions in Solution covers the significant development of some important area of electron transfer reactions of complex ions. This four-chapter book emerged from a series of lectures at the Polytechnic Institute of Brooklyn in November and December 1967. Chapter I presents research studies in cation hydration. This chapter describes principal methods for composition determination of the first coordination spheres of the aquo ions. Chapter II examines the distinction between reactions in which electron transfer takes place from one primary bond system to another. Chapter III discusses some aspects of ligand effects in electron-transfer reactions. This chapter demonstrates that differences in the behavior of systems can be expected at least in the extremes of mechanisms. Chapter IV deals with the history, principles and applications of the induced electron-transfer effect. This book is of great value to electrochemists, students, and researchers.
Book Synopsis Electron Transfer Reactions by : R. D. Cannon
Download or read book Electron Transfer Reactions written by R. D. Cannon and published by Butterworth-Heinemann. This book was released on 2016-07-29 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electron Transfer Reactions deals with the mechanisms of electron transfer reactions between metal ions in solution, as well as the electron exchange between atoms or molecules in either the gaseous or solid state. The book is divided into three parts. Part 1 covers the electron transfer between atoms and molecules in the gas state. Part 2 tackles the reaction paths of oxidation states and binuclear intermediates, as well as the mechanisms of electron transfer. Part 3 discusses the theories and models of the electron transfer process; theories and experiments involving bridged electron transfer; optical electron transfer; and electron transfer in the solid state. The text is recommended for chemists who would like to know more about the principles and mechanisms behind electron transfer reactions.
Book Synopsis The Preparation, Characterization, and Chromium (II) Reduction of Pentaamminecobalt (III) by : Robert J. Balahura
Download or read book The Preparation, Characterization, and Chromium (II) Reduction of Pentaamminecobalt (III) written by Robert J. Balahura and published by . This book was released on 1971 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chromium(II) reduction of a series of pentaammine- cobalt(III) complexes has been studied. A classification into inner- or outer-sphere paths has been made and the position of attack of the reductant on the ligand determined. The oxygen-bonded complexes of formamide, N,N-dimethylform- amide, dimethylsulfoxide, and urea as well as the nitrogen bonded N-cyanoguanidine complex are reduced by means of an outer-sphere mechanism. On the other hand ligand transfer was shown to occur in the reduction of (NH[subscript 3])[subscript 5]CoNHCHO[superscript 2+], (NH[subscript 3])[subscript 5]CoNCNH[superscript 2+], (NH[subscript 3])[subscript 5]CoO[subscript 2]CNH[subscript 2][superscript 2+], (NH[subscript 3])[subscript 5]CoO[subscript 2]CC[subscript 6]H[subscript 4]CN[superscript 2+], and (NH[subscript 3])[subscript 5]CoNCO[superscript 2+]. Both outer- and inner-sphere paths operate in the reduction of the nitrile bonded 4-cyanophenol complex, the inner-sphere path comprising 20% of the overall reaction. For the reduction of the terephthalonitrile complex a classification into an inner- or outer-sphere path cannot be made/ and an outer-sphere electron transfer to the ligand is postulated as the rate-determining step. A large part of the work has been concerned with the characterization of the complexes and Chapter III describes the spectroscopic measurements undertaken as well as the chemical reactions of some of the complexes. The acid dissociation constant of the N isomer of formamidopentaamine- cobalt(III), cyanamidopentaamminecobalt(III), and the nitrile bonded 4-cyanophenol have been determined. The protonation equilibrium constant for carbamatopentaammine- cobalt(III) was also obtained. A kinetic study of the acid hydrolysis of isocyanatopentaamminecobalt(III) to form hexaamminecobalt(III) and carbon dioxide was carried out. The acylation of the cyanamide and 4-cyanophenol complexes was also studied. The results of the kinetic studies of the chromium(II) reductions indicate a possible correlation between the reduction rate and the half-wave potential for the reduction of the free ligand. The studies have led to the following generalizations regarding electron transfer reactions: (1) attack of reductant at a coordinated atom does not occur, (2) the atom attached to chromium(II) in the transition state must have two lone pairs of electrons, and (3) the reducibility of the complexed ligand plays an important role in the detailed mechanism for the transfer of the electron.
