Electrochemical Scanning Probe Methods for the Investigation of Passivating Surface Films and Permeable Media

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (119 download)

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Book Synopsis Electrochemical Scanning Probe Methods for the Investigation of Passivating Surface Films and Permeable Media by : Nicholas Payne

Download or read book Electrochemical Scanning Probe Methods for the Investigation of Passivating Surface Films and Permeable Media written by Nicholas Payne and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: "Electrochemical scanning probe microscopy has exploded in popularity since the late 1980's and widespread adoption for routine materials analysis is swiftly become a reality. In practice, for any technique, widening the material scope, particularly for industrially-relevant materials that bring much greater levels of heterogeneity and complexity in structure, is accompanied by new instrument and theory development.This thesis demonstrates that electrochemical microscopy is capable of quantitative analysis of substrate permeability - a very common but challenging to acquire property in industrially-relevant composite electrodes and corroding materials. Measurements are performed on permeable materials in situ and can thus account for material swelling and active growth of surface films as well as identify electroactive nanoscale defects. Specifically we explore each of the major electrochemical microscopy methods, scanning electrochemical microscopy (SECM), scanning ion conductance microscopy (SICM) and scanning electrochemical cell microscopy (SECCM) and through a combination of experiment and simulation, we demonstrate that mass transport within permeable surface layers can be predicted and therefore isolated from the electrochemical reactivity of the substrate.With SECM, we derived and validated analytical equations that allow rapid determination of film porosity through non-linear curve fitting of routine approach curve measurements. Furthermore, we validated the possible implementations of the equations based on the morphology of the surface film and identified any limitations for routine use. For SICM, we demonstrated that the critical parameter, ionic conductivity within a permeable layer has a significant impact on routine imaging but can also be quantified with approach curves. We present for the first time, direct measurement of ionic conductivity within a permeable film with SICM using a lithium-ion battery cathode film. Finally, with SECCM we took advantage of its well-defined spatial resolution to resolve and assess the size of nanoscale defects in a polymeric thin film. We also introduced the density plot as a new analysis method for SECCM that consolidated the large data sets obtained by experiment and facilitates correlation with simulation"--

Scanning Electrochemical Microscopy, Second Edition

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Publisher : CRC Press
ISBN 13 : 1439831122
Total Pages : 673 pages
Book Rating : 4.4/5 (398 download)

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Book Synopsis Scanning Electrochemical Microscopy, Second Edition by : Allen J. Bard

Download or read book Scanning Electrochemical Microscopy, Second Edition written by Allen J. Bard and published by CRC Press. This book was released on 2012-04-16 with total page 673 pages. Available in PDF, EPUB and Kindle. Book excerpt: Because of its simplicity of use and quantitative results, Scanning Electrochemical Microscopy (SECM) has become an indispensable tool for the study of surface reactivity. The fast expansion of the SECM field during the last several years has been fueled by the introduction of new probes, commercially available instrumentation, and new practical applications. Scanning Electrochemical Microscopy, Second Edition offers essential background and in-depth overviews of specific applications in self-contained chapters. Recent methodological advances have greatly increased the capacity of SECM to characterize interfaces at the nanoscale and to obtain molecular-level chemical information. This thoroughly updated edition retains original chapters describing the principles of SECM measurements, instrumentation, preparation of SECM probes, imaging methodologies, and theory and offers: New chapters on studies of single biological cells, corrosion, electrocatalysis, and hybrid techniques Descriptions of recent advances of SECM in several areas of current interest: biotechnological applications, nanofabrication and surface patterning, and molecular transport across films and membranes Discussion of the ongoing shift from micrometer-scale experiments to the nanoscale Useful for a broad range of interdisciplinary research—from biological systems to probing reactions at the liquid–liquid interface—this book is invaluable to all interested in learning and applying SECM.

Scanning Probe Microscopy Studies of an Electroactive Self-assembling Monolayer and Potential Dependent Adhesion of Ferrocenyl Redox Films

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ISBN 13 :
Total Pages : 234 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis Scanning Probe Microscopy Studies of an Electroactive Self-assembling Monolayer and Potential Dependent Adhesion of Ferrocenyl Redox Films by : James Edgar Hudson

Download or read book Scanning Probe Microscopy Studies of an Electroactive Self-assembling Monolayer and Potential Dependent Adhesion of Ferrocenyl Redox Films written by James Edgar Hudson and published by . This book was released on 1996 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Electrochemical Scanning Probe Microscopy Studies of Semiconductor and Metal Surface/liquid Interfaces

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ISBN 13 :
Total Pages : 168 pages
Book Rating : 4.:/5 (285 download)

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Book Synopsis Electrochemical Scanning Probe Microscopy Studies of Semiconductor and Metal Surface/liquid Interfaces by : Keith Douglas Kepler

Download or read book Electrochemical Scanning Probe Microscopy Studies of Semiconductor and Metal Surface/liquid Interfaces written by Keith Douglas Kepler and published by . This book was released on 1993 with total page 168 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Scanning Electrochemical Microscopy

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Publisher : CRC Press
ISBN 13 : 1000584054
Total Pages : 619 pages
Book Rating : 4.0/5 (5 download)

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Book Synopsis Scanning Electrochemical Microscopy by : Allen J. Bard

Download or read book Scanning Electrochemical Microscopy written by Allen J. Bard and published by CRC Press. This book was released on 2022-07-29 with total page 619 pages. Available in PDF, EPUB and Kindle. Book excerpt: Because of its simplicity of use and quantitative results, Scanning Electrochemical Microscopy (SECM) has become an indispensable tool for the study of surface reactivity. The fast expansion of the SECM field over several years has been fueled by the introduction of new probes, commercially available instrumentation, and new practical applications. Scanning Electrochemical Microscopy, Third Edition offers essential background and in-depth overviews of specific applications in self-contained chapters. The vitality and growing popularity of SECM over the past 30+ years have largely been determined by its versatility and capability to remain useful in the changing scientific and technological environments. New applications reported during the last decade reflect significant current activity in biomedical and energy-related research. This thoroughly updated edition provides up-to-date comprehensive reviews of different aspects of SECM. New chapters by renowned professionals in the field cover recent advances in different areas of SECM including nanoSECM, surface reactions and films, batteries, and fuel cells. Expanded coverage of electrocatalysis and surface interrogation as well as photoelectrochemistry and photoelectrocatalysis are also provided. Useful for a broad range of interdisciplinary research—from biological systems to nanopatterning—this book is invaluable to all interested in learning and applying SECM.

Scanning Electrochemical Microscopy

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Publisher : CRC Press
ISBN 13 : 9780203910771
Total Pages : 668 pages
Book Rating : 4.9/5 (17 download)

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Book Synopsis Scanning Electrochemical Microscopy by : Allen J. Bard

Download or read book Scanning Electrochemical Microscopy written by Allen J. Bard and published by CRC Press. This book was released on 2001-04-18 with total page 668 pages. Available in PDF, EPUB and Kindle. Book excerpt: Scanning Electrochemical Microscopy describes the theory and operating principles of scanning electrochemical microscopy (SECM), including instrumentation, tip preparation, imaging techniques and potentiometric probes. The book explores applications relevant to electron transfer reactions, reaction kinetics, chemical events at interfaces, biologica

Paint and Coating Testing Manual

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Publisher : ASTM International
ISBN 13 :
Total Pages : 921 pages
Book Rating : 4./5 ( download)

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Book Synopsis Paint and Coating Testing Manual by :

Download or read book Paint and Coating Testing Manual written by and published by ASTM International. This book was released on with total page 921 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metals Abstracts

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ISBN 13 :
Total Pages : 782 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis Metals Abstracts by :

Download or read book Metals Abstracts written by and published by . This book was released on 1997 with total page 782 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Techniques for Corrosion Monitoring

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Publisher : Elsevier
ISBN 13 : 1845694058
Total Pages : 711 pages
Book Rating : 4.8/5 (456 download)

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Book Synopsis Techniques for Corrosion Monitoring by :

Download or read book Techniques for Corrosion Monitoring written by and published by Elsevier. This book was released on 2008-02-01 with total page 711 pages. Available in PDF, EPUB and Kindle. Book excerpt: Corrosion monitoring techniques play a key role in efforts to combat corrosion, which can have major economic and safety implications. This important book starts with a review of corrosion fundamentals and provides a four-part comprehensive analysis of a wide range of methods for corrosion monitoring, including practical applications and case studies. The first part of the book reviews electrochemical techniques for corrosion monitoring, such as polarization techniques, potentiometric methods, electrochemical noise and harmonic analyses, galvanic sensors, differential flow through cells and multielectrode systems. A second group of chapters analyses the physical or chemical methods of corrosion monitoring. These include gravimetric, radioactive tracer, hydrogen permeation, electrical resistance and rotating cage techniques. Part II also includes a chapter on the innovative nondestructive evaluation technologies that can be used to monitor corrosion. Part III examines corrosion monitoring in special environments such as microbial systems, concrete and soil, and remote monitoring and model predictions. A final group of chapters includes various case studies covering ways in which corrosion monitoring can be applied to engine exhaust systems, cooling water systems, pipelines, equipment in chemical plants, and other real world systems. With its distinguished editor and international team of contributors, Techniques for corrosion monitoring is a valuable reference guide for engineers and scientific and technical personnel who deal with corrosion in such areas as automotive engineering, power generation, water suppliers and the petrochemical industry. Provides a comprehensive analysis of the range of techniques for corrosion monitoring Specific case studies are included to highlight the main issues A valuable reference guide for engineers, scientific and technical personnel who deal with corrosion

Metals Abstracts Index

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ISBN 13 :
Total Pages : 1390 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Metals Abstracts Index by :

Download or read book Metals Abstracts Index written by and published by . This book was released on 1995 with total page 1390 pages. Available in PDF, EPUB and Kindle. Book excerpt:

International Aerospace Abstracts

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ISBN 13 :
Total Pages : 940 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis International Aerospace Abstracts by :

Download or read book International Aerospace Abstracts written by and published by . This book was released on 1996 with total page 940 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Handbook of Solid State Electrochemistry

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Publisher : CRC Press
ISBN 13 : 1420049305
Total Pages : 644 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Handbook of Solid State Electrochemistry by : P. J. Gellings

Download or read book Handbook of Solid State Electrochemistry written by P. J. Gellings and published by CRC Press. This book was released on 2019-04-24 with total page 644 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Solid State Electrochemistry is a one-stop resource treating the two main areas of solid state electrochemistry: electrochemical properties of solids such as oxides, halides, and cation conductors; and electrochemical kinetics and mechanisms of reactions occurring on solid electrolytes, including gas-phase electrocatalysis. The fund

Nanomaterials For Energy Conversion And Storage

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Publisher : World Scientific
ISBN 13 : 1786343649
Total Pages : 836 pages
Book Rating : 4.7/5 (863 download)

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Book Synopsis Nanomaterials For Energy Conversion And Storage by : Dunwei Wang

Download or read book Nanomaterials For Energy Conversion And Storage written by Dunwei Wang and published by World Scientific. This book was released on 2017-11-10 with total page 836 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of nanomaterials in energy conversion and storage represents an opportunity to improve the performance, density and ease of transportation in renewable resources. This book looks at the most recent research on the topic, with particular focus on artificial photosynthesis and lithium-ion batteries as the most promising technologies to date. Research on the broad subject of energy conversion and storage calls for expertise from a wide range of backgrounds, from the most fundamental perspectives of the key catalytic processes at the molecular level to device scale engineering and optimization. Although the nature of the processes dictates that electrochemistry is a primary characterization tool, due attention is given to advanced techniques such as synchrotron studies in operando. These studies look at the gap between the performance of current technology and what is needed for the future, for example how to improve on the lithium-ion battery and to go beyond its capabilities.Suitable for students and practitioners in the chemical, electrochemical, and environmental sciences, Nanomaterials for Energy Conversion and Storage provides the information needed to find scalable, economically viable and safe solutions for sustainable energy.

Handbook of Electrochemistry

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Publisher : Elsevier
ISBN 13 : 0444519580
Total Pages : 935 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Handbook of Electrochemistry by : Cynthia G. Zoski

Download or read book Handbook of Electrochemistry written by Cynthia G. Zoski and published by Elsevier. This book was released on 2007-02-07 with total page 935 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)

Lithium-ion Batteries

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Publisher : World Scientific
ISBN 13 : 1860943624
Total Pages : 424 pages
Book Rating : 4.8/5 (69 download)

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Book Synopsis Lithium-ion Batteries by : Perla B. Balbuena

Download or read book Lithium-ion Batteries written by Perla B. Balbuena and published by World Scientific. This book was released on 2004 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The SEI film is due to electromechanical reduction of species present in the electrolyte. It is widely recognized that the presence of the film plays an essential role in the battery performance, and its very nature can determine an extended (or shorter) life for the battery. In spite of the numerous related research efforts, details on the stability of the SEI composition and its influence on the battery capacity are still controversial. This book carefully analyzes and discusses the most recent findings and advances on this topic.

Physics of Surfaces and Interfaces

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Publisher : Springer Science & Business Media
ISBN 13 : 3540347100
Total Pages : 653 pages
Book Rating : 4.5/5 (43 download)

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Book Synopsis Physics of Surfaces and Interfaces by : Harald Ibach

Download or read book Physics of Surfaces and Interfaces written by Harald Ibach and published by Springer Science & Business Media. This book was released on 2006-11-18 with total page 653 pages. Available in PDF, EPUB and Kindle. Book excerpt: This graduate-level textbook covers the major developments in surface sciences of recent decades, from experimental tricks and basic techniques to the latest experimental methods and theoretical understanding. It is unique in its attempt to treat the physics of surfaces, thin films and interfaces, surface chemistry, thermodynamics, statistical physics and the physics of the solid/electrolyte interface in an integral manner, rather than in separate compartments. It is designed as a handbook for the researcher as well as a study-text for graduate students. Written explanations are supported by 350 graphs and illustrations.

Active Protective Coatings

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Publisher : Springer
ISBN 13 : 9401775400
Total Pages : 429 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Active Protective Coatings by : Anthony E. Hughes

Download or read book Active Protective Coatings written by Anthony E. Hughes and published by Springer. This book was released on 2016-03-01 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers a broad range of materials science that has been brought to bear on providing solutions to the challenges of developing self-healing and protective coatings for a range of metals. The book has a strong emphasis on characterisation techniques, particularly new techniques that are beginning to be used in the coatings area. It features many contributions written by experts from various industrial sectors which examine the needs of the sectors and the state of the art. The development of self-healing and protective coatings has been an expanding field in recent years and applies a lot of new knowledge gained from other fields as well as other areas of materials science to the development of coatings. It has borrowed from fields such as the food and pharmaceutical industries who have used, polymer techniques, sol-gel science and colloidosome technology for a range encapsulation techniques. It has also borrowed from fields like hydrogen storage such as from the development of hierarchical and other materials based on organic templating as “nanocontainers” for the delivery of inhibitors. In materials science, recent developments in high throughput and other characterisation techniques, such as those available from synchrotrons, are being increasing used for novel characterisation – one only needs to look at the application of these techniques in self healing polymers to gauge wealth of new information that has been gained from these techniques. This work is largely driven by the need to replace environmental pollutants and hazardous chemicals that represent risk to humans such as chromate inhibitors which are still used in some applications.