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Elaboration Characterization And Design Of Zns Thin Films For Optoelectronic Applications
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Book Synopsis Elaboration, Characterization and Design of ZnS Thin Films for Optoelectronic Applications by : Abdelhak Jrad
Download or read book Elaboration, Characterization and Design of ZnS Thin Films for Optoelectronic Applications written by Abdelhak Jrad and published by . This book was released on 2017 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zinc sulfide is one of the first semiconductors discovered. It has great potential application thanks to its physicochemical properties. It is used extensively in optoelectronic, photocatalytic and gas detection applications. In particular, it is used for photovoltaic applications. In this work, the effect of doping by transition metals (manganese, cobalt and copper) on the structural, microstructural, morphological, optical, electrical and magnetic properties of zinc sulfide thin films prepared by chemical bath deposition (CBD) technique are studied by X-ray diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy, infrared spectroscopy, scanning electron microscopy, UV-VIS-NIR spectrophotometry, Hall effect and SQUID. The modeling and optimization of higher efficiency Cu(In,Ga)Se2 solar cells are also investigated in this thesis for various layers thickness by using Silvaco ATLAS.
Book Synopsis Growth, Characterization and Applications of Zinc Sulfide Thin Films by Solution-Based Processes by : Dick Chiu
Download or read book Growth, Characterization and Applications of Zinc Sulfide Thin Films by Solution-Based Processes written by Dick Chiu and published by . This book was released on 2017 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zinc Sulfide (ZnS) thin film, with a wide band gap, has been used for many applications, such as buffer layer for CIGS solar cells, light emitting diodes and thin film electroluminescent devices. In this work, ZnS thin films were prepared using two different deposition processes. In the first method, ZnS thin films were deposited by using conventional chemical bath deposition (CBD) process. Micro-reactor assisted solution deposition (MASD) with a flow cell was used as the second method. Growth kinetics of ZnS thin films in CBD was analyzed using in-situ quartz crystal microbalance measurements, and ex-situ transmission electron microscopy (TEM) and scanning electron microscopy (SEM) measurements. The results from the TEM and SEM measurements suggest that the film growth follows a two-step process with the formation of the nuclei in the solution first, attachment to the surface, followed by aggregation of nanoparticles into half spheres on the surface of the substrate and finally half spheres connect to the neighbor half spheres, thereby forming a continuous film. The mechanism study, verified by the SEM images, shows that nucleation starts very early in the CBD process. The degree of supersaturation influences the growth rate and final surface morphology. Temperature-dependent growth rate in the linear growth region follows the Arrhenius equation with an estimated value of activation energy (Ea) to be around 36 KJ/mol. This value, which is considered low (less than 40 kJ/mol), indicates that the rate limiting step is more likely to be a physical process such as adsorption or diffusion, rather than a chemical process, which tends to have higher activation energies. In our study, the chemical bath is vigorously stirred so that the rate-limiting step is likely controlled by a physically adsorption mechanism. The continuous flow micro reactor was used to deposit ZnS thin films using various flow cells of different designs. The depositions were carried out on display glass of 1 inch wide by 3 inches long. Both analytical equations (Hagen-Poiseuille) and computational fluid dynamics were applied to determine proper height for the flow channel. COMSOL Multiphysics simulation of fluid flow along with particle tracer was carried out to find an optimum cut out radius for further study. The film thickness growth kinetics and solute concentration near the substrate surface was simulated using the COMSOL Multiphysics program with an assumption of laminar flow, transport of diluted species and a simplified first order reaction. An insert that mimics a cut out radius of 2.31 inches was fabricated using a 3D printer and installed in the flow cell to deposit ZnS thin films. ZnS thin films deposited using the flow cells with and without the 3D printed insert were investigated. The results were analyzed using plane-view and cross-sectional SEM images. The film thickness was determined by cross-sectional SEM image. The results indicated that the thickness uniformity was improved with the 3D printed insert. We found toward the end of the substrate, the ZnS thin film was not continuous due to the lower solution concentration caused by the depletion of reactants. New flow cell designs were proposed and COMSOL simulation was performed to examine the effectiveness of these flow cells. To demonstrate the utility of the ZnS thin films by solution-based processes, SnS and CuS thin films were deposited on top of the ZnS thin film to form SnS/CuS/ZnS layered precursor film then followed by selenziation at various temperatures in an attempt to produce CZTSSe absorber layers for CZTSSe thin film solar cells.
Book Synopsis Studies and Characterization of ZnS Thin Films by : Arunkumar Alagesan
Download or read book Studies and Characterization of ZnS Thin Films written by Arunkumar Alagesan and published by LAP Lambert Academic Publishing. This book was released on 2017-06-19 with total page 60 pages. Available in PDF, EPUB and Kindle. Book excerpt: The II-VI compound semiconductors are of great importance due to their application in various electro-optic devices. Thin films of ZnS find many more applications in the area of opto electronic device fabrication like UV light emitting diodes, blue light emitting diodes, emissive flat screens, electroluminescent devices and antireflection coating in solar cell technology. Several methods have been used to prepare ZnS thin films. We have deposited ZnS films using chemical bath deposition method using sodium hydroxide as a complexing agent. The structural and morphological characteristics of films have been investigated by X-ray diffraction (XRD) and scanning electron microscope. XRD shows deposited film was polycrystalline nature with cubic structure. The grain size is estimated to be in the range of 35-70 nm. The crystallinity of the ZnS film was analysed by HRTEM with the help of the electron diffraction pattern. The films show good optical properties with high transmittance in the visible region and the band gap value were found 3.3 eV - 2.1 eV. ZnS films can be used as buffer layers on CdTe solar cells.
Book Synopsis Characterization of ZnS Thin Films Grown by MOCVD by : Jie Fang
Download or read book Characterization of ZnS Thin Films Grown by MOCVD written by Jie Fang and published by . This book was released on 1992 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis ZnO Thin Films for Optoelectronic Applications by : Prasada Rao Talakonda
Download or read book ZnO Thin Films for Optoelectronic Applications written by Prasada Rao Talakonda and published by LAP Lambert Academic Publishing. This book was released on 2013 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zinc oxide (ZnO) thin films have good electro-optical properties suitable for opto-electronic applications. The present study explains the deposition and characterization of n-type and p-type ZnO thin films by spray pyrolysis. The films were characterized by different methods to understand their structural, optical and electrical properties. Gallium was chosen as the impurity dopant in ZnO films to improve the electrical properties. The electrical conductivity, carrier concentration and mobility of Ga doped ZnO (GZO) films were highly improved in comparison to undoped ZnO films. The GZO films showed good optical transmittance in the visible region. The electrical and optical results suggest that the GZO films are suitable to use as a TCO in optoelectronic industries. The p-type ZnO thin films were successesfully realized using dual acceptor method. The Hall measurements and room temperature photolumiscence results were supported p-type nature of (Li, N): ZnO thin films.
Book Synopsis Characterization of ZnS Thin Films Grown on the Basal Face of Zn Single Crystals by Reactive Diffusion by : Dave S. Gahunia
Download or read book Characterization of ZnS Thin Films Grown on the Basal Face of Zn Single Crystals by Reactive Diffusion written by Dave S. Gahunia and published by . This book was released on 1991 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Successive Ionic Layer Adsorption and Reaction (SILAR) Growth and Characterization of ZnS and ZnS:Mn Thin Films by : Seppo Lindroos
Download or read book The Successive Ionic Layer Adsorption and Reaction (SILAR) Growth and Characterization of ZnS and ZnS:Mn Thin Films written by Seppo Lindroos and published by . This book was released on 1997 with total page 47 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Thin Film Solar Cells by : Jef Poortmans
Download or read book Thin Film Solar Cells written by Jef Poortmans and published by John Wiley & Sons. This book was released on 2006-10-16 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thin-film solar cells are either emerging or about to emerge from the research laboratory to become commercially available devices finding practical various applications. Currently no textbook outlining the basic theoretical background, methods of fabrication and applications currently exist. Thus, this book aims to present for the first time an in-depth overview of this topic covering a broad range of thin-film solar cell technologies including both organic and inorganic materials, presented in a systematic fashion, by the scientific leaders in the respective domains. It covers a broad range of related topics, from physical principles to design, fabrication, characterization, and applications of novel photovoltaic devices.
Book Synopsis Functional Thin Films and Nanostructures for Sensors by : Anis Zribi
Download or read book Functional Thin Films and Nanostructures for Sensors written by Anis Zribi and published by Springer Science & Business Media. This book was released on 2009-04-05 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses advances in functional thin films for sensors and novel concepts for future breakthroughs. The focus is on guidelines and design rules for sensor systems, interaction between functional thin films and other sensor subsystems, fundamentals behind the intrinsic functionality in sensing thin films and nanostructures, state-of-the-art technologies used to develop sensors today and concrete examples of sensor designs.
Book Synopsis Chemical Solution Deposition of Functional Oxide Thin Films by : Theodor Schneller
Download or read book Chemical Solution Deposition of Functional Oxide Thin Films written by Theodor Schneller and published by Springer Science & Business Media. This book was released on 2014-01-24 with total page 801 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first text to cover all aspects of solution processed functional oxide thin-films. Chemical Solution Deposition (CSD) comprises all solution based thin- film deposition techniques, which involve chemical reactions of precursors during the formation of the oxide films, i. e. sol-gel type routes, metallo-organic decomposition routes, hybrid routes, etc. While the development of sol-gel type processes for optical coatings on glass by silicon dioxide and titanium dioxide dates from the mid-20th century, the first CSD derived electronic oxide thin films, such as lead zirconate titanate, were prepared in the 1980’s. Since then CSD has emerged as a highly flexible and cost-effective technique for the fabrication of a very wide variety of functional oxide thin films. Application areas include, for example, integrated dielectric capacitors, ferroelectric random access memories, pyroelectric infrared detectors, piezoelectric micro-electromechanical systems, antireflective coatings, optical filters, conducting-, transparent conducting-, and superconducting layers, luminescent coatings, gas sensors, thin film solid-oxide fuel cells, and photoelectrocatalytic solar cells. In the appendix detailed “cooking recipes” for selected material systems are offered.
Book Synopsis Chemical Solution Deposition Of Semiconductor Films by : Gary Hodes
Download or read book Chemical Solution Deposition Of Semiconductor Films written by Gary Hodes and published by CRC Press. This book was released on 2002-10-08 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Discussing specific depositions of a wide range of semiconductors and properties of the resulting films, Chemical Solution Deposition of Semiconductor Films examines the processes involved and explains the effect of various process parameters on final film and film deposition outcomes through the use of detailed examples. Supplying experimental res
Book Synopsis Earth-Abundant Materials for Solar Cells by : Sadao Adachi
Download or read book Earth-Abundant Materials for Solar Cells written by Sadao Adachi and published by John Wiley & Sons. This book was released on 2015-10-28 with total page 848 pages. Available in PDF, EPUB and Kindle. Book excerpt: Systematically describes the physical and materials properties of copper-based quaternary chalcogenide semiconductor materials, enabling their potential for photovoltaic device applications. Intended for scientists and engineers, in particular, in the fields of multinary semiconductor physics and a variety of photovoltaic and optoelectronic devices.
Book Synopsis The Materials Science of Thin Films by : Milton Ohring
Download or read book The Materials Science of Thin Films written by Milton Ohring and published by Academic Press. This book was released on 1992 with total page 744 pages. Available in PDF, EPUB and Kindle. Book excerpt: Prepared as a textbook complete with problems after each chapter, specifically intended for classroom use in universities.
Book Synopsis Chemically Deposited Nanocrystalline Metal Oxide Thin Films by : Fabian I. Ezema
Download or read book Chemically Deposited Nanocrystalline Metal Oxide Thin Films written by Fabian I. Ezema and published by Springer Nature. This book was released on 2021-06-26 with total page 926 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book guides beginners in the areas of thin film preparation, characterization, and device making, while providing insight into these areas for experts. As chemically deposited metal oxides are currently gaining attention in development of devices such as solar cells, supercapacitors, batteries, sensors, etc., the book illustrates how the chemical deposition route is emerging as a relatively inexpensive, simple, and convenient solution for large area deposition. The advancement in the nanostructured materials for the development of devices is fully discussed.
Book Synopsis Encyclopedia of Materials Characterization by : Charles A. Evans
Download or read book Encyclopedia of Materials Characterization written by Charles A. Evans and published by Gulf Professional Publishing. This book was released on 1992 with total page 784 pages. Available in PDF, EPUB and Kindle. Book excerpt: "This is a comprehensive volume on analytical techniques used in materials science for the characterization of surfaces, interfaces and thin films. This flagship volume is a unique, stand-alone reference for materials science practitioners, process engineers, students and anyone with a need to know about the capabilities available in materials analysis. An encyclopedia of 50 concise articles, this book will also be a practical companion to the forthcoming books in the series."--Knovel.
Download or read book Ceramic Abstracts written by and published by . This book was released on 1994 with total page 972 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Energy-Level Control at Hybrid Inorganic/Organic Semiconductor Interfaces by : Raphael Schlesinger
Download or read book Energy-Level Control at Hybrid Inorganic/Organic Semiconductor Interfaces written by Raphael Schlesinger and published by Springer. This book was released on 2016-11-21 with total page 223 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work investigates the energy-level alignment of hybrid inorganic/organic systems (HIOS) comprising ZnO as the major inorganic semiconductor. In addition to offering essential insights, the thesis demonstrates HIOS energy-level alignment tuning within an unprecedented energy range. (Sub)monolayers of organic molecular donors and acceptors are introduced as an interlayer to modify HIOS interface-energy levels. By studying numerous HIOS with varying properties, the author derives generally valid systematic insights into the fundamental processes at work. In addition to molecular pinning levels, he identifies adsorption-induced band bending and gap-state density of states as playing a crucial role in the interlayer-modified energy-level alignment, thus laying the foundation for rationally controlling HIOS interface electronic properties. The thesis also presents quantitative descriptions of many aspects of the processes, opening the door for innovative HIOS interfaces and for future applications of ZnO in electronic devices.
