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Download or read book Effects of Catalytic Mineral Matter on CO written by and published by . This book was released on 1993 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
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ISBN 13 :
Total Pages : 19 pages
Book Rating : 4.:/5 (727 download)
Download or read book Effects of Catalytic Mineral Matter CO written by and published by . This book was released on 1989 with total page 19 pages. Available in PDF, EPUB and Kindle. Book excerpt: The temperature of a char particle burning in an oxygen containing atmosphere is the product of a strongly coupled balance between particle size and physical properties, heat transfer from the particle, surface reactivity, CO/CO[sub 2] ratio and gas phase diffusion in the surrounding boundary layer and within the particle. The heat released by formation Of CO[sub 2] is a factor of 3.5 higher than for CO so the temperature of a particle will depend strongly on the CO/CO[sub 2] ratio produced. If gas diffusion through the boundary layer is fast, increased direct production of CO[sub 2] produces a higher temperature and a higher burning rate. If the supply of oxygen to the surface is limited by diffusion through the boundary layer, production of CO[sub 2] consumes half as much carbon as production of CO so carbon consumption rate is reduced even though temperature may be somewhat higher. Models of these complex interaction have been developed; however, the CO/CO[sub 2] ratio produced by the carbon-oxygen reaction must, at present be assumed or inferred from measurement of particle temperature. CO/CO[sub 2] rates can be strongly influenced by catalytic material in the carbon and by the char temperature. In this program we are measuring the CO/CO[sub 2] ratio for both catalyzed and uncatalyzed chars over a wide range of temperature. These results will then be used to develop predictive models for char temperature and burning rates.
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ISBN 13 :
Total Pages : 11 pages
Book Rating : 4.:/5 (16 download)
Download or read book Effects of Catalytic Mineral Matter on CO/CO Sub 2, Temperature and Burning Time for Char Combustion written by and published by . This book was released on 1992 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt: The temperature of a char particle burning in an oxygen containing atmosphere is the product of a strongly coupled balance between particle size and physical properties, heat transfer from the particle, surface reactivity, CO/CO2 ratio and gas phase diffusion in the surrounding boundary layer and within the particle. CO2/CO ratios can be strongly influenced by catalytic material in the carbon and by the char temperature. In this program we are measuring the CO2/CO ratio for both catalyzed and uncatalyzed chars over a wide range of temperature. These results will then be used to develop predictive models for char temperature and burning rates. The electrodynamic balance has been successfully used to make such measurements for single 200?m spherocarb particles. A few theoretical approaches to model a single particle oxidation have been made, but most of them assumed the infinitely thin reaction zone at the particle surface. This approach can not explain pore diffusion limitation, structural change, or reaction at low temperatures inside the particle. Too simplifying solid phase reaction may leads to wrong predictions. In this report, progress on constructing models including both solid and gas phase reaction are reported.
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ISBN 13 :
Total Pages : 13 pages
Book Rating : 4.:/5 (873 download)
Download or read book Effects of Catalytic Mineral Matter on CO/CO2 Ratio, Temperature and Burning Time for Char Combustion. Quarterly Progress Report No. 3, April--June 1990 written by and published by . This book was released on 1990 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: We have extended our recently reported method for determining the surface area of single microporous particles, Dudek et al., 1989 using an electrodynamic chamber (EDC) by increasing the operating pressures from 1 at to 25 at. The value of total surface area is determined from adsorption measurements of CO2 assuming monolayer adsorption. Measurements of CO2 desorption were also carried out to yield a point to point difference from the adsorption measurements of about 1%. Adsorption-desorption cycles were carried out for 10 particles to yield a scatter of less than 5% in the measured value for saturation adsorption. The major advantage of using high pressure measurements for evaluating the saturation value for CO2 adsorption is the improved accuracy of the extrapolation procedure. Previous measurements with the EDC at atmospheric pressure, Dudek, et al., 1989, yielded values for the surface area for similar particles of comparable value with a relative error of about 15%. The results of the high pressure measurements are however bounded with an error of about 3%. Also, the equilibrium adsorption-desorption coefficient was found with a high accuracy, whereas from atmospheric measurements it was not practical to obtain an accurate value.
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ISBN 13 :
Total Pages : 31 pages
Book Rating : 4.:/5 (873 download)
Download or read book Effects of Catalytic Mineral Matter on CO/CO2 Temperature and Burning Time for Char Combustion. Quarterly Progress Report No. 11, April--June 1992 written by and published by . This book was released on 1992 with total page 31 pages. Available in PDF, EPUB and Kindle. Book excerpt: The high temperature oxidation of char is of interest in a number of applications in which coal must be burned in confined spaces. These include: the conversion of oil-fired boilers to coal using coal-water slurries, the development of a new generation of pulverized-coal-fired cyclone burners, the injection of coal into the tuyeres of blast furnaces, the use of coal as a fuel in direct-fired gas turbines in large-bore low-speed diesels, and entrained flow gasifiers. In addition, there is a need to better understand the temperature history of char particles in conventional pulverized-coal-fired boilers in order to better understand the processes governing the formation of pollutants and the transformation of mineral matter. The temperature of a char particle burning in an oxygen containing atmosphere is the product of a strongly coupled balance between particle size and physical properties, heat transfer from the particle, surface reactivity, CO/CO2 ratio and gas phase diffusion in the surrounding boundary layer and within the particle. In addition to its effects on burning rate, particle temperature has major effects on ash proper-ties and mineral matter vaporization. Measurements of the temperature of individual burning char particles have become available in recent years and have clearly demonstrated large particle to particle temperature variations which depend strongly on particle size and on panicle composition. These studies, done with pulverized coal, do not allow direct determination of the CO/CO2 ratio produced at the char surface or the catalytic effects of mineral matter in the individual char particles and it has generally been assumed that CO is the only product of the carbon-oxygen reaction and that CO2 is formed by subsequent gas phase reaction More recent work, however, has pointed out the need to take CO2 Production into consideration in order to account for observed particle temperatures.
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ISBN 13 :
Total Pages : 12 pages
Book Rating : 4.:/5 (893 download)
Download or read book Effects of Catalytic Mineral Matter on CO/CO Sub 2 Ratio, Temperature and Burning Time for Char Combustion written by and published by . This book was released on 1991 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt: The temperature of a char particle burning in an oxygen containing atmosphere is the product of a strongly coupled balance between particle size and physical properties, heat transfer from the particle, surface reactivity, CO/CO2 ratio and gas phase diffusion in the surrounding boundary layer and within the particle. CO2/CO ratios can be strongly influenced by catalytic material in the carbon and by the char temperature. In this program we are measuring the CO2/CO ratio for both catalyzed and uncatalyzed chars over a wide range of temperature. These results will then be used to develop predictive models for char temperature and burning rates. The electrodynamic balance has been successfully used to make such measurements for single 200 [mu]m spherocarb particles. This work has been previously reported (progress reports 1 and 2). The electrodynamic balance has been rebuilt to improve its performance including: (1) Better control of gas flow and composition, (2) High pressure operation capability, (3) Advanced imaging system for size measurement and position determination (4) Capability of high and low temperature measurement, (5) Better position control, (6) Fast computation and memory facilities, (7) Better laser power control. In this report, progress on the calibration of the imaging system, the laser power control system, and calibration of the mass flowrate controller are reported. 6 figs.
Author : Steven J. M. Butala
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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (463 download)
Download or read book Catalytic Effects of Mineral Matter on Natural Gas Formation During Coal Maturation written by Steven J. M. Butala and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
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ISBN 13 :
Total Pages : 15 pages
Book Rating : 4.:/5 (873 download)
Download or read book Effects of Catalytic Mineral Matter on CO/CO2 Temperature and Burning Time for Char Combustion. Quarterly Progress Report No. 14, January--March 1993 written by and published by . This book was released on 1993 with total page 15 pages. Available in PDF, EPUB and Kindle. Book excerpt: The high temperature oxidation of char is of interest in a number of applications in which coal must be burned in confined spaces. The temperature of char particle burning is the product of a strongly coupled balance between particle size and physical properties, heat transfer, surface reactivity, CO/CO2 ratio and gas phase diffusion in the surrounding boundary layer and within the particle. In addition to the effects of particle temperature on burning rate, it has major effects on ash properties and mineral matter vaporization. Measurements of the temperature of individual burning char particles have become available in recent years and have clearly demonstrated large particle-to-particle temperature variations which depend strongly on particle size and on particle composition. These studies, done with pulverized coal, can not determine the CO/CO2 ratio produced at the char surface or the catalytic effects of mineral matter in the individual char particles. Consequently, it has generally been assumed that CO is the only product of the carbon-oxygen reaction and that CO2 is formed by subsequent gas phase reaction. More recent work, however, has pointed out the need to take CO2 production into consideration in order to account for observed particle temperatures.
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ISBN 13 :
Total Pages : 37 pages
Book Rating : 4.:/5 (893 download)
Download or read book Effects of Catalytic Mineral Matter on CO/CO2 Temperature and Burning Time for Char Combustion. Quarterly Progress Report No. 15 (Final Report), October 1993--December 1993 written by and published by . This book was released on 1993 with total page 37 pages. Available in PDF, EPUB and Kindle. Book excerpt: The high temperature oxidation of char is of interest in a number of applications in which coal must be burned in confined spaces including the conversion of oil-fired boilers to coal using coal-water slurries, the development of a new generation of pulverized-coal-fired cyclone burners, the injection of coal into the tuyeres of blast furnaces, the use of coal as a fuel in direct-fired gas turbines and in large-bore low-speed diesels, and entrained flow gasifiers. There is a need to understand the temperature history of char particles in conventional pulverized-coal-fired boilers to better explain the processes governing the formation of pollutants and the transformation of mineral matter. The temperature of char particle burning is the product of a strongly coupled balance between particle physical properties, heat and mass transfer, surface reaction, and CO/CO2 ratio. Particle temperature has major effects not only on the burning rate but also on ash properties and mineral matter vaporization. Measurements of the temperature of individual burning char particles have clearly demonstrated large particle-to-particle temperature variations which depend strongly on particle size and on particle composition. This report consists of two major parts. In the first part, experimental measurements of CO/CO2 ratio for a single spherocarb particle is presented along with a kinetic model which allows estimation of CO/CO2 generated at a carbon surface for temperatures higher than those reported in the experimental work. In the second part, modeling of a temperature profile during a char combustion is reported, and also progress in modeling the complex sets of coupled phenomena involving full gas phase reaction kinetics, heat transfer, and mass transfer is summarized. In the appendix progress on construction and testing of an improved electrodynamic balance is presented.
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ISBN 13 :
Total Pages : 8 pages
Book Rating : 4.:/5 (873 download)
Download or read book Effects of Catalytic Mineral Matter on CO/CO2 Temperature and Burning Time for Char Combustion. Quarterly Progress Report No. 13, October--December 1992 written by and published by . This book was released on 1992 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt: The heat released by formation of CO2 is a factor of 3.5 higher than for CO so the temperature of a particle will depend strongly on the CO/CO2 ratio produced. If gas diffusion through the boundary of CO2 produces a higher temperature and a higher burning rate. If the supply of oxygen to the surface is limited by diffusion through the boundary layer, production of CO2 consumes half as much carbon as production of CO so carbon consumption rate is reduced even though temperature may be somewhat higher. A few theoretical approaches have been attempted to model gas phase reactions using global reaction kinetics. Due to importance of CO oxidation in the boundary layer and its subsequent heat and mass transfer, we need to develop a gas phase model incorporating full reaction kinetics, heat, and mass transfer. In this report, effects of oxygen disassociation on heat transfer and modeling results of boundary gas phase reactions are reported. Due to nonlinearity and high temperature, there is a need to develop an efficient method of evaluating integration of nonlinear terms in Galerkin Finite Elements Method.
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ISBN 13 :
Total Pages : 11 pages
Book Rating : 4.:/5 (873 download)
Download or read book Effects of Catalytic Mineral Matter on CO/CO2, Temperature and Burning Time for Char Combustion. Quarterly Progress Report No. 10, January--March 1992 written by and published by . This book was released on 1992 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt: The temperature of a char particle burning in an oxygen containing atmosphere is the product of a strongly coupled balance between particle size and physical properties, heat transfer from the particle, surface reactivity, CO/CO2 ratio and gas phase diffusion in the surrounding boundary layer and within the particle. CO2/CO ratios can be strongly influenced by catalytic material in the carbon and by the char temperature. In this program we are measuring the CO2/CO ratio for both catalyzed and uncatalyzed chars over a wide range of temperature. These results will then be used to develop predictive models for char temperature and burning rates. The electrodynamic balance has been successfully used to make such measurements for single 200[mu]m spherocarb particles. A few theoretical approaches to model a single particle oxidation have been made, but most of them assumed the infinitely thin reaction zone at the particle surface. This approach can not explain pore diffusion limitation, structural change, or reaction at low temperatures inside the particle. Too simplifying solid phase reaction may leads to wrong predictions. In this report, progress on constructing models including both solid and gas phase reaction are reported.
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ISBN 13 :
Total Pages : 19 pages
Book Rating : 4.:/5 (873 download)
Download or read book Effects of Catalytic Mineral Matter CO/CO2 Ratio on Temperature and Burning Time for Char Combustion. Quarterly Progress Report No. 1, October--December 1989 written by and published by . This book was released on 1989 with total page 19 pages. Available in PDF, EPUB and Kindle. Book excerpt: The temperature of a char particle burning in an oxygen containing atmosphere is the product of a strongly coupled balance between particle size and physical properties, heat transfer from the particle, surface reactivity, CO/CO2 ratio and gas phase diffusion in the surrounding boundary layer and within the particle. The heat released by formation Of CO2 is a factor of 3.5 higher than for CO so the temperature of a particle will depend strongly on the CO/CO2 ratio produced. If gas diffusion through the boundary layer is fast, increased direct production of CO2 produces a higher temperature and a higher burning rate. If the supply of oxygen to the surface is limited by diffusion through the boundary layer, production of CO2 consumes half as much carbon as production of CO so carbon consumption rate is reduced even though temperature may be somewhat higher. Models of these complex interaction have been developed; however, the CO/CO2 ratio produced by the carbon-oxygen reaction must, at present be assumed or inferred from measurement of particle temperature. CO/CO2 rates can be strongly influenced by catalytic material in the carbon and by the char temperature. In this program we are measuring the CO/CO2 ratio for both catalyzed and uncatalyzed chars over a wide range of temperature. These results will then be used to develop predictive models for char temperature and burning rates.
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ISBN 13 :
Total Pages : 9 pages
Book Rating : 4.:/5 (873 download)
Download or read book Effects of Catalytic Mineral Matter on CO/CO2 Ratio, Temperature and Burning Time for Char Combustion. Quarterly Progress Report No. 2, January--March 1990 written by and published by . This book was released on 1990 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt: The importance of the CO2/CO ratio of carbon oxidation products is illustrated by examination of the heats of reaction for formation of these two products. The heat released by formation of CO2 is a factor of 3.5 higher than for CO so the temperature of a particle will depend strongly on the CO2/CO ratio produced. If gas diffusion through the boundary layer is fast, increased direct production Of CO2 produces a higher temperature and a higher burning rate. If the supply of oxygen to the surface is limited by diffusion through the boundary layer, production of CO2 consumes half as much carbon as production of CO so carbon consumption rate is reduced even though temperature may be somewhat higher. Models of these complex interactions have been developed; however the CO2/CO ratio produced by the carbon-oxygen reaction must, at present be assumed or inferred from measurement of particle temperature. CO2/CO ratios can be strongly influenced by catalytic material in the carbon and by the char temperature. In this program we are measuring the CO2/CO ratio for both catalyzed and uncatalyzed chars over a wide range of temperature. These results will then be used to develop predictive models for char temperature and burning rates. Measurements of CO2/CO ratio for an uncatalyzed char (spherocarb) were reported in the Oct-Dec 1989 progress report. This ratio varied from a maximum of 1.5 at 700 K and 100% oxygen to 0.06 at 1430 K and 5% oxygen.
Download or read book Study of Catalytic Effects of Mineral Matter Level on Coal Reactivity written by and published by . This book was released on 1981 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Coal liquefaction experiments using a 400-lb/day bubble-column reactor tested the catalytic effects of added mineral matter level on coal conversion, desulfurization, and distillate yields in continuous operation under recycle conditions, with specific emphasis on the use of a disposable pyrite catalyst indigenous to the feed coal. Western Kentucky No. 11 run-of-mine (ROM) and washed coals were used as feedstocks to determine the effects of levels of mineral matter, specifically iron compounds. Liquefaction reactivity as characterized by total distillate yield was lower for washed coal, which contained less mineral matter. Liquefaction reactivity was regained when pyrite concentrate was added as a disposable catalyst to the washed coal feed in sufficient quantity to match the feed iron concentration of the run-of-mine coal liquefaction test run.
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ISBN 13 :
Total Pages : 652 pages
Book Rating : 4.:/5 (319 download)
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1994 with total page 652 pages. Available in PDF, EPUB and Kindle. Book excerpt:
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ISBN 13 :
Total Pages : 66 pages
Book Rating : 4.:/5 (929 download)
Download or read book Mineral Matter Effects and Catalyst Characterization in Coal Liquefaction, Mineral Matter Effects (project No. 8008) written by and published by . This book was released on 1979 with total page 66 pages. Available in PDF, EPUB and Kindle. Book excerpt:
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ISBN 13 :
Total Pages : 544 pages
Book Rating : 4.0/5 ( download)
Download or read book Energy Research Abstracts written by and published by . This book was released on 1994-06 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt:
