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Author : Timea Stelzig
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (796 download)
Download or read book Donor-acceptor Systems in the Quest for Organic Semiconductors written by Timea Stelzig and published by . This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Timea Stelzig
Publisher :
ISBN 13 :
Total Pages : 207 pages
Book Rating : 4.:/5 (796 download)
Download or read book Donor-acceptor Systems in the Quest for Organic Semiconductors written by Timea Stelzig and published by . This book was released on 2012 with total page 207 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (81 download)
Download or read book Donor-acceptor Systems in the Quest for Organic Semiconductors written by and published by . This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The last few decades brought along the development of many new organic semiconductors that have been successfully incorporated into "high" performance devices, such as field effect transistors (FETs), organic light emitting diods (OLEDs), organic photovoltaic cells (OPVs) and sensors. With the technology in its puberty some of the materials have reached the minimal requirements for commercialization, but there is still much to be discovered, explained and understood. rnThe research described in this work aims to design, synthesize and characterize new semiconducting polymers with tuned optoelectronic properties, that would enable efficient ambipolar or n-type charge carriers transport for OFETs or OPVs applications. The main goal is achieved by following rational design principles meant to exploit the beneficial properties of the thiadiazolo[3,4-g]quinoxaline building block as a planar, electron deficient heterocycle and those of ethynylene pi-spacers, connecting the donor (D) and the acceptor (A) unit in a D-A copolymer. Within this frame of work, synthetic issues as well as detailed optoelectronic studies of the conjugated polymers and their corresponding model compounds are covered. Additionally, the first example of triple-bond containing polymer showing nearly balanced ambipolar charge transport characteristics when applied in an OFET is presented as well.rnThe last part of this thesis seeks to explore, within the Marcus-Hush theory, mixedvalence phenothiazines and their electron transfer processes, when connected via an electron deficient pi-bridge, such as benzo[c][2,1,3]thiadiazole
Author : Quan Li
Publisher : John Wiley & Sons
ISBN 13 : 1118009045
Total Pages : 376 pages
Book Rating : 4.1/5 (18 download)
Download or read book Self-Organized Organic Semiconductors written by Quan Li and published by John Wiley & Sons. This book was released on 2011-03-03 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on the exciting topic on self-organized organic semiconductors – from materials to device applications. It offers up-to-date and accessible coverage of self-organized semiconductors for organic chemistry, polymer science, liquid crystals, materials science, material engineering, electrical engineering, chemical engineering, optics, optic-electronics, nanotechnology and semiconductors. Chapters cover chemistry, physics, processing, and characterization. The applications include photovoltaics, light-emitting diodes (LEDs), and transistors.
Author : Jia Du
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (13 download)
Download or read book Donor-acceptor Organic Semiconductors written by Jia Du and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic semiconductors have drawn remarkable attention due to their light weight, feasible fabrication and flexibility in the field of organic photovoltaics and field effect transistors. The rapidly increasing world population and the accompanied with huge energy demands are becoming a big concern for the future, which makes harvesting unlimited solar power using photovoltaic devices extremely important. A remarkable amount of research has been done to improve the power conversion efficiency in terms of the materials design, morphology investigations and device engineering. Organic field effect transistors utilizing solution-processed conjugated polymers can be fabricated efficiently at a low cost roll-to-roll technique over a large area. Designing high performing conjugated polymers and investigating their morphology is essential. In this dissertation, the fundamentals and the recent developments of organic semiconductors are covered in Chapter 1. The basic operation mechanism of organic photovoltaics and field effect transistors are introduced. Semiconducting molecules and polymers that have been reported using benzo[1,2-b;4,5-b’]dithiophene (BDT), benzo[1,2-b;4,5-b’]difuran (BDF), 2,1,3-benzothiadiazole (BT), and diketopyrrolopyrrole (DPP), are discussed and summarized. Chapter 2 describes the isomeric effect of two small molecules containing BDT and BT units on the photovoltaic performance. The influence on UV-vis absorption, frontier molecular orbital energy level, and morphology due to the position of the BT unit was systematically investigated. The photovoltaic performance was studied in bulk heterojunction solar cells with [6, 6]-phenyl-C71-butyric acid methyl ester used as the acceptor. Chapter 3 describes the synthesis of novel conjugated polymers built from BDF and furan substituted DPP unit. Furan and its derivatives are regarded as green and renewable building units. This polymer was tested in bulk heterojunction solar cells with the highest power conversion efficiency of 5.55% and high fill factor of 0.73 achieved when 4% diphenyl ether was applied to optimize the phase separation. The morphology of the blend films was investigated by atomic force microscopy, grazing incident wide-angle X-ray scattering and transmission electron microscopy. In Chapter 4, an alternative copolymer built from furan substituted DPP and (E)-1,2-di(furan-2-yl)ethene was synthesized by Stille coupling and employed in organic field effect transistors. Hole mobility of 0.42 cm2 V-1 s-1 was achieved with current on/off ratio of 104 after annealing the thin film at 150 oC for 5 minutes. The higher mobility after thermal annealing was explained by the increased crystallinity, which was revealed by atomic force microscopy and grazing incident X-ray diffraction. At the end, the prospective and future work for the organic photovoltaics and field effect transistors are discussed in Chapter 5.
Author : Zixuan Guo
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (136 download)
Download or read book Understanding the Morphology at Donor-acceptor Interfaces in Organic Semiconductors written by Zixuan Guo and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic electronic devices, including organic photovoltaics (OPV), organic light-emitting diodes (OLEDs), and organic field-effect transistors (OFETs), have become increasingly important in consumer electronic applications due to the development of organic semiconductors, including organic small molecules, and conjugated polymers. They have advantages such as light weight, flexibility/stretchability, and the ability for roll-to-roll manufacturing. The structure and mechanism of organic devices are analogous to inorganic semiconductor devices, where donor materials (p-type) and acceptor materials (n-type) are used to create interfaces. To build high-performance organic electronic devices, it is essential to understand functionalities of organic heterojunction because they are building blocks of electronics. Organic heterojunction is interfaces created between donor and acceptor organic semiconductors. Exciting electronic action of devices occurs at organic interfaces. From a fundamental viewpoint, the role of interfaces must have optimal electronic and physical communication to yield highly efficient devices. From a technological viewpoint, one must understand, control, and have a rational design of the desired electronic and optical properties at organic interfaces for the development of different electronics and a host of potential new device concepts that have not yet been developed or realized. In this dissertation, we will use organic semiconductors for organic photovoltaics (OPV) as an example to investigat organic heterojunction interfaces, including interface fabrication, epitaxy, morphology control, and characterization, with the aim of building high-performance devices with good stability. We begin by discussing the growth of organic single-crystalline crystals with controlled orientations. Materials used are two small molecules: zinc phthalocyanine (ZnPc, p-type) and 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA, n-type). In this study, a self-built vertical physical vapor transport (v-PVT) chamber is used for crystallization, and a graphene-coated substrate is used to control molecular packing. Although ZnPc and PTCDA have a planar molecular shape and face-on packing motif on graphene, we find that they have different growth modes. Such growth mechanism difference can be explained by competition between intermolecular and molecule-graphene interactions. We then continue the abovementioned study by building model heterojunctions on graphene substrates using ZnPc and PTCDA. We discover that thermodynamics and kinetics of the system affect P-N junction morphology. We find that ZnPc and PTCDA form the "line-on-line" organic weak epitaxy at heterojunction interfaces from X-ray studies and crystallography refinement. We also verify that P-N junctions can generate electron-hole pairs. This work will advance the knowledge and create enabling opportunities to fabricate single-crystalline-oriented nanostructures. Besides using organic small molecules, we also explore the structure-property-performance relationship of conjugated block copolymers (BCPs) for OPV applications. In this work, a new donor-acceptor BCP is synthesized and added into polymer blend solar cells. We find that adding BCP could potentially retain the relative degree of crystallinity of [pi]-[pi] stacking regions, and decrease the detrimental interaction between donor polymer and electrode under thermal stress, thus improving the solar device's thermal stability by 30%. Finally, we explore the possibility of using graphene engineering for epitaxial growth dynamics control of organic small molecules. We determine that two distinct, alternating morphologies of ZnPc crystals are simultaneously observed on a single epitaxial SiC-graphene substrate. We hypothesize that the different morphologies arise from electronic structure and surface energy differences of underlying SiC-graphene regions ZnPc is grown on. The result will enable selective patterning of organic semiconductors for use in advanced warfare device applications. We hope these studies throughout this work will advance knowledge on fundamental crystallization mechanisms, interface engineering, morphology control, and characterization in organic crystalline systems. This work could further produce various future architectures for different applications in organic electronics.
Author : Nasim Zarrabi
Publisher : Springer Nature
ISBN 13 : 3030931625
Total Pages : 116 pages
Book Rating : 4.0/5 (39 download)
Download or read book Optoelectronic Properties of Organic Semiconductors written by Nasim Zarrabi and published by Springer Nature. This book was released on 2022-02-26 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on organic semiconductors with particular attention paid to their use as photovoltaic devices. It addresses a fundamental and hitherto overlooked concept in the field of organic optoelectronics, namely the role that sub-gap states play in the performance of organic semiconducting devices. From a technological point of view, organic semiconductor-based devices are of significant interest due to their lightweight, ease of processability, conformal flexibility, and potentially low cost and low embodied energy production. Motivated by these rather unique selling points, the performance of organic semiconductors has been a subject of multidisciplinary study for more than 60 years with steady progress in applications such as solar cells, transistors, light emitting diodes, and various sensors. The book begins with a review of the main electro-optical phenomena in organic solar cells and presents a new method for measuring exciton diffusion lengths based on a low-quencher-content device structure. Furthermore, the book reveals how mid-gap trap states are a universal feature in organic semiconductor donor–acceptor blends, unexpectedly contributing to charge generation and recombination, and having profound impact on the thermodynamic limit of organic photovoltaic devices. Featuring cutting-edge experimental observations supported with robust and novel theoretical arguments, this book delivers important new insight as to the underlying dynamics of exciton generation and diffusion, charge transfer state dissociation, and indeed the ultimate fate of photogenerated free carriers.
Author : Beata Luszczynska
Publisher : John Wiley & Sons
ISBN 13 : 3527814957
Total Pages : 688 pages
Book Rating : 4.5/5 (278 download)
Download or read book Solution-Processable Components for Organic Electronic Devices written by Beata Luszczynska and published by John Wiley & Sons. This book was released on 2019-06-07 with total page 688 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides first-hand insights into advanced fabrication techniques for solution processable organic electronics materials and devices The field of printable organic electronics has emerged as a technology which plays a major role in materials science research and development. Printable organic electronics soon compete with, and for specific applications can even outpace, conventional semiconductor devices in terms of performance, cost, and versatility. Printing techniques allow for large-scale fabrication of organic electronic components and functional devices for use as wearable electronics, health-care sensors, Internet of Things, monitoring of environment pollution and many others, yet-to-be-conceived applications. The first part of Solution-Processable Components for Organic Electronic Devices covers the synthesis of: soluble conjugated polymers; solution-processable nanoparticles of inorganic semiconductors; high-k nanoparticles by means of controlled radical polymerization; advanced blending techniques yielding novel materials with extraordinary properties. The book also discusses photogeneration of charge carriers in nanostructured bulk heterojunctions and charge carrier transport in multicomponent materials such as composites and nanocomposites as well as photovoltaic devices modelling. The second part of the book is devoted to organic electronic devices, such as field effect transistors, light emitting diodes, photovoltaics, photodiodes and electronic memory devices which can be produced by solution-based methods, including printing and roll-to-roll manufacturing. The book provides in-depth knowledge for experienced researchers and for those entering the field. It comprises 12 chapters focused on: ? novel organic electronics components synthesis and solution-based processing techniques ? advanced analysis of mechanisms governing charge carrier generation and transport in organic semiconductors and devices ? fabrication techniques and characterization methods of organic electronic devices Providing coverage of the state of the art of organic electronics, Solution-Processable Components for Organic Electronic Devices is an excellent book for materials scientists, applied physicists, engineering scientists, and those working in the electronics industry.
Author : Wolfgang Brütting
Publisher : John Wiley & Sons
ISBN 13 : 3527606793
Total Pages : 554 pages
Book Rating : 4.5/5 (276 download)
Download or read book Physics of Organic Semiconductors written by Wolfgang Brütting and published by John Wiley & Sons. This book was released on 2006-05-12 with total page 554 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the gap in the literature currently available, this book presents an overview of our knowledge of the physics behind organic semiconductor devices. Contributions from 18 international research groups cover various aspects of this field, ranging from the growth of organic layers and crystals, their electronic properties at interfaces, their photophysics and electrical transport properties to the application of these materials in such different devices as organic field-effect transistors, photovoltaic cells and organic light-emitting diodes. From the contents: * Excitation Dynamics in Organic Semiconductors * Organic Field-Effect Transistors * Spectroscopy of Organic Semiconductors * Interfaces between Organic Semiconductors and Metals * Analysis and Modeling of Devices * Exciton Formation and Energy Transfer in Organic Light Emitting Diodes * Deposition and Characterization
Author : Felix Gutmann
Publisher :
ISBN 13 :
Total Pages : 890 pages
Book Rating : 4.:/5 (318 download)
Download or read book Organic Semiconductors written by Felix Gutmann and published by . This book was released on 1981 with total page 890 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Liming Ding
Publisher : John Wiley & Sons
ISBN 13 : 3527833668
Total Pages : 988 pages
Book Rating : 4.5/5 (278 download)
Download or read book Organic Solar Cells written by Liming Ding and published by John Wiley & Sons. This book was released on 2022-02-09 with total page 988 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Solar Cells A timely and singular resource on the latest advances in organic photovoltaics Organic photovoltaics are gaining widespread attention due to their solution processability, tunable electronic properties, low temperature manufacture, and cheap and light materials. Their wide range of potential applications may result in significant near-term commercialization of the technology. In Organic Solar Cells: Materials Design, Technology and Commercialization, renowned scientist Dr. Liming Ding delivers a comprehensive exploration of organic solar cells, including discussions of their key materials, mechanisms, molecular designs, stability features, and applications. The book presents the most state-of-the-art developments in the field alongside fulsome treatments of the commercialization potential of various organic solar cell technologies. The author also provides: Thorough introductions to fullerene acceptors, polymer donors, and non-fullerene small molecule acceptors Comprehensive explorations of p-type molecular photovoltaic materials and polymer-polymer solar cell materials, devices, and stability Practical discussions of electron donating ladder-type heteroacenes for photovoltaic applications In-depth examinations of chlorinated organic and single-component organic solar cells, as well as the morphological characterization and manipulation of organic solar cells Perfect for materials scientists, organic and solid-state chemists, and solid-state physicists, Organic Solar Cells: Materials Design, Technology and Commercialization will also earn a place in the libraries of surface chemists and physicists and electrical engineers.
Author : Anna Köhler
Publisher : John Wiley & Sons
ISBN 13 : 3527332928
Total Pages : 436 pages
Book Rating : 4.5/5 (273 download)
Download or read book Electronic Processes in Organic Semiconductors written by Anna Köhler and published by John Wiley & Sons. This book was released on 2015-06-08 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first advanced textbook to provide a useful introduction in a brief, coherent and comprehensive way, with a focus on the fundamentals. After having read this book, students will be prepared to understand any of the many multi-authored books available in this field that discuss a particular aspect in more detail, and should also benefit from any of the textbooks in photochemistry or spectroscopy that concentrate on a particular mechanism. Based on a successful and well-proven lecture course given by one of the authors for many years, the book is clearly structured into four sections: electronic structure of organic semiconductors, charged and excited states in organic semiconductors, electronic and optical properties of organic semiconductors, and fundamentals of organic semiconductor devices.
Author : Yongfang Li
Publisher : Springer
ISBN 13 : 3319168622
Total Pages : 402 pages
Book Rating : 4.3/5 (191 download)
Download or read book Organic Optoelectronic Materials written by Yongfang Li and published by Springer. This book was released on 2015-05-30 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume reviews the latest trends in organic optoelectronic materials. Each comprehensive chapter allows graduate students and newcomers to the field to grasp the basics, whilst also ensuring that they have the most up-to-date overview of the latest research. Topics include: organic conductors and semiconductors; conducting polymers and conjugated polymer semiconductors, as well as their applications in organic field-effect-transistors; organic light-emitting diodes; and organic photovoltaics and transparent conducting electrodes. The molecular structures, synthesis methods, physicochemical and optoelectronic properties of the organic optoelectronic materials are also introduced and described in detail. The authors also elucidate the structures and working mechanisms of organic optoelectronic devices and outline fundamental scientific problems and future research directions. This volume is invaluable to all those interested in organic optoelectronic materials.
Author : Kohzoh Masuda
Publisher : Springer Science & Business Media
ISBN 13 : 1468421093
Total Pages : 187 pages
Book Rating : 4.4/5 (684 download)
Download or read book Energy and Charge Transfer in Organic Semiconductors written by Kohzoh Masuda and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 187 pages. Available in PDF, EPUB and Kindle. Book excerpt: Great progress has been made in the field of ordinary semiconductor physics and associated technologies. For the time being, if we could use new materials such as organic semiconductors progress in electronics could be accelerated. Characteristics of organic semiconductors that are superior to others are: i) high photo-conductivity under irradiation along with low leakage current in the dark, ii) high sensitivity of the conductivity to various gases and to pressure. iii) possibility of using them in the amorphous state, iv) possibility of making devices of extremely small size, v) large variety of the materials, which makes suitable choice of material component easy. A possible future development is a highly conductive material which could be used for electric power transmission - and which might help solve some of the problems posed by transmission losses. The U.S.-Japan Seminar on Energy and Charge Transfer in Organic Semiconductors was held in Osaka Japan, 6-9 August, 1973. Completed results were summarized and the direction for the future was discussed. Information was exchanged quite freely and actively in a pleasant atmosphere. Many of the papers presented at the seminar are published here but unfortunately a few could not be included. It would give us great pleasure if this seminar could be one step in the further development of the research in this field.
Author : Julia Maibach
Publisher :
ISBN 13 :
Total Pages : 212 pages
Book Rating : 4.:/5 (884 download)
Download or read book Preparation and Characterization of Solution Processed Organic Semiconductor Interfaces written by Julia Maibach and published by . This book was released on 2014 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Anna Köhler
Publisher : John Wiley & Sons
ISBN 13 : 3527685162
Total Pages : 436 pages
Book Rating : 4.5/5 (276 download)
Download or read book Electronic Processes in Organic Semiconductors written by Anna Köhler and published by John Wiley & Sons. This book was released on 2015-04-22 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first advanced textbook to provide a useful introduction in a brief, coherent and comprehensive way, with a focus on the fundamentals. After having read this book, students will be prepared to understand any of the many multi-authored books available in this field that discuss a particular aspect in more detail, and should also benefit from any of the textbooks in photochemistry or spectroscopy that concentrate on a particular mechanism. Based on a successful and well-proven lecture course given by one of the authors for many years, the book is clearly structured into four sections: electronic structure of organic semiconductors, charged and excited states in organic semiconductors, electronic and optical properties of organic semiconductors, and fundamentals of organic semiconductor devices.
Author : Carl. R Poelking
Publisher : Springer
ISBN 13 : 3319695991
Total Pages : 142 pages
Book Rating : 4.3/5 (196 download)
Download or read book The (Non-)Local Density of States of Electronic Excitations in Organic Semiconductors written by Carl. R Poelking and published by Springer. This book was released on 2017-10-24 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on the microscopic understanding of the function of organic semiconductors. By tracing the link between their morphological structure and electronic properties across multiple scales, it represents an important advance in this direction. Organic semiconductors are materials at the interface between hard and soft matter: they combine structural variability, processibility and mechanical flexibility with the ability to efficiently transport charge and energy. This unique set of properties makes them a promising class of materials for electronic devices, including organic solar cells and light-emitting diodes. Understanding their function at the microscopic scale – the goal of this work – is a prerequisite for the rational design and optimization of the underlying materials. Based on new multiscale simulation protocols, the book studies the complex interplay between molecular architecture, supramolecular organization and electronic structure in order to reveal why some materials perform well – and why others do not. In particular, by examining the long-range effects that interrelate microscopic states and mesoscopic structure in these materials, the book provides qualitative and quantitative insights into e.g. the charge-generation process, which also serve as a basis for new optimization strategies.
