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Dianion Chemistry In Organic Synthesis
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Book Synopsis Dianion Chemistry in Organic Synthesis by : Charles M. Thompson
Download or read book Dianion Chemistry in Organic Synthesis written by Charles M. Thompson and published by CRC Press. This book was released on 1994-08-19 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many laboratories were reluctant at first to embrace dianion chemistry as part of the standard reaction repertoire. Today, however, researchers can comfortably draw upon the dianion literature to choose an abundance of reagents and strategies that are reliable, effective, and, in many cases, the best answer to a synthetic problem. This interesting book introduces, surveys, and consolidates carbon-based dianion chemistry. Chapter 1 serves as an introduction and as an index of the various dianions covered in the book. Chapters 2 through 5 cover the ensemble of dianion types designated by their first deprotonation site. Each chapter contains an experimental section that explains relevant protocols.
Book Synopsis Dianion Chemistry in Organic Synthesis by : CM. Thompson
Download or read book Dianion Chemistry in Organic Synthesis written by CM. Thompson and published by . This book was released on 1994 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Principles of Organic Synthesis, 3rd Edition by : Richard O.C. Norman
Download or read book Principles of Organic Synthesis, 3rd Edition written by Richard O.C. Norman and published by CRC Press. This book was released on 1993-09-16 with total page 850 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is designed for those who have had no more than a brief introduction to organic chemistry and who require a broad understanding of the subject. The book is in two parts. In Part I, reaction mechanism is set in its wider context of the basic principles and concepts that underlie chemical reactions: chemical thermodynamics, structural theory, theories of reaction kinetics, mechanism itself and stereochemistry. In Part II these principles and concepts are applied to the formation of particular types of bonds, groupings, and compounds. The final chapter in Part II describes the planning and detailed execution of the multi-step syntheses of several complex, naturally occurring compounds.
Download or read book Organic Synthesis written by W A Smit and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: The view of organic synthesis as "a concentrated expression of predictive ability and creative capacity" was advocated in the early 1950s. A concise and readable account of the role of synthesis in modern science, Organic Synthesis: The Science Behind the Art presents the general ideology of pursuits in the area of organic synthesis, and examines the methodologies that have evolved in the search for solutions to synthetic problems. This unique book details outstanding achievements of modern organic synthesis, not only for their scientific merits, but also for the aesthetic appeal of the target molecules chosen and the intrinsic beauty of the solutions to the problems posed. By judicious selection of data covering the main areas of synthetic explorations, this book serves to illustrate both the evolution of well-known approaches as well as recently emerged trends most likely to determine the future development of organic synthesis. Special attention is given to the consideration of principles of molecular design in promising and challenging areas of current research. Primarily aimed at advanced undergraduate and graduate students, Organic Synthesis: The Science Behind the Art will also be of interest to teachers, researchers and anyone requiring an introduction to the problems of organic synthesis.
Book Synopsis Organic Synthesis in Water by : P.A. Grieco
Download or read book Organic Synthesis in Water written by P.A. Grieco and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of water as a medium for promoting organic reactions has been rather neglected in the development of organic synthesis, despite the fact that it is the solvent in which almost all biochemical processes take place. Chemists have only recently started to appreciate the enormous potential water has to offer in the development of new synthetic reactions and strategies, where it can offer benefits in both unique chemistry and reduced environmental impact. In this new book, the editor, well known for his contribution to the development of water as a useful medium in synthetic organic chemistry, has assembled an international team of authors, themselves at the forefront of research into the use of the unique properties of water carrying out organic transformations, to provide a timely and concise overview of current research. By focusing on the practical use of water in synthetic organic chemistry, and with the concern for the use of solvents in organic chemistry, professional chemists, particularly those involved in industrial research and development, will find this book an essential guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate and advanced undergraduate students, will find this book an invaluable guide to this exciting and important area of chemistry.
Book Synopsis Advances in the Use of Synthons in Organic Chemistry by : Alessandro Dondoni
Download or read book Advances in the Use of Synthons in Organic Chemistry written by Alessandro Dondoni and published by Elsevier. This book was released on 2013-10-22 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in the Use of Synthons in Organic Chemistry: A Research Annual, Volume 1 provides information pertinent to a useful reagent that can perform a certain chemical operation that is otherwise impossible or difficult to carry out. This book presents the developments on established synthons. Organized into four chapters, this volume begins with an overview of the significant role of the formyl group in synthetic methodologies, which has stimulated the search for other reagents. This text then describes trimethysilyldiazomethane as a stable and safe substitute for hazardous diazomethane. Other chapters consider the usefulness of trimethysilyldiazomethane in organic syntheses. This book discusses as well that malonic amides, silylenol ethers, malonic esters, and tetra-donor-substituted allenes serve as synthetic equivalents for the dianions of malonic esters, ketones, and malonic amides. The final chapter deals with the synthesis of biologically-active compounds, which has been one of the major challenges for organic chemists. This book is a valuable resource for practicing synthetic chemists.
Book Synopsis Ion-Radical Organic Chemistry by : Zory Vlad Todres
Download or read book Ion-Radical Organic Chemistry written by Zory Vlad Todres and published by CRC Press. This book was released on 2002-09-10 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: Examining the formation, transformation, and application of ion radicals in typical conditions of organic synthesis, Organic Ion Radicals: Chemistry and Applications explains the reactions and principles of ion radical chemistry. The author addresses methods of determining ion- radical mechanisms and controlling ion radical reactions, issues relati
Book Synopsis Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds by : Barry M. Trost
Download or read book Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds written by Barry M. Trost and published by Elsevier. This book was released on 1991 with total page 1328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.
Book Synopsis Worked Solutions in Organic Chemistry by : James M. Coxon
Download or read book Worked Solutions in Organic Chemistry written by James M. Coxon and published by Routledge. This book was released on 2018-10-08 with total page 538 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book illustrates and teaches the finer details of the tactics and strategies employed in the synthesis of organic molecules. As well as providing model answers to the problems, the book discusses, in detail, the reasons why particular strategies are chosen, and why, in given circumstances, alternative methods or routes may or may not be appropriate. As such it could be used as a stand alone volume for the teaching of organic chemistry with a modern and appropriate emphasis on synthesis. Extensive cross referencing to Principles of Organic Synthesis allows the two books to be used as companion volumes.
Book Synopsis Modern Organic Synthesis by : George S. Zweifel
Download or read book Modern Organic Synthesis written by George S. Zweifel and published by John Wiley & Sons. This book was released on 2017-03-09 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book bridges the gap between sophomore and advanced / graduate level organic chemistry courses, providing students with a necessary background to begin research in either an industry or academic environment. • Covers key concepts that include retrosynthesis, conformational analysis, and functional group transformations as well as presents the latest developments in organometallic chemistry and C–C bond formation • Uses a concise and easy-to-read style, with many illustrated examples • Updates material, examples, and references from the first edition • Adds coverage of organocatalysts and organometallic reagents
Book Synopsis Organic Synthesis using Samarium Diiodide by : David J Procter
Download or read book Organic Synthesis using Samarium Diiodide written by David J Procter and published by Royal Society of Chemistry. This book was released on 2009-11-10 with total page 221 pages. Available in PDF, EPUB and Kindle. Book excerpt: Samarium diiodide is one of the most important reducing agents available to synthetic organic chemists. The lanthanide(II) reagent acts by single-electron transfer to organic substrates leading to the formation of both radical and/or anionic intermediates. The power of the reagent arises from its versatility - samarium diiodide can be used in processes ranging from functional group conversions to elaborate carbon-carbon bond-forming cyclization sequences that result in a dramatic increase in molecular complexity. In addition, reactions involving samarium diiodide often show high stereoselectivity as samarium ions can coordinate to Lewis basic sites on substrates and can direct the stereochemical course of reactions. The ability to fine-tune the reactivity of the reagent by the use of additives and co-solvents is an additional, attractive feature. Although samarium diiodide is used extensively by organic chemists, there is still a widely held view that the reagent can be difficult to prepare and use. In addition, samarium diiodide can mediate such a wide variety of organic chemistry that potential new users are often overawed by the extensive primary literature on the reagent. The objective of this book is to provide a concise, practical guide to the reagent. Rather than being a comprehensive review of the chemistry of samarium diiodide, this user-friendly book adopts an "an all you need to know" approach to the topic. The international authors are well-known for their work with the reagent and their expertise covers current developments in new reactivity and selectivity, applications in target synthesis, co-solvent and additive effects, coordination chemistry and mechanism. The book includes the best methods for preparing and handling the reagent, how solvents, co-solvents and additives alter reactivity, the basic mechanisms of reactions, common transformations using the reagent, and emerging areas in samarium diiodide chemistry. The authors have distilled the extensive primary literature to allow the reader to quickly grasp an understanding of the reagent and its utility. The illustrative practical procedures help the reader to prepare and use the reagent in the laboratory while references from the recent literature allow readers to pursue their interest in the popular reagent. The book also contains many illustrations and chemical schemes.
Book Synopsis Organic Synthesis by : Jürgen-Hinrich Fuhrhop
Download or read book Organic Synthesis written by Jürgen-Hinrich Fuhrhop and published by John Wiley & Sons. This book was released on 2003-03-14 with total page 546 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since it is one of the core disciplines, every student of organic chemistry will need to cover organic synthesis at some point. This third edition of an extremely well-received and proven textbook is specially written with advanced undergraduate and graduate students in mind, although it is equally useful for research chemists, too. 50% of the text is new and includes new chapters on combinatoric chemistry, non-covalent molecular assemblies and the use of the Internet for searching chemical compounds. The authors have chosen the methods included here for their efficiency, elegance, and didactic value and have highlighted important reactions within the text. From reviews of the second edition: 'The text is very readable, and the authors are especially gifted at explaining complex concepts clearly and succinctly...This book is highly recommended reading for anyone wishing to gain an overview of organic synthesis.' J. Am. Chem. Soc. With his preface, Noble prizewinner E. J. Corey has also endorsed this already highly acclaimed work.
Book Synopsis Lanthanides: Chemistry and Use in Organic Synthesis by : Shu Kobayashi
Download or read book Lanthanides: Chemistry and Use in Organic Synthesis written by Shu Kobayashi and published by Springer. This book was released on 2003-07-01 with total page 311 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts
Book Synopsis Radical Reactions in Organic Synthesis by : Samir Z. Zard
Download or read book Radical Reactions in Organic Synthesis written by Samir Z. Zard and published by Oxford University Press, USA. This book was released on 2003 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction and some general concepts. -- General principles: chain reactions based on stannane chemistry. -- Further chain reactions of stannanes. -- Organo-silicon, -germanium, and -mercury hydrides. -- The Barton decarboxylation and related reactions. -- Atom and group transfer reactions. -- The persistent radical effect: non-chain processes. -- Redox processes. -- Some concluding remarks.
Book Synopsis Organic Synthesis by : Michael Smith
Download or read book Organic Synthesis written by Michael Smith and published by McGraw-Hill Science, Engineering & Mathematics. This book was released on 2002 with total page 1428 pages. Available in PDF, EPUB and Kindle. Book excerpt: Publisher Description
Book Synopsis Organic Synthesis Highlights by : Johann Mulzer
Download or read book Organic Synthesis Highlights written by Johann Mulzer and published by Verlag Chemie. This book was released on 1991 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Like its predecessor, Organic Synthesis Highlights II surveys recent accomplishments and current trends in synthetic organic chemistry. Part I describes new methods and reagents including asymmetric carbon-carbon bond formation with metallocenes and with enzymes, via temporary silicon connections, and by means of carbohydrate complexes. Part II describes landmarks in the synthesis of natural products and surveys synthetic strategies to different classes of natural products. The forty essays in this volume bear witness to the creativity and talent which have led to the recent advances in the field. Both advanced students and researchers active in the field will welcome this as a source of ideas and inspiration.
Book Synopsis Organic Synthesis Using Transition Metals by : Roderick Bates
Download or read book Organic Synthesis Using Transition Metals written by Roderick Bates and published by John Wiley & Sons. This book was released on 2012-04-30 with total page 469 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed - established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from "classical" organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.
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