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Development Of Improved Iron Fischer Tropsch Catalysts Quarterly Technical Progress Report 1 April 1991 30 June 1991
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Book Synopsis Development of Improved Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 April 1991--30 June 1991 by :
Download or read book Development of Improved Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 April 1991--30 June 1991 written by and published by . This book was released on 1991 with total page 22 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of proposed research is development of catalysts with enhanced slurry phase activity and better selectivity to fuel range products, through a more detailed understanding and systematic studies of the effects of pretreatment procedures and promoters/binders (silica) on catalyst performance.
Book Synopsis Development of Improved Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 July 1991--30 September 1991 by :
Download or read book Development of Improved Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 July 1991--30 September 1991 written by and published by . This book was released on 1991 with total page 26 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of proposed research is development of catalysts with enhanced slurry phase activity and better selectivity to fuel range products, through a more detailed understanding and systematic studies of the effects of pretreatment procedures and promoters/binders (silica) on catalyst performance.
Download or read book Energy Research Abstracts written by and published by . This book was released on 1995 with total page 782 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Development of Improved Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 January 1991--31 March 1991 by :
Download or read book Development of Improved Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 January 1991--31 March 1991 written by and published by . This book was released on 1991 with total page 31 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of proposed research is development of catalysts with enhanced slurry phase activity and better selectivity to fuel range products, through a more detailed understanding and systematic studies of the effects of pretreatment procedures and promoters/binders (silica) on catalyst performance.
Book Synopsis Development of Improved Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 October 1991--31 December 1991 by :
Download or read book Development of Improved Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 October 1991--31 December 1991 written by and published by . This book was released on 1992 with total page 32 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of proposed research is development of catalysts with enhanced slurry phase activity and better selectivity to fuel range products, through a more detailed understanding and systematic studies of the effects of pretreatment procedures and promoters/binders (silica) on catalyst performance.
Book Synopsis Development of Improved Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 January 1992--31 March 1992 by :
Download or read book Development of Improved Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 January 1992--31 March 1992 written by and published by . This book was released on 1992 with total page 33 pages. Available in PDF, EPUB and Kindle. Book excerpt: Three tests (two fixed bed and one stirred tank slurry reactor) were completed during the reporting period. Also, the work on catalyst characterization by different techniques (atomic absorption, BET surface area and pore size distribution and x-ray powder diffraction). The performance of a precipitated iron catalyst with nominal composition lOOFe/0.3Cu/0.8K has been evaluated in two fixed bed reactor tests designated FB-0142 and FB-0352 following pretreatment with syngas (H2/CO=0.67) at 280°C, 3Nl/g-cat/h and atomspheric pressure for 8 hours. Flow interruption occurred in the first test (FB-0142) at about 72h on stream, and the second test (FB-0352) was to assess any potential adverse effects of this flow interruption on performance of the catalyst. The catalyst was tested at 250°C, 200 psig, 2Nl/g-cat/h using syngas of the same composition as that employed during the pretreatment. Initial conversions in both tests were high (about 84%) but the catalyst deactivated fairly rapidly. The (H2 + CO) conversion at the end of the first test (120h on stream) was about 52%, whereas the syngas conversion at the end of the second test (150h) was about 55%, indicating that the brief flow interruption during test FB-0142 had resulted in higher deactivation rate. Hydrocarbon selectivities in both tests were similar and their average values werr: (CH4)=4.7, (C2-C4)=19.5, (C5-C11)=25.3 and C12=50.5 wt%.
Book Synopsis Development of Precipitated Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, April 1, 1995-June 30, 1995 by :
Download or read book Development of Precipitated Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, April 1, 1995-June 30, 1995 written by and published by . This book was released on 1995 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Technology Development for Iron Fischer-Tropsch Catalysts, September 30, 1991. Technical Progress Report for Quarterly Period Ending September 30, 1991 by :
Download or read book Technology Development for Iron Fischer-Tropsch Catalysts, September 30, 1991. Technical Progress Report for Quarterly Period Ending September 30, 1991 written by and published by . This book was released on 1991 with total page 27 pages. Available in PDF, EPUB and Kindle. Book excerpt: Although the oxidation process of Fe(OH)2 and the mechanism of formation of?-FeOOH have been studied by several groups, many questions still need to be answered. In addition, the procedure for the synthesis of pure?-FeOOH has not been well defined. This study is to an attempt to define better the chemistry associated with oxidizing Fe{sup 2+} to?-FeOOH, and to provide a rationale for scaling this method up to produce kg/hr amounts of?-FeOOH.
Book Synopsis Development of Precipitated Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 April 1996--30 June 1996 by :
Download or read book Development of Precipitated Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 April 1996--30 June 1996 written by and published by . This book was released on 1996 with total page 61 pages. Available in PDF, EPUB and Kindle. Book excerpt: The overall contract objectives are to: (1) demonstrate repeatability of performance and preparation procedure of two high activity, high alpha iron Fischer-Tropsch catalysts synthesized at Texas A & M University (TAMU) during the DOE Contract DE-AC22-89PC89868; (2) seek potential improvements in the catalyst performance through variations in process conditions, pretreatment procedures and/or modifications in catalyst synthesis; (3) investigate performance of catalysts in a small scale bubble column slurry reactor, and (4) investigate feasibility of producing catalysts on a large scale in collaboration with a catalyst manufacturer. The performance of an iron, and iron-copper-silica catalyst are described.
Book Synopsis Technology Development for Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report for Period Ending December 31, 1991 by :
Download or read book Technology Development for Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report for Period Ending December 31, 1991 written by and published by . This book was released on 1991 with total page 61 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report covers two aspects of the catalyst characterization studies: scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Two types of catalysts are the subject of this report: SEM studies with as-received, pretreated and used samples of a Ruhrchemie type catalyst and TEM examination of four crystal structures of FeOOH and Fe3O4.
Book Synopsis Technology Development for Iron Fischer-Tropsch Catalysts. Technical Progress Report No. 3, March 27, 1991--June 30, 1991 by :
Download or read book Technology Development for Iron Fischer-Tropsch Catalysts. Technical Progress Report No. 3, March 27, 1991--June 30, 1991 written by and published by . This book was released on 1991 with total page 30 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objectives of this contract are to develop a technology for the production of active and stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to develop a scale up procedure for large-scale synthesis of such catalysts for process development and long-term testing in slurry bubble-column reactors. The catalyst performance target in the slurry bubble-column reactor is 88% CO + H2 conversion at a minimum space velocity of 2.4 NL/hr/gFe. Typical feed used to attain this level of conversion is preferred to have H2 and CO in the molar ratio of 0.5 to 1.0. The desired sum of methane and ethane selectivities is no more than 4%, and the conversion loss per week is not to exceed 1%.
Book Synopsis Massachusetts Under the Constitution by :
Download or read book Massachusetts Under the Constitution written by and published by . This book was released on 1780 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Technology Development for Iron Fischer-Tropsch Catalysis. Quarterly Technical Progress Report for Period Ending March 31, 1991 by :
Download or read book Technology Development for Iron Fischer-Tropsch Catalysis. Quarterly Technical Progress Report for Period Ending March 31, 1991 written by and published by . This book was released on 1991 with total page 25 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present study shows that activation of a high surface area Fe2O3 catalyst in CO in a (CSTR), continuously stirred tank reactor using tetralin as solvent results in an activated that is three times of material that is activated in H2 or directly in the syngas.
Book Synopsis Technology Development for Iron Fischer-Tropsch Catalysis. Quarterly Technical Progress Report No. 3, April 1, 1995--June 30, 1995 by :
Download or read book Technology Development for Iron Fischer-Tropsch Catalysis. Quarterly Technical Progress Report No. 3, April 1, 1995--June 30, 1995 written by and published by . This book was released on 1995 with total page 30 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of this research project is to develop the technology for the production of physically robust iron-based Fischer-Tropsch catalysts that have suitable activity, selectivity and stability to be used in the slurry phase synthesis reactor development. The catalysts that are developed shall be suitable for testing in the Advanced Fuels Development Facility at LaPorte, Texas, to produce either low- or high-alpha product distributions. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the {open_quotes}standard-catalyst{close_quotes} developed by German workers for slurry phase synthesis. The proposed work will optimize the catalyst composition and pretreatment operation for this low-alpha catalyst. In parallel, work will be conducted to design a high-alpha iron catalyst this is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studied at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity and aging characteristics. The research is divided into four major topical areas: (a) catalyst preparation and characterization, (b) product characterization, (c) reactor operations, and (d) data assessment.
Book Synopsis Development of Precipitated Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 January 1995-31 March 1995 by :
Download or read book Development of Precipitated Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report, 1 January 1995-31 March 1995 written by and published by . This book was released on 1995 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Technology Development for Iron Fischer-Tropsch Catalysts. Technical Progress Report No. 4, June 26, 1991--September 26, 1991 by :
Download or read book Technology Development for Iron Fischer-Tropsch Catalysts. Technical Progress Report No. 4, June 26, 1991--September 26, 1991 written by and published by . This book was released on 1991 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt: Objectives are to develop active, stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to develop a scaleup procedure for large-scale synthesis of such catalysts for process development and long-term testing in slurry bubble-column reactors. For a H2-CO in molar ratio of 0.5 to 1.0, catalyst performance target is 88% CO+H2 conversion at a minimum space velocity of 2.4 NL/hr/gFe, with no more than 4% methane/ethane selectivity and 1% conversion loss per week. During this period, it was found that the performance of the slurry-phase iron and copper oxide-based catalyst depends on the amount of K. Five catalysts with differing K contents were studied. The catalysts with the lowest K were more active than the ones with higher K levels. The one with the middle K level was judged best.
Book Synopsis Development of Precipitated Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report for the Period 1 October 1995 - 31 December 1995 by :
Download or read book Development of Precipitated Iron Fischer-Tropsch Catalysts. Quarterly Technical Progress Report for the Period 1 October 1995 - 31 December 1995 written by and published by . This book was released on 1996 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
