Development Of Boron Based Catalysts For The Oxidation Of Light Alkanes To Olefins

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Development of Boron-based Catalysts for the Oxidation of Light Alkanes to Olefins

Author : William Peter McDermott
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (14 download)

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Book Synopsis Development of Boron-based Catalysts for the Oxidation of Light Alkanes to Olefins by : William Peter McDermott

Download or read book Development of Boron-based Catalysts for the Oxidation of Light Alkanes to Olefins written by William Peter McDermott and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The production of light olefins, such as ethylene and propylene, is a key pillar of the chemical industry as they can be transformed into oxygenates, polymers, and other specialty chemicals. Traditionally, these light olefins have been produced through the steam cracking of petroleum-derived feedstocks. In recent years, the wide availability of natural gas has made light olefin production from light alkanes economically advantageous. However, the current routes to light olefins from natural gas are inefficient, with both steam cracking and non-oxidative alkane dehydrogenation suffering from high reaction temperatures and coke deposition. This has driven academic and industrial research into oxidative alternatives such as the oxidative dehydrogenation (ODH) of alkanes to olefins. Catalysts such as supported vanadium oxides have been studied for the ODH of propane where kinetic and mechanistic studies have led to improvements in this system. However, despite decades of research, work in this area has still not delivered a catalyst with sufficient light olefin selectivity for industrial use.This thesis presents the discovery and development of hexagonal boron nitride (hBN) as a selective catalyst for the ODH of propane and other light alkanes. This material offers superior light olefin selectivity and reduced CO and CO2 selectivity when compared to previously studied metal oxide catalysts. Through kinetic insights, I will show that hBN activates oxygen and alkanes in a manner that is fundamentally different than metal oxides. Spectroscopic characterization shows that the surface of hBN oxidizes to form a BOx layer after exposure to reaction conditions. It is this discovery that led to the establishing of a new class of selective ODH catalysts: elemental boron and inorganic borides. The investigation of the reactivity and structure of these materials offers additional information concerning the origin of activity of boron-containing catalysts. Alongside evaluating the origin of reactivity of these promising ODH catalysts, attention was given to the oxidative cracking of hydrocarbons. Within our initial studies of hBN, we had observed that low PO2 conditions enhanced the selectivity to light olefins. However, these conditions also lead to low alkane conversions. Using n-butane as a model substrate, we optimized the reaction conditions to enhance conversion and light olefin selectivity. Here, we demonstrate that this system is one of the most selective for oxidative cracking. This study also offers further insight into the role of O2 and provides evidence for a surface-initiated gas phase radical mechanism. This thesis culminates with the latest findings in probing the gas phase reactivity of boron-based ODH catalysts. We observe enhanced rates with the dilution of catalyst, providing further evidence for a gas phase mechanism. Alongside these reactivity studies, spectroscopic insights reveal the role of agglomerated BOx formation in ODH reactivity. Also presented here is an outlook on the future study of boron-based catalysts for alkane oxidations and the targeted studies required for continued development of this promising system.

Mechanistic Insights on the Oxidative Dehydrogenation of Light Alkanes Catalyzed by Boron-based Catalysts

Author : Juan Mauricio Venegas
Publisher :
ISBN 13 :
Total Pages : 120 pages
Book Rating : 4.:/5 (116 download)

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Book Synopsis Mechanistic Insights on the Oxidative Dehydrogenation of Light Alkanes Catalyzed by Boron-based Catalysts by : Juan Mauricio Venegas

Download or read book Mechanistic Insights on the Oxidative Dehydrogenation of Light Alkanes Catalyzed by Boron-based Catalysts written by Juan Mauricio Venegas and published by . This book was released on 2019 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt: Light olefins such as ethylene and propylene form the foundation of the modern chemical industry, with yearly production volumes well into the hundreds of millions of metric tons. Currently, these light olefins are mainly produced via energy-intensive steam cracking. Alternatively, oxidative dehydrogenation (ODH) of light alkanes to produce olefins allows for lower operation temperatures and extended catalyst lifetimes, providing valuable process efficiencies. This route has led to significant research interest due to the wide availability of natural gas from shale deposits. Advances in this area have still not yielded catalysts that are sufficiently selective to olefins for industrial implementation, and ODH still remains a holy grail of selective alkane oxidation research. Research into selective heterogeneous catalysts for the ODH of propane has led to the extensive use of vanadium oxide-based catalysts, and studies on the surface mechanism involved have been used to improve the catalytic activity of the material. Despite decades of research, however, selectivity towards propylene has not proven satisfactory at industrially-relevant conversions. In this thesis, I will present the serendipitous discovery and subsequent development of hexagonal boron nitride (hBN) and other boron-containing catalysts as selective ODH catalysts. Specifically, I will illustrate the evolution of our understanding of the chemical origin of the reactivity of these materials, which until our initial discovery were deemed chemically inert. By combining reactivity studies with spectroscopic characterization highlighted a unique interaction between boron and oxiygen that differs from that of metal oxides. This methodical characterization of catalytic activity and structural changes of hBN during ODH prompted us to zero in on oxidized boron species, not hBN itself, as the true catalyst of alkane oxidation. In turn, this discovery led us to describe a whole class of B-containing materials that share (and often improve upon) the catalytic performance of hBN. At this point, we decided to step away from material studies and instead improve our understanding on how the catalytic performance of hBN is affected by reactor operating parameters. In particular, we investigated the role of heat and mass transfer on catalytic performance. Unexpectedly, we were once again surprised by hBN when various experimental results during these efforts suggested the significance of gas phase chemistry on ODH performance. For example, we observed that upon dilution of hBN with an inert thermal conductor (to mitigate hotspot formation), the observed reactivity scales with total bed volume rather than hBN mass. Up until these studies, we expected all reactivity to stem from oxidized boron species, but these may be only a part of a more complex surface-gas phase reaction network. The final portion of this thesis presents our latest efforts to understand the role of each reactant on surface and gas phase reaction pathways. Within this work, we incorporate water into our reaction feeds to assess its influence as a source of gas phase radical species to carry out propane activation. Indeed, we observe significant rate enhancements by addition of water. This reactivity enhancement likely involves influencing reactive species concentrations primarily in the gas phase and, to a lesser extent, altering the surface composition during ODH. Overall, this thesis expands our understanding of B-based materials as ODH catalysts and highlights the importance of considering gas phase radical chemistry in future process development.

Development and Characterization of Oxyfunctionalized Boron Nitride Catalysts for the Oxidative Dehydrogenation of Light Alkanes to Olefins

Download Development and Characterization of Oxyfunctionalized Boron Nitride Catalysts for the Oxidative Dehydrogenation of Light Alkanes to Olefins PDF Online Free

Author : Theodore Agbi
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (138 download)

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Book Synopsis Development and Characterization of Oxyfunctionalized Boron Nitride Catalysts for the Oxidative Dehydrogenation of Light Alkanes to Olefins by : Theodore Agbi

Download or read book Development and Characterization of Oxyfunctionalized Boron Nitride Catalysts for the Oxidative Dehydrogenation of Light Alkanes to Olefins written by Theodore Agbi and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Light olefins like ethylene and propylene are platform chemicals integral to the chemical industry. Production of polymers, oxygenates, and other important chemical intermediates demand global production volumes that top 100 million metric tons per year. Production of these light olefins, traditionally through steam cracking, is one of the most energy intensive processes in petrochemical sector. Changing refinery feedstocks (i.e. increased availability of natural gas) have created both necessity and opportunity for 'On-Purpose' propylene technologies to meet propylene demands. The oxidative dehydrogenation of propane to propylene (ODHP) is an attractive alternative process to produce propylene. ODHP enables lower process temperatures and avoids coke deactivation of the catalyst, and has the potential to significantly ease energy, capital, and material intensities of industrial propylene production. To-date, metal oxide ODHP catalysts like vanadia-based catalysts-the previous state of the art ODHP catalyst-do not achieve competitive propylene yields to make them industrially viable. The pioneering work of our research group has identified BN-a material renowned for its chemical inertness-as a highly reactive, selective, and stable ODHP catalyst. Since this discovery, we have worked to understand the fundamental reaction mechanisms present and identify structure-performance relationships that may further develop this class of catalyst. To-date, we have developed extensive spectroscopic characterization capabilities to identify the oxyfunctionalized boron layer formed in situ which contains highly dynamic active species responsible for the high reactivity and selectivity observed. Understanding the activation of molecular O2 and functionality of the oxyfunctionalized layer has been a highly collaborative process requiring a myriad of complimentary spectroscopic and reaction studies to develop fundamental insights. As such, I will provide a comprehensive context of our evolving knowledge in this collaborative project that have since been published where possible and will focus mainly on the recent insights made in this work. The work presented in this dissertation characterizes and probes the reactivity of the highly dynamic oxyfunctionalized surface layer that has been correlated with the reactivity and selectivity observed on this catalyst. Herein, the coordination environment of B and extent of oxyfunctionalization were analyzed via X-ray Photoelectron Spectroscopy (XPS), X-ray Absorption Spectroscopy (XAS), and Attenuated Total Reflectance IR (ATR-IR) as a function of the reaction progress. Corresponding reaction studies show direct correlation between the development of tri-coordinated oxygenated B networks and the increasing reactivity and selectivity of the reaction during the catalyst's activation period. The significance of a set of reaction parameters was then examined to identify process levers conducive to oxyfunctionalization quantified by XPS. The acid-base activity of these surface tri-coordnated B networks in the oxyfunctionalized layer are examined via two prototypical reactions: (1) isopropanol decomposition and (2) formic acid decomposition. Catalytic reaction via flow through reactor and temperature programmed decomposition (TPD) studies using Diffuse Reflectance Infrared Fourier Transform IR spectroscopy (DRIFTs) and Mass Spectrometry (MS) are used to extract insights for the adsorption modes of alkoxides and formates their decomposition pathways. Observed surface reactions of isopropoxy intermediates under these conditions are used to understand possible surface reaction pathways available under ODHP conditions. The role of O2 in specific homogeneous pathways of the mixed hetero-homogeneous mechanism previously proposed by us and for supported boron oxide materials are examined. A simplified model for the surface-initiated radical oxidation chemistry pathways, was then used to probe a selectivity descriptor based on the different reactivities of propyl radicals. Using this knowledge, we design, and test model 3D printed BN based monoliths that optimize homogeneous reaction pathways. These catalysts are shown to be highly active and selective and stable for ~2.5wks. The results also suggest that oxygenates may be relevant products from homogeneous reactions. "The Boron Project," as we so lovingly called it, has seen several PhD students matriculate as we contributed diligently to uncovering the behavior of this material. The goal of this work is to highlight new avenues through which we can further understand surface reactivity, new tools through which we can probe gas phase radical chemistries, and new catalyst design approaches.

Synthesis and Investigation of Boron and Vanadium Based Catalysts for the Oxidative Dehydrogenation of Light Alkanes to Olefins

Author : Natalie Raquel Altvater
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (14 download)

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Book Synopsis Synthesis and Investigation of Boron and Vanadium Based Catalysts for the Oxidative Dehydrogenation of Light Alkanes to Olefins by : Natalie Raquel Altvater

Download or read book Synthesis and Investigation of Boron and Vanadium Based Catalysts for the Oxidative Dehydrogenation of Light Alkanes to Olefins written by Natalie Raquel Altvater and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Light olefins like ethylene and propylene are important building blocks for the chemical industry. Production of these chemicals exceeds 100 million metric tons each year, and they are used in all areas of society including automotive, medical, textile, and food packaging. These light olefins are traditionally produced via steam cracking which is an energy intensive process. The increasing availability of natural gas in the present chemical industry has shifted the feedstock for refinery processes and impacted the production volume of certain olefins, particularly propylene. As a result, there is a growing need for on-purpose propylene production methods to meet the market demands. Oxidative dehydrogenation (ODH) of propane to propylene is one potential pathway for increasing propylene production. Propane ODH offers lower temperature operation and does not suffer from catalyst deactivation from coke. This process still suffers from over oxidation of products and does not achieve propylene yields required for industrial implementation. Propane ODH has been studied extensively for vanadium oxide catalysts and more recently for boron-based catalysts. Despite the wealth of literature on these ODH catalyst there are still several open questions on the catalyst structure and reaction mechanisms that continue to motivate research to improve the catalytic systems. The understanding on the mechanism and structural features of boron-based has been significantly developed in recent years. This work serves to build on this knowledge and improve current knowledge on structure activity relationships for this system. Vanadium oxide catalysts have been the center of propane ODH for much longer than boron, and while literature agrees generally on the surface mechanism description of this system, there are open questions on different pathways in the mechanism and their influence on performance. The goal of this work is to show how synthesis spectroscopy, reaction engineering, and computation work combine to further the understanding of boron and vanadium oxide catalyst for propane ODH.

Investigation of Active Site Structure and Formation on Boron-based Oxidative Dehydrogenation Catalysts

Author : Melissa Cendejas
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (128 download)

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Book Synopsis Investigation of Active Site Structure and Formation on Boron-based Oxidative Dehydrogenation Catalysts by : Melissa Cendejas

Download or read book Investigation of Active Site Structure and Formation on Boron-based Oxidative Dehydrogenation Catalysts written by Melissa Cendejas and published by . This book was released on 2021 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Light olefins such as propylene and ethylene are the two most important building blocks in the chemical industry, and their production is energetically costly. Oxidative dehydrogenation (ODH) of light alkanes has been studied as a lower energy alternative method to produce light olefins. Despite decades of research, there has yet to be a catalyst that is selective and productive enough for industrial implementation. Boron containing materials have recently been identified as highly selective catalysts for the ODH of light alkanes to olefins. These materials, such as hexagonal boron nitride (h-BN), exhibit higher propylene selectivity compared to the previous state-of-the-art supported vanadium oxide catalysts (90% propylene selectivity for h-BN vs. 70% for V/SiO2 at 4% propane conversion). Our group's previous work on these catalysts revealed that the reaction proceeds via a gas-phase radical mechanism, presumably initiated by the surface, and that dynamic boron oxy/hydroxy layer is responsible for catalytic activity. The dynamic nature of the active surface prevents the precise definition of an active site using ex situ techniques. In this work, I describe the use of controlled synthesis and detailed solid state NMR characterization to probe the requirements for active site formation on the catalyst surface. I also describe the first set of in situ/operando X-ray spectroscopy studies of propane ODH over hBN. Operando X-ray Raman spectroscopy is used to show the changes that occur to the catalyst on a bulk scale, while in situ near ambient pressure X-ray photoelectron spectroscopy reveals the near-surface of the catalyst during propane ODH. The X-ray spectroscopy measurements described set the foundation for future studies of the working catalyst.

Discovery and Development of Heterogeneous Catalysts for the Oxidative Dehydrogenation of Alkanes

Author : Joseph Grant
Publisher :
ISBN 13 :
Total Pages : 108 pages
Book Rating : 4.:/5 (12 download)

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Book Synopsis Discovery and Development of Heterogeneous Catalysts for the Oxidative Dehydrogenation of Alkanes by : Joseph Grant

Download or read book Discovery and Development of Heterogeneous Catalysts for the Oxidative Dehydrogenation of Alkanes written by Joseph Grant and published by . This book was released on 2018 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt: The recent surge in shale gas resources creates new opportunities to improve process efficiencies for the production of important chemical building blocks. Non-oxidative dehydrogenation of propane (PDH), the primary "on-purpose" propylene technology used worldwide today, has process inefficiencies that may be improved by co-feeding oxygen and propane to drive the oxidative dehydrogenation (ODH) of propane reaction. However, after decades of catalyst research for ODH of propane this reaction has yet to be commercialized due to the difficulty of controlling this partial oxidation to selectively yield propylene rather than the more-thermodynamically stable CO and CO2 (COx) products. This thesis explores the reactivity and properties of two very different classes of catalysts for the ODH of alkanes: 1) supported vanadia and 2) boron-containing catalysts. Supported vanadia catalysts, the most-studied catalyst for this transformation in the literature, show markedly higher selectivity to propylene when existing as dispersed two-dimensional metal oxide surface species. By introducing a small amount of Na+ to the surface of SiO2, the maximum two-dimensional surface density can be dramatically enhanced. This effect is proved using spectroscopic characterization, as well as the ODH of propane used as a probe reaction. Boron-containing compounds, especially boron nitride (BN) materials, were previously overlooked as catalysts for the ODH of alkanes, and rather deemed to be inert. On the contrary, these B-containing catalysts are now considered to be among the most-selective catalysts for the ODH of alkanes as a method to form their corresponding olefins. The rate of alkane consumption is dependent on oxygen adsorption to the catalyst surface, and shows second-order dependence in the concentration of the alkane. At these temperatures (400-500°C) oxygen adsorption to the B-containing catalyst only occurs when exposed to the ODH reaction (not only air or a combination of air and steam), and is verified with numerous spectroscopic techniques including X-ray Photoelectron Spectroscopy (XPS), and Attenuated Total Reflectance Infrared (ATR-IR). Recent work with X-ray Absorption Spectroscopy (XAS) and 11B MAS NMR dismisses the possibility that a potential B2O3 surface layer acts as the active site by revealing that B2O3 is not present on spent catalysts.

Heterogeneous Catalysis for Sustainable Energy

Author : Landong Li
Publisher : John Wiley & Sons
ISBN 13 : 3527815910
Total Pages : 755 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Heterogeneous Catalysis for Sustainable Energy by : Landong Li

Download or read book Heterogeneous Catalysis for Sustainable Energy written by Landong Li and published by John Wiley & Sons. This book was released on 2022-05-03 with total page 755 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous Catalysis for Sustainable Energy Explore the state-of-the-art in heterogeneous catalysis In Heterogeneous Catalysis for Sustainable Energy, a team of distinguished researchers delivers a comprehensive and cutting-edge treatment of recent advancements in energy-related catalytic reactions and processes in the field of heterogeneous catalysis. The book includes extensive coverage of the hydrogen economy, methane activation, methanol-to-hydrocarbons, carbon dioxide conversion, and biomass conversion. The authors explore different aspects of the technology, like reaction mechanisms, catalyst synthesis, and the commercial status of the reactions. The book also includes: A thorough introduction to the hydrogen economy, including hydrogen production, the reforming of oxygen-containing chemicals, and advances in Fischer-Tropsch Synthesis Comprehensive explorations of methane activation, including steam and dry reforming of methane and methane activation over zeolite catalysts Practical discussions of alkane activation, including cracking of hydrocarbons to light olefins and catalytic dehydrogenation of light alkanes In-depth examinations of zeolite catalysis and carbon dioxide as C1 building block Perfect for catalytic, physical, and surface chemists, Heterogeneous Catalysis for Sustainable Energy also belongs in the libraries of materials scientists with an interest in energy-related reactions and processes in the field of heterogeneous catalysis.

Design and Synthesis of Earth Abundant Transition Metal Catalysts for Selective Oxidation of Light Alkanes and Olefins

Author : Muntaseer Bunian
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (137 download)

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Book Synopsis Design and Synthesis of Earth Abundant Transition Metal Catalysts for Selective Oxidation of Light Alkanes and Olefins by : Muntaseer Bunian

Download or read book Design and Synthesis of Earth Abundant Transition Metal Catalysts for Selective Oxidation of Light Alkanes and Olefins written by Muntaseer Bunian and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Development of Novel Bio-inspired Iron-based Catalysts for the Oxidation of Olefins with H_1tn2O_1tn2 Or Air

Author : Kristin Schröder
Publisher :
ISBN 13 :
Total Pages : 228 pages
Book Rating : 4.:/5 (725 download)

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Book Synopsis Development of Novel Bio-inspired Iron-based Catalysts for the Oxidation of Olefins with H_1tn2O_1tn2 Or Air by : Kristin Schröder

Download or read book Development of Novel Bio-inspired Iron-based Catalysts for the Oxidation of Olefins with H_1tn2O_1tn2 Or Air written by Kristin Schröder and published by . This book was released on 2010 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I

Author : Giuliano Giambastiani
Publisher : Springer Science & Business Media
ISBN 13 : 9048138159
Total Pages : 296 pages
Book Rating : 4.0/5 (481 download)

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Book Synopsis Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I by : Giuliano Giambastiani

Download or read book Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I written by Giuliano Giambastiani and published by Springer Science & Business Media. This book was released on 2011-04-29 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights key advances that have occurred in the field of olefin conversion in recent years. The role of homogenous transition metal catalysts which contain an imine functionality is emphasized; their potential applications in the processing and upgrade of olefins to a wide variety of commodity products of very high industrial value is also explored. On the threshold of the fiftieth anniversary of the Noble Prize to Ziegler and Natta, this book gives a critical summary of the state of the art developments in the fascinating and rapidly developing field of the olefin polymerization, oligomerization, and co-polymerization catalysis.

Boron Fluoride and Its Compounds as Catalysts in Organic Chemistry

Author : A. V. Topchiev
Publisher : Elsevier
ISBN 13 : 1483184366
Total Pages : 327 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis Boron Fluoride and Its Compounds as Catalysts in Organic Chemistry by : A. V. Topchiev

Download or read book Boron Fluoride and Its Compounds as Catalysts in Organic Chemistry written by A. V. Topchiev and published by Elsevier. This book was released on 2013-10-22 with total page 327 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron Fluoride and Its Compounds as Catalysts in Organic Chemistry deals with the concerns associated with the utilization of boron fluoride as a catalyst. The title provides a comprehensive account of boron fluoride, such as its properties, compounds, and related methodologies. The coverage of the text includes the preparation and recovery of boron fluoride, along with the physical and chemical properties. The selection also covers various boron fluoride compounds and their respective reaction to various processes, such as alkylation, polymerization, and nitration. The book will be of great interest to students, researchers, and practitioners of organic chemistry.

Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II

Author : Giuliano GIAMBASTIANI
Publisher : Springer Science & Business Media
ISBN 13 : 9400706960
Total Pages : 272 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II by : Giuliano GIAMBASTIANI

Download or read book Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II written by Giuliano GIAMBASTIANI and published by Springer Science & Business Media. This book was released on 2011-05-19 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II: State-of-the-art and Perspectives provides a critical review of the state-of-the-art developments in industrially relevant processes connected to efficient and selective olefin upgrading. Specific attention is devoted to catalysts containing imine- and amine-based ligands. All the chapters in this book have been designed to provide a systematic account of the vast amount of information available for this type of catalyst as well as to highlight the factors that ultimately control the catalyst’s performance and productivity. A comprehensive panorama of catalyst precursors is presented, spanning from group 10 α-diimine complexes and iron and cobalt 2,6-bis(imino)pyridine derivatives, to vanadium, chromium, titanium, zirconium and lanthanide complexes supported by nitrogen-containing ligands. The authors of this collective work are currently involved in the development of imine-based catalysts for efficient and selective olefin upgrading and the majority of them have dedicated most of their scientific career to this important field. In writing this book, their major goal is to transfer as many ideas and experiences as possible to the global audience of scientists engaged in this area of research.

Carbenes in Ruthenium Based Olefin Metathesis Catalysts and Stabilization of Low Coordinate Boron Species

Author : Fatme Dahcheh
Publisher :
ISBN 13 :
Total Pages : 418 pages
Book Rating : 4.:/5 (977 download)

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Book Synopsis Carbenes in Ruthenium Based Olefin Metathesis Catalysts and Stabilization of Low Coordinate Boron Species by : Fatme Dahcheh

Download or read book Carbenes in Ruthenium Based Olefin Metathesis Catalysts and Stabilization of Low Coordinate Boron Species written by Fatme Dahcheh and published by . This book was released on 2014 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metal-free catalysis using boron-based systems: from designed frustrated Lewis Pairs to boranes

Author : Julien Légaré Lavergne
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (128 download)

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Book Synopsis Metal-free catalysis using boron-based systems: from designed frustrated Lewis Pairs to boranes by : Julien Légaré Lavergne

Download or read book Metal-free catalysis using boron-based systems: from designed frustrated Lewis Pairs to boranes written by Julien Légaré Lavergne and published by . This book was released on 2021 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Résumé en anglais

Boron Reagents in Synthesis

Author : Adiel Coca
Publisher : ACS Symposium
ISBN 13 : 9780841231832
Total Pages : 544 pages
Book Rating : 4.2/5 (318 download)

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Book Synopsis Boron Reagents in Synthesis by : Adiel Coca

Download or read book Boron Reagents in Synthesis written by Adiel Coca and published by ACS Symposium. This book was released on 2018-02-02 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron compounds have been used extensively in organic synthesis for more than sixty years. Some of the best known reactions in synthesis, such as the Suzuki-Miyaura cross-coupling and the hydroboration reaction, involve boron compounds. Several natural products containing boron have been isolated in the last fifty years, including ionophoric macrodiolide antibiotics boromycin, borophycin, aplasmomycins A, B, and C, and tartrolons B, C, and E, as well as autoinducer-2. The study of compounds containing boronic acids for application in pharmaceuticals and materials science has grown tremendously over the last few decades. These include bortezomib, ixazomib, and tavaborole. Several more boron-based drugs are currently in clinical trials. Boron neutron capture therapy has the potential to provide a treatment for various cancers. In addition, materials bearing boronic acids are been studied as potential sensors for biological molecules, such as saccharides and glycoproteins that possess cis-1,2- or cis-1,3-diols.

Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I

Author : Giuliano Giambastiani
Publisher : Springer
ISBN 13 : 9789048138234
Total Pages : 288 pages
Book Rating : 4.1/5 (382 download)

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Book Synopsis Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I by : Giuliano Giambastiani

Download or read book Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I written by Giuliano Giambastiani and published by Springer. This book was released on 2011-05-10 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights key advances that have occurred in the field of olefin conversion in recent years. The role of homogenous transition metal catalysts which contain an imine functionality is emphasized; their potential applications in the processing and upgrade of olefins to a wide variety of commodity products of very high industrial value is also explored. On the threshold of the fiftieth anniversary of the Noble Prize to Ziegler and Natta, this book gives a critical summary of the state of the art developments in the fascinating and rapidly developing field of the olefin polymerization, oligomerization, and co-polymerization catalysis.

Thugs-rje chen-po Yid-bźin-nor-bu ʼGro-ba-kun-grol gyi bla maʼi rnal ʼbyor daṅ rgyud ʼdebs byin rlabs myur ʼjug ces bya ba bźugs so

Author :
Publisher :
ISBN 13 :
Total Pages : 12 pages
Book Rating : 4.:/5 (799 download)

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Book Synopsis Thugs-rje chen-po Yid-bźin-nor-bu ʼGro-ba-kun-grol gyi bla maʼi rnal ʼbyor daṅ rgyud ʼdebs byin rlabs myur ʼjug ces bya ba bźugs so by :

Download or read book Thugs-rje chen-po Yid-bźin-nor-bu ʼGro-ba-kun-grol gyi bla maʼi rnal ʼbyor daṅ rgyud ʼdebs byin rlabs myur ʼjug ces bya ba bźugs so written by and published by . This book was released on 1977 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt: