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Conjugated Linoleic Acid Styrene Butyl Acrylate Bulk And Emulsion Polymerization
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Book Synopsis Conjugated Linoleic Acid/Styrene/Butyl Acrylate Bulk and Emulsion Polymerization by : Stéphane Roberge
Download or read book Conjugated Linoleic Acid/Styrene/Butyl Acrylate Bulk and Emulsion Polymerization written by Stéphane Roberge and published by . This book was released on 2016 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The potential for conjugated linoleic acid (CLA) incorporation into pressure-sensitive adhesive (PSA) formulations was evaluated. A series of free radical bulk copolymerizations of CLA/styrene (Sty) and CLA/butyl acrylate (BA) were designed to allow the estimation of reactivity ratios. Bulk terpolymerizations of CLA/Sty/BA were also evaluated before moving to emulsion terpolymerizations of CLA/Sty/BA. The polymers were characterized for composition, conversion, molecular weight and glass transition temperature while latexes were characterized for viscosity, particle size, tack, peel strength, and shear strength. All experiments were performed at 80oC and monitored with attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy. While bulk experiments were monitored off-line, the emulsion experiments were monitored in-line. Absorbance peaks related to the monomers and polymer were tracked to provide conversion and polymer composition data using a multivariate calibration method. Off-line measurements using gravimetry and 1H-NMR spectroscopy were compared to the ATR-FTIR data and no significant differences were detected between the measurement methods. Pseudo-kinetic models, developed and validated with the copolymer experimental data, were used to estimate reactivity ratios. The copolymer pseudo-kinetic models were extended to a terpolymer pseudo-kinetic model and validated with experimental data. The pseudo-kinetic models incorporated the ability of oleic acid, a common impurity found in CLA, to trap electrons thus influencing the reaction kinetics significantly. The influence of terpolymer composition, chain transfer agent concentration, cross-linker concentration, molecular weight, viscosity and particle size on tack, peel strength and shear strength was investigated by using a constrained mixture design. The final forms of the resulting empirical models allowed the creation of 3D response surfaces for PSA performance optimization. The incorporation of 30 wt.% CLA into a practical PSA application suitable for the removable adhesives category was achieved.
Book Synopsis Polymer Reaction Engineering of Dispersed Systems by : Werner Pauer
Download or read book Polymer Reaction Engineering of Dispersed Systems written by Werner Pauer and published by Springer. This book was released on 2018-11-19 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science.The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics.Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned.Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students
Book Synopsis Semi-continuous Emulsion Copolymerization of Styrene-butyl Acrylate with Methacrylic Acid by : Hong Hua
Download or read book Semi-continuous Emulsion Copolymerization of Styrene-butyl Acrylate with Methacrylic Acid written by Hong Hua and published by . This book was released on 2008 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemistry and Technology of Emulsion Polymerisation by : A. M. van Herk
Download or read book Chemistry and Technology of Emulsion Polymerisation written by A. M. van Herk and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emulsion polymerisation produces high value polymers in a low cost, environmentally friendly process. The drive to develop environmentally benign production methods for polymers has resulted in widespread development and implementation of the emulsion polymerisation technique. In addition, when combined with novel polymerisation mechanisms the process can give rise to a range of polymer products with particularly useful properties. Emulsion polymerisation is a complex process, governed by the interplay of both chemical and physical properties including polymerisation kinetics and dispersion stability. Successful industrial application relies on understanding and controlling those properties. By carefully explaining the principles of the reaction, based on well-designed experimental investigation, Chemistry and Technology of Emulsion Polymerisation provides a practical and intuitive explanation of emulsion polymerisation. In the development of industrial processes, coupling that understanding with everyday practice can be a further difficult step, so the book emphasises a clear, comprehensive and straightforward discussion to illustrate how the principles relate to practical application. Written for research chemists, technologists and engineers in the polymer, fine and specialty chemicals industries, and in university or government laboratories, this book will be particularly valuable to those early on in their careers. The comprehensive and straightforward coverage will also ensure it is an important resource for advanced courses in emulsion polymerisation.
Book Synopsis Emulsion Polymers and Emulsion Polymerization by : David R. Bassett
Download or read book Emulsion Polymers and Emulsion Polymerization written by David R. Bassett and published by . This book was released on 1981 with total page 632 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Computational Methods for Polymers by : Masoud Soroush
Download or read book Computational Methods for Polymers written by Masoud Soroush and published by MDPI. This book was released on 2020-12-10 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents recent advances in computational methods for polymers. It covers multiscale modeling of polymers, polymerization reactions, and polymerization processes as well as control, monitoring, and estimation methods applied to polymerization processes. It presents theoretical insights gained from multiscale modeling validated with exprimental measurements. The book consolidates new computational tools and methods developed by academic researchers in this area and presents them systematically. The book is useful for graduate students, researchers, and process engineers and managers.
Book Synopsis Supermicron Monodisperse Styrene/butyl Acrylate Latexes by a Novel Aggregative Emulsion Polymerization by : Florin-Iosif Vlad
Download or read book Supermicron Monodisperse Styrene/butyl Acrylate Latexes by a Novel Aggregative Emulsion Polymerization written by Florin-Iosif Vlad and published by . This book was released on 1996 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Supermicron Monodisperse Styrene/butyl Acrylate Latexes by a Novel Aggregative Emulsion Polymerization by :
Download or read book Supermicron Monodisperse Styrene/butyl Acrylate Latexes by a Novel Aggregative Emulsion Polymerization written by and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Concentrated Emulsion Polymerization by : Eli Ruckenstein
Download or read book Concentrated Emulsion Polymerization written by Eli Ruckenstein and published by CRC Press. This book was released on 2019-03-29 with total page 317 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprising one volume of Functional and Modified Polymeric Materials, Two-Volume Set, this curated collection of papers by Professor Eli Ruckenstein and co-workers discusses the merits of concentrated emulsion polymerization systems, as well as their ability to yield a broad variety of products with high synthetic efficiency. Comprised of carefully curated chapters previously published by these pioneering scientists in the field, this volume offers a comprehensive view of the subject and presents functional and modified polymeric materials prepared by concentrated emulsion polymerization approaches. It covers conductive polymer composites, core-shell latex particles, enzyme/catalyst carriers, and plastics toughening and compatibilization polymerization. The authors have performed seminal studies on the preparation of functional and modified polymeric materials via concentrated emulsion polymerization. The corresponding research papers, after further selection and classification, are collected in the four chapters of this book.
Book Synopsis Vinyl Acetate Emulsion Polymerization and Copolymerization with Acrylic Monomers by : Yildirim H. Erbil
Download or read book Vinyl Acetate Emulsion Polymerization and Copolymerization with Acrylic Monomers written by Yildirim H. Erbil and published by CRC Press. This book was released on 2000-03-22 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: The versatility of the emulsion copolymerization reaction and the ability to control the properties of the final latices have led to rapid expansion both in the quantity of polyvinylacetate and vinyl acetate-acrylic copolymer latices and in their applications. Vinyl Acetate Emulsion Polymerization and Copolymerization with Acrylic Monomers provides
Book Synopsis Emulsion Polymerization of Vinyl Acetate by : Mohamed S. El-Aasser
Download or read book Emulsion Polymerization of Vinyl Acetate written by Mohamed S. El-Aasser and published by Springer. This book was released on 2012-01-10 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is particularly appropriate that this symposium on the emulsion polymeriza tion of vinyl acetate was held in recognition of the industrial importance of poly(vinyl acetate) and vinyl acetate copolymers, and their rather unique properties among emulsion polymers in general. Poly( vinyl acetate) latexes were the first synthetic polymer latexes to be made on a commercial scale: their production using polyvinyl alcohol as emulsifier began in Germany during the mid-1930s and has continued to the present day, growing steadily with the years. Indeed, poly(vinyl acetate) latexes prepared with polyvinyl alcohol are still one of the mainstays of the adhesives industry. With the passing of time, however, vinyl acetate copolymers have been developed: copolymers with maleate esters such as dibutyl maleate, acrylate esters such as ethyl acrylate and butyl acrylate, versatic acid esters, and, more recently, ethylene. These versatile copolymers have found increasing use in more sophisticated adhesives with specialized properties, adhesives for clay coatings on paper, carpet backing, and interior and exterior paints. Thus more than 45 years after the first commercial production of vinyl acetate latexes, their use is still growing, both in actual quantities and different applications. The industrial importance of vinyl acetate latexes makes the mechanism and kinetics of their emulsion polymerization of practical as well as scientific interest.
Book Synopsis Revisiting Kinetics and Molecular Weights in the Emulsion Polymerization of Butyl Acrylate by : Alessandro Ghielmi
Download or read book Revisiting Kinetics and Molecular Weights in the Emulsion Polymerization of Butyl Acrylate written by Alessandro Ghielmi and published by . This book was released on 1999 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Kinetic Study of the Emulsion Polymerization of Vinyl Acetate by : Nils Friis
Download or read book A Kinetic Study of the Emulsion Polymerization of Vinyl Acetate written by Nils Friis and published by . This book was released on 1973 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Emulsion Polymerization of Styrene by Potassium Persulfate Catalyst with Reference to Catalyst Concentration, Nitrogen, and Air Atmospheres by : Pao-Tse Yang
Download or read book Emulsion Polymerization of Styrene by Potassium Persulfate Catalyst with Reference to Catalyst Concentration, Nitrogen, and Air Atmospheres written by Pao-Tse Yang and published by . This book was released on 1947 with total page 72 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Kinetics of the Emulsion Polymerization of Styrene by : Jan Bakker
Download or read book Kinetics of the Emulsion Polymerization of Styrene written by Jan Bakker and published by . This book was released on 1952 with total page 70 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Emulsion Polymerizations of Styrene and N-butyl Acrylate in an Automated Reaction Calorimeter by : Eser Ozdeger
Download or read book Emulsion Polymerizations of Styrene and N-butyl Acrylate in an Automated Reaction Calorimeter written by Eser Ozdeger and published by . This book was released on 1997 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solids content was shown to be an important variable in studying the role of mixing on the kinetics of these emulsion polymerizations. At low solids (30%), impeller speed and type did not have any significant effect on the kinetics of polymerizations whereas at high solids (50%), reactions using different impellers exhibited different behaviors.
Book Synopsis Emulsion Polymerization of Styrene with Different Initiators by : Alex Shao-Yu Wang
Download or read book Emulsion Polymerization of Styrene with Different Initiators written by Alex Shao-Yu Wang and published by . This book was released on 1973 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt:
