Comprehensive Characterization of Dissolved Organic Matter by Using Chemical Fractionation and High Resolution Organic Structural Spectroscopy

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (11 download)

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Book Synopsis Comprehensive Characterization of Dissolved Organic Matter by Using Chemical Fractionation and High Resolution Organic Structural Spectroscopy by : Yan Li

Download or read book Comprehensive Characterization of Dissolved Organic Matter by Using Chemical Fractionation and High Resolution Organic Structural Spectroscopy written by Yan Li and published by . This book was released on 2017 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Molecular and Optical Characterization of Dissolved Organic Matter in the Central Arctic Ocean

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (136 download)

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Book Synopsis Molecular and Optical Characterization of Dissolved Organic Matter in the Central Arctic Ocean by : Xianyu Kong

Download or read book Molecular and Optical Characterization of Dissolved Organic Matter in the Central Arctic Ocean written by Xianyu Kong and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dissolved organic matter (DOM) in the ocean is a complex mixture of molecules derived from autochthonous (marine) or allochthonous (terrestrial) origins. DOM plays an important role in marine biogeochemical cycles by attenuating light available for primary production, serving as an energy and nutrient source for heterotrophic communities, regulating the ultraviolet and visible light absorption, undergoing photochemical processing, and acting as a trace metal ligand. DOM in the Central Arctic Ocean (CAO) is influenced by increased freshwater input and associated terrestrial materials in recent decades due to rapid climate change. The quantification of DOM sources (terrestrial versus marine) in the water column of the CAO is not well constrained. Few studies have systematically investigated the seasonality and spatial variability of DOM by combining optical and molecular-level analytical techniques in the CAO, especially during winter. State of the art chemical characterization of DOM is subject to major challenges: Solid phase extraction (SPE) that is often used to desalt and pre-concentrate marine DOM introduces chemical fractionation effects, which limits the comparability between analytical results for original samples and those carried out for SPE-DOM. There is no specific method to quantify fractionation effects, nor specific guidelines to avoid fractionation. Using mass spectrometry, quantitative DOM analyses is challenged by selective ionization of molecules and the large number of unresolved structural isomers that prevent classical external calibration. In the first part of this thesis, a method was developed to quantitatively track optical or chemical fractionation during SPE and investigate the potential mechanisms. We found a decrease in extraction efficiency of dissolved organic carbon (DOC), fluorescence and absorbance, and polar organic substances with increasing carbon loading on the SPE column. As the surface loading of the solid-phase increased, the dominant extraction mechanism shifted from PPL physisorption to increased DOM self-assembly, resulting in optical and chemical fractionation. The relative DOC loading (DOCload) was used to assess the carbon loading during SPE, and a double sigmoid model was applied to our online permeate fluorescence data as a function of DOCload, which allowed us to assess the degree of variability induced by DOCload. This finding has ample implications for the future processing and previous interpretation of chemical characteristics in SPE-DOM of aquatic organic matter. For the second part of the thesis, original water samples were acquired from the “Multidisciplinary Drifting Observatory for the Study of Arctic Climate” (MOSAiC) expedition. The water column samples covered a full year (2019 / 2020) and included the regions Amundsen Basin, western Nansen Basin and Yermak Plateau and Fram Strait. Samples were analyzed using optical spectroscopy to determine chromophoric DOM (CDOM) and fluorescent DOM (FDOM). In addition, a new method was applied that used Fourier transform ion cyclotron resonance mass spectrometry hyphenated to high performance liquid chromatography (LC-FTMS). The method allowed DOM analysis in original filtered water and thus avoided the chemical fractionation introduced by SPE. During the MOSAiC expedition, DOC concentrations and CDOM characteristics in the water column were primarily influenced by regional differences. These differences were largely dependent on terrestrially-derived DOM (tDOM) input by the transpolar drift (TPD) as indicative of average 136% and 45% higher aCDOM(350) and DOC concentration, respectively, in the Amundsen compared to the western Nansen Basin and Yermak Plateau, and slightly modified by seasonal changes. Despite the convenient identification of tDOM, optical spectroscopy was not suitable to quantify the contribution of tDOM to bulk DOC or to track sea ice derived DOM in the water column. In contrast, using LC-FTMS, we found quantitative linear correlation between the summed mass peak magnitudes for each sample (intsum) and DOC concentration. By combing LC-FTMS and source identification with optical parameters, we were able to quantify DOM sources (terrestrial versus marine) in the water column: 83% of the summed peak magnitude of all samples could be related to marine or terrestrial sources. tDOM contributed ∼17% (or 8 μmol kg-1) to deep DOC (~2000 m) in the CAO and was more refractory and had a higher state of unsaturation compared to marine DOM. The quantitative characterization of DOM in original seawater from different origin is a major step in the field of research. It provides a unique and new insight into the molecular changes in marine DOM composition and an improved understanding of the terrestrial DOM distribution in the CAO.

Biogeochemistry of Marine Dissolved Organic Matter

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Publisher : Academic Press
ISBN 13 : 0124071538
Total Pages : 712 pages
Book Rating : 4.1/5 (24 download)

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Book Synopsis Biogeochemistry of Marine Dissolved Organic Matter by : Dennis A. Hansell

Download or read book Biogeochemistry of Marine Dissolved Organic Matter written by Dennis A. Hansell and published by Academic Press. This book was released on 2014-10-02 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt: Marine dissolved organic matter (DOM) is a complex mixture of molecules found throughout the world's oceans. It plays a key role in the export, distribution, and sequestration of carbon in the oceanic water column, posited to be a source of atmospheric climate regulation. Biogeochemistry of Marine Dissolved Organic Matter, Second Edition, focuses on the chemical constituents of DOM and its biogeochemical, biological, and ecological significance in the global ocean, and provides a single, unique source for the references, information, and informed judgments of the community of marine biogeochemists. Presented by some of the world's leading scientists, this revised edition reports on the major advances in this area and includes new chapters covering the role of DOM in ancient ocean carbon cycles, the long term stability of marine DOM, the biophysical dynamics of DOM, fluvial DOM qualities and fate, and the Mediterranean Sea. Biogeochemistry of Marine Dissolved Organic Matter, Second Edition, is an extremely useful resource that helps people interested in the largest pool of active carbon on the planet (DOC) get a firm grounding on the general paradigms and many of the relevant references on this topic. Features up-to-date knowledge of DOM, including five new chapters The only published work to synthesize recent research on dissolved organic carbon in the Mediterranean Sea Includes chapters that address inputs from freshwater terrestrial DOM

Linking Optical and Chemical Properties of Dissolved Organic Matter in Natural Waters

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Publisher : Frontiers Media SA
ISBN 13 : 2889450813
Total Pages : 244 pages
Book Rating : 4.8/5 (894 download)

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Book Synopsis Linking Optical and Chemical Properties of Dissolved Organic Matter in Natural Waters by : Christopher L. Osburn

Download or read book Linking Optical and Chemical Properties of Dissolved Organic Matter in Natural Waters written by Christopher L. Osburn and published by Frontiers Media SA. This book was released on 2017-01-17 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: A substantial increase in the number of studies using the optical properties (absorbance and fluorescence) of dissolved organic matter (DOM) as a proxy for its chemical properties in estuaries and the coastal and open ocean has occurred during the last decade. We are making progress on finding the actual chemical compounds or phenomena responsible for DOM’s optical properties. Ultrahigh resolution mass spectrometry, in particular, has made important progress in making the key connections between optics and chemistry. But serious questions remain and the last major special issue on DOM optics and chemistry occurred nearly 10 years ago. Controversies remain from the non-specific optical properties of DOM that are not linked to discrete sources, and sometimes provide conflicting information. The use of optics, which is relatively easier to employ in synoptic and high resolution sampling to determine chemistry, is a critical connection to make and can lead to major advances in our understanding of organic matter cycling in all aquatic ecosystems. The contentions and controversies raised by our poor understanding of the linkages between optics and chemistry of DOM are bottlenecks that need to be addressed and overcome.

Advances in the Physicochemical Characterization of Dissolved Organic Matter

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Publisher : ACS Symposium
ISBN 13 : 9780841229518
Total Pages : 0 pages
Book Rating : 4.2/5 (295 download)

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Book Synopsis Advances in the Physicochemical Characterization of Dissolved Organic Matter by : Fernando Rosario-Ortiz

Download or read book Advances in the Physicochemical Characterization of Dissolved Organic Matter written by Fernando Rosario-Ortiz and published by ACS Symposium. This book was released on 2014 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of dissolved organic matter (DOM) has fascinated scientists and engineers for at least 60 years - from the initial efforts focused on measuring the concentrations of carbon in marine and aquatic systems, to the discovery of the role of DOM in the formation of disinfection byproducts, all the way to the new emphasis on the detailed understanding of the different functional groups and basic structural features which are the basis for the physicochemical properties of the material. After 50 years of work in the area, there are still many questions regarding DOM. The study of dissolved organic matter (DOM) has fascinated researchers in different fields of science and engineering for many decades. The impact that DOM has on a wide array of environmental processes has resulted in the development of a multidisciplinary community of researchers all focusing on using different analytical techniques and experimental design to better understand DOM. This book offers select case studies focusing on the advanced characterization of DOM in different environments and with respect to different processes. It results from the conclusion of a symposium that E. M. Thurman and I had organized for the 245th meeting of the American Chemical Society, which was held on April 7-11, 2013 in New Orleans, Louisiana.

Structural Characterization of Freshwater Dissolved Organic Matter from Arctic and Temperate Climates Using Novel Analytical Approaches

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ISBN 13 :
Total Pages : 428 pages
Book Rating : 4.:/5 (977 download)

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Book Synopsis Structural Characterization of Freshwater Dissolved Organic Matter from Arctic and Temperate Climates Using Novel Analytical Approaches by : Gwen C. Woods

Download or read book Structural Characterization of Freshwater Dissolved Organic Matter from Arctic and Temperate Climates Using Novel Analytical Approaches written by Gwen C. Woods and published by . This book was released on 2012 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fractionation and characterization of organic matter in wastewater from a swine waste-retention basin

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Publisher : DIANE Publishing
ISBN 13 : 1428984062
Total Pages : 28 pages
Book Rating : 4.4/5 (289 download)

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Book Synopsis Fractionation and characterization of organic matter in wastewater from a swine waste-retention basin by :

Download or read book Fractionation and characterization of organic matter in wastewater from a swine waste-retention basin written by and published by DIANE Publishing. This book was released on with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive Environmental Mass Spectrometry

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Publisher : ILM Publications
ISBN 13 : 1906799121
Total Pages : 544 pages
Book Rating : 4.9/5 (67 download)

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Book Synopsis Comprehensive Environmental Mass Spectrometry by : Albert Lebedev

Download or read book Comprehensive Environmental Mass Spectrometry written by Albert Lebedev and published by ILM Publications. This book was released on 2012 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt: "In full colour throughout, this book describes the power of mass spectrometry in resolving environmental issues, demonstrating how real-world complex problems can be solved in a simple and elegant way."--Worldcat.

Chemical Characterization of Refractory Dissolved Organic Matter

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ISBN 13 :
Total Pages : 151 pages
Book Rating : 4.:/5 (967 download)

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Book Synopsis Chemical Characterization of Refractory Dissolved Organic Matter by : Neal Ken Arakawa

Download or read book Chemical Characterization of Refractory Dissolved Organic Matter written by Neal Ken Arakawa and published by . This book was released on 2016 with total page 151 pages. Available in PDF, EPUB and Kindle. Book excerpt: The primary objective of this thesis was to combine a chemical degradation technique together with an analytical framework centered primarily around gas chromatography (GC) to more fully interrogate the composition of aquatic dissolved organic matter (DOM). Previous studies had suggested that aliphatic compounds could represent a significant fraction of refractory organic matter isolated by solid phase extraction (SPE). These studies had also uncovered the vast complexity of DOM. Gas chromatography coupled to mass spectrometry provides superior separation capability and is ideal for examining complex mixtures of lipid-derived molecules. As such I sought to develop a comprehensive GC analysis methods to provide molecular level information for DOM isolated by solid phase extraction (SPE) onto a hydrophobic resin- PPL (Agilent Bond Elut). In Chapter II, a comprehensive chemical reduction procedure was developed and first applied to the environmental DOM standard Suwannee River Fulvic Acid (SRFA) as a proxy for marine DOM. The resulting hydrocarbons were amenable to comprehensive gas chromatography time-of-flight mass spectrometry (GCxGC-TOF-MS), and effectively resolved into multiple series of alicyclic, unsaturated compounds. This was the first direct demonstration of the isomeric complexity of aquatic DOM. Similar alicyclic compounds were recovered from the reduction of terrestrial source material, implicating resin acids and sterols as potential precursors of SRFA. In Chapter III the reduction process was applied to marine surface DOM from the Scripps Institution of Oceanography Pier, and similar alicylic compounds were found. The GCxGC-TOF-MS identified carbon backbones closely resembling carotenoids, implicating these ubiquitous and highly reactive biomolecules as the source of a significant fraction of DOM accumulating in the marine water column. The structural assignment was supported by the identification of carotenoid derived resonances in two dimensional nuclear magnetic resonance (NMR) spectra, which indicated that these molecules were highly oxidized compared to the parent molecules consistent with their present in DOM. Following up on this work in Chapter IV the carotenoid [beta]-carotene was irradiated with natural sunlight to test the hypothesis that photodegradation was one pathway that converted carotenoids into water-soluble degradation products. The first finding was that the reaction produced a series of compounds identical to compounds isolated from marine DOM. The second important result was that the reaction produced a complex mixture of isomers from a single compound that helps to at least partly explain the compositional diversity in marine DOM. Together, the data in Chapters III and IV allowed us to link a large fraction of DOM to a ubiquitous biomolecule that can now serve as a model for studies examining the formation and fate of DOM that accumulates in the ocean on long timescales. Finally, in Chapter V we sought to examine how the composition of DOM -- both the complex alicyclic fraction and small, polar biomolecules, which are considered a "fresher" signal of biological input -- evolved across a salinity gradient. Although core biochemical classes were present in all regions the data supported in situ production of compositionally similar material rather than mixing across the gradients as proposed in some studies. Together, the chapters in my thesis provide new insight in the composition of dissolved organic matter in marine and terrestrial environments. The thesis also represents the most comprehensive molecular level characterization of DOM isolated by this solid phase extraction method, which is the most commonly used isolation method in the field. My findings also provide an important foundation for future lab-based mechanistic studies of DOM cycling in the marine environment.

Characterization of Dissolved Organic Matter in Wastewater Using Liquid Chromatography-high Resolution Mass Spectrometry

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (122 download)

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Book Synopsis Characterization of Dissolved Organic Matter in Wastewater Using Liquid Chromatography-high Resolution Mass Spectrometry by : Yaroslav Verkh

Download or read book Characterization of Dissolved Organic Matter in Wastewater Using Liquid Chromatography-high Resolution Mass Spectrometry written by Yaroslav Verkh and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Individual hazardous chemicals and substance mixtures with synergistic toxicity ef-fects occur in the dissolved organic matter (DOM) of wastewater and negatively im-pact human health. Yet a large number of chemicals and their treatment by-products in wastewater makes the tracking of individual compounds nearly impossible and de-mands new analytical strategies. The thesis describes the development and evaluation of non-targeted and suspect anal-ysis methods aimed at the transformation of DOM and micro-contaminants of interest during wastewater treatment using liquid chromatography-high-resolution mass spec-trometry (LC-HRMS) data. On one hand, a non-targeted method to track transformations of DOM in a multiphase wastewater treatment using LC-HRMS data was developed. LC-MS signals were ex-tracted, aligned, and had their isotopologues clustered and elemental composition pre-dicted using open license software MZmine 2 in a way that conceptually prioritized the detection of anthropogenic compounds.

Biogeochemistry of Marine Dissolved Organic Matter

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Publisher : Elsevier
ISBN 13 : 0443138591
Total Pages : 870 pages
Book Rating : 4.4/5 (431 download)

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Book Synopsis Biogeochemistry of Marine Dissolved Organic Matter by : Dennis A. Hansell

Download or read book Biogeochemistry of Marine Dissolved Organic Matter written by Dennis A. Hansell and published by Elsevier. This book was released on 2024-07-04 with total page 870 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biogeochemistry of Marine Dissolved Organic Matter, 3rd edition is the most up-to-date revision of the fundamental reference for the biogeochemistry of marine dissolved organic matter. Since its original publication in June 2002, the science, questions, and priorities have advanced, and the editors of this essential guide, have added nine new chapters, including one on the South China Sea. An indispensable manual edited by the most distinguished experts in the field, this book is addressed to graduate students, marine scientists, and all professionals interested in advancing their knowledge of the field. Features up-to-date knowledge on DOM, including 9 new chapters Presents the only published work to synthesize recent research on dissolved organic carbon in the South China, a region receiving a great deal of attention in recent decades Offers contributions by world-class research leaders

Chemical Characterization of Dissolved Organic Matter (DOM) in Seawater

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ISBN 13 :
Total Pages : 212 pages
Book Rating : 4.:/5 (61 download)

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Book Synopsis Chemical Characterization of Dissolved Organic Matter (DOM) in Seawater by : Tracy Michelle Quan

Download or read book Chemical Characterization of Dissolved Organic Matter (DOM) in Seawater written by Tracy Michelle Quan and published by . This book was released on 2005 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt: (Cont.) This new separation protocol utilized various chromatographic techniques, including cation exchange chromatography and high- pressure liquid chromatography (HPLC) using C18 and strong cation exchange (SCX) columns. Six amino acids were isolated from a HMWDOM sample with sufficient purity and quantity for radiocarbon analysis. These amino acids had a range of A'4C values, from 121%o to -454%o. The final section investigates biological controls on the dissolved organic nitrogen (DON) pool. Total hydrolyzable amino acids (THAA), and nucleic acids were measured for four incubations: a control incubation, a grazer added incubation, a zero virus incubation, and a 10 times virus incubation. Comparison to the control showed THAA and nucleic acid release were influenced by viruses but not grazers.

The Characterisation of Antarctic Dissolved Organic Matter

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (135 download)

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Book Synopsis The Characterisation of Antarctic Dissolved Organic Matter by : Sahar Farzadnia

Download or read book The Characterisation of Antarctic Dissolved Organic Matter written by Sahar Farzadnia and published by . This book was released on 2016 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Study of the chemical structure of dissolved organic matter (DOM) has always been of great interest due to its contribution to global carbon cycle and its recognition as a source marker. Fulvic acids are a complicated mixture of organic compounds accounting for about half of Natural Organic Matter (NOM) in fresh water and 15-20 % of the NOM in marine waters. Fulvic acid composition and structure varies depending on the geographic locations and sources of inputs, but it is generally believed that it consists of weak aliphatic and aromatic organic acids soluble in water at all pH conditions. Chemical characterisation of fulvic material from the Antarctic with its cold climate and absence of higher order plants has the advantage of simpler mixture contribution and pure microbial input to the DOM. This relative simplicity helps facilitate the data interpretation and speculating origin and formation pathways of Antarctic fulvic acids. In this study, we have comprehensively examined fulvic acids from two different areas in Antarctica. Pony Lake fulvic acid (PLFA) from McMurdo Sound area, Western Antarctica as IHSS Standard Reference fulvic acid and three other fulvic acids from Vestfold Hills, Eastern Antarctica were chosen as samples. For the first time these fulvic acids were analysed using a range of derivatisation methods coupled to gas chromatography/mass spectrometry. These methods complemented each other to demonstrate the broad range of components present in these complex fulvic acids. Our findings indicated the presence of various chemical components (apart from carbohydrates and sugars); many of which have not been previously reported in fulvic acids; they mainly include aliphatic linear and branched carboxylic acids, fatty acids (saturated and unsaturated), heterocyclic nitrogen-containing compounds, aromatics and terpenoids. Our results are the first report of the presence of unbroken tricyclic terpenoids among the products of three out of four fulvic acids tabulated. It also highlighted the feasibility of characterisation of DOM using gas chromatography without the need for depolymerisation using hydrolysis or other harsh treatments. Our results also showed that using a fractionation step prior to gas chromatography can assist with providing additional information regarding molecular-level analysis of Antarctic fulvic acid as an important aquatic microbial end-member DOM. Furthermore, fractionation clearly revealed the presence of micelle-like structure in Antarctic fulvic materials supporting the theory of supramolecular structures for Humic substances.

Aquatic Organic Matter Fluorescence

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Publisher : Cambridge University Press
ISBN 13 : 0521764610
Total Pages : 407 pages
Book Rating : 4.5/5 (217 download)

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Book Synopsis Aquatic Organic Matter Fluorescence by : Paula G. Coble

Download or read book Aquatic Organic Matter Fluorescence written by Paula G. Coble and published by Cambridge University Press. This book was released on 2014-07-14 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: A core text on principles, laboratory/field methodologies, and data interpretation for fluorescence applications in aquatic science, for advanced students and researchers.

A Highly Resolved Molecular-level Interrogation of Dissolved Organic Matter (DOM) Complexity and Composition in a Snowmelt-affected System

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Publisher :
ISBN 13 : 9781303420313
Total Pages : 303 pages
Book Rating : 4.4/5 (23 download)

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Book Synopsis A Highly Resolved Molecular-level Interrogation of Dissolved Organic Matter (DOM) Complexity and Composition in a Snowmelt-affected System by : Gregory Ian Ball

Download or read book A Highly Resolved Molecular-level Interrogation of Dissolved Organic Matter (DOM) Complexity and Composition in a Snowmelt-affected System written by Gregory Ian Ball and published by . This book was released on 2013 with total page 303 pages. Available in PDF, EPUB and Kindle. Book excerpt: To better constrain the chemical composition and molecular diversity of dissolved organic matter (DOM) in natural waters, comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GCxGC-TOF-MS) was applied for the first time as a novel technique towards its characterization. This technique chromatographically resolved thousands of peaks per sample and yielded a level of chromatographic resolution that approached the effective mass resolving capabilities of Fourier transform ion cyclotron resonance mass spectrometers (FT-ICR-MS). As with peaks resolved by FT-ICR-MS, the chemical identities of peaks resolved by GCxGC-TOF-MS (> 90 %) remained largely unknown, however GCxGC-TOF-MS provided an independent means by which peaks could be tied to known compounds, which included (1) electron-impact mass spectra accompanying each peak and (2) the separation of structurally related compounds along predictable trajectories in two-dimensional GCxGC space. The development and implementation of this methodology (Chapter II) identified 451 compounds across diverse CuO-oxidized, TMS-derivatized samples and provided a basis for identifying 313 compounds (6.5 % of peaks) within a solid phase extracted (SPE) DOM sample isolated from the Upper Truckee River, Lake Tahoe, California, USA. This represented the most comprehensive compound-specific characterization of a DOM sample to date and an approximate three-folding of compounds previously identified within this oxidation product mixture, a subject of three decades of extensive study. Novel compounds were discovered, isothermal retention in the second dimension was predicted using molecular mechanics modeling, and evidence for a previously unexplored isomeric diversity within DOM was presented. Thousands (> 90 %) of GCxGC-resolvable peaks, however, resisted facile structural elucidation and motivated the development and implementation of a methodology (Chapter III) by which the chemical distance between specific peak populations (defined by chromatographic localization and peak intensity) of two samples could be quantified. Performed pair-wise across a sample set of Lake Tahoe Basin SPE-DOM samples, distance matrices amenable to linkage analysis were constructed, hierarchical relationships of similarity between peak populations were exposed, and cluster analysis identified sample groupings that were subsequently corroborated by high resolution proton nuclear magnetic resonance spectroscopy (1H-NMR) of CuO-oxidized DOM. Interpretively revealing results were obtained, including the likely identification of peak populations specific to degraded terrestrial OM. In Chapter IV, a 13,500-year organic geochemical record ([delta]13C, [delta15N, TOC, TN, C:N) spanning the Holocene was created for Fallen Leaf Lake (FLL), California Sierra Nevada, USA. This was complemented by a 4,500-year lignin phenol record which spanned the Pleistocene-Holocene transition. These records were interpreted within the context of Holocene climate and seismicity and a post-glacial history of flora succession was proposed. In Chapter V a newly developed, high resolution, two-dimensional, heart-cutting preparative capillary gas chromatograph (PCGC) was developed, applied, and successfully evaluated as a tool for the enrichment of &mug quantities of material destined for natural abundance radiocarbon (14C) analysis by accelerator mass spectrometry (AMS).

Natural Organic Matter in Water

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Publisher : Butterworth-Heinemann
ISBN 13 : 0128017198
Total Pages : 383 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Natural Organic Matter in Water by : Mika Silanpää

Download or read book Natural Organic Matter in Water written by Mika Silanpää and published by Butterworth-Heinemann. This book was released on 2014-10-07 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: Approximately 77 percent of the freshwater used in the United States comes from surface-water sources and is subject to natural organic matter contamination according to the United States Geological Survey. This presents a distinct challenge to water treatment engineers. An essential resource to the latest breakthroughs in the characterization, treatment and removal of natural organic matter (NOM) from drinking water, Natural Organic Matter in Waters: Characterization and Treatment Methods focuses on advance filtration and treatment options, and processes for reducing disinfection byproducts. Based on the author’s years of research and field experience, this book begins with the characterization of NOM including: general parameters, isolation and concentration, fractionation, composition and structural analysis and biological testing. This is followed by removal methods such as inorganic coagulants, polyelectrolytes and composite coagulants. Electrochemical and membranes removal methods such as: electrocoagulation, electrochemical oxidation, microfiltration and ultrafiltration, nanofiltration and membrane fouling. Covers conventional as well as advanced NOM removal methods Includes characterization methods of NOM Explains removal methods such as: removal by coagulation, electrochemical, advanced oxidation, and integrated methods

Comprehensive Water Quality and Purification

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Publisher : Elsevier
ISBN 13 : 0123821835
Total Pages : 1537 pages
Book Rating : 4.1/5 (238 download)

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Book Synopsis Comprehensive Water Quality and Purification by :

Download or read book Comprehensive Water Quality and Purification written by and published by Elsevier. This book was released on 2013-09-24 with total page 1537 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Water Quality and Purification, Four Volume Set provides a rich source of methods for analyzing water to assure its safety from natural and deliberate contaminants, including those that are added because of carelessness of human endeavors. Human development has great impact on water quality, and new contaminants are emerging every day. The issues of sampling for water analysis, regulatory considerations, and forensics in water quality and purity investigations are covered in detail. Microbial as well as chemical contaminations from inorganic compounds, radionuclides, volatile and semivolatile compounds, disinfectants, herbicides, and pharmaceuticals, including endocrine disruptors, are treated extensively. Researchers must be aware of all sources of contamination and know how to prescribe techniques for removing them from our water supply. Unlike other works published to date that concentrate on issues of water supply, water resource management, hydrology, and water use by industry, this work is more tightly focused on the monitoring and improvement of the quality of existing water supplies and the recovery of wastewater via new and standard separation techniques Using analytical chemistry methods, offers remediation advice on pollutants and contaminants in addition to providing the critical identification perspective The players in the global boom of water purification are numerous and varied. Having worked extensively in academia and industry, the Editor-in-Chief has been careful about constructing a work for a shared audience and cause