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Compositional Models Of Glass Melt Properties And Their Use For Glass Formulation
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Book Synopsis Compositional Models of Glass/Melt Properties and Their Use for Glass Formulation by :
Download or read book Compositional Models of Glass/Melt Properties and Their Use for Glass Formulation written by and published by . This book was released on 2014 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nuclear waste glasses must simultaneously meet a number of criteria related to their processability, product quality, and cost factors. The properties that must be controlled in glass formulation and waste vitrification plant operation tend to vary smoothly with composition allowing for glass property-composition models to be developed and used. Models have been fit to the key glass properties. The properties are transformed so that simple functions of composition (e.g., linear, polynomial, or component ratios) can be used as model forms. The model forms are fit to experimental data designed statistically to efficiently cover the composition space of interest. Examples of these models are found in literature. The glass property-composition models, their uncertainty definitions, property constraints, and optimality criteria are combined to formulate optimal glass compositions, control composition in vitrification plants, and to qualify waste glasses for disposal. An overview of current glass property-composition modeling techniques is summarized in this paper along with an example of how those models are applied to glass formulation and product qualification at the planned Hanford high-level waste vitrification plant.
Book Synopsis Properties of Glass-Forming Melts by : David Pye
Download or read book Properties of Glass-Forming Melts written by David Pye and published by CRC Press. This book was released on 2005-05-12 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents state-of-the-art information concerning properties and processes involved in glass melts. Based upon contributions by renowned authors and scientists working with glass melt systems, Properties of Glass-Forming Melts is an excellent compilation of the current knowledge on property data, mechanisms, measurement techniques, and str
Book Synopsis Advances in Fusion and Processing of Glass III by : James R. Varner
Download or read book Advances in Fusion and Processing of Glass III written by James R. Varner and published by John Wiley & Sons. This book was released on 2012-04-11 with total page 478 pages. Available in PDF, EPUB and Kindle. Book excerpt: Glass continues to be a material of great scientific and technological interest; however, the economic pressures on the glass industry, the emphasis on global markets, and the worldwide attention to energy and environmental conservation continue to increase. Forty-seven papers offer new solutions to the challenges of glass manufacturing, particularly as they pertain to melting and forming. Proceedings of the 7th International Conference on Advances in Fusion and Processing of Glass, July 27-31, 2003, Rochester, New York; Ceramic Transactions, Volume 141.
Book Synopsis Modeling of Glass Making Processes for Improved Efficiency by :
Download or read book Modeling of Glass Making Processes for Improved Efficiency written by and published by . This book was released on 2003 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The overall goal of this project was to develop a high-temperature melt properties database with sufficient reliability to allow mathematical modeling of glass melting and forming processes for improved product quality, improved efficiency and lessened environmental impact. It was initiated by the United States glass industry through the NSF Industry/University Center for Glass Research (CGR) at Alfred University [1]. Because of their important commercial value, six different types/families of glass were studied: container, float, fiberglass (E- and wool-types), low-expansion borosilicate, and color TV panel glasses. CGR member companies supplied production-quality glass from all six families upon which we measured, as a function of temperature in the molten state, density, surface tension, viscosity, electrical resistivity, infrared transmittance (to determine high temperature radiative conductivity), non-Newtonian flow behavior, and oxygen partial pres sure. With CGR cost sharing, we also studied gas solubility and diffusivity in each of these glasses. Because knowledge of the compositional dependencies of melt viscosity and electrical resistivity are extremely important for glass melting furnace design and operation, these properties were studied more fully. Composition variations were statistically designed for all six types/families of glass. About 140 different glasses were then melted on a laboratory scale and their viscosity and electrical resistivity measured as a function of temperature. The measurements were completed in February 2003 and are reported on here. The next steps will be (1) to statistically analyze the compositional dependencies of viscosity and electrical resistivity and develop composition-property response surfaces, (2) submit all the data to CGR member companies to evaluate the usefulness in their models, and (3) publish the results in technical journals and most likely in book form.
Book Synopsis Analysis of the Composition and Structure of Glass and Glass Ceramics by : Hans Bach
Download or read book Analysis of the Composition and Structure of Glass and Glass Ceramics written by Hans Bach and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 541 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first book completely devoted to the subject, this volume describes the analysis of the composition and structure of glass and glass ceramics. Although conceived as a monograph, the individual chapters are written by leading Schott experts on the corresponding subjects.
Book Synopsis Silicate Glasses and Melts by : Bjorn Mysen
Download or read book Silicate Glasses and Melts written by Bjorn Mysen and published by Elsevier. This book was released on 2018-11-27 with total page 722 pages. Available in PDF, EPUB and Kindle. Book excerpt: Silicate Glasses and Melts, Second Edition describes the structure-property-composition relationships for silicate glasses and melts from a geological and industrial perspective. Updated sections include (i) characterization of silicate melt and COHN fluid structure (with and without dissolved silicate components) with pressure, temperature, and redox conditions and responses of structural variables to chemical composition, (ii) determination of solubility and solution mechanisms of COHN volatiles in silicate melts and minerals and of solubility and solution mechanisms of silicate components in COHN fluids, and (iii) effects of very high pressure on structure and properties of melts and glasses. This new book is an essential resource for researchers in a number of fields, including geology, geophysics, geoscience, volcanology, material science, glass science, petrology and mineralogy. - Brings together multidisciplinary research scattered across the scientific literature into one reference, with a focus on silicate melts and their application to natural systems - Emphasizes linking melt properties to melt structure - Includes a discussion of the pros and cons of the use of glass as a proxy for melt structure and properties - Written by highly regarded experts in the field who, among other honors, were the 2006 recipients of the prestigious G.W. Morey award of the American Ceramic Society
Book Synopsis Property/composition Relationships for Hanford High-level Waste Glasses Melting at 115[degrees]C Volume 1: Chapters 1-11 by :
Download or read book Property/composition Relationships for Hanford High-level Waste Glasses Melting at 115[degrees]C Volume 1: Chapters 1-11 written by and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A Composition Variation study (CVS) is being performed within the Pacific Northwest Laboratory Vitrification Technology Development (PVTD) project in support of a future high-level nuclear waste vitrification plant at the Hanford site in Washington. From 1989 to 1994, over 120 nonradioactive glasses were melted and properties measured in five statistically-designed experimental phases. Glass composition is represented by the 10 components SiO[sub 2], B[sub 2]O[sub 3], Al[sub 2]O[sub 3], Fe[sub 2]O[sub 3], ZrO[sub 2], Na[sub 2]O, Li[sub 2]O, CaO, MgO, and Others (all remaining components). The properties measured include viscosity ([eta]), electrical conductivity ([epsilon]), glass transition temperature (T[sub g]), thermal expansion of solid glass ([alpha][sub s]) and molten glass ([alpha][sub m]), crystallinity (quenched and canister centerline cooled glasses), liquidus temperature (T[sub L]), durability based on normalized elemental releases from the Materials Characterization Center-1 28-day dissolution test (MCC-1, r[sub mi]) and the 7-day Product Consistency Test (PCT, r[sub pi]), and solution pHs from MCC-1 and PCT. Amorphous phase separation was also evaluated. Empirical first- and second-order mixture models were fit using the CVS data to relate the various properties to glass composition. Equations for calculating the uncertainty associated with property values predicted by the models were also developed. The models were validated using both internal and external data. Other modeling approaches (e.g., non-bridging oxygen, free energy of hydration, phase-equilibria T[sub L]) were investigated for specific properties. A preliminary Qualified Composition Region was developed to identify glass compositions with high confidence of being processable in a melter and meeting waste form acceptance criteria.
Book Synopsis Fiberglass Science and Technology by : Hong Li
Download or read book Fiberglass Science and Technology written by Hong Li and published by Springer Nature. This book was released on 2021-08-20 with total page 555 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights recent developments in fiberglass research and technology development, including high-performance fiberglass chemistry; in-depth glass network structure information derived from the-state-of-the-art spectroscopic measurements, molecular dynamics simulations, and their correlations with properties; fiber surface chemistry in relation to sizing chemistry - a critical part of composite performance; fiber process stability; fundamental understanding of the batch-to-melt conversion processes and melt flow simulations; and environmental concerns such as energy efficiency and emission of volatile species, which are key to environmentally-friendly product manufacturing. The book aims to guide fiberglass researchers and manufacturers towards better awareness and, perhaps, provides potential options for global ecosystem management. More than 500 current references are included, which will enable researchers from fiber glass industry and research institution access to the most recent progress in fiberglass science and technology. Advances scientific understanding of fiberglass-forming processes, rising in popularity as a building material throughout the world; Describes the current advances in the structure and formation of fiber glass, beginning with chemistry, a wide range of characterizations, and processes, through to applications; Contains information on environmental aspects of fiberglass production, addressing energy consumption and emission.
Book Synopsis High Temperature Glass Melt Property Database for Process Modeling by : Thomas P. Seward
Download or read book High Temperature Glass Melt Property Database for Process Modeling written by Thomas P. Seward and published by Wiley-American Ceramic Society. This book was released on 2005-09 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is the result of a study to develop a high-temperature melt properties database with sufficient comprehensiveness and reliability to allow mathematical modeling of glass melting and forming processes for improved product quality, improved efficiency and lessened environmental impact. The study was initiated by the U.S. glass industry through the National Science Foundation Industry/University Center for Glass Research at Alfred University (CGR) and funded in part by a grant from the U.S. Department of Energy's Industrial Technologies Program.
Book Synopsis Property/composition Relationships for Hanford High-level Waste Glasses Melting at 115°C Volume 1 by :
Download or read book Property/composition Relationships for Hanford High-level Waste Glasses Melting at 115°C Volume 1 written by and published by . This book was released on 1994 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Composition Variation study (CVS) is being performed within the Pacific Northwest Laboratory Vitrification Technology Development (PVTD) project in support of a future high-level nuclear waste vitrification plant at the Hanford site in Washington. From 1989 to 1994, over 120 nonradioactive glasses were melted and properties measured in five statistically-designed experimental phases. Glass composition is represented by the 10 components SiO2, B2O3, Al2O3, Fe2O3, ZrO2, Na2O, Li2O, CaO, MgO, and Others (all remaining components). The properties measured include viscosity ([eta]), electrical conductivity ([epsilon]), glass transition temperature (T{sub g}), thermal expansion of solid glass ([alpha]{sub s}) and molten glass ([alpha]{sub m}), crystallinity (quenched and canister centerline cooled glasses), liquidus temperature (T{sub L}), durability based on normalized elemental releases from the Materials Characterization Center-1 28-day dissolution test (MCC-1, r{sub mi}) and the 7-day Product Consistency Test (PCT, r{sub pi}), and solution pHs from MCC-1 and PCT. Amorphous phase separation was also evaluated. Empirical first- and second-order mixture models were fit using the CVS data to relate the various properties to glass composition. Equations for calculating the uncertainty associated with property values predicted by the models were also developed. The models were validated using both internal and external data. Other modeling approaches (e.g., non-bridging oxygen, free energy of hydration, phase-equilibria T{sub L}) were investigated for specific properties. A preliminary Qualified Composition Region was developed to identify glass compositions with high confidence of being processable in a melter and meeting waste form acceptance criteria.
Book Synopsis Fundamentals of Inorganic Glasses by : Arun K. Varshneya
Download or read book Fundamentals of Inorganic Glasses written by Arun K. Varshneya and published by Elsevier. This book was released on 2019-05-09 with total page 756 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fundamentals of Inorganic Glasses, Third Edition, is a comprehensive reference on the field of glass science and engineering that covers numerous, significant advances. This new edition includes the most recent advances in glass physics and chemistry, also discussing groundbreaking applications of glassy materials. It is suitable for upper level glass science courses and professional glass scientists and engineers at industrial and government labs. Fundamental concepts, chapter-ending problem sets, an emphasis on key ideas, and timely notes on suggested readings are all included. The book provides the breadth required of a comprehensive reference, offering coverage of the composition, structure and properties of inorganic glasses. - Clearly develops fundamental concepts and the basics of glass science and glass chemistry - Provides a comprehensive discussion of the composition, structure and properties of inorganic glasses - Features a discussion of the emerging applications of glass, including applications in energy, environment, pharmaceuticals, and more - Concludes chapters with problem sets and suggested readings to facilitate self-study
Book Synopsis Springer Handbook of Glass by : J. David Musgraves
Download or read book Springer Handbook of Glass written by J. David Musgraves and published by Springer Nature. This book was released on 2019-11-08 with total page 1851 pages. Available in PDF, EPUB and Kindle. Book excerpt: This handbook provides comprehensive treatment of the current state of glass science from the leading experts in the field. Opening with an enlightening contribution on the history of glass, the volume is then divided into eight parts. The first part covers fundamental properties, from the current understanding of the thermodynamics of the amorphous state, kinetics, and linear and nonlinear optical properties through colors, photosensitivity, and chemical durability. The second part provides dedicated chapters on each individual glass type, covering traditional systems like silicates and other oxide systems, as well as novel hybrid amorphous materials and spin glasses. The third part features detailed descriptions of modern characterization techniques for understanding this complex state of matter. The fourth part covers modeling, from first-principles calculations through molecular dynamics simulations, and statistical modeling. The fifth part presents a range of laboratory and industrial glass processing methods. The remaining parts cover a wide and representative range of applications areas from optics and photonics through environment, energy, architecture, and sensing. Written by the leading international experts in the field, the Springer Handbook of Glass represents an invaluable resource for graduate students through academic and industry researchers working in photonics, optoelectronics, materials science, energy, architecture, and more.
Book Synopsis Introduction to Glass Science and Technology by : James E Shelby
Download or read book Introduction to Glass Science and Technology written by James E Shelby and published by Royal Society of Chemistry. This book was released on 2015-11-06 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a concise and inexpensive introduction for an undergraduate course in glass science and technology. The level of the book has deliberately been maintained at the introductory level to avoid confusion of the student by inclusion of more advanced material, and is unique in that its text is limited to the amount suitable for a one term course for students in materials science, ceramics or inorganic chemistry. The contents cover the fundamental topics of importance in glass science and technology, including glass formation, crystallization, phase separation and structure of glasses. Additional chapters discuss the most important properties of glasses, including discussion of physical, optical, electrical, chemical and mechanical properties. A final chapter provides an introduction to a number of methods used to form technical glasses, including glass sheet, bottles, insulation fibre, optical fibres and other common commercial products. In addition, the book contains discussion of the effects of phase separation and crystallization on the properties of glasses, which is neglected in other texts. Although intended primarily as a textbook, Introduction to Glass Science and Technology will also be invaluable to the engineer or scientist who desires more knowledge regarding the formation, properties and production of glass.
Book Synopsis The Office of Environmental Management Technical Reports by :
Download or read book The Office of Environmental Management Technical Reports written by and published by . This book was released on 1997 with total page 972 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Ceramics for Environmental and Energy Applications II by : Fatih Dogan
Download or read book Ceramics for Environmental and Energy Applications II written by Fatih Dogan and published by John Wiley & Sons. This book was released on 2014-02-19 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: A collection of papers from the below symposia held during the 10th Pacific Rim Conference on Ceramic and Glass Technology (PacRim10), June 2-7, 2013, in Coronado, California 2012: Solid Oxide Fuel Cells and Hydrogen Technology Direct Thermal to Electrical Energy Conversion Materials and Applications Photovoltaic Materials and Technologies Ceramics for Next Generation Nuclear Energy Advances in Photocatalytic Materials for Energy and Environmental Applications Ceramics Enabling Environmental Protection: Clean Air and Water Advanced Materials and Technologies for Electrochemical Energy Storage Systems Glasses and Ceramics for Nuclear and Hazardous Waste Treatment
Book Synopsis Melt Chemistry, Relaxation, and Solidification Kinetics of Glasses by : Hong Li
Download or read book Melt Chemistry, Relaxation, and Solidification Kinetics of Glasses written by Hong Li and published by John Wiley & Sons. This book was released on 2012-04-11 with total page 249 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume will summarize the most recent development in experimentation, computation, and theory on chemistry of glass forming melt, including melt structure modeling and melt structure and characterizations. This volume provides a timely update on the advances in glass basic science research and development.
Book Synopsis Magma Redox Geochemistry by : Roberto Moretti
Download or read book Magma Redox Geochemistry written by Roberto Moretti and published by John Wiley & Sons. This book was released on 2021-10-26 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explores the many facets of redox exchanges that drive magma's behavior and evolution, from the origin of the Earth until today The redox state is one of the master variables behind the Earth's forming processes, which at depth concern magma as the major transport agent. Understanding redox exchanges in magmas is pivotal for reconstructing the history and compositional make-up of our planet, for exploring its mineral resources, and for monitoring and forecasting volcanic activity. Magma Redox Geochemistry describes the multiple facets of redox reactions in the magmatic realm and presents experimental results, theoretical approaches, and unconventional and novel techniques. Volume highlights include: Redox state and oxygen fugacity: so close, so far Redox processes from Earth’s accretion to global geodynamics Redox evolution from the magma source to volcanic emissions Redox characterization of elements and their isotopes The American Geophysical Union promotes discovery in Earth and space science for the benefit of humanity. Its publications disseminate scientific knowledge and provide resources for researchers, students, and professionals.