Chemical Disposition of Plutonium in Hanford Site Tank Wastes

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ISBN 13 :
Total Pages : 166 pages
Book Rating : 4.:/5 (94 download)

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Book Synopsis Chemical Disposition of Plutonium in Hanford Site Tank Wastes by :

Download or read book Chemical Disposition of Plutonium in Hanford Site Tank Wastes written by and published by . This book was released on 2015 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report examines the chemical disposition of plutonium (Pu) in Hanford Site tank wastes, by itself and in its observed and potential interactions with the neutron absorbers aluminum (Al), cadmium (Cd), chromium (Cr), iron (Fe), manganese (Mn), nickel (Ni), and sodium (Na). Consideration also is given to the interactions of plutonium with uranium (U). No consideration of the disposition of uranium itself as an element with fissile isotopes is considered except tangentially with respect to its interaction as an absorber for plutonium. The report begins with a brief review of Hanford Site plutonium processes, examining the various means used to recover plutonium from irradiated fuel and from scrap, and also examines the intermediate processing of plutonium to prepare useful chemical forms. The paper provides an overview of Hanford tank defined-waste-type compositions and some calculations of the ratios of plutonium to absorber elements in these waste types and in individual waste analyses. These assessments are based on Hanford tank waste inventory data derived from separately published, expert assessments of tank disposal records, process flowsheets, and chemical/radiochemical analyses. This work also investigates the distribution and expected speciation of plutonium in tank waste solution and solid phases. For the solid phases, both pure plutonium compounds and plutonium interactions with absorber elements are considered. These assessments of plutonium chemistry are based largely on analyses of idealized or simulated tank waste or strongly alkaline systems. The very limited information available on plutonium behavior, disposition, and speciation in genuine tank waste also is discussed. The assessments show that plutonium coprecipitates strongly with chromium, iron, manganese and uranium absorbers. Plutonium's chemical interactions with aluminum, nickel, and sodium are minimal to non-existent. Credit for neutronic interaction of plutonium with these absorbers occurs only if they are physically proximal in solution or the plutonium present in the solid phase is intimately mixed with compounds or solutions of these absorbers. No information on the potential chemical interaction of plutonium with cadmium was found in the technical literature. Definitive evidence of sorption or adsorption of plutonium onto various solid phases from strongly alkaline media is less clear-cut, perhaps owing to fewer studies and to some well-attributed tests run under conditions exceeding the very low solubility of plutonium. The several studies that are well-founded show that only about half of the plutonium is adsorbed from waste solutions onto sludge solid phases. The organic complexants found in many Hanford tank waste solutions seem to decrease plutonium uptake onto solids. A number of studies show plutonium sorbs effectively onto sodium titanate. Finally, this report presents findings describing the behavior of plutonium vis-à-vis other elements during sludge dissolution in nitric acid based on Hanford tank waste experience gained by lab-scale tests, chemical and radiochemical sample characterization, and full-scale processing in preparation for strontium-90 recovery from PUREX sludges.

The Hanford Tanks

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Publisher : National Academies Press
ISBN 13 : 0309055857
Total Pages : 84 pages
Book Rating : 4.3/5 (9 download)

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Book Synopsis The Hanford Tanks by : National Research Council

Download or read book The Hanford Tanks written by National Research Council and published by National Academies Press. This book was released on 1996-10-10 with total page 84 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Hanford Site (also known as the Hanford Reservation) occupies approximately 1,450 km2 (560 square miles) along the Columbia River in south-central Washington, north of the city of Richland. The site was established by the federal government in 1943 to produce plutonium for nuclear weapons. Currently, the mission of the site, under the responsibility of the U.S. Department of Energy (DOE), is management of wastes generated by the weapons program and remediation of the environment contaminated by that waste. As part of that mission, DOE and the State of Washington Department of Ecology prepared the Hanford Site Tank Waste Remediation System Draft Environmental Impact Statement (DEIS). The Hanford Tanks is a general review of the DEIS. Its findings and recommendations are the subject of this report. Selection of a disposition plan for these wastes is a decision of national importance, involving potential environmental and health risks, technical challenges, and costs of tens to hundreds of billions of dollars. The last comprehensive analysis of these issues was completed 10 years ago, and several major changes in plans have occurred since. Therefore, the current reevaluation is timely and prudent. This report endorses the decision to prepare this new environmental impact statement, and in particular the decision to evaluate a wide range of alternatives not restricted to those encouraged by current regulatory policies.

Ольга/Олег Татаринцевы. Максимум Исключений

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Publisher :
ISBN 13 : 9785942320782
Total Pages : 70 pages
Book Rating : 4.3/5 (27 download)

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Book Synopsis Ольга/Олег Татаринцевы. Максимум Исключений by :

Download or read book Ольга/Олег Татаринцевы. Максимум Исключений written by and published by . This book was released on 2011 with total page 70 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chemical Pretreatment of Nuclear Waste for Disposal

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Publisher : Springer Science & Business Media
ISBN 13 : 1461525268
Total Pages : 210 pages
Book Rating : 4.4/5 (615 download)

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Book Synopsis Chemical Pretreatment of Nuclear Waste for Disposal by : E.P. Horwitz

Download or read book Chemical Pretreatment of Nuclear Waste for Disposal written by E.P. Horwitz and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 210 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical pretreatment of nuclear wastes refers to the sequence of separations processes used to partition such wastes into a small volume of high-level waste for deep geologic disposal and a larger volume of low-level waste for disposal in a near-surface facility. Pretreatment of nuclear wastes now stored at several U. S. Department of Energy sites ranges from simple solid-liquid separations to more complex chemical steps, such as dissolution of sludges and removal of selected radionuclides, e. g. , 90Sr, 99Tc, 137CS, and TRU (transuranium) elements. The driving force for development of chemical pretreatment processes for nuclear wastes is the economic advantage of waste minimization as reflected in lower costs for near-surface disposal compared to the high cost of disposing of wastes in a deep geologic repository. This latter theme is expertly and authoritatively discussed in the introductory paper by J. and L. Bell. Seven papers in this volume describe several separations processes developed or being developed to pretreat the large volume of nuclear wastes stored at the US DOE Hanford and Savannah River sites. These papers include descriptions of the type and amount of important nuclear wastes stored at the Hanford and Savannah River sites as well as presently envisioned strategies for their treatment and final disposal. A paper by Strachan et al. discusses chemical and radiolytic mechanisms for the formation and release of potentially explosive hydrogen gas in Tank 241-SY-101 at the Hanford site.

Disposal of Hanford Defense High-level, Transuranic and Tank Wastes, Hanford Site, Richland, Washington: Text

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ISBN 13 :
Total Pages : 420 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Disposal of Hanford Defense High-level, Transuranic and Tank Wastes, Hanford Site, Richland, Washington: Text by :

Download or read book Disposal of Hanford Defense High-level, Transuranic and Tank Wastes, Hanford Site, Richland, Washington: Text written by and published by . This book was released on 1987 with total page 420 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this Environmental Impact Statement (EIS) is to provide environmental imput into the selection and implementation of final disposal actions for high-level, transuranic and tank wastes located at the Hanford Site, Richland, Washington, and into the construction, operation and decommissioning of waste alternatives. Specifically evaluated are a Hanford Waste Vitrification Plant, Transportable Grout Facility, and a Waste Receiving and Packaging Facility. Also an evaluation is presented to assist in determining whether any additional action should be taken in terms of long-term environmental protection for waste that was disposed of at Hanford prior to 1970 as low-level waste (before the transuranic waste category was established by the Atomic Energy Commission but which might fall into that category if gernerated today.).

Tank Waste Retrieval, Processing, and On-site Disposal at Three Department of Energy Sites

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Publisher : National Academies Press
ISBN 13 : 0309101700
Total Pages : 214 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Tank Waste Retrieval, Processing, and On-site Disposal at Three Department of Energy Sites by : National Research Council

Download or read book Tank Waste Retrieval, Processing, and On-site Disposal at Three Department of Energy Sites written by National Research Council and published by National Academies Press. This book was released on 2006-10-12 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: DOE Tank Waste: How clean is clean enough? The U.S. Congress asked the National Academies to evaluate the Department of Energy's (DOE's) plans for cleaning up defense-related radioactive wastes stored in underground tanks at three sites: the Hanford Site in Washington State, the Savannah River Site in South Carolina, and the Idaho National Laboratory. DOE plans to remove the waste from the tanks, separate out high-level radioactive waste to be shipped to an off-site geological repository, and dispose of the remaining lower-activity waste onsite. The report concludes that DOE's overall plan is workable, but some important challenges must be overcomeâ€"including the removal of residual waste from some tanks, especially at Hanford and Savannah River. The report recommends that DOE pursue a more risk-informed, consistent, participatory, and transparent for making decisions about how much waste to retrieve from tanks and how much to dispose of onsite. The report offers several other detailed recommendations to improve the technical soundness of DOE's tank cleanup plans.

Chemical Species of Plutonium in Hanford Radioactive Tank Waste

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (685 download)

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Book Synopsis Chemical Species of Plutonium in Hanford Radioactive Tank Waste by :

Download or read book Chemical Species of Plutonium in Hanford Radioactive Tank Waste written by and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Large quantities of radioactive wastes have been generated at the Hanford Site over its operating life. The wastes with the highest activities are stored underground in 177 large (mostly one million gallon volume) concrete tanks with steel liners. The wastes contain processing chemicals, cladding chemicals, fission products, and actinides that were neutralized to a basic pH before addition to the tanks to prevent corrosion of the steel liners. Because the mission of the Hanford Site was to provide plutonium for defense purposes, the amount of plutonium lost to the wastes was relatively small. The best estimate of the amount of plutonium lost to all the waste tanks is about 500 kg. Given uncertainties in the measurements, some estimates are as high as 1,000 kg (Roetman et al. 1994). The wastes generally consist of (1) a sludge layer generated by precipitation of dissolved metals from aqueous wastes solutions during neutralization with sodium hydroxide, (2) a salt cake layer formed by crystallization of salts after evaporation of the supernate solution, and (3) an aqueous supernate solution that exists as a separate layer or as liquid contained in cavities between sludge or salt cake particles. The identity of chemical species of plutonium in these wastes will allow a better understanding of the behavior of the plutonium during storage in tanks, retrieval of the wastes, and processing of the wastes. Plutonium chemistry in the wastes is important to criticality and environmental concerns, and in processing the wastes for final disposal. Plutonium has been found to exist mainly in the sludge layers of the tanks along with other precipitated metal hydrous oxides. This is expected due to its low solubility in basic aqueous solutions. Tank supernate solutions do not contain high concentrations of plutonium even though some tanks contain high concentrations of complexing agents. The solutions also contain significant concentrations of hydroxide which competes with other potential complexants. The sodium nitrate and sodium phosphate salts that form most of the salt cake layers have little interaction with plutonium in the wastes and contain relatively small plutonium concentrations. For these reasons the authors consider plutonium species in the sludges and supernate solutions only. The low concentrations of plutonium in waste tank supernate solutions and in the solid sludges prevent identification of chemical species of plutonium by ordinary analytical techniques. Spectrophotometric measurements are not sensitive enough to identify plutons oxidation states or complexes in these waste solutions. Identification of solid phases containing plutonium in sludge solids by x-ray diffraction or by microscopic techniques would be extremely difficult. Because of these technical problems, plutonium speciation was extrapolated from known behavior observed in laboratory studies of synthetic waste or of more chemically simple systems.

Hanford Site, Disposal of Hanford Defense High-level, Transuranic and Tank Wastes

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Publisher :
ISBN 13 :
Total Pages : 440 pages
Book Rating : 4.3/5 (555 download)

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Book Synopsis Hanford Site, Disposal of Hanford Defense High-level, Transuranic and Tank Wastes by :

Download or read book Hanford Site, Disposal of Hanford Defense High-level, Transuranic and Tank Wastes written by and published by . This book was released on 1987 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Disposal of Hanford Defense High-level, Transuranic and Tank Wastes

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Publisher :
ISBN 13 :
Total Pages : 732 pages
Book Rating : 4.:/5 (89 download)

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Book Synopsis Disposal of Hanford Defense High-level, Transuranic and Tank Wastes by : United States. Department of Energy. Office of the Assistant Secretary for Defense Programs

Download or read book Disposal of Hanford Defense High-level, Transuranic and Tank Wastes written by United States. Department of Energy. Office of the Assistant Secretary for Defense Programs and published by . This book was released on 1986 with total page 732 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Hanford Tank Cleanup

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ISBN 13 :
Total Pages : 104 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Hanford Tank Cleanup by : R. E. Gephart

Download or read book Hanford Tank Cleanup written by R. E. Gephart and published by . This book was released on 1998 with total page 104 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hanford Tank Cleanup is a first-of-its-kind report written about the most unique industrial waste ever created by modern industrial society. This waste, some 54 million gallons of radioactive and chemical residue now resting inside 177 underground storage tanks at the U.S. Department of Energy's Hanford Site in Washington State, is part of the nation's 90 million gallon inventory of highly radioactive waste.

Review of the Final Draft Analysis of Supplemental Treatment Approaches of Low-Activity Waste at the Hanford Nuclear Reservation

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Publisher : National Academies Press
ISBN 13 : 0309495210
Total Pages : 81 pages
Book Rating : 4.3/5 (94 download)

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Book Synopsis Review of the Final Draft Analysis of Supplemental Treatment Approaches of Low-Activity Waste at the Hanford Nuclear Reservation by : National Academies of Sciences, Engineering, and Medicine

Download or read book Review of the Final Draft Analysis of Supplemental Treatment Approaches of Low-Activity Waste at the Hanford Nuclear Reservation written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2019-09-15 with total page 81 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1943, as part of the Manhattan Project, the Hanford Nuclear Reservation was established with the mission to produce plutonium for nuclear weapons. During 45 years of operations, the Hanford Site produced about 67 metric tonnes of plutoniumâ€"approximately two-thirds of the nation's stockpile. Production processes generated radioactive and other hazardous wastes and resulted in airborne, surface, subsurface, and groundwater contamination. Presently, 177 underground tanks contain collectively about 210 million liters (about 56 million gallons) of waste. The chemically complex and diverse waste is difficult to manage and dispose of safely. Section 3134 of the National Defense Authorization Act for Fiscal Year 2017 calls for a Federally Funded Research and Development Center (FFRDC) to conduct an analysis of approaches for treating the portion of low-activity waste at the Hanford Nuclear Reservation intended for supplemental treatment. The third of four, this report provides an overall assessment of the FFRDC team's final draft report, dated April 5, 2019.

An End State Methodology for Identifying Technology Needs for Environmental Management, with an Example from the Hanford Site Tanks

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Publisher : National Academies Press
ISBN 13 : 0309184312
Total Pages : 105 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis An End State Methodology for Identifying Technology Needs for Environmental Management, with an Example from the Hanford Site Tanks by : National Research Council

Download or read book An End State Methodology for Identifying Technology Needs for Environmental Management, with an Example from the Hanford Site Tanks written by National Research Council and published by National Academies Press. This book was released on 1999-03-16 with total page 105 pages. Available in PDF, EPUB and Kindle. Book excerpt: A major issue in the cleanup of this country's nuclear weapons complex is how to dispose of the radioactive waste resulting primarily from the chemical processing operations for the recovery of plutonium and other defense strategic nuclear materials. The wastes are stored in hundreds of large underground tanks at four U.S. Department of Energy (DOE) sites throughout the United States. The tanks contain hundreds of thousands of cubic meters of radioactive and hazardous waste. Most of it is high-level waste (HLW), some of it is transuranic (TRU) or low- level waste (LLW), and essentially all containing significant amounts of chemicals deemed hazardous. Of the 278 tanks involved, about 70 are known or assumed to have leaked some of their contents to the environment. The remediation of the tanks and their contents requires the development of new technologies to enable cleanup and minimize costs while meeting various health, safety, and environmental objectives. While DOE has a process based on stakeholder participation for screening and formulating technology needs, it lacks transparency (in terms of being apparent to all concerned decision makers and other interested parties) and a systematic basis (in terms of identifying end states for the contaminants and developing pathways to these states from the present conditions). An End State Methodology for Identifying Technology Needs for Environmental Management, with an Example from the Hanford Site Tanks describes an approach for identifying technology development needs that is both systematic and transparent to enhance the cleanup and remediation of the tank contents and their sites. The authoring committee believes that the recommended end state based approach can be applied to DOE waste management in general, not just to waste in tanks. The approach is illustrated through an example based on the tanks at the DOE Hanford Site in southeastern Washington state, the location of some 60 percent by volume of the tank waste residues.

Research Needs for High-Level Waste Stored in Tanks and Bins at U.S. Department of Energy Sites

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Publisher : National Academies Press
ISBN 13 : 0309075653
Total Pages : 146 pages
Book Rating : 4.3/5 (9 download)

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Book Synopsis Research Needs for High-Level Waste Stored in Tanks and Bins at U.S. Department of Energy Sites by : National Research Council

Download or read book Research Needs for High-Level Waste Stored in Tanks and Bins at U.S. Department of Energy Sites written by National Research Council and published by National Academies Press. This book was released on 2001-10-05 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt: The United States Department of Energy (DOE) has approximately 400 million liters (100 million gallons) of liquid high-level waste (HLW) stored in underground tanks and approximately 4,000 cubic meters of solid HLW stored in bins. The current DOE estimate of the cost of converting these liquid and solid wastes into stable forms for shipment to a geological repository exceeds $50 billion to be spent over several decades (DOE, 2000). The Committee on Long-Term Research Needs for Radioactive High-Level Waste at Department of Energy Sites was appointed by the National Research Council (NRC) to advise the Environmental Management Science Program (EMSP) on a long-term research agenda addressing the above problems related to HLW stored in tanks and bins at DOE sites.

Effects Influencing Plutonium-Absorber Interactions and Distributions in Routine and Upset Waste Treatment Plant Operations

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Publisher :
ISBN 13 :
Total Pages : 106 pages
Book Rating : 4.:/5 (94 download)

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Book Synopsis Effects Influencing Plutonium-Absorber Interactions and Distributions in Routine and Upset Waste Treatment Plant Operations by :

Download or read book Effects Influencing Plutonium-Absorber Interactions and Distributions in Routine and Upset Waste Treatment Plant Operations written by and published by . This book was released on 2015 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report is the third in a series of analyses written in support of a plan to revise the Hanford Waste Treatment and Immobilization Plant (WTP) Preliminary Criticality Safety Evaluation Report (CSER) that is being implemented at the request of the U.S. Department of Energy (DOE) Criticality Safety Group. A report on the chemical disposition of plutonium in Hanford tank wastes was prepared as Phase 1 of this plan (Delegard and Jones 2015). Phase 2 is the provision of a chemistry report to describe the potential impacts on criticality safety of waste processing operations within the WTP (Freer 2014). In accordance with the request from the Environmental and Nuclear Safety Department of the WTP (Miles and Losey 2012), the Phase 2 report assessed the potential for WTP process conditions within and outside the range of normal control parameters to change the ratio of fissile material to neutron-absorbing material in the waste as it is processed with an eye towards potential implications for criticality safety. The Phase 2 study also considered the implications should WTP processes take place within the credible range of chemistry upset conditions. In the present Phase 3 report, the 28 phenomena described in the Phase 2 report were considered with respect to the disposition of plutonium and various absorber elements. The phenomena identified in the Phase 2 report are evaluated in light of the Phase 1 report and other resources to determine the impacts these phenomena might have to alter the plutonium/absorber dispositions and ratios. The outcomes of the Phase 3 evaluations then can be used to inform subsequent engineering decisions and provide reasonable paths forward to mitigate or overcome real or potential criticality concern in plant operations.

Hanford

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Publisher :
ISBN 13 :
Total Pages : 430 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Hanford by : R. E. Gephart

Download or read book Hanford written by R. E. Gephart and published by . This book was released on 2003 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: In Hanford: A Conversation About Nuclear Waste and Cleanup, Roy Gephart takes us on a journey through a world of facts, values, conflicts, and choices facing the most complex environmental cleanup project in the United States: the U.S. Department of Energy's Hanford Site. Starting with the top-secret Manhattan Project, Hanford was used to create tons of plutonium for nuclear weapons. Hundreds of tons of waste and millions of curies remain. In an easy-to-read, illustrated text, Gephart crafts the story of Hanford becoming the world's first nuclear weapons site to release large amounts of contaminants into the environment. This was at a time when radiation biology was in its infancy, industry practiced unbridled waste dumping, and the public trusted what it was told. Hanford history reveals how little we sometimes understand events when caught inside of them. The plutonium market stalled with the end of the Cold War. Public accountability and environmental compliance ushered in a new cleanup mission. Today, Hanford is driven by remediation choices whose outcomes remain uncertain. It's a story whose epilogue will be written by future generations. This book is an information resource, written for the general reader as well as the technically trained person. It provides an overview of Hanford and cleanup issues facing the nuclear weapons complex. Each chapter is a topical mini-series. It's an idea guide that encourages readers to be informed consumers of Hanford news, and to recognize that knowledge, high ethical standards, and social values are at the heart of coping with nuclear waste. Hanford history is a window into many environmental conflicts facing our nation; it's about building uponsuccess and learning from failure. And therein lies a key lesson: when powerful interests are involved, no generation is above pretense.

Overview of Hanford Site High-level Waste Tank Gas and Vapor Dynamics

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (565 download)

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Book Synopsis Overview of Hanford Site High-level Waste Tank Gas and Vapor Dynamics by : James L. Huckaby

Download or read book Overview of Hanford Site High-level Waste Tank Gas and Vapor Dynamics written by James L. Huckaby and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Nuclear Wastes

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Publisher : National Academies Press
ISBN 13 : 0309052262
Total Pages : 590 pages
Book Rating : 4.3/5 (9 download)

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Book Synopsis Nuclear Wastes by : National Research Council

Download or read book Nuclear Wastes written by National Research Council and published by National Academies Press. This book was released on 1996-02-23 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: Disposal of radioactive waste from nuclear weapons production and power generation has caused public outcry and political consternation. Nuclear Wastes presents a critical review of some waste management and disposal alternatives to the current national policy of direct disposal of light water reactor spent fuel. The book offers clearcut conclusions for what the nation should do today and what solutions should be explored for tomorrow. The committee examines the currently used "once-through" fuel cycle versus different alternatives of separations and transmutation technology systems, by which hazardous radionuclides are converted to nuclides that are either stable or radioactive with short half-lives. The volume provides detailed findings and conclusions about the status and feasibility of plutonium extraction and more advanced separations technologies, as well as three principal transmutation concepts for commercial reactor spent fuel. The book discusses nuclear proliferation; the U.S. nuclear regulatory structure; issues of health, safety and transportation; the proposed sale of electrical energy as a means of paying for the transmutation system; and other key issues.