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Charge Transfer In Chemical Reaction Kinetics
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Book Synopsis Charge Transfer in Chemical Reaction Kinetics by : A. M. Kuznet͡sov (dokt. fiz.-mat. nauk.)
Download or read book Charge Transfer in Chemical Reaction Kinetics written by A. M. Kuznet͡sov (dokt. fiz.-mat. nauk.) and published by EPFL Press. This book was released on 1997-01-01 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Charge Transfer Reactions in Electrochemical and Chemical Processes by : L.I. Krishtalik
Download or read book Charge Transfer Reactions in Electrochemical and Chemical Processes written by L.I. Krishtalik and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 339 pages. Available in PDF, EPUB and Kindle. Book excerpt: The mechanism of an elementary act is undoubtedly one of the most fundamental problems of chemical and, in particular, electro chemical kinetics. Although this problem has fascinated scientists for quite a long time, it was only in the late fifties and early sixties that it began to be actively investigated for charge transfer reactions. Owing to the development of new methods in the analysis of this problem, significant advancements were made in theoretical as well as experimental studies. These investigations showed that the physical mechanism of charge transfer in all processes including heterogeneous electrochemical and homogeneous chemical and bio chemical processes is basically the same. Hence, the results ob tained in the field of electrochemical kinetics are relevant to the understanding of homogeneous chemical reactions as well. This book endeavors to summarize the results of investigations carried out during the last two decades. It is based on the author's monograph "Electrode Reactions: The Mechanism of an Elementary Act" (Nauka, 1979). As compared to the first version, the book has been considerably revised and enlarged not only to include a large body of data published between 1978 and 1982, but also to analyze in detail the links between electrochemical and homogeneous, in particular enzymatic, kinetics. As a result, a new chapter has been added to the book. The change in the title reflects the fact that the material contained in the book is not restricted to an investigation of purely electrochemical problems.
Book Synopsis Charge Transfer in Chemical Reaction Kinetics by : AM. Kuznetsov
Download or read book Charge Transfer in Chemical Reaction Kinetics written by AM. Kuznetsov and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Charge Transfer Processes in Condensed Media by : J. Ulstrup
Download or read book Charge Transfer Processes in Condensed Media written by J. Ulstrup and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 427 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecules in liquid and solid media are exposed to strong inter action forces from the surrounding medium. The formulation of a comprehensive theory of chemical processes in condensed media is consequently an elaborate task involving concepts from several areas of the natural sciences. Within the las~ two and a half decades very notable results towards the formulation of a 'unified' quantum mechanical theory of such processes have in fact been achieved, and by the variety of physical, chemical, and biological processes which can be suitably covered by this framework, the new theory represents an adequate alternative to the transition state theory. The present work has a two-fold purpose. Firstly, to provide a reasonably organized exposition of some basic aspects of these developments. This part emphasizes the fundamental similarities between chemical and other kinds of radiationless processes and includes the derivation of the most important rate expressions without resorting to involved mathematical techniques. The s- ond major purpose is to illustrate the 'unified' character of the rate theory by analysis of a considerable amount of expe- mental data from both 'conventional' kinetics and from such untraditional areas as low-temperature, strongly exothermic, and biological processes. Particular attention is here given to those systems for which a classical description is inadequate, and which provide a diagnostic distinction between several alternative theoretical approaches.
Book Synopsis Electron And Ion Transfer In Condensed Media: Theoretical Physics For Reaction Kinetics by : Alexei A Kornyshev
Download or read book Electron And Ion Transfer In Condensed Media: Theoretical Physics For Reaction Kinetics written by Alexei A Kornyshev and published by World Scientific. This book was released on 1997-07-15 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: An elementary act of charge transfer determines a variety of phenomena in physics, chemistry and biology. The study of charge transfer processes has developed together with general progress in theoretical physics and in fast high resolution spectroscopy, so that research deals now with a broad class of systems, materials and environmental conditions. The specific topics covered are: (1) the environment and reactant-environment interaction at bulk and interfaces; (2) the elementary act of electron and proton transfer; homogeneous and heterogeneous processes; (3) processes of ion and heavy group transfer; ion transport in complex systems; (4) artificially and naturally organized charge transfer in physics, chemistry and biology, technological applications (molecular electronics, sensors, modified electrodes, membrane transport).
Book Synopsis Kinetics of Ion-Molecule Reactions by : Pierre J. Ausloos
Download or read book Kinetics of Ion-Molecule Reactions written by Pierre J. Ausloos and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 507 pages. Available in PDF, EPUB and Kindle. Book excerpt: The investigation of the elementary reactions of reactive intermediate species began about half a centruy ago with the advent of free radical kinetics as an active area of chemical research. In spite of the relatively greater ease of detection of a species carrying an electrical charge, and the fact that organic chemists had for decades postulated mechanisms involving ionic intermediates, the systematic study of the elementary reactions of ions was delayed for more than twenty years after the first beginnings of free radical kinetics. Even at this writing, in 1978, the word "kinetics" is considered by many chemists to be synomomous with "kinetics of neutral species". Yet in spite of the relatively late start and separation from the mainstream of kinetics, the field of ion physics and chemistry is fluorishing, and growing at an ever faster pace. Instrumentalists devise ever more sophisticated apparatuses with capabilities of delving into nearly every aspect of the interactions between ions and molecules. Even satellites orbiting the earth are now being used effectively to determine rate coefficients of ionospheric ion-neutral reactions, some of which can not as yet be measured in the laboratory.
Book Synopsis Electrochemical Kinetics by : Klaus J. Vetter
Download or read book Electrochemical Kinetics written by Klaus J. Vetter and published by Elsevier. This book was released on 2013-10-22 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemical Kinetics: Theoretical Aspects focuses on the processes, methodologies, reactions, and transformations in electrochemical kinetics. The book first offers information on electrochemical thermodynamics and the theory of overvoltage. Topics include equilibrium potentials, concepts and definitions, electrical double layer and electrocapillarity, and charge-transfer, diffusion, and reaction overvoltage. Crystallization overvoltage, total overvoltage, and resistance polarization are also discussed. The text then examines the methods of determining electrochemical reaction mechanisms, including examination of the overall electrode reaction and determination of the type of overvoltage and reaction kinetics. A list of frequently used symbols is also provided. The book is a valuable reference for readers interested in the study of electrochemical kinetics.
Book Synopsis Charge Transfer in Physics, Chemistry and Biology by : A.M. Kuznetrsov
Download or read book Charge Transfer in Physics, Chemistry and Biology written by A.M. Kuznetrsov and published by CRC Press. This book was released on 2020-09-23 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the various processes of charge transfer in physics, chemistry and biology and shows the similarities and differences between them. It focuses on the physical mechanisms of the elementary processes to demonstrate their common physical nature.
Book Synopsis Progress in Reaction Kinetics by : K. R. Jennings
Download or read book Progress in Reaction Kinetics written by K. R. Jennings and published by Elsevier. This book was released on 2013-09-03 with total page 391 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in Reaction Kinetics, Volume 9 summarizes recent advances that have been made with regards to reaction kinetics. Kinetic applications of nuclear magnetic resonance spectroscopy are described, and tunneling reactions of solvated electrons in liquids and glasses are discussed. The reactions of free radicals generated by organic compounds are also considered. This volume consists of three chapters and begins with a discussion of basic NMR theory, including the NMR phenomenon and nuclear spin relaxation processes. Special attention is paid to the dynamic characteristics of chemical exchange reactions which occur in a system at equilibrium, along with techniques for determining chemical exchange parameters from time domain spectra and time dependent frequency domain spectra. The reader is then introduced to tunneling reactions of solvated electrons in liquids and glasses, with emphasis on the mode of transport by which the electron induces such a reaction. A model of diffusion-controlled reactions incorporating a tunneling reaction mechanism is described. A chapter analyzing the use of radiation to produce reactions of free radicals from organic compounds in aqueous solution, including hydrocarbons and carbonyl compounds, concludes the book. This book will be of interest to scientists, students, and researchers working in the fields of chemistry and the molecular sciences.
Book Synopsis Electrode Kinetics: Principles and Methodology by : C.H. Bamford
Download or read book Electrode Kinetics: Principles and Methodology written by C.H. Bamford and published by Elsevier. This book was released on 1986-08-01 with total page 469 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volumes 26 and 27 are both concerned with reactions occurring at electrodes arising through the passage of current. They provide a comprehensive review of the study of electrode kinetics. The basic ideas and experimental methodology are presented in Volume 26 whilst Volume 27 deals with reactions at particular types of electrodes.Chapter 1 serves as an introduction to both volumes and is a survey of the fundamental principles of electrode kinetics. Chapter 2 deals with mass transport - how material gets to and from an electrode. Chapter 3 provides a review of linear sweep and cyclic voltammetry which constitutes an extensively used experimental technique in the field. Chapter 4 discusses a.c. and pulse methods which are a rich source of electrochemical information. Finally, chapter 5 discusses the use of electrodes in which there is forced convection, the so-called ``hydrodynamic electrodes''.
Book Synopsis Comprehensive Chemical Kinetics by : C. H. Bamford
Download or read book Comprehensive Chemical Kinetics written by C. H. Bamford and published by . This book was released on 1969 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Electrochemical Study of the Kinetics of a Chemical Reaction Coupled Between Two Charge Transfer Reactions by : Gene Stoddard Alberts
Download or read book Electrochemical Study of the Kinetics of a Chemical Reaction Coupled Between Two Charge Transfer Reactions written by Gene Stoddard Alberts and published by . This book was released on 1963 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Advanced Chemical Kinetics by : Muhammad Akhyar Farrukh
Download or read book Advanced Chemical Kinetics written by Muhammad Akhyar Farrukh and published by BoD – Books on Demand. This book was released on 2018-02-21 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book on Advanced Chemical Kinetics gives insight into different aspects of chemical reactions both at the bulk and nanoscale level and covers topics from basic to high class. This book has been divided into three sections: (i) "Kinetics Modeling and Mechanism," (ii) "Kinetics of Nanomaterials," and (iii) "Kinetics Techniques." The first section consists of six chapters with a variety of topics like activation energy and complexity of chemical reactions; the measurement of reaction routes; mathematical modeling analysis and simulation of enzyme kinetics; mechanisms of homogeneous charge compression ignition combustion for the fuels; photophysical processes and photochemical changes; the mechanism of hydroxyl radical, hydrate electron, and hydrogen atom; and acceptorless alcohol dehydrogenation. The understanding of the kinetics of nanomaterials, to bridge the knowledge gap, is presented in the second section. The third section highlights an overview of experimental techniques used to study the mechanism of reactions.
Book Synopsis Applications of Kinetic Modelling by : G. Hancock
Download or read book Applications of Kinetic Modelling written by G. Hancock and published by Elsevier. This book was released on 1999-05-07 with total page 737 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 37 is concerned with the use and role of modelling in chemical kinetics and seeks to show the interplay of theory or simulation with experiment in a diversity of physico-chemical areas in which kinetics measurements provide significant physical insight. Areas of application covered within the volume include electro- and interfacial chemistry, physiology, biochemistry, solid state chemistry and chemical engineering. A leading contributor to this general area has been Professor W. John Albery, FRS, to whom the contributors and editors dedicate this book.
Book Synopsis Beyond Born-Oppenheimer by : Michael Baer
Download or read book Beyond Born-Oppenheimer written by Michael Baer and published by John Wiley & Sons. This book was released on 2006-03-31 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: INTRODUCING A POWERFUL APPROACH TO DEVELOPING RELIABLE QUANTUM MECHANICAL TREATMENTS OF A LARGE VARIETY OF PROCESSES IN MOLECULAR SYSTEMS. The Born-Oppenheimer approximation has been fundamental to calculation in molecular spectroscopy and molecular dynamics since the early days of quantum mechanics. This is despite well-established fact that it is often not valid due to conical intersections that give rise to strong nonadiabatic effects caused by singular nonadiabatic coupling terms (NACTs). In Beyond Born-Oppenheimer, Michael Baer, a leading authority on molecular scattering theory and electronic nonadiabatic processes, addresses this deficiency and introduces a rigorous approach--diabatization--for eliminating troublesome NACTs and deriving well-converged equations to treat the interactions within and between molecules. Concentrating on both the practical and theoretical aspects of electronic nonadiabatic transitions in molecules, Professor Baer uses a simple mathematical language to rigorously eliminate the singular NACTs and enable reliable calculations of spectroscopic and dynamical cross sections. He presents models of varying complexity to illustrate the validity of the theory and explores the significance of the study of NACTs and the relationship between molecular physics and other fields in physics, particularly electrodynamics. The first book of its king Beyond Born-Oppenheimer: * Presents a detailed mathematical framework to treat electronic NACTs and their conical intersections * Describes the Born-Oppenheimer treatment, including the concepts of adiabatic and diabatic frameworks * Introduces a field-theoretical approach to calculating NACTs, which offers an alternative to time-consuming ab initio procedures * Discusses various approximations for treating a large system of diabatic Schrödinger equations * Presents numerous exercises with solutions to further clarify the material being discussed Beyond Born-Oppenheimer is required reading for physicists, physical chemists, and all researchers involved in the quantum mechanical study of molecular systems.
Book Synopsis Electrode Kinetics for Chemists, Chemical Engineers, and Materials Scientists by : Eliezer Gileadi
Download or read book Electrode Kinetics for Chemists, Chemical Engineers, and Materials Scientists written by Eliezer Gileadi and published by Capstone. This book was released on 1993 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offering a thorough explanation of electrode kinetics, this textbook emphasizes physical phenomena - rather than mathematical formalism - and elucidates the underlying principles of the different experimental techniques. Assuming an elementary knowledge of thermodynamics and chemical kinetics and minimal mathematical skills, coverage explores the arguments of two primary schools of thought: electrode kinetics and interfacial electrochemistry viewed as a branch of physical chemistry and from the perspective of analytical chemistry.
Book Synopsis Chemical Kinetics: Fundamentals and Recent Developments by : Evgeny Denisov
Download or read book Chemical Kinetics: Fundamentals and Recent Developments written by Evgeny Denisov and published by Elsevier. This book was released on 2003-05-23 with total page 567 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive manual embracing essentially all the classical and modern areas of chemical kinetics. Provides details of modern applications in chemistry, technology and biochemistry.Special sections of the book treat subjects not covered sufficiently in other manuals, including: modern methods of experimental determination of rate constants of reactions including laser pico- and femtochemistry, magnetochemistry, and ESR; and descriptions of advanced theories of elementary chemical processes.- Comprehensive manual covering practically all areas of chemical kinetics, both classical and modern. - Adequate coverage given to topics not covered sufficiently by other works. - Covers fundamentals and recent developments in homogeneous catalysis and its modeling from a chemical kinetics perspective.
