Characterization of Solid Acid Catalysts for Isobutane/butene Alkylation

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (566 download)

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Book Synopsis Characterization of Solid Acid Catalysts for Isobutane/butene Alkylation by : Alexandru Platon

Download or read book Characterization of Solid Acid Catalysts for Isobutane/butene Alkylation written by Alexandru Platon and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Alkylation of Isobutane with N-butene Over Solid Catalysts

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ISBN 13 :
Total Pages : 201 pages
Book Rating : 4.:/5 (258 download)

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Book Synopsis Alkylation of Isobutane with N-butene Over Solid Catalysts by : Chin-Huang Liang

Download or read book Alkylation of Isobutane with N-butene Over Solid Catalysts written by Chin-Huang Liang and published by . This book was released on 1993 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Supercritical Alkylation of Isobutane with 1-butene Using Solid Acid Catalysts

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (594 download)

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Book Synopsis Supercritical Alkylation of Isobutane with 1-butene Using Solid Acid Catalysts by : Iain Hunter Stewart

Download or read book Supercritical Alkylation of Isobutane with 1-butene Using Solid Acid Catalysts written by Iain Hunter Stewart and published by . This book was released on 1999 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Study of the Supercritical Alkylation Reaction of Isobutane with 1-butene on an Solid Acid Catalyst

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Publisher :
ISBN 13 : 9780599738003
Total Pages : 193 pages
Book Rating : 4.7/5 (38 download)

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Book Synopsis Study of the Supercritical Alkylation Reaction of Isobutane with 1-butene on an Solid Acid Catalyst by : Gabriel Mauricio Santana Castro

Download or read book Study of the Supercritical Alkylation Reaction of Isobutane with 1-butene on an Solid Acid Catalyst written by Gabriel Mauricio Santana Castro and published by . This book was released on 2000 with total page 193 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Alkylation of Isobutane with Light Olefins Using Mesoporous Superacidic Catalysts

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (13 download)

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Book Synopsis Alkylation of Isobutane with Light Olefins Using Mesoporous Superacidic Catalysts by : Philip Kletnieks

Download or read book Alkylation of Isobutane with Light Olefins Using Mesoporous Superacidic Catalysts written by Philip Kletnieks and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

New Chemistry with Solid-acid Catalysts in the Alkylation of Isobutane with Olefins

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (78 download)

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Book Synopsis New Chemistry with Solid-acid Catalysts in the Alkylation of Isobutane with Olefins by : American Chemical Society. Division of Petroleum Chemistry

Download or read book New Chemistry with Solid-acid Catalysts in the Alkylation of Isobutane with Olefins written by American Chemical Society. Division of Petroleum Chemistry and published by . This book was released on 1996 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Preparation, Characterization and Catalytic Activity of a New Sold Acid Catalyst System

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Publisher :
ISBN 13 : 9780530005058
Total Pages : 222 pages
Book Rating : 4.0/5 (5 download)

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Book Synopsis The Preparation, Characterization and Catalytic Activity of a New Sold Acid Catalyst System by : Cindy Getty

Download or read book The Preparation, Characterization and Catalytic Activity of a New Sold Acid Catalyst System written by Cindy Getty and published by . This book was released on 2019-05-31 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: The preparation and use of solid strong acid catalysts and superacids are active areas of research. Solid acids and superacids are reported to exhibit extremely high catalytic activities for reactions such as isomerization, cracking, hydrocracking, dehydration, alkylation, acylation, conversion of methanol to gasoline, and so forth. Recent research in this area has focused on the preparation of stronger solid acids and their characterization. Advantages of solid acid catalysts over liquid acid catalysts include ease of separation from reaction mixture and high selectivity or specific activity. A series of novel solid strong acids has been prepared by treatment of inorganic oxides by Lewis acids. The method of creating or enhancing the number of tetrahedral aluminum centers on inorganic oxides has led to a series of novel solid acid catalysts which displays an increased acidity over the supports alone. Investigations of acid sites by the infrared spectroscopy of adsorbed pyridine, calorimetric titrations and solid-state nuclear magnetic resonance on a series of new solid acid catalysts will be discussed. This new solid acid catalyst system exhibits high catalytic activity and selectivity for cracking reactions under relatively mild conditions. In addition to the reactions of hydrocarbons, the reactions of various polychlorinated molecules have been studied. Dissertation Discovery Company and University of Florida are dedicated to making scholarly works more discoverable and accessible throughout the world. This dissertation, "The Preparation, Characterization and Catalytic Activity of a New Sold Acid Catalyst System" by Cindy S. Getty, was obtained from University of Florida and is being sold with permission from the author. A digital copy of this work may also be found in the university's institutional repository, IR@UF. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation.

Solid Superacids

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ISBN 13 : 9781612096490
Total Pages : 0 pages
Book Rating : 4.0/5 (964 download)

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Book Synopsis Solid Superacids by : Kazushi Arata

Download or read book Solid Superacids written by Kazushi Arata and published by . This book was released on 2011 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: An acid that is stronger than the acid strength of 100% sulphuric acid is known as a superacid. Environmental concerns about the use of toxic liquid superacids and liquid inorganic acids in the transformation of hydrocarbons provide an impetus for a search of stable and more environmentally friendly solid acid catalysts. This book examines an important opportunity related to green chemistry where solid superacids lead to new gas- and liquid-solid phase reactions, which are environmentally benign processes in the chemical industry.

Single Event Kinetic Modeling of Solid Acid Alkylation of Isobutane with Butenes Over Proton-exchanged Y-Zeolites

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ISBN 13 :
Total Pages : pages
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Book Synopsis Single Event Kinetic Modeling of Solid Acid Alkylation of Isobutane with Butenes Over Proton-exchanged Y-Zeolites by : Jorge Maximiliano Martinis Coll

Download or read book Single Event Kinetic Modeling of Solid Acid Alkylation of Isobutane with Butenes Over Proton-exchanged Y-Zeolites written by Jorge Maximiliano Martinis Coll and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Complex reaction kinetics of the solid acid alkylation of isobutane with butenes over a proton exchanged Y-zeolite has been modeled at the elementary step level. Starting with a computer algorithm that generated the reaction network based on the fundamentals of the carbenium ion chemistry, the formation of over 100+ product species has been modeled in order to gain understanding of the underlying phenomena leading to rapid catalyst deactivation and product selectivity shifts observed in experimental runs. An experimental investigation of the solid acid alkylation process was carried out in a fixed bed catalytic reactor operating with an excess of isobutane under isothermal conditions at moderate temperatures (353-393 K) in liquid phase. Experimental data varying with run-time for a set of butene space-times and reaction temperatures were collected for parameter estimation purposes. A kinetic model was formulated in terms of rate expressions at the elementary step level including a rigorous modeling of deactivation through site coverage. The single event concept was applied to each rate coefficient at the elementary step level to achieve a significant reduction in the number of model parameters. Based on the identification of structural changes leading to the creation or destruction of symmetry axes and chiral centers in an elementary step, formulae have been developed for the calculation of the number of single events. The Evans-Polanyi relationship and the concept of stabilization energy were introduced to account for energy levels in surface-bonded carbenium ions. A novel functional dependency of the stabilization energy with the nature of the carbenium ion and the carbon number was proposed to account for energy effects from the acid sites on the catalyst. Further reductions in the number of parameters and simplification of the equations for the transient pseudohomogeneous one-dimensional plug-flow model of the reactor were achieved by means of thermodynamic constraints. Altogether, the single event concept, the Evans-Polanyi relationship, the stabilization energy approach and the thermodynamic constraints led to a set of 14 parameters necessary for a complete description of solid acid alkylation at the elementary step level.

Characterization of Solid Materials and Heterogeneous Catalysts, 2 Volume Set

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Publisher : John Wiley & Sons
ISBN 13 : 3527326871
Total Pages : 1313 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Characterization of Solid Materials and Heterogeneous Catalysts, 2 Volume Set by : Michel Che

Download or read book Characterization of Solid Materials and Heterogeneous Catalysts, 2 Volume Set written by Michel Che and published by John Wiley & Sons. This book was released on 2012-05-14 with total page 1313 pages. Available in PDF, EPUB and Kindle. Book excerpt: This two-volume book provides an overview of physical techniques used to characterize the structure of solid materials, on the one hand, and to investigate the reactivity of their surface, on the other. Therefore this book is a must-have for anyone working in fields related to surface reactivity. Among the latter, and because of its most important industrial impact, catalysis has been used as the directing thread of the book. After the preface and a general introduction to physical techniques by M. Che and J.C. Vedrine, two overviews on physical techniques are presented by G. Ertl and Sir J.M. Thomas for investigating model catalysts and porous catalysts, respectively. The book is organized into four parts: Molecular/Local Spectroscopies, Macroscopic Techniques, Characterization of the Fluid Phase (Gas and/ or Liquid), and Advanced Characterization. Each chapter focuses upon the following important themes: overview of the technique, most important parameters to interpret the experimental data, practical details, applications of the technique, particularly during chemical processes, with its advantages and disadvantages, conclusions.

Butane and Butene Isomerization Over Solid Acid Catalysts

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ISBN 13 :
Total Pages : 514 pages
Book Rating : 4.:/5 (89 download)

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Book Synopsis Butane and Butene Isomerization Over Solid Acid Catalysts by : Kevin Boyle Fogash

Download or read book Butane and Butene Isomerization Over Solid Acid Catalysts written by Kevin Boyle Fogash and published by . This book was released on 1997 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt:

New Chemistry with Solid-acid Catalysts in the Alkylation of Isobutane with Olefins

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (841 download)

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Book Synopsis New Chemistry with Solid-acid Catalysts in the Alkylation of Isobutane with Olefins by : H.J. Lovink

Download or read book New Chemistry with Solid-acid Catalysts in the Alkylation of Isobutane with Olefins written by H.J. Lovink and published by . This book was released on 1996 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Characterization of Solid Acid Catalysts

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ISBN 13 :
Total Pages : 162 pages
Book Rating : 4.:/5 (436 download)

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Book Synopsis The Characterization of Solid Acid Catalysts by : Yun You

Download or read book The Characterization of Solid Acid Catalysts written by Yun You and published by . This book was released on 1999 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Supercritical Alkylation of Isobutane with 1-butene Using Solic Acid Catalysts

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (535 download)

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Book Synopsis Supercritical Alkylation of Isobutane with 1-butene Using Solic Acid Catalysts by : Iain Hunter Stewart

Download or read book Supercritical Alkylation of Isobutane with 1-butene Using Solic Acid Catalysts written by Iain Hunter Stewart and published by . This book was released on 1999 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Simulation and Optimization of Fixed Bed Solid Acid Catalyzed Isobutane/2-butene Alkylation Process

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (15 download)

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Book Synopsis Simulation and Optimization of Fixed Bed Solid Acid Catalyzed Isobutane/2-butene Alkylation Process by :

Download or read book Simulation and Optimization of Fixed Bed Solid Acid Catalyzed Isobutane/2-butene Alkylation Process written by and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Solid Acid Catalysts

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ISBN 13 :
Total Pages : 310 pages
Book Rating : 4.:/5 (366 download)

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Book Synopsis Solid Acid Catalysts by : Nicholas E. Kob

Download or read book Solid Acid Catalysts written by Nicholas E. Kob and published by . This book was released on 1996 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Acid-Base Catalysis II

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Publisher : Elsevier
ISBN 13 : 008088752X
Total Pages : 593 pages
Book Rating : 4.0/5 (88 download)

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Book Synopsis Acid-Base Catalysis II by : H. Hattori

Download or read book Acid-Base Catalysis II written by H. Hattori and published by Elsevier. This book was released on 1994-11-01 with total page 593 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solid acid catalysts are already being used in various processes in petroleum refining and are presently being studied intensively in both academic and applied fields for usage in a variety of reactions. Solid base catalysts are also gaining increasing recognition as potential catalysts. Both acidic and basic catalysts are promising not only with respect to acid and base-catalyzed reactions but also in materials sciences, such as the production of adsorbents, sensors, ceramics, etc. The present volume presents the text of 21 invited oral presentations and 58 poster presentations. The material covers a wide range of aspects on acid-base catalysis, from quantum chemistry to industrialized processes.