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Author : Richard French
Publisher :
ISBN 13 :
Total Pages : 26 pages
Book Rating : 4.:/5 (119 download)
Download or read book Catalytic Upgrading of Pyrolysis Vapors at Bench Scale with Pt/Tio2 written by Richard French and published by . This book was released on 2019 with total page 26 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (14 download)
Download or read book Catalytic Upgrading of Biomass Pyrolysis Vapors at Bench Scale with Pt/TiO2 written by and published by . This book was released on 2018 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vapor phase upgrading can produce a liquid of lower oxygen and higher energy density than can fast pyrolysis alone. Therefore, it is anticipated that catalytic pyrolysis followed by a single stage of hydrotreating will be a more cost-effective route to hydrocarbon fuels than fast pyrolysis with multiple-stage or more-severe hydrotreating. To this end, a bench-scale bubbling fluidized bed pyrolyzer was operated at 150 g/h feed rate of pine flour with a 100 g fixed-bed catalytic upgrader. A 0.5% Pt/TiO2 catalyst produced a lower oxygen (
Author : Richard French
Publisher :
ISBN 13 :
Total Pages : 26 pages
Book Rating : 4.:/5 (119 download)
Download or read book Catalytic Upgrading of Biomass Pyrolysis Vapors at Bench Scale with Platinum on Titania written by Richard French and published by . This book was released on 2019 with total page 26 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Anju Dahiya
Publisher : Academic Press
ISBN 13 : 0128154985
Total Pages : 892 pages
Book Rating : 4.1/5 (281 download)
Download or read book Bioenergy written by Anju Dahiya and published by Academic Press. This book was released on 2020-04-09 with total page 892 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioenergy: Biomass to Biofuels and Waste to Energy, Second Edition presents a complete overview of the bioenergy value chain, from feedstock to end products. It examines current and emerging feedstocks and advanced processes and technologies enabling the development of all possible alternative energy sources. Divided into seven parts, bioenergy gives thorough consideration to topics such as feedstocks, biomass production and utilization, life-cycle analysis, energy return on invested, integrated sustainability assessments, conversions technologies, biofuels economics, business, and policy. In addition, contributions from leading industry professionals and academics, augmented by related service-learning case studies and quizzes, provide readers with a comprehensive resource that connect theory to real-world implementation.Bioenergy: Biomass to Biofuels and Waste to Energy, Second Edition provides engineers, researchers, undergraduate and graduate students, and business professionals in the bioenergy field with valuable, practical information that can be applied to implementing renewable energy projects, choosing among competing feedstocks, technologies, and products. It also serves as a basic resource for civic leaders, economic development professionals, farmers, investors, fleet managers, and reporters interested in an organized introduction to the language, feedstocks, technologies, and products in the biobased renewable energy world. - Includes current and renewed subject matter, project case studies from real world, and topic-specific sections on the impacts of biomass use for energy production from all sorts of biomass feedstocks including organic waste of all kinds - Provides a comprehensive overview and in-depth technical information of all possible bioenergy resources: solid (wood energy, grass energy, waste, and other biomass), liquid (biodiesel, algae biofuel, ethanol, waste to oils, etc.), and gaseous/electric (biogas, syngas, biopower, RNG), and cutting-edge topics such as advanced fuels - Integrates current state of art coverage on feedstocks, cost-effective conversion processes, biofuels economic analysis, environmental policy, and triple bottom line - Features quizzes for each section derived from the implementation of actual hands-on biofuel projects as part of service learning
Author :
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (14 download)
Download or read book Ex Situ Catalytic Fast Pyrolysis of Lignocellulosic Biomass to Hydrocarbon Fuels: 2020 State of Technology written by and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomass catalytic fast pyrolysis (CFP) research was funded by the Bioenergy Technologies Office (BETO) of the U.S. Department of Energy (DOE) to enable technical breakthroughs to help reduce the cost of conversion of biomass to liquid hydrocarbon fuels. The key goals were to achieve a mature plant modeled Minimum Fuel Selling Price of $3/GGE, with greater than 60% greenhouse gas (GHG) reduction over petroleum derived gasoline by 2022. Experimental results at NREL and PNNL, along with lifecycle analysis by ANL show that we achieved these goals based on performance at the bench scale. A Pt/TiO2 catalyst was used in a fixed bed reactor for upgrading pyrolysis vapors from an upstream fast pyrolysis reactor (ex-situ configuration) to produce CFP oil with 16.5% oxygen content. Subsequent co-hydrotreating of 10 vol% of CFP oil with 90 vol% straight run diesel (SRD) at the bench scale yielded greater than 95% carbon efficiency for the CFP oil portion of the feed. Light oxygenated coproducts were recovered from the off gases from the CFP process via adsorption and subsequent desorption. Aspen Plus modeling of purification of the desorbed stream using the UNIFAC property method showed that acetone and methyl-ethyl-ketone can be purified to chemicals grade and sold as coproducts to benefit the economics and reduce GHG emissions attributed to the fuel product. Some of the key risks and uncertainties associated with this process, and potential future work are mentioned in this report.
Author : Michael Griffin (Chemical engineer)
Publisher :
ISBN 13 :
Total Pages : 48 pages
Book Rating : 4.:/5 (131 download)
Download or read book Advancing Catalytic Fast Pyrolysis Through Integrated Experimentation and Multi-scale Computational Modeling written by Michael Griffin (Chemical engineer) and published by . This book was released on 2021 with total page 48 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Zhen Fang
Publisher : Springer Nature
ISBN 13 : 9811527326
Total Pages : 456 pages
Book Rating : 4.8/5 (115 download)
Download or read book Production of Biofuels and Chemicals with Pyrolysis written by Zhen Fang and published by Springer Nature. This book was released on 2020-10-27 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a collection of studies on state-of-art techniques for converting biomass to chemical products by means of pyrolysis, which are widely applicable to the valorization of biomass. In addition to discussing the fundamentals and mechanisms for producing bio-oils, chemicals, gases and biochar using pyrolysis, it outlines key reaction parameters and reactor configurations for various types of biomass. Written by leading experts and providing a broad range of perspectives on cutting-edge applications, the book is a comprehensive reference guide for academic researchers and industrial engineers in the fields of natural renewable materials, biorefinery of lignocellulose, biofuels, and environmental engineering, and a valuable resource for university students in the fields of chemical engineering, material science and environmental engineering.
Download or read book In-situ Catalytic Upgrading of Pyrolysis Vapor written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The rising fuel prices, environmental concerns over the emission of greenhouse gases, and the limited availability of fossil fuels led to the current focus on developing alternative fuel sources that are sustainable and environmentally benign. Lignocellulosic biomass, due to its high carbon value, abundance and for being greenhouse gas neutral, is a promising alternative energy resource. Fast pyrolysis of lignocellulosic biomass produces high energy density liquid fuel, called bio-oil, which has the potential as transportation fuel. But, crude bio-oils are chemically complex liquids with high oxygen contents (40 % oxygen content), high viscosity, low pH, low thermal stability, and poor heating values (20 MJ/Kg). Therefore, bio-oils must be substantially upgraded (de-oxygenated) to highly stable, non-corrosive, and high calorific value liquid fuels prior to their use as transportation fuels. This research was conducted to investigate the efficiency of various acid catalysts in upgrading (cracking) the oxygenated pine wood pyrolysis vapors to high quality liquid fuel. Initial catalyst screening studies proved that zeolite acidity and pore structure is essential for effective cracking of pyrolysis vapors. Low space velocities and moderate temperatures were found to be favorable for the deoxygenation of pyrolysis vapors. Various zeolites were tested, of which HZSM-5 with low Si/Al ratio was found to be an effective cracking catalyst. But the use of zeolites resulted in poor liquid yields. Zeolites were promoted with transition metal ions in order to inhibit the secondary cracking reactions occurring on Brönsted acid sites. The meta--promoted bi-functional catalysts were found to be the most effective catalysts, among all the catalysts employed in this research, in promoting hydrocarbon forming reactions without adversely affecting the liquid yields. Catalyst coking was unavoidable but the addition of metal ions to zeolites lowered the extent of coking. TG analysis of used catalysts indicated that the catalysts can be regenerated by calcining at 600-650 °C.
Author : Pranjali Devidas Muley
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (14 download)
Download or read book Thermo-catalytic Upgrading of Pyrolysis Vapors Using Electromagnetic Heating written by Pranjali Devidas Muley and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Robert C. Brown
Publisher : John Wiley & Sons
ISBN 13 : 1119417570
Total Pages : 426 pages
Book Rating : 4.1/5 (194 download)
Download or read book Thermochemical Processing of Biomass written by Robert C. Brown and published by John Wiley & Sons. This book was released on 2019-05-28 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive examination of the large number of possible pathways for converting biomass into fuels and power through thermochemical processes Bringing together a widely scattered body of information into a single volume, this book provides complete coverage of the many ways that thermochemical processes are used to transform biomass into fuels, chemicals and power. Fully revised and updated, this new edition highlights the substantial progress and recent developments that have been made in this rapidly growing field since publication of the first edition and incorporates up-to-date information in each chapter. Thermochemical Processing of Biomass: Conversion into Fuels, Chemicals and Power, 2nd Edition incorporates two new chapters covering: condensed phased reactions of thermal deconstruction of biomass and life cycle analysis of thermochemical processing systems. It offers a new introductory chapter that provides a more comprehensive overview of thermochemical technologies. The book also features fresh perspectives from new authors covering such evolving areas as solvent liquefaction and hybrid processing. Other chapters cover combustion, gasification, fast pyrolysis, upgrading of syngas and bio-oil to liquid transportation fuels, and the economics of thermochemically producing fuels and power, and more. Features contributions by a distinguished group of European and American researchers offering a broad and unified description of thermochemical processing options for biomass Combines an overview of the current status of thermochemical biomass conversion as well as engineering aspects to appeal to the broadest audience Edited by one of Biofuels Digest’s "Top 100 People" in bioenergy for six consecutive years Thermochemical Processing of Biomass: Conversion into Fuels, Chemicals and Power, 2nd Edition will appeal to all academic researchers, process chemists, and engineers working in the field of biomass conversion to fuels and chemicals. It is also an excellent book for graduate and advanced undergraduate students studying biomass, biofuels, renewable resources, and energy and power generation.
Author : Jyoti Gupta
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (119 download)
Download or read book Catalytic Upgrading of Biomass Fast Pyrolysis Vapours written by Jyoti Gupta and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Robert C Brown
Publisher : Royal Society of Chemistry
ISBN 13 : 1782626182
Total Pages : 291 pages
Book Rating : 4.7/5 (826 download)
Download or read book Fast Pyrolysis of Biomass written by Robert C Brown and published by Royal Society of Chemistry. This book was released on 2017-07-07 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fast pyrolysis and related catalytic pyrolysis are of increasing interest as pathways to advanced biofuels that closely mimic traditional petroleum products. Research has moved from empirical investigations to more fundamental studies of pyrolysis mechanisms. Theories on the chemical and physical pathways from plant polymers to pyrolysis products have proliferated as a result. This book brings together the latest developments in pyrolysis science and technology. It examines, reviews and challenges the unresolved and sometimes controversial questions about pyrolysis, helping advance the understanding of this important technology and stimulating discussion on the various competing theories of thermal deconstruction of plant polymers. Beginning with an introduction to the biomass-to-biofuels process via fast pyrolysis and catalytic pyrolysis, chapters address prominent questions such as whether free radicals or concerted reactions dominate deconstruction reactions. Finally, the book concludes with an economic analysis of fast pyrolysis versus catalytic pyrolysis. This book will be of interest to advanced students and researchers interested in the science behind renewable fuel technology, and particularly the thermochemical processing of biomass.
Author : Dominic C. Y. Foo
Publisher : John Wiley & Sons
ISBN 13 : 3527818723
Total Pages : 344 pages
Book Rating : 4.5/5 (278 download)
Download or read book Process Intensification and Integration for Sustainable Design written by Dominic C. Y. Foo and published by John Wiley & Sons. This book was released on 2020-12-01 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents comprehensive coverage of process intensification and integration for sustainable design, along with fundamental techniques and experiences from the industry Drawing from fundamental techniques and recent industrial experiences, this book discusses the many developments in process intensification and integration and focuses on increasing sustainability via several overarching topics such as Sustainable Manufacturing, Energy Saving Technologies, and Resource Conservation and Pollution Prevention Techniques. Process Intensification and Integration for Sustainable Design starts discussions on: shale gas as an option for the production of chemicals and challenges for process intensification; the design and techno-economic analysis of separation units to handle feedstock variability in shale gas treatment; RO-PRO desalination; and techno-economic and environmental assessment of ultrathin polysulfone membranes for oxygen-enriched combustion. Next, it looks at process intensification of membrane-based systems for water, energy, and environment applications; the design of internally heat-integrated distillation column (HIDiC); and graphical analysis and integration of heat exchanger networks with heat pumps. Decomposition and implementation of large-scale interplant heat integration is covered, as is the synthesis of combined heat and mass exchange networks (CHAMENs) with renewables. The book also covers optimization strategies for integrating and intensifying housing complexes; a sustainable biomass conversion process assessment; and more. Covers the many advances and changes in process intensification and integration Provides side-by-side discussions of fundamental techniques and recent industrial experiences to guide practitioners in their own processes Presents comprehensive coverage of topics relevant, among others, to the process industry, biorefineries, and plant energy management Offers insightful analysis and integration of reactor and heat exchanger network Looks at optimization of integrated water and multi-regenerator membrane systems involving multi-contaminants Process Intensification and Integration for Sustainable Design is an ideal book for process engineers, chemical engineers, engineering scientists, engineering consultants, and chemists.
Author : Tyler Steven Vann
Publisher :
ISBN 13 :
Total Pages : 366 pages
Book Rating : 4.:/5 (973 download)
Download or read book Strategies for Catalytic Upgrading of Vapor Streams from Thermal Fractionation of Biomass written by Tyler Steven Vann and published by . This book was released on 2016 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (14 download)
Download or read book Pyrolysis Vapor and Bio-Oil Preconditioning via Ex Situ Hydrodeoxygenation and Alkylation Using a Heteropolyacid Catalyst written by and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ex situ catalytic preconditioning of biomass pyrolysis vapors (partial deoxygenation) has the potential for both reducing the oxygen content and beneficially influencing the oxygen speciation of condense bio-oils for enhancement of downstream condensed phase upgrading processes. Here, condensed phase upgrading processes may refer to both coprocessing and hydroprocessing with vacuum gas-oil (VGO). Reduction of oxygen content to produce bio-oils with greater hydrophobicity can enhance VGO-solubility while tailoring of oxygen speciation by removal of reactive carbonyls (e.g., acetic acid) can lessen catalytic deactivation via coking reactions. 1,2 Furthermore, enhanced VGO-solubility and reduced coking leads to greater biogenic carbon incorporation in end-products from condensed phase upgrading processes. By leveraging the hydrodeoxygenation and alkylation activity of a titania-supported molybdenum-heteropolyacid (Mo-HPA/TiO2) catalyst, pyrolysis vapors and resulting condensed bio-oils were effectively preconditioned for downstream upgrading. 3 Data regarding the use of Mo-HPA/TiO2 for pyrolysis vapor preconditioning will be presented on, including method of employment, catalyst characterization, and impacts on bio-oil in relation to downstream condensed phase upgrading processes. Our approach is to: Compare Mo-HPA/TiO2 product distribution to HZSM-5; Investigate Mo-HPA/TiO2 regeneration and characterize changes in acid site character; Assess product differences in terms of enhanced VGO-solubility.
Author : Caroline Carriel Schmitt
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (122 download)
Download or read book Catalytic Upgrading of Fast Pyrolysis Bio-oils Applying Nickel-based Catalysts written by Caroline Carriel Schmitt and published by . This book was released on 2021* with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (14 download)
Download or read book The Development of Catalysts for Upgrading of Pyrolysis Vapor for Refinery Feedstocks and Intermediates: Cooperative Research and Development Final Report, CRADA Number CRD-12-00497 written by and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fast pyrolysis of biomass with vapor phase upgrading (VPU) can produce refinery feedstocks or intermediates that can meet the Department of Energy's goal of cost-competitive hydrocarbon fuels by 2017. A key technical barrier for this technology is the lack of selective, cost effective catalysts that can produce high yields of fuel-appropriate hydrocarbons from the pyrolysis vapors. In overcoming this barrier, it will be important to engage leading catalyst development companies to devote their resources and expertise to the development of these materials. Thus, we propose a Cooperative Research and Development Agreement (CRADA) between the National Renewable Energy Laboratory (NREL), a world leader in biomass pyrolysis research and Johnson Matthey (JM), a world leader in the production of advanced catalyst materials to develop and test novel catalysts for efficient VPU. Through its Intercat Inc. subsidiary in Savannah, Ga., Johnson Matthey is internationally recognized as a leader in zeolite-based vapor phase upgrading in refinery duties and an emerging developer of biomass conversion technologies. The research and development efforts described in the proposed work will build upon existing collaborations between NREL and JM and play to the strengths of both institutions. NREL will analyze the composition of pyrolysis vapors as an input to catalyst design, screen and test catalysts, characterize the resulting oil and conduct techno-economic analysis. Catalyst samples will be produced and funded by JM. JM will design and synthesize catalysts, characterize fresh and used catalysts and develop catalyst supports needed to achieve commercially meaningful lifetimes. The project will span catalyst development and testing from the fundamental stage using quantum mechanical modeling and chemical reaction analysis to catalyst screening to integrated pilot studies.
