The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals

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Publisher : Newnes
ISBN 13 : 0444563326
Total Pages : 607 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals by : Kostas Triantafyllidis

Download or read book The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals written by Kostas Triantafyllidis and published by Newnes. This book was released on 2013-03-19 with total page 607 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals describes the importance of catalysis for the sustainable production of biofuels and biochemicals, focused primarily on the state-of-the-art catalysts and catalytic processes expected to play a decisive role in the "green" production of fuels and chemicals from biomass. In addition, the book includes general elements regarding the entire chain of biomass production, conversion, environment, economy, and life-cycle assessment. Very few books are available on catalysis in production schemes using biomass or its primary conversion products, such as bio-oil and lignin. This book fills that gap with detailed discussions of: Catalytic pyrolysis of lignocellulosic biomass Hybrid biogasoline by co-processing in FCC units Fischer-Tropsch synthesis to biofuels (biomass-to-liquid process) Steam reforming of bio-oils to hydrogen With energy prices rapidly rising, environmental concerns growing, and regulatory apparatus evolving, this book is a resource with tutorial, research, and technological value for chemists, chemical engineers, policymakers, and students. Includes catalytic reaction mechanism schemes and gives a clear understanding of catalytic processes Includes flow diagrams of bench-, pilot- and industrial-scale catalytic processing units and demonstrates the various process technologies involved, enabling easy selection of the best process Incorporates many tables, enabling easy comparison of data based on a critical review of the available literature

Catalytic Processes for Production of Chemicals from Biomass Using Heterogeneous Catalysis

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (15 download)

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Book Synopsis Catalytic Processes for Production of Chemicals from Biomass Using Heterogeneous Catalysis by : Mrunmayi D. Kumbhalkar

Download or read book Catalytic Processes for Production of Chemicals from Biomass Using Heterogeneous Catalysis written by Mrunmayi D. Kumbhalkar and published by . This book was released on 2017 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomass has the potential to serve as a sustainable platform for the production of fuels and chemicals. In this work, a process to convert levoglucosan, an anhydrosugar in pyrolysis oil, to distillate range hydrocarbons is discussed. In particular, dehydration of alcohols and heterocyclics in the monofunctional oxygenates obtained from sorbitol aqueous-phase hydrodeoxygenation was investigated. Firstly, 1-hexanol dehydration was performed and highest hexenes formation rate was observed over SiO2/Al2O3. Thereafter, conversion of a simulated feed and actual effluent from sorbitol hydrodeoxygenation was performed over SiO2/Al2O3. The olefins thus obtained can be oligomerized to produce distillate range hydrocarbons. Vapor-phase dehydration of cyclic ethers to dienes over solid acids is examined. A reaction network for 2-methyltetrahydrofuran dehydration to pentadienes over SiO2/Al2O3 was proposed using weight hourly space velocity studies and the relative stability of the carbenium intermediates. Studies performed to probe the effect of temperature and partial pressure revealed a strong interaction between the heterocyclic and the catalyst surface. The catalyst deactivated with time but was regenerable upon calcination. Dehydration of cyclic ethers such as tetrahydrofuran, tetrahydropyran, and 2,5-dimethyltetrahydrofuran resulted in the formation of their respective dienes. This conversion can serve as a potential route to produce dienes from biomass. Next, the effects of Sn addition to Pt catalyst and overcoating Pt catalyst using atomic layer deposition are investigated for dehydrogenation of alkanes for their use as endothermic fuels. Interaction of alkanes with metal surfaces results in coke formation leading to catalyst deactivation. The amount of coke per surface Pt was lower on PtSn catalysts as compared to monometallic catalyst which is attributed to the geometric and/or ligand effect by Sn. Alumina-overcoated Pt catalyst showed higher turnover frequencies for alkene formation as compared to non-overcoated catalyst. Lastly, X-ray absorption spectroscopy was performed for various bimetallic catalysts- PtMo for water gas shift, AuMo for reverse water gas shift, and RhRe for C-O hydrogenolysis of tetrahydropyran-2-methanol - to determine the oxidation states, bond distances, and coordination numbers. These results were combined with reactivity data and other characterization techniques to identify the nature of the active site, thereby providing a basis for future rational catalyst design.

Production of Biofuels and Chemicals with Bifunctional Catalysts

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Author :
Publisher : Springer
ISBN 13 : 9811051372
Total Pages : 396 pages
Book Rating : 4.8/5 (11 download)

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Book Synopsis Production of Biofuels and Chemicals with Bifunctional Catalysts by : Zhen Fang

Download or read book Production of Biofuels and Chemicals with Bifunctional Catalysts written by Zhen Fang and published by Springer. This book was released on 2017-12-27 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides state-of-the-art reviews, current research, prospects and challenges of the production of biofuels and chemicals such as furanic biofuels, biodiesel, carboxylic acids, polyols and others from lignocellulosic biomass, furfurals, syngas and γ-valerolactone with bifunctional catalysts, including catalytic, and combined biological and chemical catalysis processes. The bifunctionality of catalytic materials is a concept of not only using multifunctional solid materials as activators, but also design of materials in such a way that the catalytic materials have synergistic characteristics that promote a cascade of transformations with performance beyond that of mixed mono-functional catalysts. This book is a reference designed for researchers, academicians and industrialists in the area of catalysis, energy, chemical engineering and biomass conversion. Readers will find the wealth of information contained in chapters both useful and essential, for assessing the production and application of various biofuels and chemicals by chemical catalysis and biological techniques.

Chemical Catalysts for Biomass Upgrading

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Publisher : John Wiley & Sons
ISBN 13 : 3527344667
Total Pages : 634 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Chemical Catalysts for Biomass Upgrading by : Mark Crocker

Download or read book Chemical Catalysts for Biomass Upgrading written by Mark Crocker and published by John Wiley & Sons. This book was released on 2020-03-09 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive reference to the use of innovative catalysts and processes to turn biomass into value-added chemicals Chemical Catalysts for Biomass Upgrading offers detailed descriptions of catalysts and catalytic processes employed in the synthesis of chemicals and fuels from the most abundant and important biomass types. The contributors?noted experts on the topic?focus on the application of catalysts to the pyrolysis of whole biomass and to the upgrading of bio-oils. The authors discuss catalytic approaches to the processing of biomass-derived oxygenates, as exemplified by sugars, via reactions such as reforming, hydrogenation, oxidation, and condensation reactions. Additionally, the book provides an overview of catalysts for lignin valorization via oxidative and reductive methods and considers the conversion of fats and oils to fuels and terminal olefins by means of esterification/transesterification, hydrodeoxygenation, and decarboxylation/decarbonylation processes. The authors also provide an overview of conversion processes based on terpenes and chitin, two emerging feedstocks with a rich chemistry, and summarize some of the emerging trends in the field. This important book: -Provides a comprehensive review of innovative catalysts, catalytic processes, and catalyst design -Offers a guide to one of the most promising ways to find useful alternatives for fossil fuel resources -Includes information on the most abundant and important types of biomass feedstocks -Examines fields such as catalytic cracking, pyrolysis, depolymerization, and many more Written for catalytic chemists, process engineers, environmental chemists, bioengineers, organic chemists, and polymer chemists, Chemical Catalysts for Biomass Upgrading presents deep insights on the most important aspects of biomass upgrading and their various types.

Catalysis for the Production of Sustainable Fuels and Chemicals

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Author :
Publisher : MDPI
ISBN 13 : 303936040X
Total Pages : 270 pages
Book Rating : 4.0/5 (393 download)

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Book Synopsis Catalysis for the Production of Sustainable Fuels and Chemicals by : Flora T. T. Ng

Download or read book Catalysis for the Production of Sustainable Fuels and Chemicals written by Flora T. T. Ng and published by MDPI. This book was released on 2020-12-29 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis, in the industrial production of chemicals, fuels, and materials, accounts for more than half of gross material production worldwide. Heterogeneous catalysis enables fast and selective chemical transformations, resulting in superior product yield and facilitating catalyst separation and recovery. The synthesis of novel catalysts has emerged as a hot topic for process and product development with numerous research publications and patents. Hence, development of efficient catalysts and their applications is important for sustainable energy production and use, green chemicals production and use, and economic growth. This Special Issue discusses recent developments related to catalysis for the production of sustainable fuels and chemicals and traverses many new frontiers of catalysis including synthesis, characterization, catalytic performances, reaction kinetics and modelling, as well as applications of catalysts for the production of biofuels, synthesis gas, and other green products. This covers the current state-of-the-art catalysis research applied to bioenergy, organic transformation, carbon–carbon and carbon–heteroatoms, reforming, hydrogenation, hydrodesulfurization, hydrodenitrogenation, hydrodemetalization, Fischer–Tropsch synthesis, to name a few. This book highlights new avenues in catalysis including catalyst preparation methods, analytical tools for catalyst characterization, and techno-economic assessment to enhance a chemical or biological transformation process using catalysts for a betterment of industry, academia and society.

Advanced Functional Solid Catalysts for Biomass Valorization

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Publisher : Elsevier
ISBN 13 : 012820236X
Total Pages : 274 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Advanced Functional Solid Catalysts for Biomass Valorization by : Chaudhery Mustansar Hussain

Download or read book Advanced Functional Solid Catalysts for Biomass Valorization written by Chaudhery Mustansar Hussain and published by Elsevier. This book was released on 2020-06-14 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Functional Solid Catalysts for Biomass Valorization presents the basic concepts in catalysis (homogeneous, heterogeneous, and enzymatic) and the properties of various kinds of heterogeneous solid catalysts, including their structure, porosity, particle size, BET surface area, acid-base, and redox properties. Useful information about biorefineries, types of biomass feedstocks, their structures and properties as well as about several potential catalytic routes for biomass upgrading to useful fuels and chemicals is provided in this book. Importantly, this book covers the most recent developments toward functionalization of various solid catalysts, optimization of catalysts' properties, developing cascade catalytic strategies, exploring reaction kinetics/mechanisms, and evaluating catalysts' stability/reusability during biomass upgrading. Current challenges and opportunities for the future biorefineries as well as for the design of advanced functional solid catalysts are critically discussed. Describes catalysis as a promising technology for the development of eco-friendly and economically viable strategies for several important energy and environmental applications. Covers heterogeneous solid catalysts because of their versatile benefits in terms of catalysts' synthesis, production cost, stability, and reusability as compared to homogeneous liquid catalysts. Provides promising strategies for the design of new catalytic materials, such as carbon materials, metal-organic frameworks, zeolites, and mesoporous silicas. Describes functional solid catalysts for developing one-pot cascade processes for efficient biomass valorization and other vital chemical transformations.

New and Future Developments in Catalysis

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Author :
Publisher : Newnes
ISBN 13 : 0444538798
Total Pages : 413 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis New and Future Developments in Catalysis by : Steven L Suib

Download or read book New and Future Developments in Catalysis written by Steven L Suib and published by Newnes. This book was released on 2013-07-17 with total page 413 pages. Available in PDF, EPUB and Kindle. Book excerpt: New and Future Developments in Catalysis is a package of books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes. This volume covers all the biomass sources and gives detailed and in-depth coverage of all current chemical/catalytic conversion processes of biomass into liquid hydrocarbons to be further used as a feedstock for the production of not only biofuels but a large array of chemicals. Offers an in-depth coverage of all catalytic topics of current interest and outlines the future challenges and research areas A clear and visual description of all parameters and conditions enables the reader to draw conclusions for a particular case Outline the catalytic processes applicable to energy generation and design of green processes

New and Future Developments in Catalysis

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Publisher : Elsevier Inc. Chapters
ISBN 13 : 012808197X
Total Pages : 34 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis New and Future Developments in Catalysis by : Lei Jin

Download or read book New and Future Developments in Catalysis written by Lei Jin and published by Elsevier Inc. Chapters. This book was released on 2013-07-17 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Catalysis for Clean Energy and Environmental Sustainability

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Publisher : Springer Nature
ISBN 13 : 3030650170
Total Pages : 933 pages
Book Rating : 4.0/5 (36 download)

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Book Synopsis Catalysis for Clean Energy and Environmental Sustainability by : K. K. Pant

Download or read book Catalysis for Clean Energy and Environmental Sustainability written by K. K. Pant and published by Springer Nature. This book was released on 2021-05-13 with total page 933 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is part of a two-volume work that offers a unique blend of information on realistic evaluations of catalyst-based synthesis processes using green chemistry principles and the environmental sustainability applications of such processes for biomass conversion, refining, and petrochemical production. The volumes provide a comprehensive resource of state-of-the-art technologies and green chemistry methodologies from researchers, academics, and chemical and manufacturing industrial scientists. The work will be of interest to professors, researchers, and practitioners in clean energy catalysis, green chemistry, chemical engineering and manufacturing, and environmental sustainability. This volume focuses on the potentials, recent advances, and future prospects of catalysis for biomass conversion and value-added chemicals production via green catalytic routes. Readers are presented with a mechanistic framework assessing the development of product selective catalytic processes for biomass and biomass-derived feedstock conversion. The book offers a unique combination of contributions from experts working on both lab-scale and industrial catalytic processes and provides insight into the use of various catalytic materials (e.g., mineral acids, heteropolyacid, metal catalysts, zeolites, metal oxides) for clean energy production and environmental sustainability.

Advanced Catalysis for Drop-in Chemicals

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Publisher : Elsevier
ISBN 13 : 0128238410
Total Pages : 341 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Advanced Catalysis for Drop-in Chemicals by : Putla Sudarsanam

Download or read book Advanced Catalysis for Drop-in Chemicals written by Putla Sudarsanam and published by Elsevier. This book was released on 2021-09-28 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomass conversion into drop-in chemicals using novel heterogeneous bulk- and nano-scale catalysts is currently a hot research topic with the aim of replacing petrochemicals in the chemical industry. Considering the importance of this subject to the scientific community, Advanced Catalysis for Drop-in Chemicals provides the latest developments in the catalytic synthesis of drop-in chemicals mainly from lignocellulose, carbohydrates (cellulose, hemicellulose, C6 and C5 sugars, and their derivatives), lignin, and glycerol. The role of both heterogeneous bulk solid and nanostructured catalysts, along with their advantages and disadvantages for drop-in chemicals synthesis are critically summarized. Addressing the frontiers and prospects for using drop-in chemicals in place of petrochemicals in the chemical industry is also a key topic of this book. • Describes fossil fuels, biomass, drop-in chemicals, catalysis, and nano- and atomic-scale catalysts • Includes pre- and post-treatment strategies for biomass upgrading • Provides green catalytic processes for drop-in chemicals synthesis • Outlines stabilization of nano- and atomic-scale catalysts • Examines using drop-in chemicals in place of petrochemicals in the chemical industry

Catalytic Processes for The Valorisation of Biomass Derived Molecules

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Publisher : MDPI
ISBN 13 : 3039219146
Total Pages : 114 pages
Book Rating : 4.0/5 (392 download)

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Book Synopsis Catalytic Processes for The Valorisation of Biomass Derived Molecules by : Francesco Mauriello

Download or read book Catalytic Processes for The Valorisation of Biomass Derived Molecules written by Francesco Mauriello and published by MDPI. This book was released on 2019-11-22 with total page 114 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last decades, inedible lignocellulosic biomasses have attracted significant attention for being abundant resources that are not in competition with agricultural land or food production and, therefore, can be used as starting renewable material for the production of a wide variety of platform chemicals. The three main components of lignocellulosic biomasses are cellulose, hemicellulose and lignin, complex biopolymers that can be converted into a pool of platform molecules including sugars, polyols, alchols, ketons, ethers, acids and aromatics. Various technologies have been explored for their one-pot conversion into chemicals, fuels and materials. However, in order to develop new catalytic processes for the selective production of desired products, a complete understanding of the molecular aspects of the basic chemistry and reactivity of biomass derived molecules is still crucial. This Special Issue reports on recent progress and advances in the catalytic valorization of cellulose, hemicellulose and lignin model molecules promoted by novel heterogeneous systems for the production of energy, fuels and chemicals.

Sustainable Catalytic Conversion of Biomass for the Production of Biofuels and Bioproducts

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Publisher : MDPI
ISBN 13 : 3039364332
Total Pages : 216 pages
Book Rating : 4.0/5 (393 download)

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Book Synopsis Sustainable Catalytic Conversion of Biomass for the Production of Biofuels and Bioproducts by : Gabriel Morales

Download or read book Sustainable Catalytic Conversion of Biomass for the Production of Biofuels and Bioproducts written by Gabriel Morales and published by MDPI. This book was released on 2020-12-02 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomass is widely considered as a potential alternative to dwindling fossil fuel reserves. There is a large variety of biomass sources (oleaginous, lignocellulosic, algae, etc.), with many possible conversion routes and products. Currently, biomass is not just viewed as a source of biofuels, but also as an interesting feedstock for the production of bio-based chemicals that could largely replace petrochemicals. In this context, the search for new sustainable and efficient alternatives to fossil sources is gaining increasing relevance within the chemical industry. There, the role of catalysis is often critical for the development of clean and sustainable processes, aiming to produce commodity chemicals or liquid fuels with a high efficiency and atom economy. This book gathers works at the cutting edge of investigation in the application of catalysis, for the sustainable conversion of biomass into biofuels and bio-based chemicals.

Heterogeneous Catalysis for Energy Applications

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Publisher : Royal Society of Chemistry
ISBN 13 : 178801958X
Total Pages : 533 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Heterogeneous Catalysis for Energy Applications by : Tomas R Reina

Download or read book Heterogeneous Catalysis for Energy Applications written by Tomas R Reina and published by Royal Society of Chemistry. This book was released on 2020-08-27 with total page 533 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous catalysis plays a central role in the global energy paradigm, with practically all energy-related process relying on a catalyst at a certain point. The application of heterogeneous catalysts will be of paramount importance to achieve the transition towards low carbon and sustainable societies. This book provides an overview of the design, limitations and challenges of heterogeneous catalysts for energy applications. In an attempt to cover a broad spectrum of scenarios, the book considers traditional processes linked to fossil fuels such as reforming and hydrocracking, as well as catalysis for sustainable energy applications such as hydrogen production, photocatalysis, biomass upgrading and conversion of CO2 to clean fuels. Novel approaches in catalysts design are covered, including microchannel reactors and structured catalysts, catalytic membranes and ionic liquids. With contributions from leaders in the field, Heterogeneous Catalysis for Energy Applications will be an essential toolkit for chemists, physicists, chemical engineers and industrials working on energy.

Heterogeneous Catalysis for Sustainable Energy

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Publisher : John Wiley & Sons
ISBN 13 : 3527815910
Total Pages : 755 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Heterogeneous Catalysis for Sustainable Energy by : Landong Li

Download or read book Heterogeneous Catalysis for Sustainable Energy written by Landong Li and published by John Wiley & Sons. This book was released on 2022-05-03 with total page 755 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous Catalysis for Sustainable Energy Explore the state-of-the-art in heterogeneous catalysis In Heterogeneous Catalysis for Sustainable Energy, a team of distinguished researchers delivers a comprehensive and cutting-edge treatment of recent advancements in energy-related catalytic reactions and processes in the field of heterogeneous catalysis. The book includes extensive coverage of the hydrogen economy, methane activation, methanol-to-hydrocarbons, carbon dioxide conversion, and biomass conversion. The authors explore different aspects of the technology, like reaction mechanisms, catalyst synthesis, and the commercial status of the reactions. The book also includes: A thorough introduction to the hydrogen economy, including hydrogen production, the reforming of oxygen-containing chemicals, and advances in Fischer-Tropsch Synthesis Comprehensive explorations of methane activation, including steam and dry reforming of methane and methane activation over zeolite catalysts Practical discussions of alkane activation, including cracking of hydrocarbons to light olefins and catalytic dehydrogenation of light alkanes In-depth examinations of zeolite catalysis and carbon dioxide as C1 building block Perfect for catalytic, physical, and surface chemists, Heterogeneous Catalysis for Sustainable Energy also belongs in the libraries of materials scientists with an interest in energy-related reactions and processes in the field of heterogeneous catalysis.

Sustainable Catalysis for Biorefineries

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Publisher : Royal Society of Chemistry
ISBN 13 : 1782629637
Total Pages : 386 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Sustainable Catalysis for Biorefineries by : Francesco Frusteri

Download or read book Sustainable Catalysis for Biorefineries written by Francesco Frusteri and published by Royal Society of Chemistry. This book was released on 2018 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explores the most effective or promising catalytic processes for the conversion of biobased components into high added value products, as platform chemicals and intermediates.

Heterogeneous Catalysis

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Publisher : Elsevier
ISBN 13 : 0323856322
Total Pages : 554 pages
Book Rating : 4.3/5 (238 download)

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Book Synopsis Heterogeneous Catalysis by : Moises Romolos Cesario

Download or read book Heterogeneous Catalysis written by Moises Romolos Cesario and published by Elsevier. This book was released on 2022-04-27 with total page 554 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous Catalysis: Materials and Applications focuses on heterogeneous catalysis applied to the elimination of atmospheric pollutants as an alternative solution for producing clean energy and the valorization of chemical products. The book helps users understand the properties of catalytic materials and catalysis phenomena governing electrocatalytic/catalytic reactions, and – more specifically – the study of surface and interface chemistry. By clustering knowledge in these fields, the book makes information available to both the academic and industrial communities. Further, it shows how heterogeneous catalysis applications can be used to solve environmental problems and convert energy through electrocatalytic reactions and chemical valorization. Sections cover nanomaterials for heterogeneous catalysis, heterogeneous catalysis mechanisms, SOX adsorption, greenhouse gases conversion, reforming reactions for hydrogen production, valorization of hydrogen energy, energy conversion and biomass valorization. Addresses topics of increasing interest to society such as the valorization of biomass, the use of polluting gases to produce value-added products, and the optimization of catalytic materials for water splitting, fuel cells, and other devices Discusses pollutant adsorption by industrial fume desulphurization processes Helps improve processes for obtaining chemicals using nonconventional technologies

New and Future Developments in Catalysis

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Author :
Publisher : Elsevier Inc. Chapters
ISBN 13 : 0128082011
Total Pages : 38 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis New and Future Developments in Catalysis by : Subhash Bhatia

Download or read book New and Future Developments in Catalysis written by Subhash Bhatia and published by Elsevier Inc. Chapters. This book was released on 2013-07-17 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt: