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Author :
Publisher :
ISBN 13 : 9780841231825
Total Pages : pages
Book Rating : 4.2/5 (318 download)
Download or read book Boron Reagents in Synthesis written by and published by . This book was released on 2016-12-01 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Donald S. Matteson
Publisher : Springer Science & Business Media
ISBN 13 : 3642797091
Total Pages : 417 pages
Book Rating : 4.6/5 (427 download)
Download or read book Stereodirected Synthesis with Organoboranes written by Donald S. Matteson and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 417 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph has been written to demonstrate to organic chemists and graduate students the strategies for controlling stereochemistry in carbon-carbon bond formations with borane intermediates. The boranes were initially found to be useful reagents by Nobel Laureate H.C. Brown. Their precursors are commercially available and derivatization is fast, clean and simple.
Author : Andrew Pelter
Publisher :
ISBN 13 :
Total Pages : 544 pages
Book Rating : 4.3/5 (91 download)
Download or read book Borane Reagents written by Andrew Pelter and published by . This book was released on 1988 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Adiel Coca
Publisher : ACS Symposium
ISBN 13 : 9780841231832
Total Pages : 544 pages
Book Rating : 4.2/5 (318 download)
Download or read book Boron Reagents in Synthesis written by Adiel Coca and published by ACS Symposium. This book was released on 2018-02-02 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron compounds have been used extensively in organic synthesis for more than sixty years. Some of the best known reactions in synthesis, such as the Suzuki-Miyaura cross-coupling and the hydroboration reaction, involve boron compounds. Several natural products containing boron have been isolated in the last fifty years, including ionophoric macrodiolide antibiotics boromycin, borophycin, aplasmomycins A, B, and C, and tartrolons B, C, and E, as well as autoinducer-2. The study of compounds containing boronic acids for application in pharmaceuticals and materials science has grown tremendously over the last few decades. These include bortezomib, ixazomib, and tavaborole. Several more boron-based drugs are currently in clinical trials. Boron neutron capture therapy has the potential to provide a treatment for various cancers. In addition, materials bearing boronic acids are been studied as potential sensors for biological molecules, such as saccharides and glycoproteins that possess cis-1,2- or cis-1,3-diols.
Author : Dennis G. Hall
Publisher : John Wiley & Sons
ISBN 13 : 1118344456
Total Pages : 6 pages
Book Rating : 4.1/5 (183 download)
Download or read book Organic Reactions, Volume 73 written by Dennis G. Hall and published by John Wiley & Sons. This book was released on 2012-05-29 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Brønsted acid catalyzed manifolds recently, has opened new doors for further development of this important reaction. This book provides an up-to-date, comprehensive survey of the literature of this rich chemistry as it pertains to organic synthesis. Consistent with the goal of Organic Reactions, the content and presentation emphasize the preparative aspects of the reactions, giving considerable attention to the scope and limitations of the individual transformations along with detailed experimental procedures. A tabular survey of all examples of carbonyl allylboration used in organic synthesis is presented in nine tables organized by type of allylic boron reagent with listings within each table according to increasing carbon number of the carbonyl substrates. The literature is covered through December 2010, including a new listing of nearly 200 literature citations that supplement the original coverage of 834 references used in the earlier hard cover version of the chapter. Allylboration of Carbonyl Compounds is intended to be a useful, easily read reference book for all practitioners of synthetic organic chemistry working in academic and industrial laboratories.
Author : William Gerrard
Publisher :
ISBN 13 :
Total Pages : 328 pages
Book Rating : 4.:/5 (4 download)
Download or read book The Organic Chemistry of Boron written by William Gerrard and published by . This book was released on 1961 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Dieter E. Kaufmann
Publisher : Thieme
ISBN 13 : 3131779519
Total Pages : 2230 pages
Book Rating : 4.1/5 (317 download)
Download or read book Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 6 written by Dieter E. Kaufmann and published by Thieme. This book was released on 2014-05-14 with total page 2230 pages. Available in PDF, EPUB and Kindle. Book excerpt: Science of Synthesis: Houben-Weyl Methods of Molecular Transformations is the entirely new edition of the acclaimed reference series, Houben-Weyl, the standard synthetic chemistry resource since 1909. This new edition is published in English and will comprise 48 volumes published between the years 2000 and 2008. Science of Synthesis is a quality reference work developed by a highly esteemed editorial board to provide a comprehensive and critical selection of reliable organic and organometallic synthetic methods. This unique resource is designed to be the first point of reference when searching for a synthesis strategy. Contains the expertise of presently 400 leading chemists worldwide Critically evaluates the preparative applicability and significance of the synthetic methods Discusses relevant background information and provides detailed experimental procedures For full information on the Science of Synthesis series, visit the Science of Synthesis Homepage.
Author : Meng Li
Publisher : Royal Society of Chemistry
ISBN 13 : 1782622128
Total Pages : 440 pages
Book Rating : 4.7/5 (826 download)
Download or read book Boron written by Meng Li and published by Royal Society of Chemistry. This book was released on 2015-11-03 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: The ability to monitor analytes within physiological, environmental, and industrial scenarios is of prime importance in many scenarios. Chemists have striven to mimic nature’s ability to produce robust chemosensors with the capacity to detect molecules and signal their presence. The covalent coupling interaction between boronic acids and saccharides has been exploited to monitor saccharides. The boronic acid–and Lewis acid base interaction is also suitable for the capture and recognition of anions, which are involved in fundamental processes in all living things. There have been significant advances in the field of boronic acid based receptors and this book provides a comprehensive overview and update on the topic. Not only are the applications of boron in chemical molecular sensors covered in detail, but their synthesis and supramolecular self-assembly are also presented. Topics include: the molecular recognition of saccharides, the complexation of boronic acids with saccharides, fluorescent sensors and the modular construct of fluorescent sensors, further sensory systems for saccharide recognition and an extensive bibliography. Edited by experts in the area and containing international contributions from leading research groups on the subject, this book provides a useful resource for graduate students, academic and industrial researchers in organic chemistry, supramolecular chemistry, materials science and bio-organic chemistry.
Author : Michael Richard Schrimpf
Publisher :
ISBN 13 :
Total Pages : 570 pages
Book Rating : 4.:/5 (89 download)
Download or read book Complexation of Neutral and Cationic Prochiral Boron Reagents written by Michael Richard Schrimpf and published by . This book was released on 1995 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Elena Fernández
Publisher : Springer
ISBN 13 : 3319130544
Total Pages : 334 pages
Book Rating : 4.3/5 (191 download)
Download or read book Synthesis and Application of Organoboron Compounds written by Elena Fernández and published by Springer. This book was released on 2015-03-04 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
Author : E. Fernández
Publisher : Thieme
ISBN 13 : 3132429732
Total Pages : 582 pages
Book Rating : 4.1/5 (324 download)
Download or read book Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis written by E. Fernández and published by Thieme. This book was released on 2020-05-22 with total page 582 pages. Available in PDF, EPUB and Kindle. Book excerpt: The widespread use of organoboron compounds justifies the efforts devoted to their synthesis, as well as toward developing an understanding of their reactivity. The nature of the mono- or diboron species is of paramount importance in determining the reversible covalent binding properties of the boron atom with both nucleophiles and electrophiles. By wedding the rich chemical potential of organoboron compounds to the ubiquity of organic scaffolds, advanced borylation reactions have the potential to open unprecedented synthetic alternatives, and new knowledge in the field should encourage chemists to use organoboron compounds. In this volume, the main objective is to provide a collection of the most useful, practical, and reliable methods, reported mainly within the last decade, for boron activation and boron reactivity. The volume covers the main concepts of organoboron compounds and includes experimental procedures, enabling newcomers to the field the instant and reliable application of the new tools in synthesis. Rather than aiming for a comprehensive coverage, the most advanced solutions for challenging transformations are introduced. To this end, a team of pioneers and leaders in the field have been assembled who discuss both the practical and conceptual aspects of this rapidly growing field.
Author : Dennis G. Hall
Publisher : John Wiley & Sons
ISBN 13 : 3527332146
Total Pages : 1 pages
Book Rating : 4.5/5 (273 download)
Download or read book Boronic Acids written by Dennis G. Hall and published by John Wiley & Sons. This book was released on 2012-09-05 with total page 1 pages. Available in PDF, EPUB and Kindle. Book excerpt: Following the huge success of the first edition, which has become THE reference source for everyone working in the field, this long-awaited, completely updated edition features almost 50% new content. The world-renowned chemist Prof Dennis Hall is joined by a select group of top authors to cover all modern aspects of boronic acid derivatives in one comprehensive handbook. The experimental procedures described make for extremely useful reading. From the reviews of the first edition: "...deserves to be on the bookshelf of all synthetic chemists, whether in discovery or process chemistry."
Author : Koji Kubota
Publisher : Springer
ISBN 13 : 9811049351
Total Pages : 222 pages
Book Rating : 4.8/5 (11 download)
Download or read book Synthesis of Functionalized Organoboron Compounds Through Copper(I) Catalysis written by Koji Kubota and published by Springer. This book was released on 2017-06-27 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes state-of-the-art borylation chemistry using copper(I) catalysis. Enantioselective reactions are included to afford a variety of functionalized, complex organoboronate esters, which will find wide application in asymmetric synthesis, drug discovery, and material science. Organoboron compounds are recognized as useful reagents in organic synthesis; therefore, great effort has been devoted to the development of a simple, mild, and efficient method for their preparation in the past several years. However, the synthesis of functionalized organoboron compounds remains a challenging issue because known reactions often require the use of highly reactive organometallic carbon nucleophiles. This book focuses on conceptually new, formal nucleophilic copper(I)-catalyzed borylation reactions with diboron compounds that show high selectivity and excellent functional group compatibility. Theoretical studies based on density functional theory calculations to understand the reaction mechanisms have also been described. Advances in this novel borylation chemistry will allow the rapid and efficient synthesis of complex molecules with potentially interesting properties in combination with the boron functionalization process.
Author : Dennis G. Hall
Publisher : John Wiley & Sons
ISBN 13 : 3527606823
Total Pages : 571 pages
Book Rating : 4.5/5 (276 download)
Download or read book Boronic Acids written by Dennis G. Hall and published by John Wiley & Sons. This book was released on 2006-05-12 with total page 571 pages. Available in PDF, EPUB and Kindle. Book excerpt: For the first time, the whole field of organoboronic acids is presented in one comprehensive handbook. Professor Dennis Hall, a rising star within the community, covers all aspects of this important substance class, including applications in chemistry, biology and medicine. Starting with an introduction to the structure, properties, and preparation of boronic acid derivatives, together with an overview of their reactions and applications, the book goes on to look at metal-catalyzed borylation of alkanes and arenas, coupling reactions and rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds. There follows chapters on copper-promoted C-O and C-N cross-coupling of boronic acids, recent applications in organic synthesis, as well as alpha-haloalkylboronic esters in asymmetric synthesis. Later sections deal with cycloadditions, organoboronic acids, oxazaborolidines as asymmetric inducers, and boronic acid based receptors and sensors. The whole is rounded off with experimental procedures, making this invaluable reading for organic, catalytic and medicinal chemists, as well as those working in organometallics.
Author : Matthew G Davidson
Publisher : Royal Society of Chemistry
ISBN 13 : 1847550649
Total Pages : 555 pages
Book Rating : 4.8/5 (475 download)
Download or read book Contemporary Boron Chemistry written by Matthew G Davidson and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 555 pages. Available in PDF, EPUB and Kindle. Book excerpt: The continued and evolving significance of boron chemistry to the wider chemical community is demonstrated by the international and interdisciplinary nature of the research reported in this book. Contemporary Boron Chemistry encompasses inorganic and organic compounds as well as polymers, solid-state materials, medicinal aspects and theoretical studies. Covering many areas of chemistry with boron at its centre, topics include applications to polyolefin catalysis, medicine, materials and polymers; boron cluster chemistry, including carboranes and metal-containing clusters; organic and inorganic chemistry of species containing only 1 or 2 boron atoms; and theoretical studies of boron-containing compounds. New materials with novel optical and electronic properties are also discussed. Comprehensive and up to date, graduates and researchers in a wide range of fields, particularly those in organometallic and organic chemistry and materials science, will welcome this book.
Author : Catherine Dianne Brown
Publisher :
ISBN 13 :
Total Pages : 216 pages
Book Rating : 4.:/5 (639 download)
Download or read book Synthesis of Substituted Binaphthol Boron Reagents for Enantioselective 1,2-additions to Aldehydes and Regioselective Synthesis of 2,3,5-trisubstituted Furans written by Catherine Dianne Brown and published by . This book was released on 2000 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Michael A Beckett
Publisher :
ISBN 13 : 9783725806669
Total Pages : 0 pages
Book Rating : 4.8/5 (66 download)
Download or read book New Developments in Boron Chemistry written by Michael A Beckett and published by . This book was released on 2024-04-02 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Special Issue is dedicated to all aspects of boron chemistry, including all fields of inorganic boron chemistry from oxidoborates to hydrido(hetero)borane derivatives (including boranes, carboranes, metallaboranes, and metallacarboranes), transition metal complexes of boron-containing ligands, organic and bio-organic boron chemistry (including boron-based Lewis acids, boronic acids, benzoxaboroles, aminoboranes, and the application of boron reagents in organic synthesis), boron in materials (including polymers, dendrimers, ionic liquids, liquid crystals, hydrogen storage, and catalysis), and boron in medicine (including boron neutron capture of cancer, carborane pharmacophores, boron-containing drugs, and boronic acid-based sugar sensors).
