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Biomass Ex Situ Cfp Catalyst Design A Mo2c Case Study To Evaluate If Trends In Model Compound Reactivity Translate To Real Biomass Feeds
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Book Synopsis Biomass Ex-Situ CFP Catalyst Design: A Mo2C Case Study to Evaluate if Trends in Model Compound Reactivity Translate to Real Biomass Feeds by :
Download or read book Biomass Ex-Situ CFP Catalyst Design: A Mo2C Case Study to Evaluate if Trends in Model Compound Reactivity Translate to Real Biomass Feeds written by and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pyrolysis of biomass generates hundreds of molecules with different functional groups; water, char and inorganics are also produced. In general, new catalysts are evaluated with single model compounds.
Book Synopsis Challenges for Scaling-Up Biomass Catalytic Fast Pyrolysis Process Technology: A Case Study for Ex Situ CFP in Fixed-Bed Configuration by :
Download or read book Challenges for Scaling-Up Biomass Catalytic Fast Pyrolysis Process Technology: A Case Study for Ex Situ CFP in Fixed-Bed Configuration written by and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: CFP catalysts need to achieve extensive deoxygenation and high carbon yields. Carbon yield is a major economic driver for the integrated CFP-HT process.
Book Synopsis Molybdenum Trioxide and Molybdenum Carbide as Promising Hydrodeoxygenation Catalysts for Biomass Conversion by : Karthick Murugappan
Download or read book Molybdenum Trioxide and Molybdenum Carbide as Promising Hydrodeoxygenation Catalysts for Biomass Conversion written by Karthick Murugappan and published by . This book was released on 2017 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt: Growing concerns due to rising CO2 emissions have made biomass an indispensable source of renewable fuels and chemicals. However, biomass inherently has high oxygen content, which translates to low energy density, thereby necessitating a deoxygenation step before being utilized as fuels. Recently, MoO3 and Mo2C have emerged as promising earth-abundant cheap catalysts that perform hydrodeoxygenation (HDO) at relatively low temperatures ( 673 K) and ambient H2 pressures wherein oxygen is selectively removed as water. However, there exists a significant knowledge gap in understanding the stability and the active phases responsible for HDO of these catalysts. Furthermore, their applicability for real biomass conversions has not been largely demonstrated. In this thesis, first, HDO of m-cresol, a biomass-derived model compound, is investigated over bulk and supported MoO 3 catalysts. Detailed reactivity and characterization studies reveal that Mo5+ species plays a critical role during HDO. Specifically, TiO2 and ZrO2 are identified as ideal supports as they feature superior HDO reactivity and stability over bulk MoO3 by stabilizing intermediate Mo oxidation states (i.e. Mo5+) while bulk MoO 3 over-reduces to inactive metallic Mo. Translating from model compound studies, supported MoO3 catalysts are demonstrated to be effective in converting biomass (pine) pyrolysis vapors to hydrocarbons (ca. 30 % yield). In comparison with MoO 3, Mo2C is significantly more stable and selective for HDO of 4-methylanisole to toluene under identical reaction conditions. Mo2C predominantly breaks the stronger phenolic C-0 bond while MoO 3 also breaks the weaker aliphatic C-0 bond, likely due to the presence of Bronsted acid sites. To gain insights into the surface active sites, operando near-ambient XPS is employed during HDO and this technique revealed that HDO seems to operate via distinct active sites over both these materials. Finally, Mo2C is shown to be effective in upgrading real lignin streams to a single product propylbenzene, a precursor for renewable polymer. Overall, this thesis demonstrates the applicability of MoO3 and Mo2C in real biomass conversions and provides insights on the working nature of these catalysts, which will enable the design of more effective HDO catalysts.
Book Synopsis Fast Pyrolysis of Biomass by : Robert C Brown
Download or read book Fast Pyrolysis of Biomass written by Robert C Brown and published by Royal Society of Chemistry. This book was released on 2017-07-07 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fast pyrolysis and related catalytic pyrolysis are of increasing interest as pathways to advanced biofuels that closely mimic traditional petroleum products. Research has moved from empirical investigations to more fundamental studies of pyrolysis mechanisms. Theories on the chemical and physical pathways from plant polymers to pyrolysis products have proliferated as a result. This book brings together the latest developments in pyrolysis science and technology. It examines, reviews and challenges the unresolved and sometimes controversial questions about pyrolysis, helping advance the understanding of this important technology and stimulating discussion on the various competing theories of thermal deconstruction of plant polymers. Beginning with an introduction to the biomass-to-biofuels process via fast pyrolysis and catalytic pyrolysis, chapters address prominent questions such as whether free radicals or concerted reactions dominate deconstruction reactions. Finally, the book concludes with an economic analysis of fast pyrolysis versus catalytic pyrolysis. This book will be of interest to advanced students and researchers interested in the science behind renewable fuel technology, and particularly the thermochemical processing of biomass.
Book Synopsis Conceptual Process Design and Techno-economic Assessment of Ex Situ Catalytic Fast Pyrolysis of Biomass by :
Download or read book Conceptual Process Design and Techno-economic Assessment of Ex Situ Catalytic Fast Pyrolysis of Biomass written by and published by . This book was released on 2015 with total page 17 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ex situ catalytic fast pyrolysis of biomass is a promising route for the production of fungible liquid biofuels. There is significant ongoing research on the design and development of catalysts for this process. However, there are a limited number of studies investigating process configurations and their effects on biorefinery economics. Herein we present a conceptual process design with techno-economic assessment; it includes the production of upgraded bio-oil via fixed bed ex situ catalytic fast pyrolysis followed by final hydroprocessing to hydrocarbon fuel blendstocks. This study builds upon previous work using fluidized bed systems, as detailed in a recent design report led by the National Renewable Energy Laboratory (NREL/TP-5100-62455); overall yields are assumed to be similar, and are based on enabling future feasibility. Assuming similar yields provides a basis for easy comparison and for studying the impacts of areas of focus in this study, namely, fixed bed reactor configurations and their catalyst development requirements, and the impacts of an inline hot gas filter. A comparison with the fluidized bed system shows that there is potential for higher capital costs and lower catalyst costs in the fixed bed system, leading to comparable overall costs. The key catalyst requirement is to enable the effective transformation of highly oxygenated biomass into hydrocarbons products with properties suitable for blending into current fuels. Potential catalyst materials are discussed, along with their suitability for deoxygenation, hydrogenation and C-C coupling chemistry. This chemistry is necessary during pyrolysis vapor upgrading for improved bio-oil quality, which enables efficient downstream hydroprocessing; C-C coupling helps increase the proportion of diesel/jet fuel range product. One potential benefit of fixed bed upgrading over fluidized bed upgrading is catalyst flexibility, providing greater control over chemistry and product composition. Since this study is based on future projections, the impacts of uncertainties in the underlying assumptions are quantified via sensitivity analysis. As a result, this analysis indicates that catalyst researchers should prioritize by: carbon efficiency> catalyst cost> catalyst lifetime, after initially testing for basic operational feasibility.
Book Synopsis Experimental and Computational Investigation of Acetic Acid Deoxygenation Over Oxophilic Molybdenum Carbide by :
Download or read book Experimental and Computational Investigation of Acetic Acid Deoxygenation Over Oxophilic Molybdenum Carbide written by and published by . This book was released on 2016 with total page 17 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ex situ catalytic fast pyrolysis (CFP) is a promising route for producing fungible biofuels; however, this process requires bifunctional catalysts that favor C-O bond cleavage, activate hydrogen at near atmospheric pressure and high temperature (350-500 °C), and are stable under high-steam, low hydrogen-to-carbon environments. Recently, early transition-metal carbides have been reported to selectively cleave C-O bonds of alcohols, aldehydes, and oxygenated aromatics, yet there is limited understanding of the metal carbide surface chemistry under reaction conditions and the identity of the active sites for deoxygenation. In this study, we evaluated molybdenum carbide (Mo2C) for the deoxygenation of acetic acid, an abundant component of biomass pyrolysis vapors, under ex situ CFP conditions, and we probed the Mo2C surface chemistry, identity of the active sites, and deoxygenation pathways using in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), X-ray photoelectron spectroscopy (XPS), and density functional theory (DFT) calculations.
Book Synopsis Formation Mechanism of Char and Coke in Biomass Catalytic Pyrolysis by :
Download or read book Formation Mechanism of Char and Coke in Biomass Catalytic Pyrolysis written by and published by . This book was released on 2015 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Stainless Steels for Design Engineers by : Michael F. McGuire
Download or read book Stainless Steels for Design Engineers written by Michael F. McGuire and published by ASM International. This book was released on 2008 with total page 311 pages. Available in PDF, EPUB and Kindle. Book excerpt: The rate of growth of stainless steel has outpaced that of other metals and alloys, and by 2010 may surpass aluminum as the second most widely used metal after carbon steel. The 2007 world production of stainless steel was approximately 30,000,000 tons and has nearly doubled in the last ten years. This growth is occurring at the same time that the production of stainless steel continues to become more consolidated. One result of this is a more widespread need to understand stainless steel with fewer resources to provide that information. The concurrent technical evolution in stainless steel and increasing volatility of raw material prices has made it more important for the engineers and designers who use stainless steel to make sound technical judgments about which stainless steels to use and how to use them.
Book Synopsis Electro-Fenton Process by : Minghua Zhou
Download or read book Electro-Fenton Process written by Minghua Zhou and published by Springer. This book was released on 2017-11-25 with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume discusses the theoretical fundamentals and potential applications of the original electro-Fenton (EF) process and its most innovative and promising versions, all of which are classified as electrochemical advanced oxidation processes. It consists of 15 chapters that review the latest advances and trends, material selection, reaction and reactor modeling and EF scale-up. It particularly focuses on the applications of EF process in the treatment of toxic and persistent organic pollutants in water and soil, showing highly efficient removal for both lab-scale and pre-pilot setups. Indeed, the EF technology is now mature enough to be brought to market, and this collection of contributions from leading experts in the field constitutes a timely milestone for scientists and engineers.
Book Synopsis Pyrolysis of Biomass by : Shurong Wang
Download or read book Pyrolysis of Biomass written by Shurong Wang and published by Walter de Gruyter GmbH & Co KG. This book was released on 2016-12-05 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: With the development of societies fossil energy is no longer the only energy resource, and increasing attention had been paid to alternative energy. Biomass is considered to be one of the alternatives due to efficiency and low cost. This book presents biomass pyrolysis behavior for three main components: Cellulose, Hemicellulose and Lignin, and discusses the influence of mineral salts , zeolite catalysts and metal oxide on their pyrolysis.
Book Synopsis Fuel Production with Heterogeneous Catalysis by : Jacinto Sa
Download or read book Fuel Production with Heterogeneous Catalysis written by Jacinto Sa and published by CRC Press. This book was released on 2014-09-16 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fuel Production with Heterogeneous Catalysis presents the groundbreaking discoveries, recent developments, and future perspectives of one of the most important areas of renewable energy research—the heterogeneous catalytic production of fuels. Comprised of chapters authored by leading experts in the field, this authoritative text: Focuses primarily on the state-of-the-art catalysts and catalytic processes anticipated to play a pivotal role in the production of fuels Describes production of fuels from renewable sources using environmentally friendly technologies Exposes the advantages and disadvantages of each production process Suggests solutions to minimize the impact of fuel transportation Conveys the importance of catalysis for the sustainable production of fuels Fuel Production with Heterogeneous Catalysis delivers a comprehensive overview of the current state of the art of the heterogeneous catalytic production of fuels, providing reaction mechanism schemes, engineering solutions, valuable industry insights, and more.
Book Synopsis Catalytic Hydrogenation for Biomass Valorization by : Roberto Rinaldi
Download or read book Catalytic Hydrogenation for Biomass Valorization written by Roberto Rinaldi and published by Royal Society of Chemistry. This book was released on 2015 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: As the biorefinery industry expands to meet the latest discoveries in biomass conversion, this book provides a thorough grounding in the subject.
Book Synopsis Developments in Thermochemical Biomass Conversion by : A.V. Bridgwater
Download or read book Developments in Thermochemical Biomass Conversion written by A.V. Bridgwater and published by Springer Science & Business Media. This book was released on 2013-11-21 with total page 1630 pages. Available in PDF, EPUB and Kindle. Book excerpt: There have been many developments in the science and technology of thermo chemical biomass conversion since the previous conference on Advances in Thermochemical Biomass Conversion in Interlaken, Switzerland, in 1992. This fourth conference again covers all aspects of thermal biomass conversion systems from fundamental research through applied research and development to demon stration and commercial applications to reflect the progress made in the last four years. All aspects of bioenergy systems are covered from pretreatment through to end-user applications with increased consideration paid to the environmental benefits and problems of implementing bio-energy systems. There was an excellent response with over 200 papers offered and over 180 delegates from 29 countries attending the conference. The programme was divided into five main areas covering pyrolysis, pretreatment, gasification, combustion and system studies and this division is reflected in the structure of these conference proceedings. Each main section was preceded by a state-of-the-art review to provide a focus for the ensuing presentations and an authoritative reference. All the papers included have been subject to a full peer review process. As with any international conference, an important aim was to exchange ideas and discuss problems with fellow researchers, as well as to hear about the latest research and development and applications. A workshop programme was included to encourage this interaction in areas of interest selected by participants. The resul tant workshop reports provide a summary of topical problems and opportunities.
Book Synopsis Recent Advances in Thermochemical Conversion of Biomass by : Ashok Pandey
Download or read book Recent Advances in Thermochemical Conversion of Biomass written by Ashok Pandey and published by Elsevier. This book was released on 2015-01-28 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides general information and data on one of the most promising renewable energy sources: biomass for its thermochemical conversion. During the last few years, there has been increasing focus on developing the processes and technologies for the conversion of biomass to liquid and gaseous fuels and chemicals, in particular to develop low-cost technologies. This book provides date-based scientific information on the most advanced and innovative processing of biomass as well as the process development elements on thermochemical processing of biomass for the production of biofuels and bio-products on (biomass-based biorefinery). The conversion of biomass to biofuels and other value-added products on the principle biorefinery offers potential from technological perspectives as alternate energy. The book covers intensive R&D and technological developments done during the last few years in the area of renewable energy utilizing biomass as feedstock and will be highly beneficial for the researchers, scientists and engineers working in the area of biomass-biofuels- biorefinery. Provides the most advanced and innovative thermochemical conversion technology for biomass Provides information on large scales such as thermochemical biorefinery Useful for researchers intending to study scale up Serves as both a textbook for graduate students and a reference book for researchers Provides information on integration of process and technology on thermochemical conversion of biomass
Book Synopsis The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals by : Kostas Triantafyllidis
Download or read book The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals written by Kostas Triantafyllidis and published by Newnes. This book was released on 2013-03-19 with total page 607 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals describes the importance of catalysis for the sustainable production of biofuels and biochemicals, focused primarily on the state-of-the-art catalysts and catalytic processes expected to play a decisive role in the "green" production of fuels and chemicals from biomass. In addition, the book includes general elements regarding the entire chain of biomass production, conversion, environment, economy, and life-cycle assessment. Very few books are available on catalysis in production schemes using biomass or its primary conversion products, such as bio-oil and lignin. This book fills that gap with detailed discussions of: Catalytic pyrolysis of lignocellulosic biomass Hybrid biogasoline by co-processing in FCC units Fischer-Tropsch synthesis to biofuels (biomass-to-liquid process) Steam reforming of bio-oils to hydrogen With energy prices rapidly rising, environmental concerns growing, and regulatory apparatus evolving, this book is a resource with tutorial, research, and technological value for chemists, chemical engineers, policymakers, and students. Includes catalytic reaction mechanism schemes and gives a clear understanding of catalytic processes Includes flow diagrams of bench-, pilot- and industrial-scale catalytic processing units and demonstrates the various process technologies involved, enabling easy selection of the best process Incorporates many tables, enabling easy comparison of data based on a critical review of the available literature
Book Synopsis Zeolites and Catalysis by : Jiri Cejka
Download or read book Zeolites and Catalysis written by Jiri Cejka and published by John Wiley & Sons. This book was released on 2010-05-27 with total page 918 pages. Available in PDF, EPUB and Kindle. Book excerpt: This indispensable two-volume handbook covers everything on this hot research field. The first part deals with the synthesis, modification, characterization and application of catalytic active zeolites, while the second focuses on such reaction types as cracking, hydrocracking, isomerization, reforming and other industrially important topics. Edited by a highly experienced and internationally renowned team with chapters written by the "Who's Who" of zeolite research.
Book Synopsis Biorefinery by : Juan-Rodrigo Bastidas-Oyanedel
Download or read book Biorefinery written by Juan-Rodrigo Bastidas-Oyanedel and published by Springer. This book was released on 2019-04-15 with total page 763 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses the biorefinery of biomass feedstocks. In-depth chapters highlight the scientific and technical aspects and present a techno-economic analysis of such systems. By using a TEA approach, the authors present feasible pathways for conversion of biomass (both residual biomass, energy crops and algae biomass), showing the different possibilities for the production of biochemical materials, biofuels, and fertilizers. The concepts presented in this book will link companies, investors, and governments by providing a framework that will help reduce pollutants and create a biomass related economy that incorporates the newest developments and technologies in the area.
