Assessment of Supercritical Water Oxidation System Testing for the Blue Grass Chemical Agent Destruction Pilot Plant

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Publisher : National Academies Press
ISBN 13 : 0309287324
Total Pages : 119 pages
Book Rating : 4.3/5 (92 download)

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Book Synopsis Assessment of Supercritical Water Oxidation System Testing for the Blue Grass Chemical Agent Destruction Pilot Plant by : National Research Council

Download or read book Assessment of Supercritical Water Oxidation System Testing for the Blue Grass Chemical Agent Destruction Pilot Plant written by National Research Council and published by National Academies Press. This book was released on 2013-10-10 with total page 119 pages. Available in PDF, EPUB and Kindle. Book excerpt: Assessment of Supercritical Water Oxidation System Testing for the Blue Grass Chemical Agent Destruction Pilot Plant reviews and evaluates the results of the tests conducted on one of the SCWO units to be provided to Blue Grass Chemical Agent Destruction Pilot Plant. The Army Element, Assembled Chemical Weapons Alternatives (ACWA) is responsible for managing the conduct of destruction operations for the remaining 10 percent of the nation's chemical agent stockpile, stored at the Blue Grass Army Depot (Kentucky) and the Pueblo Chemical Depot (Colorado). Facilities to destroy the agents and their associated munitions are currently being constructed at these sites. The Blue Grass Chemical Agent Destruction Pilot Plant (BGCAPP) will destroy chemical agent and some associated energetic materials by a process of chemical neutralization known as hydrolysis. The resulting chemical waste stream is known as hydrolysate. Among the first-of-a-kind equipment to be installed at BGCAPP are three supercritical water oxidation (SCWO) reactor systems. These particular hydrolysate feeds present unique non-agent-related challenges to subsequent processing via SCWO due to their caustic nature and issues of salt management.This report provides recommendations on SCWO systemization testing inclusive of durability testing and discusses systemization testing objectives and concepts.

Metrics for Successful Supercritical Water Oxidation System Operation at the Blue Grass Chemical Agent Destruction Pilot Plant

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Publisher :
ISBN 13 : 9780309490252
Total Pages : 30 pages
Book Rating : 4.4/5 (92 download)

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Book Synopsis Metrics for Successful Supercritical Water Oxidation System Operation at the Blue Grass Chemical Agent Destruction Pilot Plant by : Engineering National Academies of Sciences (and Medicine)

Download or read book Metrics for Successful Supercritical Water Oxidation System Operation at the Blue Grass Chemical Agent Destruction Pilot Plant written by Engineering National Academies of Sciences (and Medicine) and published by . This book was released on 2019 with total page 30 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Review Criteria for Successful Treatment of Hydrolysate at the Blue Grass Chemical Agent Destruction Pilot Plant

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Publisher : National Academies Press
ISBN 13 : 0309376432
Total Pages : 194 pages
Book Rating : 4.3/5 (93 download)

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Book Synopsis Review Criteria for Successful Treatment of Hydrolysate at the Blue Grass Chemical Agent Destruction Pilot Plant by : National Academies of Sciences, Engineering, and Medicine

Download or read book Review Criteria for Successful Treatment of Hydrolysate at the Blue Grass Chemical Agent Destruction Pilot Plant written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2015-10-05 with total page 194 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1993, the United States signed the Chemical Weapons Convention (CWC), an international treaty outlawing the production, stockpiling, and use of chemical weapons. The chemical weapons stockpiles at five of the U.S. chemical weapons storage sites have now been destroyed. At those sites, the munitions were robotically opened and the chemical agent was removed, collected, and incinerated. One of the remaining sites with chemical weapons stockpiles is the Blue Grass Army Depot near Richmond, Kentucky. In this case, caustic hydrolysis will be used to destroy the agents and energetics, resulting in a secondary waste stream known as hydrolysate. Review Criteria for Successful Treatment of Hydrolysate at the Blue Grass Chemical Agent Destruction Pilot Plant develops criteria for successfully treating the hydrolysate, identifies systemization data that should factor into the criteria/decision process, suggests potential modifications to suggested treatment that would allow continued onsite processing, and assesses waste disposal procedures. This study further examines the possibility of delay or failure of the existing technology and examines possible alternatives to onsite treatment.

Interim Design Assessment for the Blue Grass Chemical Agent Destruction Pilot Plant

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Publisher : National Academies Press
ISBN 13 : 0309096987
Total Pages : 94 pages
Book Rating : 4.3/5 (9 download)

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Book Synopsis Interim Design Assessment for the Blue Grass Chemical Agent Destruction Pilot Plant by : National Research Council

Download or read book Interim Design Assessment for the Blue Grass Chemical Agent Destruction Pilot Plant written by National Research Council and published by National Academies Press. This book was released on 2005-11-25 with total page 94 pages. Available in PDF, EPUB and Kindle. Book excerpt: Because of concerns about incineration, the Department of Defense plans to use alternative means to destroy the chemical agent stockpiles at the Pueblo and Blue Grass facilities. The DOD contracted with Bechtel Parsons to design and operate pilot plants for this purpose. As part of the NRC efforts to assist the DOD with its chemical demilitarization efforts, the Department requested a review and assessment of the Bechtel designs for both plants. An earlier report presented an assessment of the Pueblo design. This report provides a review of the Blue Grass Chemical Agent Destruction Pilot Plant based on review of data and information about the initial design and some intermediate design data. Among other topics, the report presents technical risk assessment issues, an analysis of delivery and disassembly operations and of agent destruction core processes, and an examination of waste treatment.

Assessment of Approaches for Using Process Safety Metrics at the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants

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Publisher : National Academies Press
ISBN 13 : 0309215072
Total Pages : 60 pages
Book Rating : 4.3/5 (92 download)

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Book Synopsis Assessment of Approaches for Using Process Safety Metrics at the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants by : National Research Council

Download or read book Assessment of Approaches for Using Process Safety Metrics at the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants written by National Research Council and published by National Academies Press. This book was released on 2011-04-19 with total page 60 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Department of Defense, through the Assembled Chemical Weapons Alternatives program, is currently in the process of constructing two full-scale pilot plants at the Pueblo Chemical Depot in Colorado and the Blue Grass Army Depot in Kentucky to destroy the last two remaining inventories of chemical weapons in the U.S. stockpile. These two storage sites together account for about 10 percent of the original U.S. chemical agent stockpile that is in the process of being destroyed in accordance with the international Chemical Weapons Convention treaty. Unlike their predecessors, these facilities will use neutralization technologies to destroy agents contained within rockets, projectiles, and mortar rounds, requiring the use of specially designed equipment. As part of its focus on safe operation of the planned facilities, the Program Manager for Assembled Chemical Weapons Alternatives asked the National Research Council (NRC) to conduct a study to offer guidance on the application of process safety metrics at the Pueblo Chemical Depot and Blue Grass Army Depot. Process safety is a disciplined framework for managing the integrity of operating systems, processes and personnel handling hazardous substances, and operations by applying good design principles, engineering, and operating practices. Process Safety Metrics at the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants discusses the use of leading and lagging process safety metrics that could provide feedback on the effectiveness of controls to mitigate risks and minimize consequences of potential incidents. The book makes several recommendations that will facilitate the development and application of process safety metrics at both sites.

Alternatives for the Demilitarization of Conventional Munitions

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Publisher : National Academies Press
ISBN 13 : 0309477352
Total Pages : 133 pages
Book Rating : 4.3/5 (94 download)

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Book Synopsis Alternatives for the Demilitarization of Conventional Munitions by : National Academies of Sciences, Engineering, and Medicine

Download or read book Alternatives for the Demilitarization of Conventional Munitions written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2019-01-11 with total page 133 pages. Available in PDF, EPUB and Kindle. Book excerpt: The U.S. military has a stockpile of approximately 400,000 tons of excess, obsolete, or unserviceable munitions. About 60,000 tons are added to the stockpile each year. Munitions include projectiles, bombs, rockets, landmines, and missiles. Open burning/open detonation (OB/OD) of these munitions has been a common disposal practice for decades, although it has decreased significantly since 2011. OB/OD is relatively quick, procedurally straightforward, and inexpensive. However, the downside of OB and OD is that they release contaminants from the operation directly into the environment. Over time, a number of technology alternatives to OB/OD have become available and more are in research and development. Alternative technologies generally involve some type of contained destruction of the energetic materials, including contained burning or contained detonation as well as contained methods that forego combustion or detonation. Alternatives for the Demilitarization of Conventional Munitions reviews the current conventional munitions demilitarization stockpile and analyzes existing and emerging disposal, treatment, and reuse technologies. This report identifies and evaluates any barriers to full-scale deployment of alternatives to OB/OD or non-closed loop incineration/combustion, and provides recommendations to overcome such barriers.

Assessment of Explosive Destruction Technologies for Specific Munitions at the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants

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Publisher : National Academies Press
ISBN 13 : 0309126835
Total Pages : 134 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Assessment of Explosive Destruction Technologies for Specific Munitions at the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants by : National Research Council

Download or read book Assessment of Explosive Destruction Technologies for Specific Munitions at the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants written by National Research Council and published by National Academies Press. This book was released on 2009-05-22 with total page 134 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Army's ability to meet public and congressional demands to destroy expeditiously all of the U.S. declared chemical weapons would be enhanced by the selection and acquisition of appropriate explosive destruction technologies (EDTs) to augment the main technologies to be used to destroy the chemical weapons currently at the Blue Grass Army Depot (BGAD) in Kentucky and the Pueblo Chemical Depot (PCD) in Colorado. The Army is considering four EDTs for the destruction of chemical weapons: three from private sector vendors, and a fourth, Army-developed explosive destruction system (EDS). This book updates earlier evaluations of these technologies, as well as any other viable detonation technologies, based on several considerations including process maturity, process efficacy, process throughput, process safety, public and regulatory acceptability, and secondary waste issues, among others. It also provides detailed information on each of the requirements at BGAD and PCD and rates each of the existing suitable EDTs plus the Army's EDS with respect to how well it satisfies these requirements.

Letter Report on the Blue Grass Chemical Agent Destruction Pilot Plant's Water Recovery System

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Publisher :
ISBN 13 :
Total Pages : 52 pages
Book Rating : 4.:/5 (83 download)

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Book Synopsis Letter Report on the Blue Grass Chemical Agent Destruction Pilot Plant's Water Recovery System by :

Download or read book Letter Report on the Blue Grass Chemical Agent Destruction Pilot Plant's Water Recovery System written by and published by . This book was released on 2012 with total page 52 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Letter Report on the Blue Grass Chemical Agent Destruction Pilot Plant's Water Recovery System

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Publisher :
ISBN 13 :
Total Pages : 52 pages
Book Rating : 4.:/5 (83 download)

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Book Synopsis Letter Report on the Blue Grass Chemical Agent Destruction Pilot Plant's Water Recovery System by : National Research Council (U.S.). Committee to Review the Water Recovery System for the Blue Grass Chemical Agent Destruction Pilot Plant

Download or read book Letter Report on the Blue Grass Chemical Agent Destruction Pilot Plant's Water Recovery System written by National Research Council (U.S.). Committee to Review the Water Recovery System for the Blue Grass Chemical Agent Destruction Pilot Plant and published by . This book was released on 2012 with total page 52 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Workshop on Federal Programs Involving Supercritical Water Oxidation

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Publisher : DIANE Publishing
ISBN 13 : 9780788100420
Total Pages : 318 pages
Book Rating : 4.1/5 (4 download)

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Book Synopsis Workshop on Federal Programs Involving Supercritical Water Oxidation by : Gregory J. Rosasco

Download or read book Workshop on Federal Programs Involving Supercritical Water Oxidation written by Gregory J. Rosasco and published by DIANE Publishing. This book was released on 1993-12 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers: energy recovery, space life support applications, hazardous waste, shipboard applications, conventional munitions, therodynamics and kinetics, and much more. Graphs and diagrams.

Supercritical Water Oxidation Data Acquisition Testing

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (684 download)

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Book Synopsis Supercritical Water Oxidation Data Acquisition Testing by :

Download or read book Supercritical Water Oxidation Data Acquisition Testing written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Supercritical Water Oxidation (SCWO) is a high pressure oxidation process that blends air, water, and organic waste material in an oxidizer in which where the temperature and pressure in the oxidizer are maintained above the critical point of water. Supercritical water mixed with hydrocarbons, which would be insoluble at subcritical conditions, forms a homogeneous phase which possesses properties associated with both a gas and a liquid. Hydrocarbons in contact with oxygen and SCW are readily oxidized. These properties of SCW make it an attractive means for the destruction of waste streams containing organic materials. SCWO technology holds great promise for treating mixed wastes in an environmentally safe and efficient manner. In the spring of 1994 the U.S. Department of Energy (DOE) initiated a Supercritical Water Oxidation Data Acquisition Testing (SCWODAT) program. The SCWODAT program provided further information and operational data on the effectiveness of treating both simulated mixed waste and typical Navy hazardous waste using the SCWO technology. The program concentrated on the acquisition of data through pilot plant testing. The Phase I DOE testing used a simulated waste stream that contained a complex machine cutting oil and metals, that acted as surrogates for radionuclides. The Phase II Navy testing included pilot testing using hazardous waste materials to demonstrate the effectiveness of the SCWO technology. The SCWODAT program demonstrated that the SCWO process oxidized the simulated waste stream containing complex machine cutting oil, selected by DOE as representative of one of the most difficult of the organic waste streams for which SCWO had been applied. The simulated waste stream with surrogate metals in solution was oxidized, with a high destruction efficiency, on the order of 99.97%, in both the neutralized and unneutralized modes of operation.

Assessment of Supercritical Water Oxidation Technology Development for Treatment of VX Hydrolysate at the Newport Chemical Agent Disposal Facility

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (87 download)

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Book Synopsis Assessment of Supercritical Water Oxidation Technology Development for Treatment of VX Hydrolysate at the Newport Chemical Agent Disposal Facility by :

Download or read book Assessment of Supercritical Water Oxidation Technology Development for Treatment of VX Hydrolysate at the Newport Chemical Agent Disposal Facility written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Supercritical Water Oxidation Program (SCWOP)

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ISBN 13 :
Total Pages : 34 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis Supercritical Water Oxidation Program (SCWOP) by : United States. Department of Energy

Download or read book Supercritical Water Oxidation Program (SCWOP) written by United States. Department of Energy and published by . This book was released on 1994 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Federal Register

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Publisher :
ISBN 13 :
Total Pages : 324 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis Federal Register by :

Download or read book Federal Register written by and published by . This book was released on 2002-05-30 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt:

EIS Cumulative

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ISBN 13 :
Total Pages : 374 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis EIS Cumulative by :

Download or read book EIS Cumulative written by and published by . This book was released on 2002 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Destruction of Chemical Agent Simulants in Supercritical Water Oxidation

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Publisher :
ISBN 13 :
Total Pages : 176 pages
Book Rating : 4.:/5 (355 download)

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Book Synopsis Destruction of Chemical Agent Simulants in Supercritical Water Oxidation by : Michael R. Blank

Download or read book Destruction of Chemical Agent Simulants in Supercritical Water Oxidation written by Michael R. Blank and published by . This book was released on 1992 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt:

An Evaluation of Supercritical Water Oxidation Technology

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Publisher :
ISBN 13 :
Total Pages : 57 pages
Book Rating : 4.:/5 (56 download)

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Book Synopsis An Evaluation of Supercritical Water Oxidation Technology by : David Neil Kupferer

Download or read book An Evaluation of Supercritical Water Oxidation Technology written by David Neil Kupferer and published by . This book was released on 2002 with total page 57 pages. Available in PDF, EPUB and Kindle. Book excerpt: