Anodic oxidation of uo2 part i. electrochemical and x-ray photoelectron spectroscopic studies in neutral solutions

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Book Synopsis Anodic oxidation of uo2 part i. electrochemical and x-ray photoelectron spectroscopic studies in neutral solutions by : S. Sunder

Download or read book Anodic oxidation of uo2 part i. electrochemical and x-ray photoelectron spectroscopic studies in neutral solutions written by S. Sunder and published by . This book was released on 1981 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Anodic oxidation of uo2. part ii. electrochemical and x-ray photoelectron spectroscopic studies in alkaline solutions

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Book Synopsis Anodic oxidation of uo2. part ii. electrochemical and x-ray photoelectron spectroscopic studies in alkaline solutions by : S. Sunder

Download or read book Anodic oxidation of uo2. part ii. electrochemical and x-ray photoelectron spectroscopic studies in alkaline solutions written by S. Sunder and published by . This book was released on 1983 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Anodic oxidation of uo2. v. electrochemical and x-ray photoelectron spectroscopic studies of film-growth and dissolution in phosphate-containing solutions

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Book Synopsis Anodic oxidation of uo2. v. electrochemical and x-ray photoelectron spectroscopic studies of film-growth and dissolution in phosphate-containing solutions by : D. W. Shoesmith

Download or read book Anodic oxidation of uo2. v. electrochemical and x-ray photoelectron spectroscopic studies of film-growth and dissolution in phosphate-containing solutions written by D. W. Shoesmith and published by . This book was released on 1988 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Anodic oxidation of uo2. iv. x-ray photoelectron spectroscopic and electrochemical studies of film growth in carbonate-containing solutions

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Book Synopsis Anodic oxidation of uo2. iv. x-ray photoelectron spectroscopic and electrochemical studies of film growth in carbonate-containing solutions by : D. W. Shoesmith

Download or read book Anodic oxidation of uo2. iv. x-ray photoelectron spectroscopic and electrochemical studies of film growth in carbonate-containing solutions written by D. W. Shoesmith and published by . This book was released on 1984 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

High Level Radioactive Waste Management

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Total Pages : 1110 pages
Book Rating : 4.3/5 (91 download)

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Download or read book High Level Radioactive Waste Management written by and published by . This book was released on 1994 with total page 1110 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Proceedings, ... Annual Conference

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Total Pages : 512 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis Proceedings, ... Annual Conference by : Canadian Nuclear Society. Conference

Download or read book Proceedings, ... Annual Conference written by Canadian Nuclear Society. Conference and published by . This book was released on 1988 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Extended Abstracts

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Total Pages : 1004 pages
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Book Synopsis Extended Abstracts by : Electrochemical Society

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Environmental Geochemistry

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Total Pages : 328 pages
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Download or read book Environmental Geochemistry written by and published by . This book was released on 1984 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Anodic oxidation of uo2-part iii. electrochemical studies in carbonate solutions

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Book Synopsis Anodic oxidation of uo2-part iii. electrochemical studies in carbonate solutions by : D. W. Shoesmith

Download or read book Anodic oxidation of uo2-part iii. electrochemical studies in carbonate solutions written by D. W. Shoesmith and published by . This book was released on 1983 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Development of a Kinetic Model to Predict the Rate of Oxidation and Dissolution of Nuclear Fuel (UO@) by the Radiolysis of Water

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Publisher : Pinewa, Man. : Whiteshell Laboratories
ISBN 13 :
Total Pages : 44 pages
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Book Synopsis Development of a Kinetic Model to Predict the Rate of Oxidation and Dissolution of Nuclear Fuel (UO@) by the Radiolysis of Water by : H. Christensen

Download or read book Development of a Kinetic Model to Predict the Rate of Oxidation and Dissolution of Nuclear Fuel (UO@) by the Radiolysis of Water written by H. Christensen and published by Pinewa, Man. : Whiteshell Laboratories. This book was released on 1994 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radiolysis of groundwater would produce oxidants and reductants that could affect the oxidation and dissolution of used fuel (UO2) placed in a geological disposal vault. To avoid the extensive experimentation involved, a kinetic model originally proposed by Christensen and Bjergbakke to predict the rate of UO2 dissolution induced by water radiolysis is being refined. This report summarizes the understanding of the mechanisms of oxidation and dissolution of UO2 as well as other pertinent experimental results used in then of UO2 as well as other pertinent experimental results used in the refinement of the original model. The model and its refinements are described and the rates predicted are presented. These predicted dissolution rates are then compared with the rates determined from the electro-chemical model. The limitations and necessary further developments are then discussed.

Canadian Journal of Civil Engineering

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Total Pages : 1034 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Canadian Journal of Civil Engineering by :

Download or read book Canadian Journal of Civil Engineering written by and published by . This book was released on 1989 with total page 1034 pages. Available in PDF, EPUB and Kindle. Book excerpt:

List of Publications

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Total Pages : 576 pages
Book Rating : 4.:/5 (3 download)

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Book Synopsis List of Publications by : Atomic Energy of Canada Limited

Download or read book List of Publications written by Atomic Energy of Canada Limited and published by . This book was released on 1976-04 with total page 576 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Canadian Journal of Chemistry

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Total Pages : 572 pages
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Book Synopsis Canadian Journal of Chemistry by :

Download or read book Canadian Journal of Chemistry written by and published by . This book was released on 1988 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Physics Briefs

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Total Pages : 934 pages
Book Rating : 4.3/5 (91 download)

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Download or read book Physics Briefs written by and published by . This book was released on 1986 with total page 934 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Electroanalytical Abstracts

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Total Pages : 1148 pages
Book Rating : 4.:/5 (6 download)

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Download or read book Electroanalytical Abstracts written by and published by . This book was released on 1982 with total page 1148 pages. Available in PDF, EPUB and Kindle. Book excerpt: International journal dealing with the documentation of all aspects of fundamental, physico-chemical and analytical electrochemistry.

Nuclear Technology

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Total Pages : 478 pages
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Book Synopsis Nuclear Technology by :

Download or read book Nuclear Technology written by and published by . This book was released on 1990 with total page 478 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Anodic dissolution of uo2 in slightly alkaline sodium perchlorate solutions

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Book Synopsis Anodic dissolution of uo2 in slightly alkaline sodium perchlorate solutions by : S. Sunder

Download or read book Anodic dissolution of uo2 in slightly alkaline sodium perchlorate solutions written by S. Sunder and published by . This book was released on 1996 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The anodic dissolution of uo2 has been studied in aqueous sodium perchlorate solutions at ph approximately 9.5. under potentiostatic conditions two distinct regions of oxidation/dissolution behaviour were observed. in the potential (e) range 0.100 v approximately e approximately 0.350 v (vs. sce) currents decayed continuously with time due to the formation of oxidized surface films which gradually blocked further oxidation of the electrode. steady-state currents were not achieved even after 24 hours. on the basis of anodic and cathodic charges (q sub(a), q sub(c) respectively) obtained by integration of the anodic current-time plots (q sub(a)) and cathodic potential scans to reduce accumulated oxidized surface films (q sub(c)), it was shown that approximately 90% of the anodic oxidation current went to produce these films. for e approximately 0.350 v, steady-state currrents were obtained and measurements of q sub(a) and q sub(c) showed the majority of the current went to produce soluble species. the film blocking anodic dissolution appeared to be either uo sub(2.67) or, more probably, uo3 middle dot 2h2o located primarily at grain boundaries. it is proposed that, at the higher potentials, rapid oxidation and dissolution followed by the hydrolysis of dissolved uranyl species leads to the development of acidic conditions in the grain boundaries. at these lower ph values the uo3 middle dot 2h2o is soluble and therefore does not accumulate. alternatively, if this oxide has been formed by prior oxidation at a lower potential, the formation of protons on oxidizing at e > approximately 0.350v causes its redissolution, allowing the current to rise to a steady-state value. on the basis of tafel slopes, an attempt was made to demonstrate that the observed behaviour was consistent with dissolution under acidic conditions. this analysis was only partially successful.