Activation of Unreactive Bonds and Organic Synthesis

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Publisher : Springer Science & Business Media
ISBN 13 : 3540648623
Total Pages : 275 pages
Book Rating : 4.5/5 (46 download)

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Book Synopsis Activation of Unreactive Bonds and Organic Synthesis by : Shinji Murai

Download or read book Activation of Unreactive Bonds and Organic Synthesis written by Shinji Murai and published by Springer Science & Business Media. This book was released on 1999-04-16 with total page 275 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts

Activation of Unreactive Bonds and Organic Synthesis

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Author :
Publisher : Springer
ISBN 13 : 3540685251
Total Pages : 275 pages
Book Rating : 4.5/5 (46 download)

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Book Synopsis Activation of Unreactive Bonds and Organic Synthesis by : Shinji Murai

Download or read book Activation of Unreactive Bonds and Organic Synthesis written by Shinji Murai and published by Springer. This book was released on 2003-07-01 with total page 275 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last few years a large repetoire of methods for the activation of unreactive organic functionalities and for their use in organic synthesis has been developed. In this volume, areas ranging from the activation of C-H bonds to the chemical transformation of dinitrogen are authoritatively discussed by leading experts in the field. To activate means to be able to cleave otherwise inert chemical bonds. The cleavage and formation of chemical bonds is fundamental to organic synthesis; these new activation methodologies make hitherto infeasible reactions extremely easy and create new opportunities for innovative organic transformations, for both industry and academia. This is the first book that provides a thorough and timely coverage of both inorganic and organic synthetic aspects of bond activation, thus giving a broad overview of the field and allowing both inorganic and organic chemists ready access to the methodologies involved.

Activation of Unreactive Bonds and Organic Synthesis

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Author :
Publisher : Springer
ISBN 13 : 9783662142516
Total Pages : 288 pages
Book Rating : 4.1/5 (425 download)

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Book Synopsis Activation of Unreactive Bonds and Organic Synthesis by : Shinji Murai

Download or read book Activation of Unreactive Bonds and Organic Synthesis written by Shinji Murai and published by Springer. This book was released on 2014-01-15 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last few years a large repetoire of methods for the activation of unreactive organic functionalities and for their use in organic synthesis has been developed. In this volume, areas ranging from the activation of C-H bonds to the chemical transformation of dinitrogen are authoritatively discussed by leading experts in the field. To activate means to be able to cleave otherwise inert chemical bonds. The cleavage and formation of chemical bonds is fundamental to organic synthesis; these new activation methodologies make hitherto infeasible reactions extremely easy and create new opportunities for innovative organic transformations, for both industry and academia. This is the first book that provides a thorough and timely coverage of both inorganic and organic synthetic aspects of bond activation, thus giving a broad overview of the field and allowing both inorganic and organic chemists ready access to the methodologies involved.

Homogeneous Catalysis for Unreactive Bond Activation

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 1118788990
Total Pages : 791 pages
Book Rating : 4.1/5 (187 download)

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Book Synopsis Homogeneous Catalysis for Unreactive Bond Activation by : Zhang-Jie Shi

Download or read book Homogeneous Catalysis for Unreactive Bond Activation written by Zhang-Jie Shi and published by John Wiley & Sons. This book was released on 2014-10-17 with total page 791 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive overview of different catalytic reactions applied to the activation of chemical bonds. Each of the seven chapters covers key C-X classes where carbon is combined with another element: chlorine, fluorine, nitrogen, sulfur, oxygen, hydrogen, and carbon. The first part of the book discusses homogeneous catalysis in the activation and transformation of C-Cl and C-F, highlighting their basic activation modes, cross-coupling, and intensive mechanisms. The second part of the book focuses on C-N, C-S, and C-O bonds, mentioning their catalytic pathways. Finally, C-H and C-C bonds, their activation, chemical transformations, and applicability are covered. Overall, the book presents methodologies that can be applied to the efficient synthesis of drug molecules and fine chemicals. Through their presentation, the authors show that synthetic chemistry can be done in greener ways that limit hazards and pollution.

Activating Unreactive Substrates

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Publisher : John Wiley & Sons
ISBN 13 : 3527318232
Total Pages : 483 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Activating Unreactive Substrates by : Carsten Bolm

Download or read book Activating Unreactive Substrates written by Carsten Bolm and published by John Wiley & Sons. This book was released on 2009-03-02 with total page 483 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of secondary interactions for the activation of non-reactive substrates constitutes a new and modern approach in catalysis. This first comprehensive treatment of this important research field covers the entire field and reveals the links between the various chemical disciplines. It thus adopts an interdisciplinary approach, making it of interest to the whole chemical community. A must for organic, inorganic, catalytic and complex chemists, as well as those working with/on organometallics.

Amide Bond Activation

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Publisher : MDPI
ISBN 13 : 3039212036
Total Pages : 466 pages
Book Rating : 4.0/5 (392 download)

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Book Synopsis Amide Bond Activation by : Michal Szostak

Download or read book Amide Bond Activation written by Michal Szostak and published by MDPI. This book was released on 2019-07-12 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt: The amide bond represents a privileged motif in chemistry. The recent years have witnessed an explosion of interest in the development of new chemical transformations of amides. These developments cover an impressive range of catalytic N–C bond activation in electrophilic, Lewis acid, radical, and nucleophilic reaction pathways, among other transformations. Equally relevant are structural and theoretical studies that provide the basis for chemoselective manipulation of amidic resonance. This monograph on amide bonds offers a broad survey of recent advances in activation of amides and addresses various approaches in the field.

Activation and Functionalization of C-H Bonds

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Publisher : ACS Symposium
ISBN 13 : 9780841238497
Total Pages : 0 pages
Book Rating : 4.2/5 (384 download)

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Book Synopsis Activation and Functionalization of C-H Bonds by : Karen I. Goldberg

Download or read book Activation and Functionalization of C-H Bonds written by Karen I. Goldberg and published by ACS Symposium. This book was released on 2004 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Activation and Functionalization of C-H Bonds explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationally leading research groups contributed to this volume, and their chapters cover such topics as fundamental theoretical and mechanistic studies of C-H bond activation by metal complexes, catalytic systems for alkane functionalization, and new applications in synthetic organic chemistry. An introductory chapter offers an overview of stoichiometric and catalytic reactions of C-H bonds with transition metal complexes. The C-H bond is the most widespread linkage in organic chemistry, present in virtually every organic molecule. Unfortunately, C-H bonds are famously resistant to selective chemical transformations. The development of methods for their selective transformations has enormous potential value in fields ranging from the chemistry of fuels (for example, the conversion of methane to methanol) to the synthesis of the most complex organic molecules.

Nickel Catalysis in Organic Synthesis

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Publisher : John Wiley & Sons
ISBN 13 : 3527344071
Total Pages : 348 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Nickel Catalysis in Organic Synthesis by : Sensuke Ogoshi

Download or read book Nickel Catalysis in Organic Synthesis written by Sensuke Ogoshi and published by John Wiley & Sons. This book was released on 2020-03-09 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive reference to nickel chemistry for every scientist working with organometallic catalysts Written by one of the world?s leading reseachers in the field, Nickel Catalysis in Organic Synthesis presents a comprehensive review of the high potential of modern nickel catalysis and its application in synthesis. Structured in a clear and assessible manner, the book offers a collection of various reaction types, such as cross-coupling reactions, reactions for the activation of unreactive bonds, carbon dioxide fixation, and many more. Nickel has been recognized as one of the most interesting transition metals for homogeneous catalysis. This book offers an overview to the recently developed new ligands, new reaction conditions, and new apparatus to control the reactivity of nickel catalysts, allowing scientists to apply nickel catalysts to a variety of bond-forming reactions. A must-read for anyone working with organometallic compounds and their application in organic synthesis, this important guide: -Reviews the numerous applications of nickel catalysis in synthesis -Explores the use of nickel as a relatively cheap and earth-abundant metal -Examines the versatility of nickel catalysis in reactions like cross-coupling reactions and CH activations -Offers a resource for academics and industry professionals Written for catalytic chemists, organic chemists, inorganic chemists, structural chemists, and chemists in industry, Nickel Catalysis in Organic Synthesis provides a much-needed overview of the most recent developments in modern nickel catalysis and its application in synthesis.

Advances in Organometallic Chemistry

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Publisher : Academic Press
ISBN 13 : 0128155108
Total Pages : 324 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Advances in Organometallic Chemistry by : Pedro J. Perez

Download or read book Advances in Organometallic Chemistry written by Pedro J. Perez and published by Academic Press. This book was released on 2018-10-25 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Organometallic Chemistry, Volume 70, contains authoritative review articles of worldwide known researchers in the field of organometallic chemistry. This longstanding serial is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. Topics of note in this new release include Carbon Dioxide Electroreduction Catalyzed by Organometallic Complexes, Single-electron Elementary Steps in Homogeneous Organometallic Catalysis, Recent advances in catalytic hydrosilylation of carbonyl groups mediated by well-defined first-row late transition metals, and more. - Contains contributions from leading authorities in the field of organometallic chemistry - Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more - Informs and updates readers on the latest developments in the field - Carefully edited to provide easy-to-read material

Fundamentals of Molecular Catalysis

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Author :
Publisher : Elsevier
ISBN 13 : 0080532136
Total Pages : 537 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Fundamentals of Molecular Catalysis by :

Download or read book Fundamentals of Molecular Catalysis written by and published by Elsevier. This book was released on 2003-04-02 with total page 537 pages. Available in PDF, EPUB and Kindle. Book excerpt: Almost all contemporary organic synthesis involve transition metal complexes as catalysts or particular reagents. The aim of this book is to provide the reader with detailed accounts of elementary processes within molecular catalysis to allow its development and as an aid in designing novel catalytic systems. The book comprises authoritative reviews on elementary processes from experts working at the forefront of organometallic chemistry. · This is the first book that focuses on elementary processes in transition metal complexes for understanding catalytic mechanisms· Provides detailed description of elementary processes involved in catalytic cycles by experts in the field· Provides an overview of the mechanisms of various homogeneous catalyses

Computational Advances of Rh-Catalyzed C–H Functionalization

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Author :
Publisher : Springer Nature
ISBN 13 : 9811604320
Total Pages : 132 pages
Book Rating : 4.8/5 (116 download)

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Book Synopsis Computational Advances of Rh-Catalyzed C–H Functionalization by : Yu Lan

Download or read book Computational Advances of Rh-Catalyzed C–H Functionalization written by Yu Lan and published by Springer Nature. This book was released on 2021-02-26 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive overview of recent theoretical studies on rhodium-catalyzed C-H functionalization, a topic that has attracted considerable attention over the years. It includes a brief experimental history, elementary reactions, and theoretical perspectives and describes in detail recent advanced computational studies on different types of Rh-catalyzed C-H functionalization, the underlying mechanisms, and the origin of regioselectivity in a series of such reactions. Providing examples shows readers how to use theoretical tools to solve problems related to mechanisms of organometallic reactions. As such, the book is an interesting and useful resource for a wide readership in various fields involving synthetic organic, organometallic, and catalysis reactions.

Handbook of Reagents for Organic Synthesis

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Publisher : John Wiley & Sons
ISBN 13 : 1118726596
Total Pages : 826 pages
Book Rating : 4.1/5 (187 download)

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Book Synopsis Handbook of Reagents for Organic Synthesis by : André B. Charette

Download or read book Handbook of Reagents for Organic Synthesis written by André B. Charette and published by John Wiley & Sons. This book was released on 2015-09-28 with total page 826 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heteroarenes are among the most prevalent structural units in natural products, pharmaceuticals, agrochemicals, and other compounds of scientific or commercial interest. In the last decade, a broad range of novel synthetic methods has been developed to not only facilitate construction of the heteroarene motif, but to enable its modification through direct C H functionalization. This Handbook describes 117 key reagents for selective heteroarene functionalization reactions, including both traditional and transition metal-catalyzed C H functionalization. Since these reactions typically involve one heteroarene, a coupling partner and a catalyst, the handbook not only focuses on the catalyst itself but also contains other key reaction species. All the information compiled in this volume is also available in electronic format on Wiley Online Library. The 117 reagents represented here are but a small fraction of the ca. 5,000 reagents available in the electronic Encyclopedia of Reagents for Organic Synthesis (e-EROS). e-EROS offers various search interfaces to locate reagents of interest, including chemical structure, substructure and reactions search modes. e-EROS is updated regularly with new and updated entries.

Perhalopyridines: Synthesis and Synthetic Utility

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Publisher : Bentham Science Publishers
ISBN 13 : 9811473773
Total Pages : 256 pages
Book Rating : 4.8/5 (114 download)

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Book Synopsis Perhalopyridines: Synthesis and Synthetic Utility by : Reza Ranjbar-Karimi

Download or read book Perhalopyridines: Synthesis and Synthetic Utility written by Reza Ranjbar-Karimi and published by Bentham Science Publishers. This book was released on 2020-09-08 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: Halogenated pyridines can be used as interesting starting materials in a wide range of organic synthesis methods. Substituted pyridine compounds are used generally as starting materials in the nucleophilic substitution reactions and have unique scaffolds for the construction of other heterocyclic and macrocyclic compounds. They also have important medicinal properties. Due to synthetic difficulties in the synthesis of the highly substituted pyridine derivatives from pyridine itself, perhalopyridines have a special importance in this regard. This book covers the synthetic reactions and applications of perhalopyridines. An introductory chapter introduces the reader to the physical and chemical properties of halopyridines, followed by 3 chapters which focus on pentafluoropyridine, pentachloropyridine and pentabromopyridine, respectively. The focused chapters provide information about synthetic methods and relevant nucleophilic reactions for each of the listed perhalopyridines and their derivatives. The book is a quick reference on perhalopyridines for students of applied chemistry, organic chemistry and chemical engineering.

C-C Bond Activation

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Publisher : Springer
ISBN 13 : 364255055X
Total Pages : 265 pages
Book Rating : 4.6/5 (425 download)

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Book Synopsis C-C Bond Activation by : Guangbin Dong

Download or read book C-C Bond Activation written by Guangbin Dong and published by Springer. This book was released on 2014-09-18 with total page 265 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students

Ruthenium in Organic Synthesis

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Publisher : John Wiley & Sons
ISBN 13 : 3527605797
Total Pages : 398 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Ruthenium in Organic Synthesis by : Shun-Ichi Murahashi

Download or read book Ruthenium in Organic Synthesis written by Shun-Ichi Murahashi and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry. From the contents: Introduction (S.-I. Murahashi) Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori) Oxidations (S.-I. Murahashi and N. Komiya) Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh) Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo) Olefin Metathesis (R. H. Grubbs) Cyclopropanation (H. Nishiyama) Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf) Reactions via C-H Activation (N. Chatani) Lewis Acid Reactions (E. P. Kundig) Reactions with CO and CO2 (T. Mitsudo) Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki) Radical Reactions (H. Nagashima) Bond Cleavage Reactions (S. Komiya)

Purification of Laboratory Chemicals

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Publisher : Butterworth-Heinemann
ISBN 13 : 0123821614
Total Pages : 1025 pages
Book Rating : 4.1/5 (238 download)

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Book Synopsis Purification of Laboratory Chemicals by : W.L.F. Armarego

Download or read book Purification of Laboratory Chemicals written by W.L.F. Armarego and published by Butterworth-Heinemann. This book was released on 2013 with total page 1025 pages. Available in PDF, EPUB and Kindle. Book excerpt: A best seller since 1966, Purification of Laboratory Chemicals keeps engineers, scientists, chemists, biochemists and students up to date with the purification of the chemical reagents with which they work, the processes for their purification, and guides readers on critical safety and hazards for the safe handling of chemicals and processes. The Seventh Edition is fully updated and provides expanded coverage of the latest commercially available chemical products and processing techniques, safety and hazards: over 200 pages of coverage of new commercially available chemicals since the previous edition. The only comprehensive chemical purification reference, a market leader since 1966, Amarego delivers essential information for research and industrial chemists, pharmacists and engineers: '... (it) will be the most commonly used reference book in any chemical or biochemical laboratory' (MDPI Journal) An essential lab practice and proceedures manual. Improves efficiency, results and safety by providing critical information for day-to-day lab and processing work. Improved, clear organization and new indexing delivers accurate, reliable information on processes and techniques of purification along with detailed physical properties The Sixth Edition has been reorganised and is fully indexed by CAS Registry Numbers; compounds are now grouped to make navigation easier; literature references for all substances and techniques have been added; ambiguous alternate names and cross references removed; new chemical products and processing techniques are covered; hazards and safety remain central to the book

Organophosphorus Chemistry

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 3527672265
Total Pages : 802 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Organophosphorus Chemistry by : Viktor Iaroshenko

Download or read book Organophosphorus Chemistry written by Viktor Iaroshenko and published by John Wiley & Sons. This book was released on 2019-01-07 with total page 802 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the gap for an up-to-date reference that presents the field of organophosphorus chemistry in a comprehensive and clearly structured way, this one-stop source covers the chemistry, properties, and applications from life science and medicine. Divided into two parts, the first presents the chemistry of various phosphorus-containing compounds and their synthesis, including ylides, acids, and heterocycles. The second part then goes on to look at applications in life science and bioorganic chemistry. Last but not least, such important practical aspects as 31P-NMR and protecting strategies for these compounds are presented. For organic, bioinorganic, and medicinal chemists, as well as those working on organometallics, and for materials scientists. The book, a contributed work, features a team of renowned scientists from around the world whose expertise spans the many aspects of modern organophosphorus chemistry.