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A Field Scale Test Of In Situ Chemical Oxidation Through Recirculation
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Book Synopsis A Field-scale Test of in Situ Chemical Oxidation Through Recirculation by :
Download or read book A Field-scale Test of in Situ Chemical Oxidation Through Recirculation written by and published by . This book was released on 1998 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt: In situ chemical oxidation is a developing class of remediation technologies in which organic contaminants are degraded in place by powerful oxidants. Successful implementation of this technology requires an effective means for dispersing the oxidant to contaminated regions in the subsurface. An oxidant delivery technique has been developed wherein the treatment solution is made by adding an oxidant to extracted groundwater. The oxidant-laden groundwater is then injected and recirculated into a contaminated aquifer through multiple horizontal and/or vertical wells. This technique, referred to as in situ chemical oxidation through recirculation (ISCOR), can be applied to saturated and hydraulically conductive formations and used with relatively stable oxidants such as potassium permanganate (KMnO4). A field-scale test of ISCOR was conducted at a site (Portsmouth Gaseous Diffusion Plant) where groundwater in a 5-ft thick silty gravel aquifer is contaminated with trichloroethylene (TCE) at levels that indicate the presence of residual dense non-aqueous phase liquids (DNAPLs). The field test was implemented using a pair of parallel horizontal wells with 200-ft screened sections. For approximately one month, groundwater was extracted from one horizontal well, dosed with crystalline KMnO4, and re-injected into the other horizontal well 90 ft away. Post-treatment characterization showed that ISCOR was effective at removing TCE in the saturated region. Lateral and vertical heterogeneities within the treatment zone impacted the uniform delivery of the oxidant solution. However, TCE was not detected in groundwater samples collected from monitoring wells and soil samples from borings in locations where the oxidant had permeated.
Book Synopsis A Full-scale Demonstration of in Situ Chemical Oxidation Through Recirculation at the X-701B Site by :
Download or read book A Full-scale Demonstration of in Situ Chemical Oxidation Through Recirculation at the X-701B Site written by and published by . This book was released on 1997 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1996, researchers at Oak Ridge National Laboratory (ORNL) proposed an oxidant delivery technique involving injection and recirculation of the oxidant solution into a contaminated aquifer through multiple horizontal and vertical wells. This technique would be applicable to saturated, hydraulically conductive formations. In the spring of 1997, the Department of Energy (DOE) at the Portsmouth Gaseous Diffusion Plant (PORTS) agreed to collaborate with the DOE's Subsurface Contaminants Focus Area to conduct a field-scale treatability study using in situ chemical oxidation through recirculation (ISCOR). PORTS agreed to support the demonstration at the X-701B site where the technology can potentially be used to remediate TCE-contaminated groundwater and sediments. The ISCOR field demonstration took advantage of existing infrastructure and extensive site characterization data generated from previous field demonstrations at X-701B. The field test was implemented using a pair of previously installed horizontal wells that transect an area of DNAPL contamination. Groundwater was extracted from one horizontal well, pumped to an existing pump and treat facility, dosed with KMnO4, and re-injected into a parallel horizontal well approximately 90 ft away. The field demonstration lasted approximately one month. Treatment effectiveness was determined by comparing contaminant levels in pre-treatment, during, and post-treatment groundwater samples and pre- and post-treatment soil samples.
Book Synopsis In Situ Chemical Oxidation for Groundwater Remediation by : Robert L. Siegrist
Download or read book In Situ Chemical Oxidation for Groundwater Remediation written by Robert L. Siegrist and published by Springer Science & Business Media. This book was released on 2011-02-25 with total page 715 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides comprehensive up-to-date descriptions of the principles and practices of in situ chemical oxidation (ISCO) for groundwater remediation based on a decade of intensive research, development, and demonstrations, and lessons learned from commercial field applications.
Book Synopsis Principles and Practices of in Situ Chemical Oxidation Using Permanganate by : Robert L. Siegrist
Download or read book Principles and Practices of in Situ Chemical Oxidation Using Permanganate written by Robert L. Siegrist and published by . This book was released on 2001 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt: - Chapter 1: An overview of chemical oxidation including its development and application for in situ treatment of contaminated sites. The oxidation chemistry of Fenton's reagent, permanganate, and ozone are highlighted along with optional methods of oxidant delivery for in situ application. The results of lab-and field-scale applications are summarized.- Chapter 2: A description of the principles and processes of chemical oxidation using potassium or sodium permanganate for organic chemical degradation, including reaction stoichiometry, equilibria, and kinetics, as well as the effects of environmental factors.- Chapter 3: Information provided on the effects of permanganate on the behavior of metals.- Chapter 4: A discussion of the potential for permeability loss and other secondary effects during in situ oxidation using permanganate.- Chapter 5: A description of optional methods of oxidant delivery for in situ remediation.- Chapter 6: A description of a process for evaluation, design, and implementation of permanganate systems.- Chapter 7: A detailed description of five different applications of an in situ chemical oxidation using potassium or sodium permanganate.- Chapter 8: Highlights of the current status and future directions of this remediation technology.
Book Synopsis Field Applications of In Situ Remediation Technologies by :
Download or read book Field Applications of In Situ Remediation Technologies written by and published by . This book was released on 1998 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt: Approximately 85% of the hazardous waste sites in the United States have contaminated ground water. The conventional approach for remediating contaminated ground water has been to extract the contaminated water, treat it above ground, and reinject or discharge the clean water ("pump- and-treat"). The recovered contaminants must be disposed of separately. It is becoming increasingly apparent that pump-and-treat technologies require considerable investment over extended period of time, and often times do not actually clean up the source of the contamination. Current policies and law stress "permanent" remedies over containment. Consequently, there is considerable interest and effort being expended on alternative, innovative treatment technologies for contaminated ground water. This report is one in a series that document recent pilot demonstrations and full-scale applications that either treat soil and ground water in place or increase the solubility and mobility of contaminants to improve their removal by other remediation technologies. It is hoped that this information will allow more regular consideration of new, less costly, and more effective technologies to address the problems associated with hazardous waste sites and petroleum.
Book Synopsis Chlorinated Solvent Source Zone Remediation by : Bernard H. Kueper
Download or read book Chlorinated Solvent Source Zone Remediation written by Bernard H. Kueper and published by Springer Science & Business. This book was released on 2014-04-22 with total page 759 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this book is to help engineers and scientists better understand dense nonaqueous phase liquid (DNAPL) contamination of groundwater and the methods and technology used for characterization and remediation. Remediation of DNAPL source zones is very difficult and controversial and must be based on state-of-the-art knowledge of the behavior (transport and fate) of nonaqueous phase liquids in the subsurface and site specific geology, chemistry and hydrology. This volume is focused on the characterization and remediation of nonaqueous phase chlorinated solvents and it is hoped that mid-level engineers and scientists will find this book helpful in understanding the current state-of-practice of DNAPL source zone management and remediation.
Book Synopsis Groundwater Management in Large River Basins by : Milan Dimkic
Download or read book Groundwater Management in Large River Basins written by Milan Dimkic and published by IWA Publishing. This book was released on 2008-11-15 with total page 721 pages. Available in PDF, EPUB and Kindle. Book excerpt: Part of Groundwater Set - Buy all six books and save over 30% on buying separately! This book reviews the state-of-the-art of groundwater management in large river basins, providing an innovative, informative and consistent approach with technical tools for planners, decision makers and engineers. Groundwater Management in Large River Basins provides comprehensive coverage of the basic elements of groundwater management in large river basins, including: Social, economic and legislative framework, goals, practices and possible tools Review of EU groundwater legislation and its implementation Natural groundwater occurrence and natural circumstances and processes Groundwater management and maintenance issues: Role of natural factors in groundwater management Different methods of groundwater abstraction and protection Groundwater treatment technologies Well ageing and maintenance Nitrate problems, etc. Groundwater modeling as a tool for groundwater assessment Aquifer restoration A spectrum of technical appendices for engineers, which address groundwater issues Also included will be appendices intended to support the work of groundwater engineers. This book will be of interest to groundwater engineers and planners, as well as lecturers and postgraduate and postdoctoral students.
Book Synopsis Proceedings of the International Conference on Decommissioning and Decontamination and on Nuclear and Hazardous Waste Management by :
Download or read book Proceedings of the International Conference on Decommissioning and Decontamination and on Nuclear and Hazardous Waste Management written by and published by . This book was released on 1998 with total page 804 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Abiotic in Situ Technologies for Groundwater Remediation Conference by :
Download or read book Abiotic in Situ Technologies for Groundwater Remediation Conference written by and published by . This book was released on 2000 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Bringing Groundwater Quality Research to the Watershed Scale by : Neil R. Thomson
Download or read book Bringing Groundwater Quality Research to the Watershed Scale written by Neil R. Thomson and published by . This book was released on 2005 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Push-pull Tests to Support in Situ Chemical Oxidation System Design by : Ashley Mathai
Download or read book Push-pull Tests to Support in Situ Chemical Oxidation System Design written by Ashley Mathai and published by . This book was released on 2011 with total page 90 pages. Available in PDF, EPUB and Kindle. Book excerpt: The problems associated with the contamination of groundwater environments by non-aqueous phase liquids (NAPLs) such as chlorinated solvents, gasoline and manufacturing gas plant (MGP) residuals, including their distribution and persistence, are well accepted. The treatment of groundwater by in situ chemical oxidation (ISCO) relies on the oxidation potential of chemical reagents to destroy harmful organic compounds. The interaction of these oxidants with target and non-target compounds in the subsurface will help determine effectiveness and efficiency of an ISCO treatment system. Push-pull tests (PPTs) have the utility to estimate key properties in situ and allow for sampling a larger volume of aquifer to yield more representative estimates as compared to conventional bench-scale tests. The scale and cost-effectiveness of a PPT make it an ideal tool to collect valuable information on subsurface system behaviour so that uncertainties can be minimized. The use of PPTs to provide insight into treatment expectations or to support the design of an ISCO system requires a suitable interpretation tool. A multi-species numerical model ('PPT-ISCO') in a radial coordinate system was developed to simulate a PPT with the injection of a conservative tracer and oxidant (persulfate or permanganate) into the saturated zone of a porous medium environment. The pore space may contain variable amounts of immobile, multicomponent, residual NAPL. The aquifer material contains a natural organic matter (NOM) fraction and/or other oxidizable aquifer material (OAM) species. The model is capable of simulating mass transport for an arbitrary number of conservative and reactive tracers and NAPL constituents subjected to chemical reactions. The ability of PPTs to capture the in situ natural oxidant interaction (NOI) was tested with PPTISCO. Breakthrough curve (BTC) data collected from permanganate and persulfate PPTs conducted in the field were compared to simulated BTCs by assigning the same field operational parameters to the model and applying NOI kinetic information obtained from batch tests. These tests confirmed the usability of the model and PPTs to obtain the NOI kinetics from PPT BTCs. The sensitivity of PPT BTCs to variations in the field operating and NOI parameters were investigated. The results of varying the field operating parameters indicated that the oxidant BTCs could be scaled to match varying injection and extraction flow rates. Variations in NOI parameters revealed that the permanganate BTC is primarily controlled by the permanganate fast reaction rate coefficient and the quantity of OAM present in the aquifer. The spatial profiles of OAM across the test zone revealed that the majority of the OAM consumption is from the fast fraction and occurs in the vicinity of the well where the permanganate concentration is greatest. An estimate of the permanganate fast reaction rate coefficient can be obtained from a permanganate PPT BTC by employing the model to simulate the PPT with the operational parameters (used in the field) and literature estimates of the remaining NOI parameters. Calibration between the simulated and observed BTCs can be undertaken to adjust the permanganate fast reaction rate coefficient to fit the permanganate PPT BTC. Persulfate NOI sensitivity investigations revealed that persulfate PPT BTCs can be characterized by a concentration plateau at early times as a result of the increased ionic strength in the area around the injection well. The ionic strength is primarily controlled by the injected persulfate concentration, and as persulfate degrades into sulphate and acid, the ionic strength is enhanced. Graphical analysis of the BTC revealed that an underestimated value of the persulfate degradation rate coefficient can be obtained from the PPT BTC. A more representative estimate of the persulfate degradation rate coefficient can be achieved after fitting the field BTC to the simulated results, applying the underestimated value as a starting point. PPTs investigating ISCO treatability have the ability to provide insight into the effect of the NOI on the oxidation of target compounds, site-specific oxidant dosage requirements and NAPL treatment expectations. NAPL component BTCs from treatability PPTs are primarily controlled by the mass in the fast region, and the fast region mass transfer rate coefficient. Oxidation estimates extracted from NAPL component BTCs were shown to accurately approximate the mass of each NAPL component oxidized when compared to model calculations. The mass of NAPL oxidized for each of the components yields a site-specific oxidant dosage. This estimate exceeds what is prescribed by the stoichiometry between permanganate and the contaminant of concern due to the effect of the NOI. The utility of PPTs to study and quantify the interaction between injected oxidants and the aquifer material has been demonstrated with PPT-ISCO. In addition, PPT-ISCO has revealed that treatability PPTs can be tailored to investigate the dosage requirements and treatment expectations of residual NAPLs. Results from this effort will be used to support ongoing field research exploring the use of PPTs to assist in understanding the competing subsurface processes affecting ISCO applications.
Book Synopsis Laboratory Evaluation of In Situ Chemical Oxidation for Groundwater Remediation, Test Area North, Operable Unit 1-07B, Idaho National Engineering and Environmental Laboratory, Volume Two, Appendices C, D, and E. by :
Download or read book Laboratory Evaluation of In Situ Chemical Oxidation for Groundwater Remediation, Test Area North, Operable Unit 1-07B, Idaho National Engineering and Environmental Laboratory, Volume Two, Appendices C, D, and E. written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: These appendices support the results and discussion of the laboratory work performed to evaluate the feasibility of in situ chemical oxidation for Idaho National Environmental and Engineering Laboratory's (INEEL) Test Area North (TAN) which is contained in ORNL/TM-1371 l/Vol. This volume contains Appendices C-E. Appendix C is a compilation of all recorded data and mathematical calculations made to interpret the data. For the Task 3 and Task 4 work, the spreadsheet column definitions are included immediately before the actual spreadsheet pages and are listed as ''Sample Calculations/Column Definitions'' in the table of contents. Appendix D includes the chronological order in which the experiments were conducted and the final project costs through October 1998. Appendix E is a compilation of the monthly progress reports submitted to INEEL during the course of the project.
Book Synopsis Performance of in Situ Chemical Oxidation Field Demonstrations at DOE Sites by :
Download or read book Performance of in Situ Chemical Oxidation Field Demonstrations at DOE Sites written by and published by . This book was released on 1997 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: Researchers at the Oak Ridge National Laboratory (ORNL) have been investigating the use of in situ chemical oxidation to remediate organic contaminants (VOCs, SVOCs, and PCBs) in soils and groundwater at the laboratory and field scales. Field scale design parameters (e.g., oxidant loading rates and oxidant delivery techniques) are often dictated by site conditions (e.g., soil properties and initial contaminant concentrations). Chemical destruction of organic compounds can be accomplished using a variety of oxidants. Recent research has involved field scale in situ chemical oxidation demonstrations using H2O2 and KMnO4 in conjunction with soil mixing as the oxidant delivery mechanism. A description of some of these fields activities and future field-scale work is presented here.
Book Synopsis Laboratory Evaluation of In Situ Chemical Oxidation for Groundwater Remediation, Test Area North, Operable Unit 1-07B, Idaho National Engineering and Environmental Laboratory, Volume One - Main Text and Appendices A and B. by :
Download or read book Laboratory Evaluation of In Situ Chemical Oxidation for Groundwater Remediation, Test Area North, Operable Unit 1-07B, Idaho National Engineering and Environmental Laboratory, Volume One - Main Text and Appendices A and B. written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The laboratory investigation was performed to evaluate the feasibility of utilizing in situ chemical oxidation for remediating the secondary source of groundwater contaminants at the Idaho National Engineering and Environmental Laboratory (INEEL) Test Area North (TAN) Site. The study involved trichloroethene (TCE) contaminated media (groundwater, soil, and sludge) from TAN. The effectiveness of the selected oxidant, potassium permanganate (KMn0(sub4)), was evaluated at multiple oxidant and contaminant concentrations. Experiments were performed to determine the oxidant demand of each medium and the rate of TCE oxidation. The experiments were performed under highly controlled conditions (gas-tight reactors, constant 12C temperature). Multiple parameter were monitored over time including MN0(sub 4) and TCE concentrations and pH.
Book Synopsis Vadose Zone Science and Technology Solutions by : Brian B. Looney
Download or read book Vadose Zone Science and Technology Solutions written by Brian B. Looney and published by . This book was released on 2000 with total page 982 pages. Available in PDF, EPUB and Kindle. Book excerpt: CD contains the entire text of the book plus additional case studies.
Book Synopsis Laboratory Evaluation of In Situ Chemical Oxidation for Groundwater Remediation, Test Area North, Operable Unit 1-07B, Idaho National Engineering and Environmental Laboratory, Volume Four - Appendix G. by :
Download or read book Laboratory Evaluation of In Situ Chemical Oxidation for Groundwater Remediation, Test Area North, Operable Unit 1-07B, Idaho National Engineering and Environmental Laboratory, Volume Four - Appendix G. written by and published by . This book was released on 1999 with total page 175 pages. Available in PDF, EPUB and Kindle. Book excerpt: This appendix supports the results and discussion of the laboratory work performed to evaluate the feasibility of in situ chemical oxidation for Idaho National Environmental and Engineering Laboratory's (INEEL) Test Area North (TAN) which is contained in ORNL/TM-13711/V1. This volume contains Appendix G. Appendix G is a presentation of VOC chromatography data collected during the study. Information on the calibration curves and calibration checks used as well as the sample GC reports themselves are included here. The concentration values presented on the GC reports are calculation using the data from the applicable calibration curve and any necessary dilutions which were made.
Book Synopsis Laboratory Evaluation of In Situ Chemical Oxidation for Groundwater Remediation, Test Area North, Operable Unit 1-07B, Idaho National Engineering and Environmental Laboratory, Volume Three - Appendix F. by :
Download or read book Laboratory Evaluation of In Situ Chemical Oxidation for Groundwater Remediation, Test Area North, Operable Unit 1-07B, Idaho National Engineering and Environmental Laboratory, Volume Three - Appendix F. written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This appendix supports the results and discussion of the laboratory work performed to evaluate the feasibility of in situ chemical oxidation for Idaho National Environmental and Engineering Laboratory's (INEEL) Test Area North (TAN) which is contained in ORNL/TM-13711/V1. This volume contains Appendix F. Appendix F is essentially a photocopy of the ORNL researchers' laboratory notebooks from the Environmental Sciences Division (ESD) and the Radioactive Materials Analytical Laboratory (RMAL).
